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71. 发明授权

US08138365B2 Method for producing organosilanes 有权
标题翻译：生产有机硅烷的方法
公开(公告)号：US08138365B2
公开(公告)日：2012-03-20
申请号：US12310549
申请日：2007-06-11
申请人： Karsten Korth , Philipp Albert , Susann Witzsche , Ingo Kiefer , Jörg Kiefer , Stefan Lotter , Jaroslaw Monkiewicz , Jörg Schmidt
发明人： Karsten Korth , Philipp Albert , Susann Witzsche , Ingo Kiefer , Jörg Kiefer , Stefan Lotter , Jaroslaw Monkiewicz , Jörg Schmidt
IPC分类号： C07F7/00 , C07F7/04
CPC分类号： C07F7/1892
摘要： The invention relates to a method for producing organosilanes of general formula I, [R(R)(R′O)Si—R″—]2Sm I by reaction of (halo-organo)alkoxysilanes of formula II, [R(R)(R′O)Si—R″-Hal II with a sulfuring reagent, selected from alkaline hydrogensulfide, alkaline sulfide Me2S, alkaline polysulfide Me2Sg and any combination thereof and optionally additionally with sulfur and/or with H2S in a solvent, the alkaline hydroxy content of all materials used being
摘要翻译：本发明涉及通过式II的（卤代 - 有机）烷氧基硅烷与[R（R）（R'O）Si-R“ - ] 2SmI的有机硅烷的制备方法[ （R'O）Si-R“-Hal II与硫化试剂，选自碱式硫化氢，碱式硫化物Me2S，碱性多硫化物Me2Sg及其任何组合，任选地另外含有硫和/或与硫化氢在溶剂中，碱性羟基使用的所有材料的含量<0.44wt。％。

72. 发明授权

US08119730B2 Silane formulation with high filler content 失效
标题翻译：硅烷配方，填料含量高
公开(公告)号：US08119730B2
公开(公告)日：2012-02-21
申请号：US10563022
申请日：2004-05-14
申请人： Roland Edelmann , Björn Borup , Christian Wassmer , Jaroslaw Monkiewicz
发明人： Roland Edelmann , Björn Borup , Christian Wassmer , Jaroslaw Monkiewicz
IPC分类号： C08L83/00
CPC分类号： C08K5/5415 , B82Y30/00 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/22 , C08K3/22 , C08K5/09 , C09C1/3081 , C09C1/3684 , C09C1/407 , C09D183/04
摘要： A formulation containing: (i) at least one organoalkoxysilane and/or at least one organoalkoxysiloxane; (ii) at least one inorganic oxidic powder; and (iii), optionally, an organic or inorganic acid is provided. The formulation contains from 5 to 50% of the inorganic oxide powder and has a viscosity of less than 1500 mPa·s. A weight ratio of the organoalkoxysilane and/or at least one organoalkoxysiloxane to the inorganic oxidic powder is from 19:1 to 1:1.
摘要翻译：一种制剂，其含有：（i）至少一种有机烷氧基硅烷和/或至少一种有机烷氧基硅氧烷; （ii）至少一种无机氧化粉末; 和（iii）任选地提供有机或无机酸。该制剂含有5至50％的无机氧化物粉末，其粘度小于1500mPa·s。有机烷氧基硅烷和/或至少一种有机烷氧基硅氧烷与无机氧化物粉末的重量比为19:1至1:1。

73. 发明授权

US07026398B2 Air-drying silane coating compositions 失效
标题翻译：风干硅烷涂料组合物
公开(公告)号：US07026398B2
公开(公告)日：2006-04-11
申请号：US10393067
申请日：2003-03-21
申请人： Jaroslaw Monkiewicz , Roland Edelmann , Andrea Edinger , Bjoern Borup
发明人： Jaroslaw Monkiewicz , Roland Edelmann , Andrea Edinger , Bjoern Borup
IPC分类号： C08L83/08
CPC分类号： C09D163/00 , C08K3/36 , C08K5/5415 , C08K2201/014 , C09D133/02 , Y10T428/31663 , C08L2666/28 , C08L2666/22
摘要： The present invention relates to an air-drying silane coating composition containing an epoxy or acrylic resin, an optional silicic ester or alkyl silicate, an aminoalkylsilane component, an optional organoalkyoxysilane, and possible auxiliaries; methods of use thereof, and articles and substrates coated accordingly.
摘要翻译：本发明涉及包含环氧树脂或丙烯酸树脂，任选的硅酸酯或烷基硅酸盐，氨基烷基硅烷组分，任选的有机烷氧基硅烷和可能的助剂的空气干燥硅烷涂料组合物; 使用方法，以及相应地涂覆的制品和基材。

74. 发明授权

US06689468B2 Organosilicon nanocapsules 失效
标题翻译：有机硅纳米胶囊
公开(公告)号：US06689468B2
公开(公告)日：2004-02-10
申请号：US09971146
申请日：2001-10-05
申请人： Roland Edelmann , Jaroslaw Monkiewicz
发明人： Roland Edelmann , Jaroslaw Monkiewicz
IPC分类号： C08K900
CPC分类号： C09C3/006 , C01P2004/64 , C01P2006/12 , C08K9/06 , C09C1/3072 , C09C1/3081 , C09C1/309 , C09C3/10 , C09C3/12 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2996 , Y10T428/2998
摘要： The present invention provides an organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle including at least one oxide or mixed oxide, KA—O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R (Ia) wherein R is a linear, branched, cyclic or substituted alkyl group having from 1 to 50 carbon atoms; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA—O)—, SiO— or —Z; wherein remaining free valences of Si′ are each independently (KA—O)—, SiO—, —R, or —Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attatched thereto.
摘要翻译：本发明提供了一种有机硅纳米胶囊，其包括：纳米级芯A，其包括：至少一种包含至少一种选自包括主要基团的金属或半金属的金属或半金属的氧化物或混合氧化物KA-O的颗粒周期表的2至6，周期表的过渡组1至8，镧系元素及其混合物; 和有机硅壳B，其包括：至少一种具有式（Ia）的有机硅化合物：其中R是具有1至50个碳原子的直链，支链，环状或取代的烷基;其中x是0至20的数 ;其中Si的剩余游离价分别独立地为（KA-O） - ，SiO-或-Z;其中Si'的剩余游离价各自独立地为（KA-O） - ， - SiO-，-R或-Z; 其中Z各自独立地为羟基或烷氧基; 并且其中壳体B中的每个Si和Si'具有不多于一个R基团。

75. 发明授权

US5366658A Use of polymethylalkanes as biodegradable base oils in lubricants and functional fluids 失效
标题翻译：使用聚甲基烷烃作为润滑剂和功能液中的可生物降解基础油
公开(公告)号：US5366658A
公开(公告)日：1994-11-22
申请号：US179246
申请日：1994-01-10
申请人： Dirk Hoppe , Horst Pennewiss , Frank Kraushaar , Michael Stehr , Roland Streck , Jaroslaw Monkiewicz , Hans G. Wey
发明人： Dirk Hoppe , Horst Pennewiss , Frank Kraushaar , Michael Stehr , Roland Streck , Jaroslaw Monkiewicz , Hans G. Wey
IPC分类号： B01J31/14 , C07B61/00 , C07C2/38 , C07C5/03 , C07C9/22 , C08C19/02 , C08F8/04 , C08F8/50 , C08F136/20 , C08L101/16 , C10M105/04 , C10M107/00 , C10M107/06 , C10M107/16 , C10N30/00 , C10M107/04 , C10M105/32
CPC分类号： C08C19/02 , C08F136/20 , C08F8/04 , C10M105/04 , C10M107/00 , C10M107/06 , C10M107/16 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2205/00 , C10M2205/02 , C10M2205/0225 , C10M2205/0245 , C10N2220/02
摘要： The invention relates to the use of polymethylalkanes having terminal methyl groups and methylene and ethylidene groups of the formula I ##STR1## in which the total number of C atoms n+2 m+2 is 20 to 100 and the ratio of the methyl and methylene groups to the ethylidene groups is 3 to 20:1 and the ethylidene groups are always separated by at least one methylene group, as biodegradable base oils for lubricants and functional fluids. Suitable polymethylalkanes are obtained by oligomerization of .alpha.,.omega.-diolefins, for example in particular according to P 41 19 332.6, or by pyrolysis of ethene/propane copolymers and subsequent hydrogenation in each case. The polymethylalkanes can be combined with conventional additives and other degradable or non-degradable base oils.
摘要翻译：本发明涉及具有末端甲基的聚甲基烷基和式I“IMAGE”的亚甲基和亚乙基的用途，其中C原子n + 2m + 2的总数为20至100，甲基和亚甲基的比例亚乙基的基团为3至20:1，并且亚乙基总是通过至少一个亚甲基分离，作为用于润滑剂和功能流体的可生物降解的基础油。合适的聚甲基烷烃通过α，ω-二烯烃的低聚获得，特别是根据P 41 19 332.6，或通过乙烯/丙烷共聚物的热分解和随后的氢化在每种情况下。聚甲基烷烃可与常规添加剂和其它可降解或不可降解的基础油组合。

76. 发明授权

US5306856A Method of manufacturing methylidene-group-containing .alpha.,.omega.-unsaturated oligomers from .alpha.,.omega.-diolefins in the presence of organoaluminum compounds as catalysts 失效
标题翻译：在有机铝化合物作为催化剂存在下，从α，ω-二烯烃制备含亚甲基基团的α，ω-不饱和低聚物的方法
公开(公告)号：US5306856A
公开(公告)日：1994-04-26
申请号：US897388
申请日：1992-06-12
申请人： Roland Streck , Jaroslaw Monkiewicz , Hans G. Wey
发明人： Roland Streck , Jaroslaw Monkiewicz , Hans G. Wey
IPC分类号： B01J31/14 , C07B61/00 , C07C2/38 , C07C11/12 , C07C11/21 , C07C2/46
CPC分类号： C07C2/38 , C07C11/21 , C07C2531/14
摘要： A method of manufacturing methylidene-group-containing .alpha.,.omega.-unsaturated oligomers from .alpha.,.omega.-diolefins in the presence of a catalytic amount of organoaluminum compounds, wherein the .alpha.,.omega.-diolefins are reacted in the liquid phase, at 150.degree.-350.degree. C., and the organoaluminum compounds have formula AlX.sub.3 or AlX.sub.2 H, where X represents an aliphatic, alicyclic, or aromatic hydrocarbon group with 1-30 C atoms. The higher molecular weight hydrocarbons manufactured according to this method are substantially linear oligomers which contain reactive double bonds.
摘要翻译：一种在催化量的有机铝化合物存在下从α，ω-二烯烃制备含亚甲基基团的α，ω-不饱和低聚物的方法，其中α，ω-二烯烃在液相中在150℃反应， 350℃，有机铝化合物具有式AlX 3或AlX 2 H，其中X表示具有1-30个C原子的脂族，脂环族或芳族烃基。根据该方法制造的较高分子量烃是含有反应性双键的基本上为线性的低聚物。

77. 发明申请

US20130012691A1 Process for Preparing Silicon-Containing Azodicarbamides 有权
标题翻译：制备含硅偶氮二酰胺的方法
公开(公告)号：US20130012691A1
公开(公告)日：2013-01-10
申请号：US13580780
申请日：2011-03-15
申请人： Karsten Korth , Julia Keck , Susann Witzsche , Oliver Klockmann , Jaroslaw Monkiewicz , Christian Springer
发明人： Karsten Korth , Julia Keck , Susann Witzsche , Oliver Klockmann , Jaroslaw Monkiewicz , Christian Springer
IPC分类号： C07F7/18
CPC分类号： C07F7/1892
摘要： The invention relates to a process for preparing silicon-containing azodicarbamides of the general formula (I) (R1)3-a(R2)aSi—RI—NH—C(O)—N═N—C(O)—NH—RI—Si(R1)3-a(R2)a (I), by reaction of azobiscarboxy compounds of the general formula II R3—X1—C(O)—N═N—C(O)—X1—R4 (II) with aminosilanes of the general formula III (R1)3-a(R2)aSi—RI—NH2 (III).
摘要翻译：本发明涉及制备通式（I）（R1）3-a（R2）aSi-RI-NH-C（O）-N = N-C（O）-NH-的硅氧偶氮二酰胺的方法，通过使通式II的R 3 -X 1 -C（O）-N = N-C（O）-X 1 -R 4（II）的偶氮二羧基化合物反应，得到RI-Si（R 1）3-a（R 2）a ）与通式III（R1）3-a（R2）aSi-RI-NH2（III）的氨基硅烷反应。

78. 发明申请

US20120183464A1 PROCESS AND USE OF AMINO-FUNCTIONAL RESINS FOR DISMUTATING HALOSILANES AND FOR REMOVING EXTRANEOUS METALS 有权
标题翻译：氨基官能树脂用于分离HALOSILANES和去除超细金属的方法和用途
公开(公告)号：US20120183464A1
公开(公告)日：2012-07-19
申请号：US13383681
申请日：2010-05-18
申请人： Ekkehard Mueh , Hartwig Rauleder , Jaroslaw Monkiewicz , Reinhoid Schork
发明人： Ekkehard Mueh , Hartwig Rauleder , Jaroslaw Monkiewicz , Reinhoid Schork
IPC分类号： C01B33/107 , C08F212/36 , C01B33/029
CPC分类号： C01B33/107 , C01B33/10773 , C01B33/10784 , C01P2006/80
摘要： The invention relates to a process for dismutating at least one halosilane and reducing the content of extraneous metal and/or a compound containing extraneous metal in the at least one halosilane and in the at least one silane obtained, by contacting at least one halosilane of the general formula I, HnSiClm (I), where n and m are integers and n=1, 2 or 3 and m=1, 2 or 3 and n+m=4, with a particulate, organic, amino-functional resin to obtain at least one silane of the general formula II, HaSiClb (II), where a and b are integers and a=0, 2, 3 or 4 and b=0, 1, 2 or 4 where a+b=4, in one step, in which the content of extraneous metal and/or compounds containing extraneous metal has been reduced compared to the halosilane of the formula I. The invention further provides for the use of this resin for dismutating halosilanes and as an absorbent of extraneous metals or compounds containing extraneous metal in a process for preparing monosilane.
摘要翻译：本发明涉及一种用于将至少一种卤代硅烷和至少一种卤代硅烷中含有外来金属的化合物和/或含至少一种卤代硅烷的化合物和至少一种所得的硅烷中的至少一种卤代硅烷，通式I，HnSiClm（I），其中n和m为整数，n = 1,2或3，m = 1,2或3，n + m = 4，与颗粒状有机氨基官能树脂得到至少一种通式II的硅烷，其中a和b为整数，a = 0,2,3或4，b = 0,1,2或4，其中a + b = 4，一个步骤，其中与式I的卤代硅烷相比，含有外来金属的外来金属和/或化合物的含量已经降低。本发明还提供了用于分解卤代硅烷和作为外来金属或化合物的吸收剂的该树脂的用途在制备甲硅烷的方法中含有外来金属。

79. 发明申请

US20080283972A1 Silicon Compounds for Producing Sio2-Containing Insulating Layers on Chips 审中-公开
标题翻译：用于在芯片上生产含Sio2的绝缘层的硅化合物
公开(公告)号：US20080283972A1
公开(公告)日：2008-11-20
申请号：US10586675
申请日：2004-12-22
申请人： Ekkehard Muh , Hartwig Rauleder , Harald Klein , Jaroslaw Monkiewicz , Iordanis Savvopoulos
发明人： Ekkehard Muh , Hartwig Rauleder , Harald Klein , Jaroslaw Monkiewicz , Iordanis Savvopoulos
IPC分类号： H01L23/58 , H01L21/31
CPC分类号： C23C16/401 , H01L21/02164 , H01L21/02214 , H01L21/02216 , H01L21/02219 , H01L21/02222 , H01L21/02271 , H01L21/02282 , H01L21/31612
摘要： The present invention relates to a process for producing an SiO2-containing insulating layer on chips and the use of specific precursors for this purpose. The invention further relates to an insulating layer obtainable in this way and also to chips which have been provided with such an insulating layer.
摘要翻译：本发明涉及一种在芯片上制备含SiO 2的绝缘层的方法以及为此目的使用特定的前体。本发明还涉及以这种方式获得的绝缘层，还涉及已经设置有这种绝缘层的芯片。

80. 发明申请

US20070110906A1 Silane formulation with high filler content 失效
标题翻译：硅烷配方，填料含量高
公开(公告)号：US20070110906A1
公开(公告)日：2007-05-17
申请号：US10563022
申请日：2004-05-14
申请人： Roland Edelmann , Bjorn Borup , Christian Wassmer , Jaroslaw Monkiewicz
发明人： Roland Edelmann , Bjorn Borup , Christian Wassmer , Jaroslaw Monkiewicz
IPC分类号： B05D3/02
CPC分类号： C08K5/5415 , B82Y30/00 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/22 , C08K3/22 , C08K5/09 , C09C1/3081 , C09C1/3684 , C09C1/407 , C09D183/04
摘要： Me present invention relates to a formulation comprising (I) at least one organoalkoxysilane and/or at least one organoalkoxysiloxane and (ii) at least one inorganic oxidic powder and (iii), if desired, an organic or inorganic acid, component (ii) making up from 5 to 50% by weight of formulation, and the formulation having a viscosity of less than 1500 mPa·s. The present invention further relates to a process for preparing such formulations, and to their use.
摘要翻译：本发明涉及包含（I）至少一种有机烷氧基硅烷和/或至少一种有机烷氧基硅氧烷和（ii）至少一种无机氧化物粉末和（iii）如果需要的有机或无机酸，组分（ii）占制剂重量的5-50％，制剂的粘度小于1500mPa.s。本发明还涉及制备这些制剂的方法及其应用。

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