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    • 72. 发明授权
    • Additive approach to ballistic and slag melting point control of
azide-based gas generant compositions
    • 基于叠氮化物气体发生剂组合物的弹道和炉渣熔点控制的添加剂方法
    • US5387296A
    • 1995-02-07
    • US926119
    • 1992-08-05
    • Robert D. TaylorLewis R. Huntsman
    • Robert D. TaylorLewis R. Huntsman
    • C05D5/00B60R21/26C06B35/00C06D5/00C06D5/06
    • C06B35/00C06D5/06
    • Gas generant pyrotechnic compositions especially suitable for inflating vehicle occupant restraint systems with nitrogen gas are described. The compositions are comprised (in wt. %) of about 65-74% of an azide, preferably sodium azide; about 17-29.5% of iron oxide, preferably ferric oxide; and about 1.0-6% metal nitrite or nitrate co-oxidizer, preferably sodium nitrate; to which base composition is added about 0.5-8% silica, alumina, titania or mixtures thereof; up to 6% bentonite and up to 4% molybdenum disulfide. Preferred driver and passenger side formulations are disclosed. The compositions burn from about 0.8 to 1.5 inches per second, have excellent slag and clinker properties, as well as excellent aging and mechanical strength characteristics when formed into cylindrical pellets or wafers. The formulation ingredients are amenable to water slurry mixing, spray drying and machine pressing into cylindrical pellets or wafers for insertion into a suitable gas generating device.
    • 描述了特别适合用于充气具有氮气的车辆乘员约束系统的气体发生器烟火组合物。 组合物包含(重量%)约65-74%的叠氮化物,优选叠氮化钠; 约17-29.5%的氧化铁,优选氧化铁; 和约1.0-6%的金属亚硝酸盐或硝酸盐共氧化剂,优选硝酸钠; 向其中加入约0.5-8%二氧化硅,氧化铝,二氧化钛或其混合物的基础组合物; 高达6%的膨润土和高达4%的二硫化钼。 公开了优选的驾驶员和乘客侧配方。 组合物每秒钟燃烧约0.8至1.5英寸,具有优异的炉渣和熟料性能,以及当形成圆柱形丸粒或晶片时具有优异的老化和机械强度特性。 制剂成分适于将水浆料混合,喷雾干燥和机械压制成圆柱形丸粒或晶片以插入合适的气体发生装置中。
    • 73. 发明授权
    • Additive approach to ballistic and slag melting point control of
azide-based gas generant compositions
    • 基于叠氮化物气体发生剂组合物的弹道和炉渣熔点控制的添加剂方法
    • US5143567A
    • 1992-09-01
    • US749032
    • 1991-08-23
    • Robert D. TaylorLewis R. Huntsman
    • Robert D. TaylorLewis R. Huntsman
    • C06B35/00C06D5/06
    • C06B35/00C06D5/06
    • Gas generant pyrotechnic compositions especially suitable for inflating vehicle occupant restraint systems with nitrogen gas are described. The compositions are comprised (in wt. %) of about 65-74% of an azide, preferably sodium azide; about 17-25% of iron oxide, preferably ferric oxide; and about 3.5-6% metal nitrite or nitrate co-oxidizer, preferably sodium nitrate; to which base composition is added about 2.5-8% silica, alumina, titania or mixtures thereof, up to 6% bentonite and up to 4% molybdenum disulfide. Preferred driver and passenger side formulations are disclosed.The compositions burn from about 1.0 to 1.5 inches per second, have excellent slag and clinker properties, as well as excellent aging and mechanical strength characteristics when formed into cylindrical pellets or wafers.The formulation ingredients are amenable to water slurry mixing, spray drying and machine pressing into cylindrical pellets or wafers for insertion into a suitable gas generating device.
    • 描述了特别适合用于充气具有氮气的车辆乘员约束系统的气体发生器烟火组合物。 组合物包含(重量%)约65-74%的叠氮化物,优选叠氮化钠; 约17-25%的氧化铁,优选氧化铁; 和约3.5-6%的金属亚硝酸盐或硝酸盐共氧化剂,优选硝酸钠; 向其中加入约2.5-8%二氧化硅,氧化铝,二氧化钛或其混合物,至多6%的膨润土和至多4%的二硫化钼。 公开了优选的驾驶员和乘客侧配方。 组合物每秒燃烧约1.0至1.5英寸,具有优异的炉渣和熟料性能,以及当形成圆柱形丸粒或晶片时具有优异的老化和机械强度特性。 制剂成分适于将水浆料混合,喷雾干燥和机械压制成圆柱形丸粒或晶片以插入合适的气体发生装置中。