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71. 发明申请

US20020183558A1 Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and alpha, beta-unsaturated carboxylic acid and aldehyde compounds 失效
标题翻译：醛，酮，肟，胺，异羟肟酸和α，β-不饱和羧酸和醛化合物的固相合成方法
公开(公告)号：US20020183558A1
公开(公告)日：2002-12-05
申请号：US10107771
申请日：2002-03-27
发明人： Joseph M. Salvino , George C. Morton , Helen J. Mason , Richard F. Labaudiniere
IPC分类号： C07C045/00
CPC分类号： C07D307/33 , C07B2200/11 , C07C45/004 , C07C45/41 , C07C45/45 , C07C45/516 , C07C209/00 , C07C209/40 , C07C209/42 , C07C209/66 , C07C239/08 , C07C259/06 , C07C259/08 , C07C259/10 , C07C315/04 , C07D311/68 , C07D311/82 , C07D313/12 , C08F8/10 , C08F8/12 , C08F8/18 , C08F8/30 , C08F8/34 , C08F2800/20 , C08F2810/30 , C07C49/807 , C07C49/213 , C07C47/55 , C07C47/228 , C07C47/23 , C07C47/277 , C07C317/44 , C08F212/08 , C08F8/02 , C08F8/00
摘要： This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and (null,null-unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor.
摘要翻译：本发明涉及一种固相合成醛，酮，肟，胺，异羟肟酸和（α，β-不饱和羧酸和醛化合物）以及用于其的聚合羟胺树脂化合物的方法。

72. 发明授权

US06306959B1 Rapid purification by polymer supported quench 失效
标题翻译：通过聚合物快速纯化支持淬火
公开(公告)号：US06306959B1
公开(公告)日：2001-10-23
申请号：US09171258
申请日：1998-10-15
申请人： Gary L. Bolton , Richard J. Booth , Mark W. Creswell , John C. Hodges , Joseph S. Warmus , Michael W. Wilson
发明人： Gary L. Bolton , Richard J. Booth , Mark W. Creswell , John C. Hodges , Joseph S. Warmus , Michael W. Wilson
IPC分类号： C08G6348
CPC分类号： C07D295/215 , B01J20/265 , C07B2200/11 , C07C231/24 , C07C273/189 , C08F8/00 , C08F8/10 , C08F8/26 , C08F8/30 , C08F8/32 , C08F8/34 , C08F8/36 , C08F8/42 , C08F8/48 , C08F2810/20 , C08G85/00 , C40B40/04 , C40B50/08 , C40B99/00 , Y10S530/81 , Y10S530/815 , Y10S530/816 , Y10S530/817 , C08F212/08
摘要： Novel polymer-supported quenching reagents of Formula (I): P-L-Q, wherein P is a polymer of low chemical reactivity which is soluble or insoluble; Q is one or more quenching reagents, or an acid or base addition salts thereof, that are capable of selective covalent reaction with unwanted byproducts, or excess reagents; and L is one or more chemically robust linkers that join P and Q; are described, as well as methods for their preparation and methods for their use in the rapid purification of synthetic intermediates and products in organic synthesis, combinatorial chemistry and automated organic synthesis.
摘要翻译：式（I）的新型聚合物支持的猝灭试剂：P-L-Q，其中P是可溶或不溶性的化学反应性低的聚合物; Q是能够与不想要的副产物或过量试剂选择性共价反应的一种或多种猝灭试剂或其酸或碱加成盐; L是连接P和Q的一个或多个化学稳定的接头; 以及其制备方法及其用于快速纯化有机合成，组合化学和自动化有机合成中的合成中间体和产物的方法。

73. 发明授权

US5717039A Functionalization of polymers based on Koch chemistry and derivatives thereof 失效
标题翻译：基于Koch化学及其衍生物的聚合物的功能化
公开(公告)号：US5717039A
公开(公告)日：1998-02-10
申请号：US470883
申请日：1995-06-06
申请人： Joseph Victor Cusumano , William Daniel Diana , Jacob Emert , Keith Raymond Gorda , Richard H. Schlosberg , David A. Young , Albert I. Yezrielev , William Bernard Eckstrom , Edris Eileen Manry , Michael John Keenan
发明人： Joseph Victor Cusumano , William Daniel Diana , Jacob Emert , Keith Raymond Gorda , Richard H. Schlosberg , David A. Young , Albert I. Yezrielev , William Bernard Eckstrom , Edris Eileen Manry , Michael John Keenan
IPC分类号： C10M159/12 , B01J10/00 , B01J19/24 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/32 , C08F8/34 , C08L23/26 , C08L101/00 , C08L101/06 , C10L1/14 , C10L1/18 , C10L1/195 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , C10M159/18 , C10N20/04 , C10N30/04
CPC分类号： C10M159/18 , B01J19/2415 , B01J19/242 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/14 , C08F8/18 , C08F8/32 , C08F8/34 , C10L1/143 , C10L1/1817 , C10L1/195 , C10L1/198 , C10L1/206 , C10L1/221 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/2475 , C10L1/2493 , C10L1/2691 , C10L1/285 , C10L1/303 , C10L10/04 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , B01J2219/00094 , C08F2800/20 , C10L1/208 , C10L1/2387 , C10L1/2683 , C10L1/30 , C10M2207/023 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/289 , C10M2209/00 , C10M2209/02 , C10M2209/082 , C10M2209/10 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/22 , C10M2215/221 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/024 , C10M2217/046 , C10M2217/06 , C10M2219/062 , C10M2227/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/05 , C10N2210/06 , C10N2210/07 , C10N2210/08 , C10N2240/00 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/40 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2270/02
摘要： A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.
摘要翻译：作为至少一种数均分子量为至少500且每个聚合物链至少烯属双键的聚合物与一氧化碳和亲核捕集剂的反应产物的Koch官能化产物。本发明包括官能化聚合物，其衍生物及其制备方法。

74. 发明授权

US5597871A Comb polymers 失效
标题翻译：梳子聚合物
公开(公告)号：US5597871A
公开(公告)日：1997-01-28
申请号：US523518
申请日：1995-09-01
申请人： Clemens Auschra , Juergen Omeis , Horst Pennewiss
发明人： Clemens Auschra , Juergen Omeis , Horst Pennewiss
IPC分类号： C08F8/00 , C08F8/10 , C08F290/00 , C08F290/04 , C08F299/00
CPC分类号： C08F290/042 , C08F8/10
摘要： The present invention relates to comb polymers KP, produced from macromonomers of formula (I) ##STR1## where X represents a group which comes from the initiator system, preferably an alkyl group with 1-50 C atoms; R1 represents an alkyl group with 1-18 C atoms, preferably 1-10 C atoms, particularly preferably 1-4 C atoms; R2 and R3 each represent an alkyl group with 1-8 C atoms; and B represents a terminal alkene group with at least 2 and not more than 12 C atoms; wherewith the compound of formula (I) is converted, by means which are per se known, to a compound of formula (II) which contains an active hydrogen substituent in the terminal position: ##STR2## where X, R1, R2, a, b, and c are as defined above, and a represents the group B modified by introduction of the active hydrogen function; wherewith the compound of formula (II) in turn is acylated to a macromonomer of formula (IV) by a reagent MR which introduces the (meth)acryloyl group: ##STR3## where X, R1, R2, R3, A, a, b, and c are as defined above, and R4 represents hydrogen or methyl; and the macromonomers of formula (IV) thus obtained are converted to the comb polymers KP by radical polymerization with monomers M chosen from the group comprised of: (meth)acrylic acids of C.sub.1 -C.sub.28 -alkanols, functionalized radically polymerizable monomers, vinyl esters of fatty acids and vinylaromatic monomers.
摘要翻译：本发明涉及由式（I）的大分子单体（I）制备的梳状聚合物KP，其中X代表来自引发剂体系的基团，优选具有1-50个C原子的烷基; R1表示具有1-18个C原子，优选1-10个C原子，特别优选1-4 C原子的烷基; R2和R3各自表示具有1-8个C原子的烷基; B表示具有至少2个且不超过12个C原子的末端烯烃基; 通过本身已知的方法将式（I）化合物转化为在末端位置含有活性氢取代基的式（II）化合物：其中X，R 1，R 2 ，a，b和c如上所定义，a表示通过引入活性氢官能团而改性的基团B; （II）化合物又通过引入（甲基）丙烯酰基的试剂MR酰化成式（IV）的大分子单体：其中X，R 1，R 2，R 3，A， a，b和c如上定义，R 4表示氢或甲基; 并且由此获得的式（Ⅳ）的大分子单体通过与单体M的自由基聚合转化为梳状聚合物KP，所述单体M选自：C 1 -C 28 - 链烷醇的（甲基）丙烯酸，官能化的可自由基聚合的单体，脂肪酸和乙烯基芳族单体。

75. 发明授权

US5576390A Polyisobutylenes having aspartic acid ester terminal groups 失效
标题翻译：具有天冬氨酸酯端基的聚异丁烯
公开(公告)号：US5576390A
公开(公告)日：1996-11-19
申请号：US488654
申请日：1995-06-08
申请人： Burkhard Kohler , Wolfgang Ebert , Klaus Horn , Richard Weider , Thomas Scholl
发明人： Burkhard Kohler , Wolfgang Ebert , Klaus Horn , Richard Weider , Thomas Scholl
IPC分类号： C08F8/00 , C08F8/46 , C08G64/18 , C08G81/02 , C08L69/00 , C08F8/32
CPC分类号： C08G81/027 , C08F8/10 , C08G64/18 , C08L69/00 , C08F2810/40
摘要： The present invention provides telechelic polyisobutylenes having aspartic acid ester terminal groups, the production thereof and the use thereof as modifiers preferably for thermoplastic aromatic polycarbonates, and the mixing thereof with reaction-less polyisobutylenes.
摘要翻译：本发明提供具有天冬氨酸酯端基的遥爪聚异丁烯，其制备方法及其作为改性剂的用途，优选用于热塑性芳族聚碳酸酯，以及与无反应聚异丁烯的混合。

76. 发明授权

US5272215A Modified plastic elastomer block copolymers 失效
标题翻译：改性塑料弹性体嵌段共聚物
公开(公告)号：US5272215A
公开(公告)日：1993-12-21
申请号：US639916
申请日：1991-01-10
申请人： H. James Harwood , Allan S. Jones , Malcolm A. Smook
发明人： H. James Harwood , Allan S. Jones , Malcolm A. Smook
IPC分类号： C08F8/00 , C08F8/10 , C08F297/04 , C08F297/08 , C08F293/00
CPC分类号： C08F8/10 , C08F8/00
摘要： A thermoplastic elastomeric block copolymer comprising olefin elastomeric mid block units and terminal polystyrene units having substitution in an amount sufficient to raise the glass transition temperature of the polymer. The substitution comprises cycloaliphatic or aromatic acylation and the acylation substitution is accomplished by reaction of an acylhalide with the copolymer in the presence of a catalytic amount of triflic acid.
摘要翻译：一种包含烯烃弹性体中间嵌段单元和末端聚苯乙烯单元的热塑性弹性体嵌段共聚物，其具有足以提高聚合物的玻璃化转变温度的量的取代。该取代包括脂环族或芳族酰化，并且酰化取代通过酰基卤与共聚物在催化量的三氟甲酸的存在下反应来完成。

77. 发明授权

US5128418A Polymerization of cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadiene and other substituted cyclohexadienes 失效
标题翻译：顺式-5,6-二（三甲基甲硅烷氧基）-1,3-环己二烯和其它取代的环己二烯的聚合
公开(公告)号：US5128418A
公开(公告)日：1992-07-07
申请号：US647576
申请日：1991-01-29
申请人： Robert H. Grubbs , Douglas L. Gin , Vincent P. Conticello , Philip D. Hampton , David R. Wheeler
发明人： Robert H. Grubbs , Douglas L. Gin , Vincent P. Conticello , Philip D. Hampton , David R. Wheeler
IPC分类号： C08F8/10 , C08F8/12 , C08G61/10
CPC分类号： C08F8/10 , C08F8/12 , C08G61/10
摘要： The monomer cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadiene can be polymerized with certain catalysts, such as bis(allyltrifluoroacetato nickel (II) and bis(allylpentafluorophenoxy nickel II). The resulting polymer is a precursor to poly(para-phenylene). Other substituted cyclohexadienes may also be polymerized by these catalysts to form useful polymers.
摘要翻译：单体顺式-5,6-双（三甲基甲硅烷氧基）-1,3-环己二烯可以与某些催化剂如双（烯丙基三氟乙酰基镍（II）和双（烯丙基五氟苯氧基镍II））聚合，得到的聚合物是聚（对亚苯基），其它取代的环己二烯也可以通过这些催化剂聚合形成有用的聚合物。

78. 发明授权

US4228152A Polymers containing prostaglandin radicals, process for their preparation and use thereof 失效
标题翻译：含有前列腺素自由基的聚合物，其制备方法和用途
公开(公告)号：US4228152A
公开(公告)日：1980-10-14
申请号：US960665
申请日：1978-11-14
申请人： Paolo Ferruti , Rodolfo Paoletti
发明人： Paolo Ferruti , Rodolfo Paoletti
IPC分类号： A61K31/19 , A61K31/557 , A61K31/5575 , A61K47/48 , C07C67/00 , C07C401/00 , C07C405/00 , C07D249/18 , C08F8/00 , C08F8/10 , C08F8/14 , C08F8/30 , C08G81/02 , A61K31/78
CPC分类号： C08F8/14 , A61K47/48176 , C08F8/10 , C08F8/30 , C08G81/02
摘要： There are disclosed non-toxic polymers having a molecular weight between 1,000 and 1,500,000 and containing prostaglandin radicals directly connected or connected through an oxyalkylenic, aminoalkylenic, or oxyaminoalkylenic chain to a polyacrylic or polymethacrylic backbone. Upon entry of the polymer into the body, the prostaglandin radicals are hydrolyzed causing free prostaglandins to be released in the body. Methods for making the non-toxic polymers and therapeutic compositions containing the non-toxic polymers are also disclosed.
摘要翻译：公开了分子量在1,000至1,500,000之间的无毒聚合物，并且含有通过氧亚烷基，氨基亚烷基或氧氨基亚烷基链直接连接或连接到聚丙烯酸或聚甲基丙烯酸骨架上的前列腺素基团。当聚合物进入体内时，前列腺素自由基被水解，导致游离的前列腺素释放到体内。还公开了制备无毒聚合物的方法和含有无毒聚合物的治疗组合物。

79. 发明授权

US4076913A Solid or gel polymers containing a plurality of free hydrazone groups 失效
标题翻译：含有多个游离腙基团的固体或凝胶聚合物
公开(公告)号：US4076913A
公开(公告)日：1978-02-28
申请号：US726784
申请日：1976-09-27
申请人： Derek Walker , Philip Howard Chapman
发明人： Derek Walker , Philip Howard Chapman
IPC分类号： C08F8/06 , C08G61/02 , C08G85/00 , C08F236/00 , C08C19/12 , C08F210/00 , C08G2/00
CPC分类号： C08G61/02 , C08F8/06 , C08F8/10 , C08F8/20 , C08F8/26 , C08F8/30 , C08F8/32 , C08G85/00 , C08G85/004 , C08F2810/20
摘要： Novel polymers are provided which carry diazomethylene or hydrazonomethylene groups. Such polymers are of special use in immobilizing carboxylic acids, such as amino acids, with a view to subsequent chemical transformation of such acids, e.g. peptide synthesis. Alcohols and thiols may also be immobilized using the new polymers. Methods for the preparation of the polymers are provided, starting from a variety of polymer types.
摘要翻译：提供了携带重氮亚甲基或亚肼基亚甲基的新型聚合物。这样的聚合物特别用于固定羧酸，例如氨基酸，以期随后化学转化这些酸，例如氨基酸。肽合成。也可以使用新的聚合物固定醇和硫醇。提供了从各种聚合物类型开始制备聚合物的方法。

80. 发明授权

US4025580A Modified styrenepolymers 失效
标题翻译：改性苯乙烯聚合物
公开(公告)号：US4025580A
公开(公告)日：1977-05-24
申请号：US315798
申请日：1972-12-18
申请人： Lynn J. Taylor
发明人： Lynn J. Taylor
IPC分类号： C08F8/10 , C08F8/50 , C08L25/18
CPC分类号： C08F8/10 , C08F8/50 , Y10S260/43
摘要： There is disclosed a process for preparing chemically modified styrene polymers and copolymers which comprises treating a polystyrene or a styrene copolymer with an acyl halide in the presence of a Lewis acid so as to introduce ketone groups into the treated polymer or copolymer in an amount sufficient to promote environmental photodegradation of the treated polymer or copolymer. The resulting modified polymers may be used as degradable packaging materials, or as additives to promote the environmental degradation of polystyrene and related materials.
摘要翻译：公开了一种制备化学改性苯乙烯聚合物和共聚物的方法，其包括在路易斯酸存在下用酰卤处理聚苯乙烯或苯乙烯共聚物，以便将酮基引入经处理的聚合物或共聚物中，其量足以促进经处理的聚合物或共聚物的环境光降解。所得改性聚合物可用作可降解包装材料，或用作促进聚苯乙烯和相关材料的环境降解的添加剂。

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