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    • 74. 发明授权
    • Cationic polymers as antistatic additives for hair preparations
    • 阳离子聚合物作为头发制剂的抗静电添加剂
    • US4900543A
    • 1990-02-13
    • US885387
    • 1986-07-17
    • Wolfgang RitterRolf TenhaefHorst HoffkesKurt Seidel
    • Wolfgang RitterRolf TenhaefHorst HoffkesKurt Seidel
    • C08C19/40C08G59/34C08G73/02C11D3/37
    • A61K8/84A61Q5/02C08C19/40C08G59/027C08G73/0273A61Q5/10Y10S514/88Y10S514/881
    • An aqueous hair-treatment preparation containing an antistatic additive imparting an antistatic effect to the hair, characterized in that said antistatic additive is at least one cationic polymer produced by the process of (1) epoxidizing 1,3-diene homopolymers or copolymers, (2) amine reacting the epoxide compound so produced with low molecular weight amines selected from the group consisting of primary amines, secondary amines and tertiary amines, and (3) converting the reaction products into the salt form or into polymeric quaternary ammonium salts. The use of these polymeric amine salts or quaternary ammonium salts in cosmetic hair-treatment preparations provides these preparations with antistatic effects. Preferred cationic polymers are obtained by the expoxidation of polybutadiene, of which more than 50% of the monomer units show the 1,4-cis- configuration, reaction with dimethylamine or morpholine and conversion into the hydrochlorides or alkylation with glycidyl trimethylammonium chloride, 3-chloro-2-hydroxypropyl trimethylammonium chloride or ethylene oxide. The cationic polymers are preferably used in shampoos in quantities of from 0.5 to 5.0% by weight in addition to 5 to 30% by weight of alkylether sulfate tensides and 1 to 5% by weight of a zwitterionic or amphoteric washing-active substance.
    • 一种含有对头发赋予抗静电效果的抗静电添加剂的水性护发剂,其特征在于,所述抗静电添加剂是通过(1)环氧化1,3-二烯均聚物或共聚物的方法制备的至少一种阳离子聚合物,(2 )胺使如此制备的环氧化合物与选自伯胺,仲胺和叔胺的低分子量胺反应,和(3)将反应产物转化为盐形式或转化为聚合季铵盐。 在化妆品头发处理制剂中使用这些聚合胺盐或季铵盐使这些制剂具有抗静电效果。 优选的阳离子聚合物通过聚合丁二烯的过氧化获得,其中多于50%的单体单元显示1,4-顺式构型,与二甲胺或吗啉反应并转化为盐酸盐或用缩水甘油基三甲基氯化铵进行烷基化, 氯-2-羟丙基三甲基氯化铵或环氧乙烷。 除了5〜30重量%的烷基醚硫酸盐表面活性剂和1〜5重量%的两性离子或两性洗涤活性物质之外,阳离子性聚合物优选以洗发剂的量计为0.5〜5.0重量%。