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    • 80. 发明授权
    • Intrachain charge transfer complexes
    • 室内电荷转移络合物
    • US4013623A
    • 1977-03-22
    • US596532
    • 1975-07-16
    • Sam R. TurnerMilan Stolka
    • Sam R. TurnerMilan Stolka
    • C08F20/30C08F220/12G03G5/07C08F220/10C08F220/26
    • C08F20/30C08F220/12G03G5/071Y10S430/10
    • Method for achieving free radical initiated copolymerization of an addition monomer having pendant therefrom a strong donor group with an addition monomer having pendant therefrom a strong acceptor group. Copolymers prepared according to this method can be represented by the following formula: ##STR1## wherein R is hydrogen or methyl;R' is hydrogen or methyl;R" is hydrogen or methyl;R'" is alkyl of 1-10 carbon atoms;R'.sup.v is selected from the group consisting of --NO.sub.2, halogen, --CN and --CF.sub.3 ;X and Y are independently selected from the group consisting of hydrogen, chlorine, bromine, alkyl or 1-4 carbon atoms and phenyl;Z is oxygen or dicyanomethylene;a and b can range from 0-4; andn and m can range from about 5 to about 95 percent.The polymeric compositions prepared according to this method are suitable for use in electrophotography either alone as the primary photoresponsive entity or in combination with other photoconductive materials.
    • 用于实现自由基引发共聚合的方法,其具有从其侧向的强供体基团的加成单体与其上具有强受体基团的加成单体。 根据该方法制备的共聚物可以由下式表示:其中R是氢或甲基; R'是氢或甲基; R“是氢或甲基; R“是1-10个碳原子的烷基; R'v选自-NO 2,卤素,-CN和-CF 3; X和Y独立地选自氢,氯,溴,烷基或1-4个碳原子和苯基; Z是氧或二氰基亚甲基; A和B可以从0-4开始; 而且N和M可以从约5到95%的范围。