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    • 76. 发明申请
    • SYNTHESIS OF MSE-FRAMEWORK TYPE MOLECULAR SIEVES
    • MSE-FRAMEWORK型分子筛的合成
    • US20150087841A1
    • 2015-03-26
    • US14541777
    • 2014-11-14
    • Simon C. WestonKarl G. StrohmaierHilda B. Vroman
    • Simon C. WestonKarl G. StrohmaierHilda B. Vroman
    • C07D453/02C07D211/12
    • C07D453/02B01J29/70C01B39/04C01B39/48C07D211/12C07D295/037
    • A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1-yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1′-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1′-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).
    • 合成具有MSE骨架类型的结晶分子筛的方法包括使包含水源,四价元素的氧化物源Y的反应混合物结晶,Y选自硅,锡,钛,钒, 和锗,任选的三价元素的源,X,碱金属或碱土金属的源,M和有机二价元素的Q,例如3-羟基-1-(4-(1-甲基哌啶-4-基) (1-(1-甲基哌啶-1-基)戊基)奎宁环ium,1,1'ium基-1- yl基)丁基)奎宁环ium,3-羟基-1- - (丁烷-1,4-二基)双(1-甲基哌啶-1-基),1,1' - (戊烷-1,5-二基)双(1-甲基哌啶-1-基),1,1' - (己烷-1,6-二基)双(1-甲基哌啶-1-基)和1,1' - ((3as,6as) - 八氢二烯-2,5-二基)双(1-甲基哌啶-1-基) ium)。
    • 78. 发明授权
    • Synthesis of MSE-framework type molecular sieves
    • MSE-骨架型分子筛的合成
    • US08916130B2
    • 2014-12-23
    • US13649283
    • 2012-10-11
    • ExxonMobil Research and Engineering Company
    • Simon C. WestonKarl G. StrohmaierHilda B. Vroman
    • C01B39/04C01B39/48B01J29/70C07D295/037C07D453/02
    • C07D453/02B01J29/70C01B39/04C01B39/48C07D211/12C07D295/037
    • A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1-yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1′-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1′-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).
    • 合成具有MSE骨架类型的结晶分子筛的方法包括使包含水源,四价元素的氧化物源Y的反应混合物结晶,Y选自硅,锡,钛,钒, 和锗,任选的三价元素的源,X,碱金属或碱土金属的源,M和有机二价元素的Q,例如3-羟基-1-(4-(1-甲基哌啶-4-基) (1-(1-甲基哌啶-1-基)戊基)奎宁环ium,1,1'ium基-1- yl基)丁基)奎宁环ium,3-羟基-1- - (丁烷-1,4-二基)双(1-甲基哌啶-1-基),1,1' - (戊烷-1,5-二基)双(1-甲基哌啶-1-基),1,1' - (己烷-1,6-二基)双(1-甲基哌啶-1-基)和1,1' - ((3as,6as) - 八氢二烯-2,5-二基)双(1-甲基哌啶-1-基) ium)。
    • 80. 发明授权
    • Dehydrocyclodimerization using UZM-44 aluminosilicate zeolite
    • 使用UZM-44硅铝酸盐沸石进行脱氢环化二聚
    • US08889939B2
    • 2014-11-18
    • US14094060
    • 2013-12-02
    • UOP LLC
    • Christopher P. NicholasMark A. Miller
    • C07C2/76
    • C07C2/76B01J29/70B01J29/90B01J35/002B01J35/1019B01J35/1038B01J35/108C01B39/48C07C2529/70Y02P20/584C07C15/02
    • A process for dehydrocyclodimerization using a catalytic composite comprising at least one of a new family of aluminosilicate zeolites designated UZM-44 has been developed. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zine, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. UZM-44 has catalytic properties for carrying processes involving contacting at least one aliphatic hydrocarbon having from 2 to about 6 carbon atoms per molecule with the UZM-44 to produce at least one aromatic hydrocarbon.
    • 已经开发了使用指定为UZM-44的新型硅铝酸盐系列中的至少一种的催化复合物的脱氢环二聚化方法。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中“n”是Na与(Al + E)的摩尔比,M表示来自ine,第1族,第2族,第3族和/或元素周期表的镧系元素的金属, m“是M与(Al + E)的摩尔比,”k“是金属或金属M的平均电荷,T是有机结构导向剂或试剂,E是骨架元素如镓。 UZM-44具有催化性能,用于承载使每分子具有2至约6个碳原子的至少一种脂族烃与UZM-44接触以产生至少一种芳族烃。