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    • 73. 发明授权
    • Weather-resistant epoxy resin system
    • 耐候环氧树脂系统
    • US08436079B2
    • 2013-05-07
    • US12094422
    • 2006-10-26
    • Christian Beisele
    • Christian Beisele
    • C08G59/34C08G59/18C08G59/20C08L63/00B32B27/18B32B27/38B32B33/00
    • C08K5/3435Y10T428/31511C08L63/00
    • A curable epoxy resin composition of an epoxy resin (a) and a combination (b) of an antioxidant (b1) and a UV absorber (b2). The UV absorber (b2) is a benzotriazole. The antioxidant (b1) is a compound of general formula I: wherein: R1=—H, —OH, —O—C1-18 alkyl, —C1-18 alkyl, —C5-12 cycloalkyl being unsubstituted or being substituted with C1-6 alkyl or C1-6 alkoxy, or —CH2—C5-12 cycloalkyl being unsubstituted or being substituted with C1-6 alkyl or C1-6 alkoxy; R2,3,4,5=independent from each other —C1-6 alkyl; and R6=a bivalent aliphatic, cycloaliphatic or aromatic residue. The weight ratio of (a) to (b) is from 90.0:10.0 to 98.5:1.5, with the proviso that the weight portion of (b1) is at least 0.5. The cured product has very good weather resistance after curing by polyaddition with a polycarboxylic acid anhydride or by homopolymerization. The cured product is suitable as an electrical insulation material.
    • 环氧树脂(a)和抗氧化剂(b1)和紫外线吸收剂(b2)的组合(b))的可固化环氧树脂组合物。 紫外线吸收剂(b2)是苯并三唑。 抗氧化剂(b1)是通式I的化合物:其中:R1 = -H,-OH,-O-C1-18烷基,-C1-18烷基,-C5-12环烷基是未取代的或被C1- 6烷基或C 1-6烷氧基,或未被取代或被C 1-6烷基或C 1-6烷氧基取代的-CH 2 -C 5-12环烷基; R2,3,4,5 =彼此独立地-C 1-6烷基; 并且R6 =二价脂族,脂环族或芳族残基。 (a)至(b)的重量比为90.0:108至98.5:1.5,条件是(b1)的重量份至少为0.5。 固化产物通过用聚羧酸酐加聚固化或通过均聚固化后具有非常好的耐候性。 固化产品适合作为电绝缘材料。
    • 75. 发明授权
    • Rotomolding process for polyethylene articles
    • 聚乙烯制品的滚塑工艺
    • US08357324B2
    • 2013-01-22
    • US12762847
    • 2010-04-19
    • Jiong YuJohn SiglerEric Wallis
    • Jiong YuJohn SiglerEric Wallis
    • B28B1/02
    • B29C41/06B29K2023/06B29K2023/0641C08K5/3435C08L23/04
    • The present invention relates to a process for the production of polyethylene hollow articles, which process comprises charging the polyethylene with one or more NO-acyl hindered amine additives containing one or more groups of formula (I), filling this mixture into a mold, heating this mold in an oven to above 280° C., such that the additized polyethylene melts, rotating the mold around at least 2 axes, the additized polyethylene spreading to the walls, cooling the mold while still rotating, opening it, and taking the resultant hollow article out, where the group of formula (I) is where Ra is a monoacyl or diacyl radical; R1-R4 are each C1-C6alkyl; and R5 and R6 are each, independently of one another, hydrogen, C1-C6alkyl or C6-C10aryl; or R5 and R6 are together oxygen.
    • 本发明涉及一种生产聚乙烯中空制品的方法,该方法包括将聚乙烯与一种或多种含有一个或多个式(I)基团的NO-酰基受阻胺添加剂进行加入,将该混合物填充到模具中,加热 该模具在烘箱中高于280℃,使得加入的聚乙烯熔融,将模具绕至少2个轴线旋转,将加入的聚乙烯铺展到壁上,同时在旋转的同时冷却模具,将其打开并取出 中空制品,其中式(I)的基团是其中R a是单酰基或二酰基; R 1 -R 4各自为C 1 -C 6烷基; R 5和R 6各自独立地为氢,C 1 -C 6烷基或C 6 -C 10芳基; 或R 5和R 6一起为氧。
    • 76. 发明授权
    • Piping member formed by using propylene-based resin composition
    • 使用丙烯类树脂组合物形成的管件
    • US08344050B2
    • 2013-01-01
    • US12523238
    • 2008-02-01
    • Takanori InoueHidehiro Kourogi
    • Takanori InoueHidehiro Kourogi
    • C08K5/34B29D23/00
    • C08L23/142C08K5/005C08K5/3435C08L9/06C08L53/02C08L53/025Y10T428/139C08L2666/08C08L2666/24C08L2666/02C08L2666/04
    • Disclosed are a piping member formed by using a propylene-based resin composition comprising 100 parts by mass of a propylene-ethylene random copolymer (A) having an ethylene content of 2 to 5%, a crystallization temperature of 86 to 105° C., a melt flow rate of 0.01 to 2.00 g/10 min and a molecular weight distribution of 3 to 8, and 1 to 15 parts by mass of a styrene-butadiene-base rubber (B) having a styrene content of 10 to 40% and a weight average molecular weight of 200,000 or more as essential components, a melt flow rate after kneading being from 0.01 to 2.00 g/10 min, characterized in that the propylene-based resin composition further comprising a hindered amine-based light stabilizer (C) having a weight average molecular weight of 2,000 or more in the amount of 0.1 to 1.0 parts by mass based on 100 parts by mass of the propylene-ethylene random copolymer; and a piping member formed by using a propylene-based resin composition, wherein the styrene-butadiene-base rubber is a hydrogenated styrene-butadiene block copolymer rubber.
    • 公开了一种通过使用丙烯类树脂组合物形成的配管构件,其包含100质量份乙烯含量为2〜5%,结晶温度为86〜105℃的丙烯 - 乙烯无规共聚物(A) 熔体流动速率为0.01〜2.00g / 10分钟,分子量分布为3〜8,1〜15质量份苯乙烯含量为10〜40%的苯乙烯 - 丁二烯类橡胶(B)和 重均分子量为20万以上作为必要成分,捏合后的熔体流动速率为0.01〜2.00g / 10分钟,其特征在于,进一步含有受阻胺类光稳定剂(C)的丙烯类树脂组合物, 相对于丙烯 - 乙烯无规共聚物100质量份,其重量平均分子量为2,000以上,为0.1〜1.0质量份。 以及通过使用丙烯类树脂组合物形成的配管构件,其中所述苯乙烯 - 丁二烯基橡胶是氢化苯乙烯 - 丁二烯嵌段共聚物橡胶。
    • 77. 发明申请
    • THERMOPLASTIC RESIN FOAM AND PROCESS FOR PRODUCING THE SAME
    • 热塑性树脂泡沫及其制造方法
    • US20120302655A1
    • 2012-11-29
    • US13577179
    • 2011-01-18
    • Mitsuhiro KanadaTakayuki YamamotoYoshinori KounoHironori Yasuda
    • Mitsuhiro KanadaTakayuki YamamotoYoshinori KounoHironori Yasuda
    • C08F20/06B29C44/02
    • C08J9/122C08J9/0023C08J9/0028C08J2203/08C08J2333/08C08J2333/20C08K5/0025C08K5/13C08K5/3435
    • There is provided a thermoplastic resin foam being excellent in strength, flexibility, cushioning properties, strain recovery and the like, particularly being low in the shrinkage of the cell structure due to the resilience of the resin, and being good in productivity. There is also provided a process for producing a thermoplastic resin foam which can produce, with good productivity, the thermoplastic resin foam being excellent in strength, flexibility, cushioning properties, strain recovery and the like, particularly being low in the shrinkage of the cell structure due to the resilience of the resin. The thermoplastic resin foam according to the present invention is obtained from a thermoplastic resin composition containing a thermoplastic elastomer, an active energy-ray curable compound and a radical trapping agent. The thermoplastic resin foam according to the present invention is also obtained from a thermoplastic resin composition containing a thermoplastic elastomer, an active energy-ray curable compound, a thermal crosslinking agent and a radical trapping agent.
    • 提供了强度,柔韧性,缓冲性,应变恢复等优异的热塑性树脂发泡体,特别是由于树脂的弹性而导致的电池结构的收缩率低,生产率高。 还提供了一种热塑性树脂发泡体的制造方法,其能够以良好的生产率制造强度,柔软性,缓冲性,应变恢复等优异的热塑性树脂发泡体,特别是电池结构的收缩率低 由于树脂的弹性。 本发明的热塑性树脂发泡体由含有热塑性弹性体,活性能量射线固化性化合物和自由基捕捉剂的热塑性树脂组合物得到。 本发明的热塑性树脂发泡体也可以由含有热塑性弹性体,活性能量射线固化性化合物,热交联剂,自由基捕捉剂的热塑性树脂组合物得到。
    • 79. 发明授权
    • Polylactic acid resin composition
    • 聚乳酸树脂组合物
    • US08293824B2
    • 2012-10-23
    • US12919784
    • 2009-02-16
    • Yoshinori NegishiShigeo Mizokawa
    • Yoshinori NegishiShigeo Mizokawa
    • C08K5/34
    • C08K5/3435C08L101/16C08L67/04
    • Provided are a polylactic acid resin composition which has a superior weatherability while inhibiting crystallization, and a resin molded article using this polylactic acid resin composition.The polylactic acid resin composition according to the present invention is a polylactic acid resin composition in which a hindered amine compound having a partial structure represented by the following General Formula (1): (wherein, R1, R2, R3 and R4 each independently represents a C1 to C4 alkyl group; and R represents a C1 to C18 alkyl group, C1 to C18 acyl group or C5 to C8 cycloalkyl group, which is optionally substituted with a hydroxyl group) is blended at an amount of 0.005 to 30 parts by mass with respect to 100 parts by mass of polylactic acid resin. The resin molded article according to the present invention is obtained by molding this polylactic acid resin composition.
    • 提供一种具有优异的耐候性同时抑制结晶的聚乳酸树脂组合物和使用该聚乳酸树脂组合物的树脂模塑制品。 本发明的聚乳酸树脂组合物是具有以下通式(1)表示的部分结构的受阻胺化合物的聚乳酸树脂组合物:(其中,R1,R2,R3和R4各自独立地表示 C1〜C4烷基; R表示C1〜C18烷基,C1〜C18酰基或任选被羟基取代的C5〜C8环烷基)以0.005〜30质量份的量配合,与 相对于100质量份的聚乳酸树脂。 通过将该聚乳酸树脂组合物成型而得到本发明的树脂成形品。