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    • 73. 发明授权
    • Magnetic recording material
    • 磁记录材料
    • US4468436A
    • 1984-08-28
    • US452555
    • 1982-12-23
    • Tsutomu OkitaKiritani Masataka
    • Tsutomu OkitaKiritani Masataka
    • G11B5/738B05D3/06
    • G11B5/738Y10S428/90Y10T428/31554Y10T428/31609Y10T428/31928
    • A magnetic recording material and a process for producing it are disclosed. The material is excellent in abrasion resistance and has good electric characteristics. The material is obtained by coating on a support a subbing layer having a compound which contains a compound having an unsaturated bond polymerizable upon irradiation with electron beams. Upon the subbing layer is coated a ferromagnetic layer which contains a compound having an unsaturated bond polymerizable upon irradiation with electron beams, an organic solvent capable of dissolving the compound, and a ferromagnetic fine powder. The material is then subjected to an electron-beam irradiating processing to result in the hardening of the subbing and ferromagnetic layers through polymerization.
    • 公开了磁记录材料及其制造方法。 该材料具有优异的耐磨性和良好的电特性。 该材料通过在载体上涂布具有含有具有在电子束照射下可聚合的不饱和键的化合物的化合物的底层而获得。 在底层涂覆铁氧体层时,该铁磁层含有在电子束照射下可聚合的具有不饱和键的化合物,可溶解该化合物的有机溶剂和铁磁性细粉末。 然后对该材料进行电子束照射处理,以通过聚合导致底层和铁磁性层的硬化。
    • 77. 发明授权
    • Magnetic recording medium having a cobalt thin film magnetic layer,
carbon protective layer, and fluorolubricant layer
    • 具有钴薄膜磁性层,碳保护层和氟润滑剂层的磁记录介质
    • US5567524A
    • 1996-10-22
    • US379931
    • 1995-01-27
    • Toshio IshidaMasaki SatakeHideomi WatanabeTadashi YasunagaTsutomu Okita
    • Toshio IshidaMasaki SatakeHideomi WatanabeTadashi YasunagaTsutomu Okita
    • G11B5/66C10M105/54C10N40/18G11B5/64G11B5/65G11B5/72G11B5/725G11B5/735
    • G11B5/725Y10S428/90Y10T428/30Y10T428/3154Y10T428/31678
    • A magnetic recording medium having a ferromagnetic metal thin film formed over at least one surface of a non-magnetic support, wherein the improvement has a lubricant layer consisting essentially of at least one of unsaturated bond-containing fluoroalkyl carboxylic acid esters which are represented by the following formulae (1) to (3):Rf--R.sub.1 --COO--R.sup.2 Formula (1)R.sup.3 --COO--R.sub.4 --Rf Formula (2)Rf--R.sup.5 --COO--R.sup.6 Rf Formula (3)where Rf: (CF.sub.3).sub.a CF.sub.3-a (CF.sub.2).sub.ba: 1 to 3 a+b: 1 to 17R.sup.1 is an alkyl group having from 2 to 18 carbon atoms, or a hydrocarbon group having from 2 to 18 carbon atoms and containing at least one double or triple bond, and R.sup.2 is an alkyl group having from 4 to 22 carbon atoms, or a hydrocarbon group having from 4 to 22 carbon atoms and containing at least one double or triple bond. At least either one of R.sup.1 and R.sup.2 contains at least one double or triple bond. R.sup.3 is an alkyl group having from 3 to 21 carbon atoms, and R.sup.4 is a hydrocarbon group having from 4 to 18 carbon atoms and containing at least one double or triple bond. R.sup.5 and R.sup.6 are each an alkyl group having from 2 to 18 carbon atoms, or a hydrocarbon group having from 2 to 18 carbon atoms and containing at least one double or triple bond. At least either one of R.sup.5 and R.sup.6 contains at least one double or triple bond. R.sup.5 and R.sup.6 have from 20 to 44 carbon atoms in total.
    • 一种具有在非磁性载体的至少一个表面上形成的强磁性金属薄膜的磁记录介质,其中所述改进具有基本上由至少一种含不饱和键的氟烷基羧酸酯组成的润滑层,所述不饱和键的氟烷基羧酸酯由 (1)至(3):Rf-R1-COO-R2(1)R3-COO-R4-Rf(2)Rf-R5-COO-R6RfFormula(3)其中Rf:(CF3)aCF3-a CF 2)ba:1〜3 a + b:1〜17 R 1为碳原子数2〜18的烷基或碳原子数为2〜18的含有至少一个双键或三键的烃基,R 2 是具有4至22个碳原子的烷基或具有4至22个碳原子并且含有至少一个双键或三键的烃基。 R1和R2中至少有一个含有至少一个双键或三键。 R3是具有3至21个碳原子的烷基,R4是具有4至18个碳原子并含有至少一个双键或三键的烃基。 R 5和R 6各自为具有2至18个碳原子的烷基或具有2至18个碳原子且含有至少一个双键或三键的烃基。 R5和R6中的至少一个含有至少一个双键或三键。 R5和R6总共具有20至44个碳原子。