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71. 发明授权

US5196483A Rubber compositions with a high elastic modulus 失效
标题翻译：具有高弹性模量的橡胶组合物
公开(公告)号：US5196483A
公开(公告)日：1993-03-23
申请号：US549322
申请日：1990-07-06
申请人： Daniel Zimmerman , John Milks , Sidney Binder , Roger J. Card , Winfried Wunderlich , Werner Siol
发明人： Daniel Zimmerman , John Milks , Sidney Binder , Roger J. Card , Winfried Wunderlich , Werner Siol
IPC分类号： C08F255/06 , C08F291/02
CPC分类号： C08F291/02 , C08F255/06
摘要： Modified rubber compositions comprise by weight about 15-60% of a highly saturated aliphatic rubber such as ethylene-propylene-diene rubber, about 25-80% of acrylate monomer units; and less than about 5% multi-functional monomer units. The compositions exist as amorphous heterogeneously dispersed phases. The first phase comprises the copolymer rubber to which polymers of at least 10% of the other monomer units are grafted. The second phase comprises the other monomers polymerized as homo and copolymers, not grafted to the rubber. Optionally, up to 20% of the composition comprises high index monomer units. The high index monomer units may be copolymerized with the acrylate and grafted to the rubber. Greater than 10% of the monomer units other than rubber are grafted to the rubber. The number average molecular weight of the grafts is between 10,000 and 80,000 daltons. About 2-20% by weight of one or more polymers may be provided to adjust the refractive indices of the rubber or the polyacrylate phase in the final product such that when the composition is present at the 10% rubber level, the haze can be reduced to less than 20%.
摘要翻译：改性橡胶组合物包含约15-60％的高饱和脂肪族橡胶如乙烯 - 丙烯 - 二烯橡胶，约25-80％的丙烯酸酯单体单元; 和小于约5％的多官能单体单元。组合物以无定形非均相分散相存在。第一相包含其中至少10％的其它单体单元的聚合物被接枝的共聚物橡胶。第二相包含其它单体作为均聚物和共聚物聚合而未接枝到橡胶上。任选地，高达20％的组合物包含高折射率单体单元。高指数单体单元可以与丙烯酸酯共聚并接枝到橡胶上。大于10％的橡胶以外的单体单元被接枝到橡胶上。移植物的数均分子量为10,000至80,000道尔顿。可以提供约2-20重量％的一种或多种聚合物以调节最终产品中橡胶或聚丙烯酸酯相的折射率，使得当组合物以10％橡胶水平存在时，雾度可以降低至少于20％。

72. 发明授权

US5063112A Impact-resistant methacrylate protective layer for polycarbonate, containing UV absorber 失效
标题翻译：含抗紫外线吸收剂的聚碳酸酯防甲基丙烯酸酯保护层
公开(公告)号：US5063112A
公开(公告)日：1991-11-05
申请号：US432388
申请日：1989-11-06
申请人： Heinz Gross , Jens-Dieter Fischer , Werner Siol , Thomas Sufke , Thomas Rhein
发明人： Heinz Gross , Jens-Dieter Fischer , Werner Siol , Thomas Sufke , Thomas Rhein
IPC分类号： B29C47/02 , B32B27/30 , B32B27/36 , C08J7/04
CPC分类号： C08J7/047 , C08J2369/00 , Y10T428/31507 , Y10T428/31928 , Y10T428/31935
摘要： Multi-layer plastic elements containing a polycarbonate core, with a polymethacrylate layer containing a UV absorber, and modified to be impact-resistant, applied to the core, where the polymethacrylate plastic layer is composed of methacrylate copolymers, which form compatible mixtures with polycarbonate, especially the polycarbonate of bisphenol A, exhibit good adhesion between the polycarbonate and the polymethacrylate. The methacrylate copolymers are methyl methacrylate copolymers with (meth)acrylic monomers which contain carbocyclic substituents in the ester group. The protective layer containing UV absorber is applied to the polycarbonate plastic in thickness from 1 to 500 .mu.m by coextrusion or by lacquering.
摘要翻译：包含聚碳酸酯芯的多层塑料元件，其中含有紫外线吸收剂的聚甲基丙烯酸酯层，并被改性为抗冲击的，应用于芯，其中聚甲基丙烯酸酯塑料层由与聚碳酸酯形成相容的混合物的甲基丙烯酸酯共聚物组成，特别是双酚A的聚碳酸酯，在聚碳酸酯和聚甲基丙烯酸酯之间表现出良好的粘合性。甲基丙烯酸酯共聚物是甲基丙烯酸甲酯共聚物与在酯基中含有碳环取代基的（甲基）丙烯酸单体。通过共挤出或通过涂漆将含有UV吸收剂的保护层施加至厚度为1至500μm的聚碳酸酯塑料。

73. 发明授权

US5053177A Method for making a coated synthetic resin web 失效
标题翻译：制造涂层合成树脂网的方法
公开(公告)号：US5053177A
公开(公告)日：1991-10-01
申请号：US352051
申请日：1989-05-15
申请人： Heinz Vetter , Werner Siol
发明人： Heinz Vetter , Werner Siol
IPC分类号： B05D1/28 , B05C1/14 , B29C37/00 , B29C43/30 , B29C47/00 , B32B37/24
CPC分类号： B32B37/24 , B05C1/14 , B29C37/0025 , B29C43/305 , B29C47/00 , B29C47/0021 , B29C47/003 , B32B2327/06 , B32B2333/12
摘要： An extruded web of synthetic resin having a scratch resistant coating thereon is made by depositing a material adapted to form a scratch resistant coating onto the return run of at least one of the endless belts of a dual belt continuous casting machine, the coating being transferred to the surface of the web as the extruded web is polished and cooled in the casting machine.
摘要翻译：通过将适于形成耐刮擦涂层的材料沉积到双带连续铸造机的至少一个循环带的返回路径上，将涂层转移到作为挤出纤维网的纤维网的表面在铸造机中被抛光和冷却。

74. 发明授权

US4520172A Method for coating medicaments 失效
标题翻译：药物涂敷方法
公开(公告)号：US4520172A
公开(公告)日：1985-05-28
申请号：US474469
申请日：1983-03-11
申请人： Klaus Lehmann , Dieter Dreher , Hubert Rauch , Werner Siol
发明人： Klaus Lehmann , Dieter Dreher , Hubert Rauch , Werner Siol
IPC分类号： A61K9/58 , A61K9/28 , A61K9/32 , A61K47/00 , A61K47/32 , C08F8/28 , C08F8/12 , C08F8/44
CPC分类号： A61K9/2846
摘要： What are disclosed are methods for dispersing a powdered salt-forming synthetic resin in water in the presence of an agent forming a salt with said resin, methods for coating pharmaceutical dosage forms with a dispersion made by such a method, and powdered mixtures of a salt forming resin and salt forming agent for dispersion in water.
摘要翻译：所公开的方法是在形成与所述树脂形成盐的试剂的存在下将粉状成盐合成树脂分散在水中的方法，用通过这种方法制备的分散体涂覆药物剂型的方法和盐的混合物形成用于分散在水中的树脂和成盐剂。

75. 发明授权

US4452862A Pharmaceutical coating materials soluble or swellable in gastric juice and pharmaceutical dosage forms coated therewith 失效
标题翻译：在胃液中可溶或溶胀的药物包衣材料和用其涂覆的药物剂型
公开(公告)号：US4452862A
公开(公告)日：1984-06-05
申请号：US345478
申请日：1982-02-03
申请人： Gerhard Markert , Dieter Dreher , Klaus Lehmann , Werner Siol , Hubert Rauch
发明人： Gerhard Markert , Dieter Dreher , Klaus Lehmann , Werner Siol , Hubert Rauch
IPC分类号： A61K9/58 , A61K9/28 , A61K9/32 , A61K47/32 , B32B5/16
CPC分类号： A61K9/2846 , Y10T428/2998
摘要： Coating materials for pharmaceutical dosage forms contain, besides the conventional liquid or solid additives for pharmaceutical coatings, a binder comprising a synthetic polymer, prepared by emulsion polymerization, having 5 to 100% by weight of units derived from monomers of the formula ##STR1## wherein R.sub.1 is a hydrogen atom or a lower alkyl group, R.sub.2 is an alkylene or aralkylene group having at least 3 carbon atoms in the chain between the amino nitrogen and the ester oxygen atom of which at least one is tertiary or quaternary, and R.sub.3 and R.sub.4 are lower alkyl radicals or together with the amino-nitrogen atom form a heteroaliphatic ring, and, optionally, additional comonomer units.
摘要翻译：用于药物剂型的涂层材料除了用于药物涂层的常规液体或固体添加剂外，还包含通过乳液聚合制备的包含合成聚合物的粘合剂，其具有5至100重量％的衍生自下式的单体的单元：其中 R1是氢原子或低级烷基，R2是在氨基氮和酯氧原子之间的链中具有至少3个碳原子的亚烷基或亚芳基，其至少一个是叔或四价，R3和R4 是低级烷基或与氨基 - 氮原子一起形成杂脂族环，和任选的另外的共聚单体单元。

76. 发明授权

US4314800A Method for treating pelts and leather 失效
标题翻译：毛皮和皮革的处理方法
公开(公告)号：US4314800A
公开(公告)日：1982-02-09
申请号：US252164
申请日：1981-04-08
申请人： Rolf Monsheimer , Ernst Pfleiderer , Werner Siol , Hanns Boessler , Hans Trabitzsch
发明人： Rolf Monsheimer , Ernst Pfleiderer , Werner Siol , Hanns Boessler , Hans Trabitzsch
IPC分类号： C08F20/00 , C08F20/34 , C08F220/34 , C08F261/00 , C08F289/00 , C14C3/00 , C14C3/22 , C14C9/00 , C14C11/00
CPC分类号： C14C3/22 , C08F261/00 , C08F289/00 , C14C3/00
摘要： What is disclosed are a method for treating pelts or leather in the beamhouse, for tanning, or as an aftertreatment, which method comprises contacting said pelts or leather with an aqueous solution or dispersion of a copolymer comprising monomers of a nitrogenous ester of acrylic acid or of methacrylic acid, a further different ester of acrylic acid or of methacrylic acid, and acrylic acid or methacrylic acid, whereby portions of said copolymer are deposited in the grain layer without formation of a superficial film, and pelts and leather treated by this method.
摘要翻译：所公开的是用于处理波纹室中的皮革或皮革，用于鞣制或后处理的方法，该方法包括使所述毛皮或皮革与包含丙烯酸的含氮酯的单体的共聚物的水溶液或分散体接触，或的甲基丙烯酸，另一种不同的丙烯酸或甲基丙烯酸酯，以及丙烯酸或甲基丙烯酸，其中所述共聚物的一部分沉积在晶粒层中而不形成表面膜，并通过该方法处理皮毛和皮革。

77. 发明申请

US20130046050A1 HYBRID PARTICLES MADE OF POLYMERS AND NANOPARTICLES 审中-公开
标题翻译：聚合物和纳米颗粒的混合颗粒
公开(公告)号：US20130046050A1
公开(公告)日：2013-02-21
申请号：US13502345
申请日：2010-10-18
申请人： Werner Siol , Klaus Langerbeins , Uwe Dietrich Kühner
发明人： Werner Siol , Klaus Langerbeins , Uwe Dietrich Kühner
IPC分类号： C08L33/12 , C08K3/36 , B82Y30/00
CPC分类号： C08F20/18 , C08F2/44 , C08F20/06 , C08F20/14 , C08K3/34 , C08L33/08 , C08L33/12 , C08L2308/00 , C08L2312/00 , C08L2666/04
摘要： Subject of the invention is a hybrid particle comprising at least two vinyl polymers (vinyl polymers A and B), wherein vinyl polymer A comprises colloidal SiO2 particles with an average particle size from 1 to 150 nm and vinyl polymer B is capable of crosslinking hybrid particles to one another.
摘要翻译：本发明的主题是包含至少两种乙烯基聚合物（乙烯基聚合物A和B）的混合颗粒，其中乙烯基聚合物A包含平均粒径为1-150nm的胶体SiO 2颗粒，乙烯基聚合物B能够交联混合颗粒彼此。

78. 发明申请

US20070224274A1 Polymer Particles Containing Active Agents 审中-公开
标题翻译：含有活性剂的聚合物颗粒
公开(公告)号：US20070224274A1
公开(公告)日：2007-09-27
申请号：US10594365
申请日：2005-04-02
申请人： Werner Siol
发明人： Werner Siol
IPC分类号： A61K47/32 , A61K47/48 , C08F220/12
CPC分类号： A61K9/5138 , A61K9/1635 , C08F220/06 , C08F220/14
摘要： The invention relates to active ingredient-containing polymer particles comprising a vinyl polymer from 10-80% by weight monomers comprising amino and/or carboxyl groups, which is insoluble in one part of the pH range 0-10 and is soluble in another part of the range, wherein these active ingredient-containing polymer particles comprise 3-1000 parts of active ingredient per part of vinyl polymer, have a particle size in the range 20 nm-8 μm and the vinyl polymer is >50% by weight composed of polymers having a molecular weight of
摘要翻译：本发明涉及含活性成分的聚合物颗粒，其包含10-80重量％的包含氨基和/或羧基的单体的乙烯基聚合物，其不溶于pH范围0-10的一部分，并且可溶于该范围，其中这些含活性成分的聚合物颗粒包含3-1000份活性成分/乙烯基聚合物，其粒径为20nm-8μm，乙烯基聚合物的重量百分数为50重量％分子量<100 000道尔顿。

79. 发明申请

US20060287431A1 Polymer networks 审中-公开
标题翻译：聚合物网络
公开(公告)号：US20060287431A1
公开(公告)日：2006-12-21
申请号：US10571116
申请日：2004-09-20
申请人： Werner Siol
发明人： Werner Siol
IPC分类号： C09D5/02 , C08L31/00
CPC分类号： C08F222/1006 , C08F290/042 , C08F290/061 , C08L67/07
摘要： The invention relates to polymer networks comprising dimethacrylates of formula CH2═CCH3COO—X—O—COCCH3═CH2 and thiols as main components, X representing a bifunctional radical. Said dimethacrylate/modifier networks represent materials whose properties are determined essentially by the properties of the X group as a result of the very short polymethacrylate blocks used. The networks are very soft and flexible or highly solid, tough, and solvent-resistant depending on the type of the X group that is used.
摘要翻译：本发明涉及包含式CH 2 -CCH 3 COO-XO-COCH 3 -CH 2的二甲基丙烯酸酯的聚合物网络，和硫醇作为主要成分，X代表双官能团。所述二甲基丙烯酸酯/改性剂网络表示由于使用非常短的聚甲基丙烯酸酯嵌段的结果，其性质主要由X基团的性质决定。根据所使用的X组的类型，网络非常柔软，灵活或高度固体，韧性和耐溶剂性。

80. 发明授权

US5859140A Method for the production of branched polymerizates 失效
标题翻译：生产支化聚合物的方法
公开(公告)号：US5859140A
公开(公告)日：1999-01-12
申请号：US877640
申请日：1997-06-17
申请人： Martina Pfirmann , Werner Siol , Klaus Koralewski , Michael Wicker
发明人： Martina Pfirmann , Werner Siol , Klaus Koralewski , Michael Wicker
IPC分类号： C08F2/06 , C08F2/38 , C08F265/06 , C09D7/12 , C09J11/08 , C10M145/14 , C10M149/06 , C08F273/00
CPC分类号： C09J11/08 , C08F265/06 , C09D7/125 , C10M145/14 , C10M149/06 , C10M2209/084 , C10M2217/024 , C10M2217/06 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A method for producing branched polymerizates by radical polymerization of monomers in two stages comprisingin a first stage, adding 10 to 500 parts by weight of at least one monomer M.sub.1 and 0.1 to 20 parts by weight of a mercaptan with an olefinic, radically polymerizable double bond RM as a molecular weight regulator, and polymerizing said at least one monomer M.sub.1 and mercaptan RM to form a copolymer MM.sub.1 in the presence of at least one polymerization initiator and 0 to 100 parts by weight of an inert, non-aqueous solvent, which completely dissolves the monomer M.sub.1, the mercaptan RM and the copolymer MM.sub.1, where the polymerizable double bonds and M.sub.1 and RM have a reactivity, expressed by a copolymerization parameter r, between 0.1 and 10, andin a second stage, adding 10 to 2000 parts by weight of a monomer M.sub.2 and 0.01 to 10 parts by weight of a saturated molecular weight regulator, and optionally, an inert, non-aqueous solvent, to the reaction mixture formed in the first stage, and polymerizing in the presence of at least one polymerization initiator to form a branched polymerizate. Branched polymerzates made by the method.
摘要翻译：通过两步单体的自由基聚合制备支化聚合物的方法，包括在第一阶段中，加入10至500重量份的至少一种单体M1和0.1至20重量份的具有烯属可自由基聚合双酚的硫醇键RM作为分子量调节剂，并且在至少一种聚合引发剂和0至100重量份的惰性非水溶剂的存在下，聚合所述至少一种单体M1和硫醇RM以形成共聚物MM1，其中完全溶解单体M1，硫醇RM和共聚物MM1，其中可聚合双键和M1和RM具有由共聚参数r表示的反应性，为0.1至10，在第二阶段中，加入10至2000份的单体M2和0.01至10重量份的饱和分子量调节剂和任选的惰性非水溶剂加入到第一阶段中形成的反应混合物中，和聚在存在至少一种聚合引发剂的情况下化合以形成支化聚合物。通过该方法制备的支化聚合物。

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