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    • 75. 发明授权
    • Photographic element containing polymeric particles made by a
microsuspension process
    • 含有通过微悬浮法制备的聚合物颗粒的照相元件
    • US5858634A
    • 1999-01-12
    • US879059
    • 1997-06-19
    • Yongcai WangDennis E. SmithAlfred B. FantJohn L. Muehlbauer
    • Yongcai WangDennis E. SmithAlfred B. FantJohn L. Muehlbauer
    • G03C1/04G03C1/005G03C1/76G03C1/95G03C1/815G03C1/89
    • G03C1/95G03C1/7614G03C1/005G03C1/04Y10S430/162
    • The present invention is a photographic element which includes a support, at least one silver halide emulsion layer; and at least one layer containing a binder and polymer particles. The polymeric particles are prepared by the process of mechanically forming droplets having a size less than 400 nm of an ethylenically unsaturated monomer having hydrophobic groups, the hydrophobic groups having a logP.sub.(calc) greater than a logP.sub.(calc) of the ethylenically unsaturated monomer by at least 1 unit, and polymerizing said droplets so that the polymerized droplets have a size of less than 400 nm. The present invention also is a photographic element which includes a support, at least one silver halide emulsion layer; and at least one layer containing a binder and polymer particles. The polymeric particles are prepared by the process of mechanically forming droplets having a size less than 400 nm of an ethylenically unsaturated monomer having a logP.sub.(calc) greater than 4, preferably greater than 6, and polymerizing said droplets so that the polymerized droplets have a size of less than 400 nm.
    • 本发明是一种照相元件,它包括一个载体,至少一个卤化银乳剂层; 和至少一层含有粘合剂和聚合物颗粒的层。 聚合物颗粒通过机械地形成尺寸小于400nm的具有疏水基团的烯属不饱和单体的液滴的方法制备,疏水基团的logP(calc)大于烯键式不饱和单体的logP(calc),由 至少1个单位,并聚合所述液滴,使得聚合的液滴具有小于400nm的尺寸。 本发明还是一种照相元件,它包括一个载体,至少一个卤化银乳剂层; 和至少一层含有粘合剂和聚合物颗粒的层。 聚合物颗粒通过机械地形成尺寸小于400nm的具有logP(calc)大于4,优选大于6的烯属不饱和单体的液滴并聚合所述液滴以使聚合的液滴具有 尺寸小于400nm。
    • 77. 发明授权
    • Photographic element having improved ferrotyping resistance and surface
appearance
    • 具有改善耐铁性和表面外观的照相元件
    • US5770353A
    • 1998-06-23
    • US673433
    • 1996-06-28
    • Yongcai WangAlfred Bruce FantDennis Edward SmithKurt Michael SchroederMelvin Michael Kestner
    • Yongcai WangAlfred Bruce FantDennis Edward SmithKurt Michael SchroederMelvin Michael Kestner
    • G03C1/00G03C1/76G03C1/815G03C1/95G03C3/00G03C11/02G03C11/06G03C1/32
    • G03C1/7614G03C1/8155G03C1/95G03C11/02G03C3/00Y10S430/132Y10S430/151Y10S430/162
    • Silver halide photographic elements are disclosed comprising a support having a front and a back side, at least one light-sensitive silver halide emulsion layer and a light-insensitive protective overcoat on the front side of the support, and a magnetic recording layer on the back side of the support, the light-insensitive protective overcoat comprising an outermost protective layer, wherein the outermost protective layer comprises a hydrophilic binder and dispersed particles having a mean size of less than 0.4 .mu.m of a polymer having a glass transition temperature of at least 70.degree. C. comprising units derived from monomers A and B at a weight ratio of A:B of from 97:3 to 80:20 and less than 3 wt % ionic monomers, where A represents ethylenically unsaturated monomers which form substantially water insoluble homopolymers and B represents ethylenically unsaturated non-ionic monomers capable of forming water soluble homopolymers. In preferred embodiments of the invention, the light-insensitive protective overcoat further comprises an ultraviolet absorbing layer, which is preferably positioned between the light sensitive silver halide emulsion layer and the outermost protective layer, and which preferably comprises an ultraviolet absorbing dye, a high boiling organic solvent, and a hydrophilic binder. The outermost protective layer preferably also comprises photographic process insoluble matte particles having a mean particle size of larger than 0.5 .mu.m.
    • 公开了卤化银照相元件,其包括具有前侧和后侧的支撑体,至少一个感光卤化银乳剂层和在支撑体前侧上的不光泽的保护外涂层,以及背面的磁记录层 所述不透光保护外涂层包括最外保护层,其中最外保护层包括亲水性粘合剂,并且平均尺寸小于0.4μm的聚合物的分散颗粒具有玻璃化转变温度至少为 70℃,包含A:B重量比为97:3至80:20和小于3重量%离子单体的单体A和B的单体,其中A表示烯键式不饱和单体,其形成基本上不溶于水的均聚物 而B代表能形成水溶性均聚物的烯属不饱和非离子单体。 在本发明的优选实施方案中,光不敏感保护外涂层还包括紫外线吸收层,其优选位于感光卤化银乳剂层和最外保护层之间,并且其优选包含紫外线吸收染料,高沸点 有机溶剂和亲水性粘合剂。 最外面的保护层优选还包括平均粒度大于0.5μm的照相工艺不溶性锍颗粒。