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    • 74. 发明授权
    • Carbon dioxide reforming process
    • 二氧化碳重整过程
    • US08518301B2
    • 2013-08-27
    • US12971552
    • 2010-12-17
    • Hideto SatoYoshinori Saito
    • Hideto SatoYoshinori Saito
    • C01B3/38C01B3/24
    • C01B3/40B01J21/063B01J23/78C01B2203/0238C01B2203/1047C01B2203/1058C01B2203/1064C01B2203/1082Y02E60/324Y02P20/52
    • A synthetic gas containing hydrogen and carbon monoxide is efficiently obtained by reacting a hydrocarbon feedstock gas with carbon dioxide under pressure, while suppressing carbon deposition. The pressure is preferably 3 atmospheres (0.304 MPa), and used is a carbon dioxide reforming catalyst that contains at least one alkaline earth metal carbonate a catalytic metal promoting the decomposition reaction of a hydrocarbon feedstock gas, at least one alkaline earth metal selected from the group consisting of Ca, Sr, and Ba, and a complex oxide containing at least one component selected from the group consisting of Ti, Al, Zr, Fe, W, and Mo, such as ATiO3, AAl2O4, AZrO3, AFe2O4, A3W2O9, A2WO5, or AMoO4, where A is at least one of Ca, Sr, and Ba.
    • 通过在压力下使烃原料气体与二氧化碳反应同时抑制碳沉积而有效地获得含有氢和一氧化碳的合成气体。 压力优选为3个大气压(0.304MPa),并且使用二氧化碳重整催化剂,其含有至少一种碱土金属碳酸盐,催化金属促进烃原料气体的分解反应,至少一种碱土金属选自 由Ca,Sr和Ba组成的组,以及包含选自Ti,Al,Zr,Fe,W和Mo中的至少一种组分的复合氧化物,例如ATiO 3,AAl 2 O 4,AZrO 3,AFe 2 O 4,A 3 W 2 O 9, A2WO5或AMoO4,其中A是Ca,Sr和Ba中的至少一种。
    • 75. 发明申请
    • CATALYST FOR REVERSE SHIFT REACTION AND METHOD FOR PRODUCING SYNTHESIS GAS USING THE SAME
    • 用于反向移动反应的催化剂及其合成气合成方法
    • US20120231948A1
    • 2012-09-13
    • US13472644
    • 2012-05-16
    • Yoshinori Saito
    • Yoshinori Saito
    • C01B3/02C01F11/02B01J21/06
    • B01J23/02B01J23/002B01J23/007B01J35/1009C01B32/40
    • There are provided a catalyst for reverse shift reaction which has excellent durability at a high temperature, can suppress generation of a methanation reaction, and can efficiently generate a reverse shift reaction to produce a synthesis gas including carbon monoxide and unreacted hydrogen with a reduced methane content, and a method for producing a synthesis gas using the catalyst for reverse shift reaction. The composition of the catalyst for the reverse shift reaction includes a composite oxide containing at least one alkali earth metal selected from the group consisting of Ca, Sr and Ba and at least one transition metal selected from the group consisting of Ti and Zr. A raw material gas containing carbon dioxide and hydrogen is contacted with the catalyst for reverse shift reaction at a temperature of 700° C. or higher.
    • 提供了一种反相转移反应催化剂,其在高温下具有优异的耐久性,可以抑制甲烷化反应的产生,并且可以有效地产生反向转移反应以产生包含一氧化碳和未反应的氢的合成气,甲烷含量降低 以及使用该反转移反应用催化剂制造合成气的方法。 用于逆转换反应的催化剂的组成包括含有至少一种选自Ca,Sr和Ba的碱土金属和至少一种选自Ti和Zr的过渡金属的复合氧化物。 在700℃以上的温度下,将含有二氧化碳和氢的原料气与催化剂接触进行逆转换反应。