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71. 发明授权

US4822406A O-aryl-N'-(triazin-2-yl)-isourea herbicides 失效
标题翻译： O-（芳基-N' - （三嗪-2-基） - 异脲除草剂
公开(公告)号：US4822406A
公开(公告)日：1989-04-18
申请号：US105852
申请日：1987-10-07
申请人： Christa Fest , Hans-Jochem Riebel , Hans-Joachim Santel , Robert R. Schmidt , Robert H. Strang
发明人： Christa Fest , Hans-Jochem Riebel , Hans-Joachim Santel , Robert R. Schmidt , Robert H. Strang
IPC分类号： C07D251/16 , A01N47/42 , C07D251/18 , C07D251/22 , C07D251/46 , C07D521/00 , A01N43/66 , A01N43/68 , C07D251/52
CPC分类号： C07D521/00 , A01N47/42
摘要： An O-aryl-N'-(triazin-2-yl)-isourea of the formula ##STR1## in which R.sup.1 represents the radical ##STR2## wherein R.sup.5 represents trifluoromethoxy, difluoromethoxy, phenyl, phenoxy, trifluoromethylthio, difluoromethylthio, di-(C.sub.1 -C.sub.4 -alkyl)-aminocarbonyl, C.sub.1 -C.sub.4 -alkylsulphonyl, C.sub.1 -C.sub.4 - alkoxyaminosulphonyl, N-(C.sub.1 -C.sub.4 -alkoxy)-N-(C.sub.1 -C.sub.4 -alkyl)-aminosulphonyl, C.sub.1 -C.sub.4 -alkylaminosulphonyl or di-(C.sub.1 -C.sub.4-alkyl)-aminosulphonyl,or whereinR.sup.1 represents the radical ##STR3## wherein R.sup.6 represents hydrogen or C.sub.1 -C.sub.4 -alkyl andR.sup.7 and R.sup.8 are identical or different and represent hydrogen, fluorine, chlorine, bromine, nitro, cyano, C.sub.1 -C.sub.4 -alkyl (which is optionally substituted by fluorine and /or chlorine), C.sub.1 -C.sub.4 -alkoxy (which is optionally substituted by fluorine and/or chlorine), carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkylsulphonyl or di-(C.sub.1 -C.sub.4 -alkyl)-aminosulphonyl;R.sup.2 represents optionally substituted aryl,R.sup.3 represents hydrogen, halogen, hydroxyl, C.sub.1 -C.sub.6 -alkylamino or di-(C.sub.1 -C.sub.6 -alkyl)-amino, or represents optionally substituted C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio andR.sup.4 respresents hydrogen, halogen or hydroxyl, or represents optionally substituted C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio, or represents C.sub.1 -C.sub.6 -alkylamino or di-(C.sub.1 -C.sub.6 -alkyl)-amino.
摘要翻译：其中R 1表示基团的O-芳基-N' - （三嗪-2-基） - 异脲，其中R 5表示三氟甲氧基，二氟甲氧基，苯基，苯氧基，三氟甲硫基，二氟甲硫基，二（ C 1 -C 4 - 烷基） - 氨基羰基，C 1 -C 4 - 烷基磺酰基，C 1 -C 4 - 烷氧基氨基磺酰基，N-（C 1 -C 4 - 烷氧基）-N-（C 1 -C 4 - 烷基） - 氨基磺酰基，C 1 -C 4烷基氨基磺酰基或二 - （C 1 -C 4 - 烷基） - 氨基磺酰基，或其中R 1表示基团，其中R 6表示氢或C 1 -C 4烷基，R 7和R 8相同或不同，表示氢，氟，氯，溴，硝基，氰基，C 1 -C 4 - 烷基（其任选被氟和/或氯取代），C 1 -C 4 - 烷氧基（其任选被氟和/或氯取代），羧基，C 1 -C 4 - 烷氧基羰基，C 1 -C 4 - 烷基磺酰基或二（C 1 -C 4 - 烷基） - 氨基磺酰基; R 2表示任选取代的芳基，R 3表示氢，卤素，羟基，C 1 -C 6 - 烷基氨基或二 - （C 1 -C 6 - 烷基） - 氨基，或表示任选取代的C 1 -C 6烷基，C 1 -C 6 - C 1 -C 6 - 烷硫基和R 4表示氢，卤素或羟基，或表示任选取代的C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基或C 1 -C 6 - 烷硫基，或表示C 1 -C 6烷基氨基或二 - （C 1 -C 6 - ） - 氨基。

72. 发明授权

US5086177A Preparation of oxyguanidines 失效
标题翻译：氧化剂的制备
公开(公告)号：US5086177A
公开(公告)日：1992-02-04
申请号：US517985
申请日：1990-05-24
申请人： Hans-Jochem Riebel , Klaus-Helmut Muller
发明人： Hans-Jochem Riebel , Klaus-Helmut Muller
IPC分类号： C07D251/42 , C07D213/74 , C07D213/75 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/38 , C07D251/44 , C07D251/46 , C07D251/50 , C07D251/52 , C07D251/70 , C07D253/04 , C07D253/06 , C07D257/08
CPC分类号： C07D239/42 , C07D239/47 , C07D239/52 , C07D251/16 , C07D251/46
摘要： A process for the preparation of an oxyguanidine of the formula ##STR1## in which R.sup.1 is an organic radical,R.sup.2, R.sup.3 each is hydrogen or an organic or inorganic substituent,X is N or CH,Y is N or CR.sup.3, andZ is N or CR.sup.4,comprising reacting ##STR2## in which R.sup.5 is optionally substituted alkyl or aralkyl, or its hydrogen halide, with a hydroxylamine derivative of the formulaH.sub.2 N--O--R.sup.1 (III)at a temperature between about 0.degree. C. and 150.degree. C. New isothioureas of the formula ##STR3## are also shown.

73. 发明授权

US5968873A Selective herbicides based on 4-amino-5-(1-methyl-ethyl)-2-(1,1-dimethylethylaminocarbonyl)-2,4-dihydr o-3H-1,2,4-triazol-3-one 失效
标题翻译：基于4-氨基-5-（1-甲基 - 乙基）-2-（1,1-二甲基乙基氨基羰基）-2,4-二氢-3H-1,2,4-三唑-3-酮的选择性除草剂
公开(公告)号：US5968873A
公开(公告)日：1999-10-19
申请号：US917026
申请日：1997-08-22
申请人： Peter Dahmen , Wolfgang Thielert , Klaus-Helmut Muller , Hans-Jochem Riebel
发明人： Peter Dahmen , Wolfgang Thielert , Klaus-Helmut Muller , Hans-Jochem Riebel
IPC分类号： A01N47/38 , A01N43/653
CPC分类号： A01N47/38
摘要： The invention relates to novel herbicidal synergistic active compound combinations comprising, on the one hand, 4-amino-5-(1-methyl-ethyl)-2-(1,1-dimethyl-ethylaminocarbonyl)-2,4-dihydro-3H-1,2,4-triazol-3-one and, on the other hand, known herbicidally active compounds, which can be used particularly successfully for selectively controlling weeds in a variety of crops, in particular in maize and wheat cultures.
摘要翻译：本发明涉及新型除草协同活性化合物组合，其一方面包括4-氨基-5-（1-甲基 - 乙基）-2-（1,1-二甲基 - 乙基氨基羰基）-2,4-二氢-3H 1,2,4-三唑-3-酮，另一方面是已知的除草活性化合物，其可以特别成功地用于选择性地控制各种作物，特别是玉米和小麦培养物中的杂草。

74. 发明授权

US4980469A Preparation of oxyguanidines 失效
标题翻译：氧基胍的制备
公开(公告)号：US4980469A
公开(公告)日：1990-12-25
申请号：US400916
申请日：1989-08-30
申请人： Hans-Jochem Riebel , Klaus-Helmut Muller
发明人： Hans-Jochem Riebel , Klaus-Helmut Muller
IPC分类号： C07D251/42 , C07D213/74 , C07D213/75 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/38 , C07D251/44 , C07D251/46 , C07D251/50 , C07D251/52 , C07D251/70 , C07D253/04 , C07D253/06 , C07D257/08
CPC分类号： C07D239/42 , C07D239/47 , C07D239/52 , C07D251/16 , C07D251/46
摘要： A process for the preparation of an oxyguanidine of the formula ##STR1## in which R.sup.1 is an organic radical,R.sup.2, R.sup.3 and R.sup.4 each is hydrogen or an organic or inorganic substituent,X is N or CH,Y is N or CR.sup.3, andZ is N or CR.sup.4,comprising reacting ##STR2## in which R.sup.5 is optionally substituted alkyl or aralkyl, or its hydrogen halide, with a hydroxylamine derivative of the formulaH.sub.2 N--O--R.sup.1 (III) at a temperature between about 0.degree. C. and 150.degree. C. New isothioureas of the formula ##STR3## are also shown.
摘要翻译：制备式（I）的氧基胍的方法，其中R 1是有机基团，R 2，R 3和R 4各自是氢或有机或无机取代基，X是N或CH，Y是N或 CR 3和Z是N或CR 4，包括其中R 5是任选取代的烷基或芳烷基或其卤化氢的式（II）与式H2N-O-R1（III）的羟胺衍生物在温度在约0℃至150℃之间。还显示了新的式（IIa）的异硫脲。

75. 发明授权

US06358886B1 6-Substituted 2,4-diamino-1,3,5-triazine derivatives having at least two asymmetrically substituted carbon atoms, the production thereof, and their use as herbicides 失效
标题翻译：具有至少两个不对称取代的碳原子的6-取代的2,4-二氨基-1,3,5-三嗪衍生物，其制备及其作为除草剂的用途
公开(公告)号：US06358886B1
公开(公告)日：2002-03-19
申请号：US09623612
申请日：2000-11-03
申请人： Hans-Jochem Riebel , Stefan Lehr , Katharina Voigt , Markus Dollinger , Mark Wilhelm Drewes , Ingo Wetcholowsky , Randy Allen Myers , Yukiyoshi Watanabe , Toshio Goto
发明人： Hans-Jochem Riebel , Stefan Lehr , Katharina Voigt , Markus Dollinger , Mark Wilhelm Drewes , Ingo Wetcholowsky , Randy Allen Myers , Yukiyoshi Watanabe , Toshio Goto
IPC分类号： C07D25118
CPC分类号： C07D405/12 , A01N43/68 , C07D251/48 , C07D409/12
摘要： The invention relates to novel substituted optically active aminotriazines having at least two asymmetrically substituted carbon atoms of the formula (I), in which A represents a single bond or represents in each case straight-chain or branched alkanediyl or oxaalkanediyl having in each case up to 6 carbon atoms, Z represents certain carbocyclic or heterocyclic radicals and the substituents R1, R2, R3, R4 and Y are as defined in the description, with the proviso that in each individual case R2, R3 and Y are different from one another and that the substituents at the two carbon atoms to which R2 and R3 or R4 are attached are configured as follows: (a) R configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“R,R-diastereomers”), (b) R configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“R,S-diastereomers”), (c) S configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“S,R-diastereomers”), (d) S configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“S,S-diastereomers”), (e) R configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“R,racdiastereomers”), (f) S configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“S,rac-diastereomers”), and to a process for preparing the compounds of the formula (I) and to their use as herbicides.
摘要翻译：本发明涉及具有式（I）的至少两个不对称取代的碳原子的新的取代的光学活性氨基三嗪，其中A表示单键或表示在每种情况下为直链或支链烷二基或氧杂烷二基，在每种情况下最多为6 碳原子，Z表示某些碳环或杂环基团，并且取代基R 1，R 2，R 3，R 4和Y如说明书中所定义，条件是在各个别情况下，R 2，R 3和Y彼此不同， R2和R3或R4连接的两个碳原子上的取代基配置如下：（a）R 2和R 3连接的碳原子上的R构型，R 4连接的碳原子上的R构型（“ R，R非对映异构体“），（b）R 2和R 3连接的碳原子上的R构型，R 4连接的碳原子上的S构型（”R，S-非对映异构体“），（c）S 配置在碳ato m与R 2相连的碳原子上的R构型（“S，R-非对映异构体”），（d）在R2和R3所连接的碳原子上的S构型， R 4连接的碳原子（“S，S-非对映异构体”），（e）R 2和R 3所连接的碳原子上的R构型，R 4连接的碳原子上的外消旋构型（“R” 外消旋异构体“），（f）R 2和R 3所连接的碳原子上的S构型以及与R4连接的碳原子上的外消旋构型（”S，外消旋 - 非对映体“），以及制备该化合物的方法的式（I）和它们作为除草剂的用途。

76. 发明授权

US06403794B2 Substituted 2-amino-4-alkylamino-1,3,5-triazines as herbicides 失效
公开(公告)号：US06403794B2
公开(公告)日：2002-06-11
申请号：US09827228
申请日：2001-04-05
申请人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Yukiyoshi Watanabe , Markus Dollinger
发明人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Yukiyoshi Watanabe , Markus Dollinger
IPC分类号： C07C27912
CPC分类号： C07D401/12 , A01N43/68 , A01N43/70 , C07D251/18 , C07D403/12 , C07D409/12
摘要： The invention relates to novel substituted 2-amino-4-alkylamino-1,3,5-triazines of the formula (I) in which R1 represents in each case optionally substituted alkyl having 2 to 6 carbon atoms or cycloalkyl having 3 to 6 carbon atoms, R2 represents hydrogen or represents alkyl having 1 to 4 carbon atoms, A represents oxygen or methylene, Ar represents in each case optionally substituted phenyl, naphthyl or heterocyclyl, and Z represents hydrogen, represents halogen or represents in each case optionally substituted alkyl, alkoxy, alkylcarboxyl, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkenyl or alkinyl, to processes and to novel intermediates for their preparation and to their use as herbicides.

77. 发明授权

US06348435B1 Substituted 2,4-diamino-1,3,5-triazine and their use as herbicides 失效
标题翻译：取代的2,4-二氨基-1,3,5-三嗪及其作为除草剂的用途
公开(公告)号：US06348435B1
公开(公告)日：2002-02-19
申请号：US09508383
申请日：2000-05-01
申请人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Markus Dollinger , Mark Wilhelm Drewes , Randy Allen Meyers
发明人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Markus Dollinger , Mark Wilhelm Drewes , Randy Allen Meyers
IPC分类号： C07D25118
CPC分类号： C07D409/12 , A01N43/68 , C07D333/20
摘要： The invention relates to novel substituted 2,4-diamino-1,3,5-triazines of the formula (I) in which R1 represents, for exampe, H or C1-C6-alkyl, R2 represents, for example, H, C1-C6-alkyl or —CO—R6, R3 represents, for example, H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl or C3-C6-cycloalkyl, R4 represents, for example, H, C1-C6-alkyl or C3-C6-cycloalkyl, R5 represents one of the groupings below, where R6 represents, for example, C1-C6-alkyl, C1-C6-alkoxy or C2-C6-alkenyl, R7 to R12 represents, for example, H or certain organic radicals and Q represents O or S, to processes and novel intermediates for their preparation and to their use as herbicides.
摘要翻译：本发明涉及式（I）的新型取代的2,4-二氨基-1,3,5-三嗪，其中R 1表示例如H或C 1 -C 6烷基，R 2表示例如H，C 1 -C 6烷基， C6烷基或-CO-R6，R3表示例如H，C1-C6-烷基，C2-C6-烯基，C2-C6-炔基或C3-C6-环烷基，R4表示例如H，C1 C 1-6 - 烷基或C 3 -C 6 - 环烷基，R 5表示以下基团之一，其中R 6表示例如C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基或C 2 -C 6 - 链烯基，R 7至R 12表示例如，H或某些有机基团，Q表示O或S，用于其制备和用作除草剂的新型中间体。

78. 发明授权

US06346503B1 Substituted 2-amino-4-alkylamino-1,3,5-triazines as herbicides 失效
标题翻译：取代的2-氨基-4-烷基氨基-1,3,5-三嗪作为除草剂
公开(公告)号：US06346503B1
公开(公告)日：2002-02-12
申请号：US09284053
申请日：1999-04-06
申请人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Yukiyoshi Watanbe , Markus Dollinger
发明人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Yukiyoshi Watanbe , Markus Dollinger
IPC分类号： A01N4368
CPC分类号： C07D401/12 , A01N43/68 , A01N43/70 , C07D251/18 , C07D403/12 , C07D409/12
摘要： The invention relates to novel substituted 2-amino-4-alkylamino-1,3,5-triazines of the formula (I) in which R1 represents in each case optionally substituted alkyl having 2 to 6 carbon atoms or cycloalkyl having 3 to 6 carbon atoms, R2 represents hydrogen or represents alkyl having 1 to 4 carbon atoms, A represents oxygen or methylene, Ar represents in each case optionally substituted phenyl, naphthyl or heterocyclyl, and Z represents hydrogen, represents halogen or represents in each case optionally substituted alkyl, alkoxy, alkylcarboxyl, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkenyl or alkinyl, to processes and to novel intermediates for their preparation and to their use as herbicides.
摘要翻译：本发明涉及式（I）的新的取代的2-氨基-4-烷基氨基-1,3,5-三嗪，其中R 1表示在各种情况下是任选取代的具有2至6个碳原子的烷基或具有3至6个碳原子的环烷基，R 2表示氢或表示具有1至4个碳原子的烷基，A表示氧或亚甲基，Ar表示各自为任意取代的苯基，萘基或杂环基，Z表示氢，表示卤素或表示任意取代的烷基，烷氧基，烷基羧基，烷氧基羰基，烷硫基，烷基亚磺酰基，烷基磺酰基，烯基或炔基，以制备和用于制备新的中间体及其作为除草剂的用途。

79. 发明授权

US06271178B1 Substituted 2,4-diamino-1,3,5-triazine as herbicide 失效
标题翻译：取代的2,4-二氨基-1,3,5-三嗪作为除草剂
公开(公告)号：US06271178B1
公开(公告)日：2001-08-07
申请号：US09284089
申请日：1999-04-07
申请人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Yukiyoshi Watanabe , Markus Dollinger , Toshio Goto
发明人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Yukiyoshi Watanabe , Markus Dollinger , Toshio Goto
IPC分类号： C07D25152
CPC分类号： C07D401/12 , A01N43/68 , A01N43/70 , C07D251/18 , C07D251/50 , C07D251/52 , C07D403/12
摘要： The invention relates to novel substituted 2,4-diamino-1,3,5-triazines of the formula (I) In which R1 represents hydrogen or optionally substitued alkyl, R2 represents formyl or represents in each case optionally substituted alkylcarbonyl, alkoxycarbonyl, alkylsulphonyl, arylcarbonyl or arylsulphonyl, R3 represents in each case optionally substituted alkyl or cycloalkyl, R4 represents hydrogen or alkyl, A represents oxygen or methylene, Ar represents in each case optionally substituted aryl or heterocyclyl, and z represents hydrogen, hydroxyl, cyano, nitrogen, halogen or represents in each case optionally substituted alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkenyl or alkinyl, (except for three prior-art compounds), to processes and to novel intermediates for preparation of the novel compounds and to their use as herbicides.
摘要翻译：本发明涉及式（I）的新型取代的2,4-二氨基-1,3,5-三嗪其中R 1表示氢或任选取代的烷基，R 2表示甲酰基或在各自的情况下表示任选取代的烷基羰基，烷氧基羰基，烷基磺酰基，芳基羰基或芳基磺酰基，R 3表示在任何情况下为任选取代的烷基或环烷基，R 4表示氢或烷基，A表示氧或亚甲基，Ar表示在各情况下为任选取代的芳基或杂环基，并且z表示氢，羟基，氰基，氮，卤素或表示在各种情况下任选取代的烷基，烷氧基，烷基羰基，烷氧基羰基，烷硫基，烷基亚磺酰基，烷基磺酰基，烯基或炔基（除三种现有技术化合物之外），用于制备新化合物及其用途的方法和新型中间体作为除草剂。

80. 发明授权

US06284710B1 Substituting 2-amino-4-alkylamino-1,3,5-triazine as herbicide 失效
标题翻译：代替2-氨基-4-烷基氨基-1,3,5-三嗪作为除草剂
公开(公告)号：US06284710B1
公开(公告)日：2001-09-04
申请号：US09284052
申请日：1999-04-06
申请人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Yukiyoshi Watanabe , Markus Dollinger , Peter Dahmen , Seishi Ito , Toshio Goto , Akihiko Yanagi
发明人： Hans-Jochem Riebel , Stefan Lehr , Uwe Stelzer , Yukiyoshi Watanabe , Markus Dollinger , Peter Dahmen , Seishi Ito , Toshio Goto , Akihiko Yanagi
IPC分类号： C07D25152
CPC分类号： C07D401/12 , A01N43/68 , A01N43/70 , C07C279/26 , C07D251/18 , C07D251/50 , C07D251/52 , C07D403/12
摘要： The invention relates to novel substituted 2-amino-4-alkylamino-1,3,5-triazines of the formula (I) in which R1 represents optionally substituted methyl, R2 represents hydrogen or alkyl, Y represents in each case optionally substituted benzyl, naphthylmethyl, heterocyclylmethyl or heterocyclyloxy, and Z represents hydrogen, represents halogen or represents in each case optionally substituted alkyl, alkoxy, alkylcarboxyl, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkenyl or alkinyl, to processes and to novel intermediates for their preparation and to their use as herbicides.
摘要翻译：本发明涉及式（I）的新的取代的2-氨基-4-烷基氨基-1,3,5-三嗪，其中R 1表示任选取代的甲基，R 2表示氢或烷基，Y表示在各种情况下任选取代的苄基，萘基甲基，杂环基甲基或杂环氧基，Z代表氢，代表卤素或代表任意取代的烷基，烷氧基，烷基羧基，烷氧基羰基，烷硫基，烷基亚磺酰基，烷基磺酰基，链烯基或炔基，用于制备和制备新的中间体及其用途除草剂。

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