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    • 73. 发明申请
    • Polyorganosiloxane Containing Methacryloxy Group Or Acryloxy Group And Method For Producing The Same
    • 含有甲基丙烯酰氧基或丙烯氧基的聚有机硅氧烷基及其制备方法
    • US20110092660A1
    • 2011-04-21
    • US12863165
    • 2009-01-14
    • Tadashi OkawaEiji Ando
    • Tadashi OkawaEiji Ando
    • C08G77/04
    • C08G77/38C08G77/12C08G77/46
    • A methacryloxy group- or acryloxy group-containing polyorganosiloxane in which a methacryloxy group or acryloxy group is bonded to a silicon atom in the polyorganosiloxane across a long-chain alkylene group or poly(alkyleneoxy)-long chain-alkylene group having 11 to 20 carbon atoms. A method of producing this methacryloxy group- or acryloxy group-containing polyorganosiloxane, in which a silicon-bonded hydrogen atom-containing polyorganosiloxane is addition reacted in the presence of a hydrosilylation reaction catalyst with a 1-alkenyl methacrylate or a 1-alkenyl acrylate or a 1-alkenyloxypolyalkylene glycol methacrylate or a 1-alkenyloxypolyalkylene glycol acrylate.
    • 含有甲基丙烯酰氧基或丙烯酰氧基的聚有机硅氧烷,其中甲基丙烯酰氧基或丙烯酰氧基通过长链亚烷基或聚(亚烷氧基) - 长链亚烷基键合到聚有机硅氧烷中的硅原子上,其具有11至20碳 原子 在含硅键合的含氢原子的聚有机硅氧烷的加成反应催化剂的存在下,在氢化硅烷化反应催化剂与1-链烯基甲基丙烯酸酯或1-烯基丙烯酸酯的情况下生产该含甲基丙烯酰氧基或含丙烯酰氧基的聚有机硅氧烷的方法,或 1-链烯氧基聚亚烷基二醇甲基丙烯酸酯或1-链烯氧基聚亚烷基二醇丙烯酸酯。
    • 80. 发明授权
    • Carbosiloxane dendrimer and dendrimer-containing organic polymers
    • 碳硅氧烷树枝状大分子和含树枝状大分子的有机聚合物
    • US06306992B1
    • 2001-10-23
    • US09625011
    • 2000-07-25
    • Makoto YoshitakeTadashi OkawaYoshitsugu MoritaHaruhiko Furukawa
    • Makoto YoshitakeTadashi OkawaYoshitsugu MoritaHaruhiko Furukawa
    • C08F23008
    • C07F7/0838
    • A novel carbosiloxane dendrimer is disclosed containing a radically polymerizable group in the molecule and which possesses excellent polymerization reactivity. The carbosiloxane dendrimer can be used to provide organic polymers as afforded by the polymerization of the carbosiloxane dendrimer either alone or with other organic monomers. The radically polymerizable group-functional carbosiloxane dendrimer with the general formula (R1 is C1 to C10 alkyl or aryl, R2 is a divalent organic group excluding C1 to C10 alkylene, b is 1 to 3, X1 is a silylalkyl group, and Y is a radically polymerizable group). Also, dendrimer-containing organic polymer as afforded by the polymerization of (A) the aforesaid carbosiloxane dendrimer and (B) radically polymerizable organic monomer.
    • 公开了一种在分子中含有自由基聚合性基团并且具有优异的聚合反应性的新型碳硅氧烷树枝状聚合物。 碳硅氧烷树枝状聚合物可以用于提供单独或与其它有机单体聚合碳硅氧烷树枝状聚合物所提供的有机聚合物。 具有通式(R1为C1〜C10烷基或芳基,R2为除C1〜C10亚烷基外的二价有机基团,b为1〜3,X 1为甲硅烷基烷基,Y为甲硅烷基烷基)的自由基聚合性基团官能团的碳硅氧烷树枝状大分子 自由基聚合性基团)。 另外,通过(A)上述碳硅氧烷树枝状聚合物和(B)可自由基聚合的有机单体的聚合提供的含树枝状大分子的有机聚合物。