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    • 73. 发明授权
    • Process for preparing ink-jet system printing plate
    • 制备喷墨系统印版的方法
    • US06532870B1
    • 2003-03-18
    • US08906815
    • 1997-08-06
    • Eiichi KatoSadao OsawaHiroyuki OhishiKazuo Ishii
    • Eiichi KatoSadao OsawaHiroyuki OhishiKazuo Ishii
    • B41C110
    • B41C1/1066
    • A process for preparing an ink-jet system printing plate, wherein an image is formed according to a hot melt type ink-jet system by heat-melting an ink composition that is solid at ordinary temperature, spraying droplets of the ink composition in a hot melt state from nozzles onto an intermediate transferrer to form an image, and contact-transferring the image on the intermediate transferrer to an image receiving layer of a planographic printing plate precursor, the image receiving layer being provided on a water-resistive support and containing zinc oxide and a binder resin, and thereafter, a nonimage area of the image receiving layer is desensitized by chemical reaction treatment to prepare a planographic printing plate.
    • 一种制备喷墨系统印版的方法,其中根据热熔型喷墨系统通过将常温下为固体的油墨组合物进行加热熔融形成图像,将油墨组合物的液滴喷射在热 从喷嘴到中间转印器的熔融状态以形成图像,并且将中间转印器上的图像接触转印到平版印刷版原版的图像接收层上,图像接收层设置在耐水性支持体上并含有锌 氧化物和粘合剂树脂,然后通过化学反应处理使图像接收层的非图像区域脱敏以制备平版印刷版。
    • 75. 发明授权
    • Oil-based ink for preparing printing plate by ink jet process and method
for preparing printing plate by ink jet process
    • 通过喷墨法制备印版的油性油墨和通过喷墨法制备印版的方法
    • US6080449A
    • 2000-06-27
    • US14160
    • 1998-01-27
    • Eiichi KatoSadao OsawaKazuo Ishii
    • Eiichi KatoSadao OsawaKazuo Ishii
    • B41C1/10B05D1/04
    • B41C1/1066
    • An oil-based ink for a printing plate by an ink jet process comprising spraying an oil-based ink comprising at least resin particles dispersed in a nonaqueous carrier liquid having an electric resistance of 10.sup.9 .OMEGA.cm or more and a dielectric constant of 3.5 or less on an image receiving layer of a lithographic printing plate precursor dropwise from a nozzle to form an image, and then desensitizing a non-image area of the image receiving layer by a chemical reaction to prepare a lithographic printing plate, the image receiving layer being formed on a water-resistant support and comprising zinc oxide and a binding resin; and a surface of the image receiving layer having a contact angle with water of 50.degree. or more, wherein the resin particles dispersed are polymer particles obtained by polymerization granulation of a solution comprising (i), (ii) and (iii): (i) at least one monofunctional monomer (A) which is soluble in a nonaqueous solvent which is at least miscible with the nonaqueous carrier liquid and becomes insoluble therein by polymerization; (ii) (ii-a) at least one monomer which is copolymerizable with the monomer (A), or (ii-b) at least one monofunctional macromonomer (MA) having a weight average molecular weight of 2.times.10.sup.4 or less in which a polymerizable double bond group is combined with only one end of a main chain of a polymer comprising a repeating unit corresponding to a monomer; and (iii) at least one dispersion-stabilizing resin which is soluble in the nonaqueous solvent and has no graft group polymerizing with a monomer.
    • 一种喷墨方法的印刷用油性油墨,其特征在于,喷涂含有至少分散在电阻为10 9Ω·cm以上,介电常数为3.5以下的非水载体液中的树脂颗粒的油性油墨 在平版印刷版前体的图像接收层上从喷嘴滴落形成图像,然后通过化学反应对图像接收层的非图像区域进行脱敏以制备平版印刷版,形成图像接收层 在防水载体上并包含氧化锌和粘合树脂; 和图像接收层的与水的接触角为50°以上的表面,其中分散的树脂颗粒是通过聚合造粒包含(i),(ii)和(iii)的溶液获得的聚合物颗粒:(i )至少一种单官能单体(A),其可溶于非水溶剂中,所述非水溶剂至少与非水性载体液体可混溶并通过聚合而不溶于其中; (ii)(ii-a)至少一种可与单体(A)共聚的单体或(ii-b)至少一种重均分子量为2×10 4或更小的单官能大分子单体(MA),其中可聚合的 双键基团仅与包含对应于单体的重复单元的聚合物主链的一端结合; 和(iii)至少一种可溶于非水溶剂且不与单体聚合的接枝基团的分散体稳定树脂。
    • 77. 发明授权
    • Electrophotolithographic printing plate precursor
    • 电子光刻印版前体
    • US5393625A
    • 1995-02-28
    • US181243
    • 1994-01-13
    • Eiichi KatoSeishi KasaiKazuo Ishii
    • Eiichi KatoSeishi KasaiKazuo Ishii
    • C08F8/00C08K3/22G03G5/05G03G5/06G03G5/08G03G5/087G03G5/09G03G13/28
    • G03G5/0589C08F8/00C08K3/22
    • Disclosed is electrophotolithographic plate precursor having on a conductive support at least one photoconductive layer containing at least a random copolymer binder resin (P) (i) having a weight average molecular weight of from 5.times.10.sup.4 to 5.times.10.sup.5, (ii) comprising (a) a polymer component comprising particular methacrylate or acrylate monomers, (b) a polymer component containing at least one particular polar group and (c) a polymer component having a Fedors' solution parameter of 9.0 or more and containing at least a particular aprotic polar group, and (iii) having at least a particular polar group at one end of the main chain of the copolymer. The plate precursor may be etched with a combination of an etchant and a wetting water both having no problem in the environmental sanitation, to be formed into an offset printing plate not generating background staining. The printing plate has high printing durability and has excellent rubbing resistance.
    • 公开了电子照相平版印刷版原版,其在导电载体上具有至少一个光导电层,其至少含有重均分子量为5×10 4至5×10 5的无规共聚物粘合剂树脂(ⅰ),(ⅱ)包含(a)聚合物 包含特定的甲基丙烯酸酯或丙烯酸酯单体的组分,(b)含有至少一个特定极性基团的聚合物组分和(c)具有9.0或更高的Fedors溶液参数并且至少含有特定非质子极性基团的聚合物组分和( iii)在共聚物的主链的一端具有至少一个特定的极性基团。 可以用环境卫生中没有问题的蚀刻剂和润湿水的组合来蚀刻板前体,以形成不产生背景染色的胶版印刷版。 该印版具有高的印刷耐久性并且具有优异的耐摩擦性。
    • 78. 发明授权
    • Electrophotographic light-sensitive material
    • 电子照相感光材料
    • US5382488A
    • 1995-01-17
    • US64056
    • 1993-05-18
    • Eiichi KatoKazuo Ishii
    • Eiichi KatoKazuo Ishii
    • G03G5/05G03G5/087G03G5/09
    • G03G5/0589G03G5/0592
    • An electrophotographic light-sensitive material which has improved electrostatic characteristics and image forming performance and is excellent particularly in reproducibility of highly accurate image using a liquid developer and image forming performance upon a scanning exposure system using a laser beam of a low power.The electrophotographic light-sensitive material contains, as a binder resin, a low molecular weight resin (A) comprising an organic molecule having bonded thereto at least three polymer chains each containing a polymer component of formula (I) and a polymer component having a specified polar group, and a resin (B) which is a medium to high molecular weight AB block copolymer comprising an A block containing a specified polar group and a B block containing a polymer component of formula (I). ##STR1## wherein a.sup.1 and a2: hydrogen, halogen, a cyano group, a hydrocarbon group, --COOR.sup.4 or --COOR.sup.4 bonded via a hydrocarbon group (R.sup.4 : hydrocarbon group); and R.sup.3 : a hydrocarbon group.
    • PCT No.PCT / JP92 / 01194 Sec。 371日期:1993年5月18日 102(e)日期1993年5月18日PCT PCT日期为1992年9月18日。具有改善的静电特性和成像性能并且特别是使用液体显影剂的高精度图像的再现性和成像性能优异的电子照相感光材料 在使用低功率的激光束的扫描曝光系统上。 电子照相感光材料包含作为粘合剂树脂的低分子量树脂(A),其包含键合有至少三个聚合物链的有机分子,每个聚合物链均含有式(I)的聚合物组分和具有指定的聚合物组分的聚合物组分 和含有特定极性基团的A嵌段和含有式(I)的聚合物成分的B嵌段的中高分子量AB嵌段共聚物的树脂(B)。 式(I)其中a1和a2:通过烃基键合的氢,卤素,氰基,烃基,-COOR4或-COOR4(R4:烃基); 和R3:烃基。