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71. 发明申请

US20070027229A1 Photopolymerizable dental materials with bisacylphosphine oxides as initiators 有权
标题翻译：具有双酰基氧化膦作为引发剂的光聚合牙科材料
公开(公告)号：US20070027229A1
公开(公告)日：2007-02-01
申请号：US11385058
申请日：2006-03-21
申请人： Norbert Moszner , Volker Rheinberger , Ulrich Salz , Heinrich Gruber , Robert Liska , Beate Ganster , Gerald Ullrich
发明人： Norbert Moszner , Volker Rheinberger , Ulrich Salz , Heinrich Gruber , Robert Liska , Beate Ganster , Gerald Ullrich
IPC分类号： A61K6/10
CPC分类号： A61K6/083 , A61K6/0023 , C08L33/00
摘要： Polymerizable dental material which contains at least one radically-polymerizable monomer and at least one bisacylphosphine oxide of the Formula I, in which R1 is a linear or branched C2 to C14 alkyl residue, which can be interrupted by one or more O atoms, PG-Y-R2-X- or a substituted or unsubstituted, aromatic C6 to C14 radical; R2 is absent or a linear or branched C1 to C20 alkylene radical, which can be interrupted by one or more O atoms; R3 is H, a linear or branched C1 to C6 alkyl residue or PG-Y-R2-X-; R4 is a linear or branched C1-C6 alkyl or —O—C1-C6 alkyl residue; R5 is H or PG-Y-R2-X-; R6 is H or PG-Y-R2-X-; PG is a polymerizable group; X is absent, O or S; Y is absent, O, S, an ester, amide or urethane group; the bisacylphosphine oxide having at least one PG-Y-R2-X group and X and/or Y being absent if R2 is absent.
摘要翻译：含有至少一种可自由基聚合的单体和至少一种式I的双酰基氧化膦的可聚合的牙科材料，其中R 1是直链或支链C 2〜C 可以被一个或多个O原子间隔的烷基残基，PG-YR 2 -X-或取代或未取代的芳族C 6 - SUB>至C 14 基团; R 2不存在或可以被一个或多个O原子中断的直链或支链C 1至C 20亚烷基; R 3是H，直链或支链C 1至C 6烷基或PG-YR 2 - X-; R 4是直链或支链C 1 -C 6烷基或-OC 1 -C 1 -C 6烷基， 6个烷基残基; R 5是H或PG-Y-R 2 -X-; R 6是H或PG-Y-R 2 -X-; PG是可聚合基团; X不存在，O或S; Y不存在，O，S，酯，酰胺或氨基甲酸酯基; 具有至少一个PG-Y-R 2 -X基团的双酰基氧化膦和如果R 2不存在X和/或Y不存在。

72. 发明申请

US20060247329A1 Surface-modified fillers 有权
公开(公告)号：US20060247329A1
公开(公告)日：2006-11-02
申请号：US11292578
申请日：2005-12-02
申请人： Norbert Moszner , Simone Klapdohr , Ulrich Salz , Jorg Zimmermann , Volker Rheinberger
发明人： Norbert Moszner , Simone Klapdohr , Ulrich Salz , Jorg Zimmermann , Volker Rheinberger
IPC分类号： A61K6/08 , A61K6/083
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/0073 , A61K6/093 , Y10T428/29 , C08L33/14 , C08L43/02 , C08L83/06
摘要： Filler which is surface-modified with a compound of the formula [(PG)—R1—Z]n—SP—[Y—R2—(AG)]m, in which AG is —COOH, —P(═O)(OH)2, —O—P(═O)(OH)2, —SO2OH, —SiR3R4X, or a chelating group; R1 is a C1-C3 alkylene group or cyclopropylene group or is absent; R2 is a C1-C10 alkylene group or is absent; R3 is a C1-C8 alkyl group, chlorine or OR5; R4 is a C1-C8 alkyl group, phenyl, chlorine or OR5; R5 is a C1-C6 alkyl group; X is OR5 or chlorine; Y is O, S, CO—NH, O—CO—NH, NH—CO—NH or is absent, Y being absent if R2 is absent; Z is O, S, CO—NR6, O—CO—NH, NH—CO—NH or is absent, R6 being H or C1-C6 alkyl; PG is a radically polymerizable group of the formula in which R9 is H, C1-C3 alkyl, C1-C3 hydroxyalkyl or COOR10; R10 is H, C1-C10 alkyl, 1,6-dimethylphenyl or mesityl; R11 is H or phenyl; m is 1 or 2; n is 1, 2, 3 or 4; SP is absent or is an (n+m)-valent linear or branched aliphatic C1-C30 radical, in which the carbon chain can be interrupted by O, S, CO—NH, O—CO—NH or NH—CO—NH, an (n+m)-valent aromatic C6-C18 radical, an (n+m)-valent cycloaliphatic C3-C18 radical or an (n+m)-valent heterocyclic C3-C18 radical, where the radicals can be substituted or unsubstituted; in which, if AG is a silyl radical of the formula —SiR3R4X and PG is a vinyl group of the formula H2C═CH—, R1 and Z are not absent simultaneously.

73. 发明申请

US20060004158A1 Dental materials polymerizable by photo-induced ring-opening metathesis polymerization of cyclic olefins 有权
公开(公告)号：US20060004158A1
公开(公告)日：2006-01-05
申请号：US11172008
申请日：2005-06-30
申请人： Norbert Moszner , Alfred Noels , Lionel Delaude , Anna Maj
发明人： Norbert Moszner , Alfred Noels , Lionel Delaude , Anna Maj
IPC分类号： C08F4/80
CPC分类号： A61K6/083 , A61K6/0023 , C08G61/06 , C08L23/16
摘要： Dental material being polymerizable by ring-opening metathesis polymerization comprising (i) at lest one ruthenium complex bearing at least one N-heterocyclic carbene ligand or precursors which generate a ruthenium complex bearing at least one N-heterocyclic carbene ligand in situ; and (ii) at least one cyclic olefin capable of metathesis.

74. 发明申请

US20050159510A1 Dental materials based on ROMP composites 失效
标题翻译：基于ROMP复合材料的牙科材料
公开(公告)号：US20050159510A1
公开(公告)日：2005-07-21
申请号：US10934904
申请日：2004-09-03
申请人： Sonja Smolak , Franz Stelzer , Norbert Moszner , Volker Rheinberger
发明人： Sonja Smolak , Franz Stelzer , Norbert Moszner , Volker Rheinberger
IPC分类号： A61K6/02 , A61K6/027 , A61K6/083 , A61K6/087 , C08G61/00 , C08G61/08 , C08K9/04 , C08K9/12 , C08L65/00 , C08K9/00
CPC分类号： A61K6/083 , C08G61/08 , C08L101/005
摘要： The invention relates to compositions, polymerizable by ring-opening metathesis, which contain (a) at least one monomer and/or oligomer which is polymerizable by ring-opening metathesis polymerization, (b) at least one filler and (c) at least one initiator for the ring-opening metathesis polymerization. The compositions are characterized in that the initiator is chemically or physically bound to the filler.
摘要翻译：本发明涉及通过开环复分解可聚合的组合物，其含有（a）至少一种通过开环易位聚合可聚合的单体和/或低聚物，（b）至少一种填料和（c）至少一种引发剂用于开环易位聚合。组合物的特征在于引发剂与填料化学或物理结合。

75. 发明授权

US06713555B2 Hydrolyzable and polymerizable silanes based on methylene dithiepane 有权
标题翻译：基于亚甲基二硫杂环丁烷的可水解和可聚合硅烷
公开(公告)号：US06713555B2
公开(公告)日：2004-03-30
申请号：US10260069
申请日：2002-09-27
申请人： Norbert Moszner , Sabine Stein , Thomas Völkel , Volker Rheinberger
发明人： Norbert Moszner , Sabine Stein , Thomas Völkel , Volker Rheinberger
IPC分类号： C08L8308
CPC分类号： C07F7/1804
摘要： Methylene dithiepane silanes according to Formula I in which R1 is a saturated or unsaturated aliphatic or alicyclic hydrocarbon radical with 1 to 10 carbon atoms, which can be interrupted by one or more oxygen and/or sulphur atoms and can contain one or more ester, carbonyl, amide and/or urethane groups, or is an aromatic or heteroaromatic hydrocarbon radical with 6 to 18 carbon atoms, the hydrocarbon radicals being able to be substituted or unsubstituted; R2 has one of the meanings given for R1 or is absent; R3 has one of the meanings given for R1 or is absent; R4 is equal to —(CHR6)n—, —Y—CO—NH—(CHR6)n—, —Y—CO—NH—R5—, —(CHR6)n—S—R5—, —S—R5—, —CO—O—R5— or is absent, with n being equal to 1 to 4, R6 is hydrogen, C1 to C10 alkyl or C6 to C10 aryl, R5 has one of the meanings given for R1 and Y stands for an O or S atom or is absent; with R5 and R6 being able to be substituted or unsubstituted; X is a hydrolyzable group; a, b, c and x each independently of each other being 1, 2 or 3; and the sum of a+x=2 to 4. The silanes are particularly suitable for the preparation of dental materials.
摘要翻译：具有式Iin的亚甲基二噻吩烷硅烷，其中R 1是具有1至10个碳原子的饱和或不饱和脂族或脂环族烃基，其可被一个或多个氧和/或硫原子间隔并且可含有一个或多个酯，羰基，酰胺和/或氨基甲酸酯基团，或是具有6至18个碳原子的芳族或杂芳族烃基，所述烃基能够被取代或未取代; R 2具有R 1给出的含义之一或不存在; R 3具有R 1给出的含义之一或不存在; R 4等于 - （CHR 6）n - ， - O-CO-NH-（CHR 6）n-，-Y-CO-NH-R 5 - ， - （CHR < 6））nSR 5 - ， - SR 5 - ， - CO-OR 5 - 或不存在，n等于1至4，R 6是氢，C 1至C 10烷基或C 6 对于C 10芳基，R 5具有对R 1给出的含义之一，Y表示O或S原子或不存在; 其中R 5和R 6能够被取代或未取代; X是可水解基团; a，b，c和x各自独立地为1,2或3; 并且a + x = 2至4的总和。硅烷特别适用于制备牙科材料。

76. 发明授权

US06569917B1 Dental materials based on polysiloxanes 失效
标题翻译：基于聚硅氧烷的牙科材料
公开(公告)号：US06569917B1
公开(公告)日：2003-05-27
申请号：US09488489
申请日：2000-01-20
申请人： Norbert Moszner , Thomas Völkel , Sabine Stein , Volkner Rheinberger
发明人： Norbert Moszner , Thomas Völkel , Sabine Stein , Volkner Rheinberger
IPC分类号： A16F200
CPC分类号： A61K6/0023 , A61K6/083 , A61K6/093 , C08L51/085 , C08L83/12
摘要： The invention relates to dental materials which contain at least one polysiloxane based on one or several silanes according to formula (I) [(Wq—R6—Z)p—R3]mY—R2—SiXnR13−n Formula (I) in which X stands for a halogen atom, a hydroxyl, alkoxy and/or acyloxy group; n is equal to 1 to 3, R1 stands for an alkyl, alkenyl, aryl, alkylaryl, arylalkyl group; R2 stands for an alkylene group; R3 stands for a p-time substituted, straight, branched or cyclic, saturated or unsaturated, aromatic or aliphatic organic radical with 2 to 40 carbon atoms and optionally 1 to 6 heteroatoms; R6 stands for a q-times substituted, straight, branched or cyclic organic radical with 1 to 20 carbon atoms or is absent; p is equal to 1 to 6; q is equal to 1 to 6; Y stands for —NR4—, N or —(C═O)—NH—; m is equal to 2 for Y═N and equal to 1 for Y═—NR4—, or —(C═O)—NH—; R4 stands for an alkyl or aryl group; Z stands for O, S, —(C═O)—O—, —(C═O)—NH—, —O—(C═O)—NH— or is absent; W stands for CH2═CR5—(C═O)—O—; and R5 stands for a hydrogen atom or an alkyl group and optionally one or several further hydrolytically condensable compounds of silicon, aluminium, zirconium, titanium, boron, tin, vanadium and/or phosphorus.
摘要翻译：本发明涉及含有至少一种基于一种或几种根据式（I）的硅烷的聚硅氧烷的牙科材料，其中X代表卤素原子，羟基，烷氧基和/或酰氧基; n等于1至3，R1代表烷基，烯基，芳基，烷基芳基，芳基烷基; R2表示亚烷基; R3表示具有2至40个碳原子和任选1至6个杂原子的p时间取代的，直链，支链或环状饱和或不饱和的芳族或脂族有机基团; R6代表具有1至20个碳原子的q次取代的，直链，支链或环状的有机基团或不存在; p等于1至6; q等于1至6; Y代表-NR4-，N或 - （C = O）-NH-; 对于Y = N，m等于2，Y = -NR4-等于1，或 - （C = O）-NH-; R4代表烷基或芳基; Z代表O，S， - （C = O）-O-， - （C = O）-NH-，-O-（C = O）-NH-或不存在; W代表CH 2 = CR 5 - （C = O）-O-; R5代表氢原子或烷基，以及任选的一种或几种其它可水解缩合的硅，铝，锆，钛，硼，锡，钒和/或磷的化合物。

77. 发明授权

US5733968A Multi-component dental cement based on calcium hydroxide 失效
标题翻译：基于氢氧化钙的多组分牙科水泥
公开(公告)号：US5733968A
公开(公告)日：1998-03-31
申请号：US746157
申请日：1996-11-06
申请人： Norbert Moszner , Ulrich Salz , Volker Rheinberger
发明人： Norbert Moszner , Ulrich Salz , Volker Rheinberger
IPC分类号： A61K6/083 , C08J3/00 , C08F4/44 , C08K3/08 , C08L23/00
CPC分类号： A61K6/083
摘要： The invention relates to a multi-component dental cement which contains as a first component an ethylenically unsaturated polymerisable compound, as a second component calcium hydroxide, calcium oxide or a precursor thereof and also a polymerisation initiator, the constituents of which can be contained in one or more cement components, which is characterized in that the ethylenically unsaturated polymerisable compound has both at least one .beta.-dicarbonyl group and also at least one acrylic, alkacrylic or vinyl aromatic group. Also included are a process for the production of a multi-component dental cement and the use of the described polymerisable .beta.-dicarbonyl compounds in calcium hydroxide dental cements.
摘要翻译：本发明涉及一种多组分牙科粘固剂，其包含作为第一组分的烯属不饱和可聚合化合物，作为第二组分氢氧化钙，氧化钙或其前体，以及聚合引发剂，其组分可以包含在一种或更多的水泥组分，其特征在于烯属不饱和可聚合化合物具有至少一个β-二羰基和至少一个丙烯酸，丙烯酸或乙烯基芳族基团。还包括用于生产多组分牙科粘固剂的方法以及所述可聚合的β-二羰基化合物在氢氧化钙牙科用水泥中的用途。

78. 发明授权

US08404760B2 Filled dental material based on polymerizable dihydroxy-phenylalanine derivatives 有权
标题翻译：基于可聚合二羟基 - 苯丙氨酸衍生物的填充牙科材料
公开(公告)号：US08404760B2
公开(公告)日：2013-03-26
申请号：US12889481
申请日：2010-09-24
申请人： Norbert Moszner , Jörg Angermann , Urs Karl Fisher , Volker Rheinberger
发明人： Norbert Moszner , Jörg Angermann , Urs Karl Fisher , Volker Rheinberger
IPC分类号： A61K6/083
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/09 , C08L33/00 , C08L75/16
摘要： Polymerizable dental material which contains (a) at least one radically polymerizable compound according to the general formula I (b) initiators for radical polymerization; and (c) filler.
摘要翻译：含有（a）至少一种根据通式I（b）的自由基聚合性化合物的可聚合牙科材料用于自由基聚合; 和（c）填料。

79. 发明授权

US07927538B2 Light-curing slips for the stereolithographic preparation of dental ceramics 有权
标题翻译：用于牙科陶瓷立体光刻制备的光固化片
公开(公告)号：US07927538B2
公开(公告)日：2011-04-19
申请号：US12394452
申请日：2009-02-27
申请人： Norbert Moszner , Wolfgang Wachter , Christoph Appert , Volker M. Rheinberger , Robert Liska , Jurgen Stampfl , Johannes Patzer
发明人： Norbert Moszner , Wolfgang Wachter , Christoph Appert , Volker M. Rheinberger , Robert Liska , Jurgen Stampfl , Johannes Patzer
IPC分类号： A61K6/00 , A61C5/00 , C08K9/00 , C08K3/22 , G03F7/00 , B29C35/04
CPC分类号： A61L27/46 , A61C13/0013 , A61K6/0215 , A61K6/024 , A61K6/025 , A61K6/0273 , B33Y70/00 , B33Y80/00 , C04B35/111 , C04B35/486 , C04B35/6263 , C04B35/6264 , C04B35/632 , C04B35/63488 , C04B35/638 , C04B2235/3224 , C04B2235/3225 , C04B2235/3246 , C04B2235/3262 , C04B2235/3272 , C04B2235/3287 , C04B2235/441 , C04B2235/449 , C04B2235/6026 , C04B2235/6562 , C04B2235/77 , C04B2235/96 , C04B2235/9661 , G03F7/0037 , G03F7/0047 , G03F7/027
摘要： Slip based on a polyreactive binder, polymerization initiator and filler, which contains (A) 5-65 wt.-% polymerizable binder, (B) 0.001-1.0 wt.-% photoinitiator and (C) 35-90 wt.-% surface-modified ceramic and/or glass ceramic particles relative to the overall mass of the slip, and process for the preparation of ceramic mouldings by rapid prototyping processes using the slip.
摘要翻译：基于聚反应性粘合剂，聚合引发剂和填料，其含有（A）5-65重量％可聚合粘合剂，（B）0.001-1.0重量％光引发剂和（C）35-90重量％表面改性的陶瓷和/或玻璃陶瓷颗粒相对于滑移的总体质量，以及通过使用滑移的快速成型方法制备陶瓷模制品的方法。

80. 发明授权

US06939489B2 Desktop process for producing dental products by means of 3-dimensional plotting 有权
标题翻译：通过三维绘图生产牙科产品的桌面工艺
公开(公告)号：US06939489B2
公开(公告)日：2005-09-06
申请号：US10107526
申请日：2002-03-25
申请人： Norbert Moszner , Armin Burgath , Rolf Mulhaupt , Ulrich Salz , Volker Rheinberger , Rudiger Landers
发明人： Norbert Moszner , Armin Burgath , Rolf Mulhaupt , Ulrich Salz , Volker Rheinberger , Rudiger Landers
IPC分类号： A61C13/00 , A61C19/00 , A61K6/083 , B29C67/00 , A61C13/20 , B29C35/08 , B29C41/02 , B29C41/22
CPC分类号： A61K6/083 , A61C13/0004 , A61C13/0019 , A61C19/003 , B29C64/165 , B29L2031/7536 , B33Y80/00 , C08L33/00 , C08L25/04
摘要： A process for fabricating dental form pieces for dental restoration and replacement parts is provided and includes the step of applying a material, on a firm support or a fluid medium, by a three dimensional plotting technology in a layer by layer manner. The material has micro cords and/or micro drops which include at least one of a meltable, polymerizable, polycondensable, and polyaddable constituent element that is an unfilled monomer, a reinforced monomer, oligomer, polymer, or a ceramic element. The process also includes the step of hardening the applied material by cooling of the material, chemical reaction, polymerization with thermal handling, or polymerization by irradiation of the material with UV or visible light.
摘要翻译：提供了一种用于制造用于牙科修复和更换部件的牙形片的方法，并且包括通过三维绘图技术逐层施加材料在坚固的支撑物或流体介质上的步骤。所述材料具有微丝和/或微滴，其包括作为未填充单体，增强单体，低聚物，聚合物或陶瓷元素的可熔化，可聚合，可缩聚和可共聚的构成元素中的至少一种。该方法还包括通过材料的冷却，化学反应，热处理聚合或用UV或可见光照射材料进行聚合来硬化所施加的材料的步骤。

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