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    • 73. 发明申请
    • Free-flowing sulfur transport, storage and use to produce energy, fertilizer or hydrogen without carbon dioxide
    • 自由流动的硫运输,储存和使用以产生能量,肥料或氢气,无二氧化碳
    • US20040247402A1
    • 2004-12-09
    • US10734741
    • 2003-12-11
    • Daniel G. Stecher
    • B65G053/00
    • C10L5/00C01B17/02C01B17/033Y02P20/128
    • Elemental sulfur is combined with either liquid anhydrous ammonia, liquid sulfur dioxide, or both to form a solution or slurry which is transportable through pipelines or other transport vessels without a risk of clogging due to the environmental temperature drops that these vessels typically encounter. This unusual behavior and the advantages it offers arise from the discovery of unexpected solubility vs. temperature relationships of elemental sulfur in each of these two carriers. Among the advantages are significant improvements in the economics of many industrial chemical processes that involve the presence of sulfur either in elemental or chemically combined form, including natural gas or tar sands production and processing, hydrogen sulfide abatement, hydrogen production without carbon dioxide emissions, and sulfur extraction from ores, subterranean deposits, depositories, or fouled impaired industrial facilities. Large-scale ramifications for energy and fertilizer mineral resource utilization, greenhouse gas abatement, hydrogen economy, and nitrogen fertilizer production are taught.
    • 元素硫与液体无水氨,液态二氧化硫或两者混合,以形成可通过管道或其他运输容器运输的溶液或浆料,而不会由于这些容器通常遇到的环境温度下降而堵塞。 这种不寻常的行为及其提供的优点来自于在这两种载体中的每一种中发现元素硫的意想不到的溶解度与温度的关系。 其优点是许多工业化学过程的经济性显着改善,这些工艺涉及以元素或化学组合形式存在硫,包括天然气或焦油砂生产和加工,硫化氢减排,无二氧化碳排放的氢气生产,以及 矿石,地下沉积物,储存库或污染受损的工业设施的硫磺提取。 教授了能源和化肥矿产资源利用,温室气体减排,氢气经济和氮肥生产的大规模影响。
    • 75. 发明授权
    • Apparatus for solidifying molten material
    • 用于固化熔融材料的装置
    • US4292016A
    • 1981-09-29
    • US886230
    • 1978-03-13
    • Herbert J. Elliott
    • Herbert J. Elliott
    • B01J19/06C01B17/02B29C23/00
    • C01B17/0216B01J19/06C01B17/02
    • Process and apparatus for solidifying molten materials by pouring onto a substrate and cooling, in which undesired crystallinity is avoided by first forming a solidified protective stabilizing skin on the melt surface, e.g. by carefully controlled air cooling or dusting with powdered material, before more vigorous cooling by fluid coolant, e.g. air or water, directed against the solidified skin. Optionally, silicone liquids and/or kerosene or other hydrocarbons of lower boiling range are used in minor amounts to treat the melt before pouring to promote the formation of amorphous solidified material and provide increased hardness on aging. When using an endless belt as substrate, the plain solidification surface may be modified by superposing a skeleton framework to form selectively shaped tablet or bar molds. The process and apparatus are particularly applicable to the solidification of molten sulphur.
    • 通过倾倒到基材上并冷却而使熔融材料固化的方法和装置,其中通过首先在熔体表面上形成固化的保护性稳定皮肤,例如避免不希望的结晶性而避免。 在通过流体冷却剂进行更剧烈的冷却之前,通过精心控制的空气冷却或粉末状材料的除尘。 空气或水,针对凝固的皮肤。 任选地,少量使用有机硅液体和/或煤油或其它较低沸点的烃,以在浇注之前处理熔体以促进无定形凝固材料的形成并提供老化时的增加的硬度。 当使用环形带作为基底时,可以通过叠加骨架骨架来形成平坦的固化表面以形成选择性形状的片剂或棒模。 该方法和装置特别适用于熔融硫的固化。
    • 76. 发明授权
    • Method of solidifying molten material
    • 凝固熔融材料的方法
    • US4088727A
    • 1978-05-09
    • US685849
    • 1976-05-13
    • Herbert James Elliott
    • Herbert James Elliott
    • B01J19/06C01B17/02B29D7/24B29D7/02
    • C01B17/0216B01J19/06C01B17/02
    • Process and apparatus for solidifying molten materials by pouring onto a substrate and cooling, in which undesired crystallinity is avoided by first forming a solidified protective stabilizing skin on the melt surface, e.g. by carefully controlled air cooling or dusting with powdered material, before more vigorous cooling by fluid coolant, e.g. air or water, directed against the solidified skin. Optionally, silicone liquids and/or kerosene or other hydrocarbons of lower boiling range are used in minor amounts to treat the melt before pouring to promote the formation of amorphous solidified material and provide increased hardness on aging. When using an endless belt as substrate, the plain solidification surface may be modified by superposing a skeleton framework to form selectively shaped tablet or bar molds. The process and apparatus are particularly applicable to the solidification of molten sulphur.
    • 通过倾倒到基材上并冷却而使熔融材料固化的方法和装置,其中通过首先在熔体表面上形成固化的保护性稳定皮肤,例如避免不希望的结晶性而避免。 在通过流体冷却剂进行更剧烈的冷却之前,通过精心控制的空气冷却或粉末状材料的除尘。 空气或水,针对凝固的皮肤。 任选地,少量使用有机硅液体和/或煤油或其它较低沸点的烃,以在浇注之前处理熔体以促进无定形凝固材料的形成并提供老化时的增加的硬度。 当使用环形带作为基底时,可以通过叠加骨架骨架来形成平坦的固化表面以形成选择性形状的片剂或棒模。 该方法和装置特别适用于熔融硫的固化。