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71. 发明授权

US4897220A Detergents containing water-soluble copolymers containing as copolymerized units monomers having two or more ethylenically unsaturated double bonds 失效
标题翻译：含有含有共聚单元的含有两个或更多个烯属不饱和双键的单体的水溶性共聚物的洗涤剂
公开(公告)号：US4897220A
公开(公告)日：1990-01-30
申请号：US191979
申请日：1988-05-10
申请人： Wolfgang Trieselt , Richard Baur , Ekhard Winkler , Paul Diessel , Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann
发明人： Wolfgang Trieselt , Richard Baur , Ekhard Winkler , Paul Diessel , Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann
IPC分类号： C08L33/02 , C08F20/10 , C08F220/04 , C08F220/06 , C08F222/16 , C11D3/37
CPC分类号： C11D3/3761
摘要： A surfactant-based detergent contains water-soluble copolymers which contain(a) from 99.5 to 15 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.6 -monocarboxylic acids,(b) from 0.5 to 20 mol % of one or more comonomers which contain two or more ethylenically unsaturated nonconjugated double bonds and have one or more --CO--OX groups where X is hydrogen, an alkali metal, one equivalent of an alkaline earth metal or ammonium,(c) from 0 to 84.5 mol % of one or more monoethylenically unsaturated C.sub.4 - to C.sub.6 -dicarboxylic acids,(d) from 0 to 20 mol % of one or more hydroxyalkyl esters of monoethylenically unsaturated C.sub.3 - to C.sub.6 -carboxylic acids and(e) from 0 to 30 mol % of other water-soluble monoethylenically unsaturated monomers copolymerizable with (a) to (d)as copolymerized units, with the proviso that the sum of the mol % ages (a) to (e) is always 100 and which have a Finkentscher K value of from 8 to 120.
摘要翻译：基于表面活性剂的洗涤剂含有水溶性共聚物，其含有（a）99.5〜15摩尔％的一种或多种单烯属不饱和C3〜C6-一元羧酸，（b）0.5〜20摩尔％的一种或多种共聚单体，含有两个或多个烯键式不饱和非共轭双键，并且具有一个或多个-CO-OX基团，其中X为氢，碱金属，1当量碱土金属或铵，（c）0至84.5摩尔％更多的单烯属不饱和C 4 -C 6 - 二羧酸，（d）0至20摩尔％的一种或多种单烯属不饱和C 3 -C 6羧酸的羟烷基酯和（e）0至30摩尔％可与（a）至（d）共聚的可溶性单烯属不饱和单体作为共聚单元，条件是mol％年龄（a）至（e）的总和始终为100，Finkentscher K值为8至120 。

72. 发明授权

US4846994A Use of graft polymers based on polyalkylene oxides as grayness inhibitors in the wash and aftertreatment of textile material containing synthetic fibers 失效
标题翻译：在含有合成纤维的纺织材料的洗涤和后处理中使用基于聚环氧烷作为灰色抑制剂的接枝聚合物
公开(公告)号：US4846994A
公开(公告)日：1989-07-11
申请号：US175175
申请日：1988-03-31
申请人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
发明人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
IPC分类号： C08F283/10 , C11D3/00 , C11D3/37 , D06M13/02 , D06M13/184 , D06M13/203 , D06M13/224 , D06M15/53
CPC分类号： C11D3/3788 , C08F283/10 , C11D3/0036
摘要： A detergent containing as grayness inhibitor in the wash and aftertreatment of textile material containing synthetic fibers graft polymers obtainable by grafting(a) polyalkylene oxides which have a number average molecular weight of from 300 to 100,000 and are based on ethylene oxide, propylene oxide and/or butylene oxide, with(b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 3 to 6 carbon atoms, a methyl or ethyl ester of (meth)acrylic acid and optionally mixtures of at least one of the monomers mentioned and up to 95% by weight of vinyl acetate in a weight ratio (a):(b) of from 1:02 to 1:10.
摘要翻译：在含有合成纤维的纺织材料的洗涤和后处理中含有灰色抑制剂的洗涤剂，其可通过接枝（a）数均分子量为300至100,000的聚环氧烷并且基于环氧乙烷，环氧丙烷和/ 或环氧丁烷与（b）至少一种衍生自含有3-6个碳原子的饱和一元羧酸的乙烯基酯，（甲基）丙烯酸的甲酯或乙酯和至少一种所提及的单体的混合物至95重量％的重量比（a）：（b）为1:02至1:10的乙酸乙烯酯。

73. 发明授权

US4814505A Purification of n-vinylformamide 失效
标题翻译：正乙烯基甲酰胺的纯化
公开(公告)号：US4814505A
公开(公告)日：1989-03-21
申请号：US008171
申请日：1987-01-29
申请人： Michael Kroener , Willi Schmidt , Alfred Oftring , Theo Proll , Heinrich Hartmann
发明人： Michael Kroener , Willi Schmidt , Alfred Oftring , Theo Proll , Heinrich Hartmann
IPC分类号： C07C231/24 , C07C67/00 , C07C231/00 , C07C233/00 , C07C233/03 , C08F26/00 , C08F126/02 , C07C102/00 , C07C103/34 , C07C103/365
CPC分类号： C07C233/00
摘要： N-Vinylformamide is purified by fractional distillation in the presence of formamide in a column under from 0.5 to 30 mbar by a method in which the distillation is controlled so that N-vinylformamide containing from 0.1 to 15% by weight of formamide is obtained as the distillate. Homopolymers having particularly high molecular weights can be prepared from the N-vinylformamide purified in this manner.
摘要翻译： N-乙烯基甲酰胺通过在甲酰胺存在下，在0.5至30毫巴的柱中通过分馏进行纯化，其中控制蒸馏的方法使得得到含有0.1-15％（重量）甲酰胺的N-乙烯基甲酰胺作为馏出物具有特别高分子量的均聚物可以由以这种方式纯化的N-乙烯基甲酰胺制备。

74. 发明授权

US4334034A Process for the preparation of polymerizable polyurethane elastomers 失效
标题翻译：制备可聚合聚氨酯弹性体的方法
公开(公告)号：US4334034A
公开(公告)日：1982-06-08
申请号：US231836
申请日：1981-02-05
申请人： August Lehner , Heinrich Hartmann , Guenter Heil , Werner Lenz , Ingolf Buethe , Rudolf Bachmann
发明人： August Lehner , Heinrich Hartmann , Guenter Heil , Werner Lenz , Ingolf Buethe , Rudolf Bachmann
IPC分类号： C08G18/00 , C08G18/67 , C08G63/76 , C08G18/62
CPC分类号： C08G18/6705 , C08G18/675
摘要： A process for the preparation of polymerizable, primarily linear thermoplastic polyurethane elastomers with acrylate side groups comprising reacting an organic polyisocyanate with a mixture of(a) an acrylate diol having a molecular weight of 146 to 3000,(b) an organic polyhydroxyl compound other than those of paragraph (a) having a molecular weight between 400 and 5000, and(c) a chain extender selected from the group consisting of diols, diamines, aminoalcohols, and triols, having molecular weights between 61 and 400, water, and mixtures thereofwherein the ratio of isocyanate to active hydrogen containing groups is from 0.8:1 to 1.2:1 and wherein 1.4 to 1.8 moles of organic polyisocyante, 0 to 15 moles of component (c) and 0.3 to 6 moles of component (a) are used per mole of component (b). The polymerizable polyurethane elastomers may be used for the manufacture of molded parts, laminates, adhesives, coatings, magnetic tapes, and other articles.
摘要翻译：一种制备具有丙烯酸酯侧基的可聚合的主要线性的热塑性聚氨酯弹性体的方法，包括使有机多异氰酸酯与（a）分子量为146至3000的丙烯酸酯二醇和（b）有机多羟基化合物的混合物段落（a）分子量在400和5000之间的那些，和（c）分子量在61和400之间的选自二醇，二胺，氨基醇和三醇的增链剂，水及其混合物其中异氰酸酯与含活性氢的基团的比例为0.8:1至1.2:1，并且其中使用1.4至1.8摩尔有机聚异氰酸酯，0至15摩尔的组分（c）和0.3至6摩尔的组分（a）每摩尔组分（b）。可聚合的聚氨酯弹性体可用于制造模制件，层压材料，粘合剂，涂料，磁带和其它制品。

75. 发明授权

US4134932A Surface-coating binders for cathodic electrocoating 失效
标题翻译：用于阴极电泳的表面涂层粘合剂
公开(公告)号：US4134932A
公开(公告)日：1979-01-16
申请号：US884909
申请日：1978-03-09
申请人： Fritz E. Kempter , Heinrich Hartmann , Erich Gulbins
发明人： Fritz E. Kempter , Heinrich Hartmann , Erich Gulbins
IPC分类号： C08G18/00 , C08G59/00 , C08G59/62 , C08L63/00 , C08L75/00 , C09D5/44 , C09D175/00
CPC分类号： C09D5/4419 , C08G59/623 , C08L63/00
摘要： Surface-coating binders for cathodic electrocoating which comprise a protonized heat-curable reaction product (A), substantially free from epoxide groups, of(a) one or more Mannich bases, prepared from(a.sub.1) one or more polyhydric condensed phenols which may or may not contain ether groups.(a.sub.2) one or more secondary amines which contain one or more hydroxyalkyl groups, with or without one or more secondary amines which do not contain such groups, and(a.sub.3) formaldehyde or a formaldehyde donor, with(b) one or more epoxy resins,Which binder also contains from 1 to 40% by weight, based on the total of (A) + (B), of a water-insoluble non-ionic resin (B), free from epoxide groups and containing urethane groups, which resin has been obtained by reacting a partially blocked diisocyanate or higher polyisocyanate with a reaction product of a polyepoxide and one or more low molecular weight compounds containing SH and/or OH groups.These surface-coating binders are especially used for the cathodic electrocoating of metal articles.
摘要翻译：包含基本上不含环氧基团的质子化热固化反应产物（A）的（A）一种或多种曼尼希碱的质子化可热固化反应产物（A）的表面涂层粘合剂，其由（A1）一种或多种多元稠合的酚制成，其可以是可能不包含以下组。

76. 发明授权

US4000336A Production of magnetic recording media 失效
标题翻译：生产磁记录介质
公开(公告)号：US4000336A
公开(公告)日：1976-12-28
申请号：US521476
申请日：1974-11-06
申请人： Job Werner Hartmann , Hans Joerg Hartmann , Hermann Roller , Joachim Hack , Heinrich Hartmann
发明人： Job Werner Hartmann , Hans Joerg Hartmann , Hermann Roller , Joachim Hack , Heinrich Hartmann
IPC分类号： G11B5/702 , H01F10/02
CPC分类号： G11B5/7021 , Y10S428/90
摘要： In a process for the production of magnetic recording media by applying a layer of a dispersion of a magnetic pigment in a polyurethane-containing binder and a solvent to non-magnetic supports, small amounts of ethylenically unsaturated polymerizable carboxylic acids or their anhydrides with or without copolymerizable monomers are added and polymerized during dispersion of the magnetic pigment. Recording media produced by this process exhibit excellent output level, coefficient of friction and electrical resistance values and have particularly good operational durability.
摘要翻译：在通过将磁性颜料的分散体在含聚氨酯的粘合剂和溶剂中的一层施加到非磁性载体上来制造磁记录介质的方法中，少量的烯属不饱和可聚合羧酸或其酸酐具有或不具有可共聚单体在磁性颜料的分散过程中加入并聚合。通过该方法生产的记录介质表现出优异的输出水平，摩擦系数和电阻值，并且具有特别好的操作耐久性。

77. 发明授权

US5520834A Polyacetals containing acetaldehyde acetal units, preparation thereof and use thereof in detergents and cleaners 失效
标题翻译：含有乙醛缩醛单元的聚缩醛，其制备方法及其在洗涤剂和清洁剂中的应用
公开(公告)号：US5520834A
公开(公告)日：1996-05-28
申请号：US397244
申请日：1995-03-20
申请人： Matthias Kroner , Heinrich Hartmann , Johannes Perner , Hans-Ulrich Jaeger , Paul Diessel , Richard Baur , Volker Schwendemann
发明人： Matthias Kroner , Heinrich Hartmann , Johannes Perner , Hans-Ulrich Jaeger , Paul Diessel , Richard Baur , Volker Schwendemann
IPC分类号： B01F17/00 , B01F17/52 , C04B24/28 , C04B24/38 , C08B31/00 , C08G65/34 , C11D3/37
CPC分类号： C04B24/28 , B01F17/0028 , C04B24/383 , C08B31/00 , C08G65/34 , C11D3/3707
摘要： Soluble polyacetals containing acetaldehyde acetal units are obtainable by cationically initiated addition polymerization of(a) compounds containing at least 3 hydroxyl groups, and(b) divinyl ethers containing terminal vinyl ether groups, or mixtures of such divinyl ethers and monovinyl ethers, in the presence or absence of(c) dihydroxy compounds and/or monohydroxy compounds, and are useful as admixture in phosphate-reduced and phosphate-free detergents and cleaners and as dispersant for finely divided minerals.
摘要翻译： PCT No.PCT / EP93 / 02613 371日期1995年3月20日 102（e）1995年3月20日PCT PCT 1993年9月25日PCT公布。出版物WO94 / 07939 含有乙醛缩醛单元的可溶性聚缩醛可通过阳离子引发加成聚合得到（a）含有至少3个羟基的化合物，和（b）含有末端乙烯基醚基团的二乙烯基醚，或这些二乙烯基醚的混合物在（c）二羟基化合物和/或单羟基化合物存在或不存在下，并且可用作磷酸盐还原和无磷酸盐洗涤剂和清洁剂中的混合物以及作为细碎矿物质的分散剂的单乙烯基醚。

78. 发明授权

US5508394A Citric esters of polyhydroxy compounds and use thereof in detergents 失效
标题翻译：多羟基化合物的柠檬酸酯及其在洗涤剂中的用途
公开(公告)号：US5508394A
公开(公告)日：1996-04-16
申请号：US117134
申请日：1993-09-16
申请人： Elisabeth Kappes , Alfred Oftring , Richard Baur , Alexander Kud , Dieter Boeckh , Heinrich Hartmann , Volker Schwendemann
发明人： Elisabeth Kappes , Alfred Oftring , Richard Baur , Alexander Kud , Dieter Boeckh , Heinrich Hartmann , Volker Schwendemann
IPC分类号： C07C67/08 , C07C69/704 , C07C219/06 , C07H13/04 , C07H15/04 , C11D3/20 , C11D3/22 , C11D3/30 , C07H5/04 , A01N43/04 , C07H5/06 , C07H13/02
CPC分类号： C07H13/04 , C07C69/704 , C07H15/04 , C11D3/2093 , C11D3/221 , C11D3/30
摘要： Esters of citric acid or acetylcitric anhydride with compounds of at least 3 OH groups selected from the group consisting of polyglycerol, sugarcarboxylic acids, alkyl glucosides, derivatives of oligosaccharides, aminosorbitol, aminodisorbitol, glucosamine, triethanolamine and trishydroxyethylmelamine, each OH group of the alcohol component of the esters being esterified on average with from 0.15 to 1 molecule of citric acid or acetylcitric anhydride, are useful as additives in low-phosphate or phosphate-free detergents.
摘要翻译： PCT No.PCT / EP92 / 00512 Sec。 371日期：1993年9月16日 102（e）1993年9月16日PCT PCT 1991年3月7日PCT公布。 WO92 / 16493 PCT出版物日期：1992年10月1日。具有至少3个OH基团的化合物的柠檬酸或乙酰柠檬酸酯选自聚甘油，糖羧酸，烷基葡糖苷，寡糖衍生物，氨基异山梨醇，氨基二异山梨醇，葡糖胺，三乙醇胺和三羟乙基三聚氰胺，酯的醇组分的每个OH基团平均被0.15至1分子的柠檬酸或乙酰柠檬酸酐酯化，可用作低磷酸盐或无磷酸盐洗涤剂中的添加剂。

79. 发明授权

US5346986A Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers, the preparation thereof and the use thereof 失效
标题翻译：精细分散的水溶性或水可溶胀聚合物的聚集的聚合物颗粒，其制备及其用途
公开(公告)号：US5346986A
公开(公告)日：1994-09-13
申请号：US104066
申请日：1993-08-09
申请人： Reinhard Schneider , Norbert Grund , Heinrich Hartmann
发明人： Reinhard Schneider , Norbert Grund , Heinrich Hartmann
IPC分类号： C02F1/52 , C02F1/54 , C02F1/56 , C08F2/32 , C08J3/12 , C08J3/16 , C09B67/38 , C09B67/46 , C09K3/00 , D06P1/52 , C08F6/20
CPC分类号： C08J3/12 , C02F1/5227 , C02F1/54 , C02F1/547 , C02F1/56 , C08J3/16 , D06P1/5207 , D06P1/5242 , D06P1/525 , D06P1/5257 , C02F2305/04 , C08J2300/14
摘要： Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers are prepared by azeotropic dewatering of water-in-oil emulsions of water-soluble or water-swellable polymers in the presence of from 1 to 40% by weight, based on the polymers, of polyalkylene glycols which(a) are obtainable by an addition reaction of C.sub.2 -C.sub.4 -alkylene oxides with alcohols, phenols, amines or carboxylic acids and(b) contain not less than 2 polymerized alkylene oxide unitsand isolation of the agglomerated polymer particles. The water-soluble agglomerated polymer particles are used as flocculants and retention and drainage aids, while the water-swellable polymer powders are employed as thickeners for aqueous systems, in particular as thickeners for textile print pastes.
摘要翻译：通过使水溶性或水可溶胀聚合物的油包水乳液在1至40重量％存在下，基于以下物质共沸脱水来制备细分散的水溶性或水可溶胀聚合物的聚集的聚合物颗粒：聚亚烷基二醇的聚合物，（a）可通过C2-C4-环氧烷与醇，酚，胺或羧酸的加成反应获得，和（b）含有不少于2个聚合的烯化氧单元和分离的聚集的聚合物颗粒。水溶性附聚聚合物颗粒用作絮凝剂和保留和引流助剂，而水溶胀性聚合物粉末用作水性体系的增稠剂，特别是作为织物印刷浆料的增稠剂。

80. 发明授权

US5228915A Fluid loss control additives for oil well cementing compositions 失效
标题翻译：油井固井组合物的流体损失控制添加剂
公开(公告)号：US5228915A
公开(公告)日：1993-07-20
申请号：US981921
申请日：1992-11-23
申请人： Stefano C. Crema , Clare H. Kucera , Gerd Konrad , Heinrich Hartmann
发明人： Stefano C. Crema , Clare H. Kucera , Gerd Konrad , Heinrich Hartmann
IPC分类号： C04B24/16 , C04B24/26 , C04B28/02 , C09K8/46 , C09K8/487
CPC分类号： C04B24/26 , C04B24/16 , C04B28/02 , C09K8/46 , C09K8/487 , C04B2103/46
摘要： A cementing composition useful in cementing oil, gas and water wells, comprising water, hydraulic cement and an effective amount of water soluble fluid loss additive comprised of a blend of a copolymer (i) of acrylamide/vinyl imidazole in a weight percent ratio of from about 95:5 to 5:95, said copolymer (i) having a molecular weight range of from about 100,000 to 3,000,000, and a copolymer (ii) of vinyl pyrrolidone and the sodium salt of vinyl sulfonate in a weight percent ratio of 80:20 to 20:80, said copolymer (ii) having a molecular weight range of from about 100,000 to 3,000,000. The blend is comprised of a weight percent ratio of copolymer (i) to copolymer (ii) in the range of 20:80 to 80:20. The composition can also optionally include a dispersant such as sodium or potassium salts or a sulfonated naphthalene formaldehyde condensate.
摘要翻译：用于固井油，气和水井的固井组合物，包括水，水硬性水泥和有效量的水溶性流体损失添加剂，其由丙烯酰胺/乙烯基咪唑共聚物（i）的共混物组成，其重量百分比为约95:5至5:95，所述共聚物（i）的分子量范围为约100,000至3,000,000，和乙烯基吡咯烷酮和乙烯基磺酸钠盐的共聚物（ii）的重量比为80： 20至20:80，所述共聚物（ii）的分子量范围为约100,000至3,000,000。共混物由共聚物（i）与共聚物（ii）的重量百分比的比例在20:80至80:20的范围内组成。组合物还可任选地包括分散剂如钠盐或钾盐或磺化萘甲醛缩合物。

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