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71. 发明授权

US06825241B1 Solid containing groups which are bound to the base structure via ureathane groups and which contain bonds that can be activated by actinic radiation, and the use thereof 失效
标题翻译：通过ureathane基团结合到碱基结构并含有可被光化辐射活化的键的固体含量基团及其用途
公开(公告)号：US06825241B1
公开(公告)日：2004-11-30
申请号：US10089171
申请日：2002-03-27
申请人： Rainer Blum , Reinhold Schwalm , Rainer Königer
发明人： Rainer Blum , Reinhold Schwalm , Rainer Königer
IPC分类号： C08F246
CPC分类号： C08G18/672 , C08G18/3206 , C08G18/3253 , C08G18/4277 , C08G18/686 , C08G2150/20 , Y10T428/31551 , Y10T428/31935
摘要： Solids containing (i) on average per molecule at least two groups (a) having at least one bond which can be activated with actinic radiation whereby the groups (a) are structurally different from one another and are attached to the parent structure of the solid via urethane groups, or containing (ii) on average per molecule more than one group (a) having at least one bond which can be activated with actinic radiation, the groups being structurally different from one another or the same and being attached to the parent structure of the solid via urethane groups, and from 0.01 to 1 mol %, based on the bonds present which can be activated with actinic radiation, of at least one chemically bonded polymerization inhibitor (b), preparable by reacting the starting products in the melt; use of the solids as coating materials, adhesives or sealing compounds or for preparing them; coating materials, adhesives or sealing compounds preparable using the solids; and coatings, adhesive films or seals producible from the coating materials, adhesives or sealing compounds.
摘要翻译：含有（i）平均每分子至少两个（a）具有至少一个可以用光化辐射活化的键的基团（a），由此基团（a）在结构上彼此不同并且连接到固体的母体结构通过氨基甲酸酯基团，或者每个分子平均包含多于一个具有至少一个可以用光化辐射活化的键的组（a），所述基团在结构上彼此不同或相同并附着于母体至少一种化学键合的聚合抑制剂（b）可以通过氨基甲酸酯基团的固体的结构和0.01至1摩尔％（基于可用光化辐射活化的键），其可通过使熔融物中的起始产物反应 ; 使用固体作为涂料，粘合剂或密封剂或用于制备它们; 可使用固体制备的涂料，粘合剂或密封剂; 以及可从涂层材料，粘合剂或密封化合物生产的涂料，粘合剂膜或密封剂。

72. 发明授权

US06350523B1 Radiation-curable weather-resistant compositions comprising carbonate (meth) acrylates 失效
标题翻译：包含碳酸（甲基）丙烯酸酯的可辐射固化耐候组合物
公开(公告)号：US06350523B1
公开(公告)日：2002-02-26
申请号：US09334929
申请日：1999-06-17
申请人： Reinhold Schwalm
发明人： Reinhold Schwalm
IPC分类号： B32B2730
CPC分类号： C08F290/06 , C09D4/06 , Y10T428/31551 , Y10T428/31678 , Y10T428/31692 , Y10T428/31935
摘要： The use of radiation-curable compositions containing from 0.5 to 100% by weight of carbonate (meth)acrylates, based on the overall amount of radiation-curable compounds, as coating compositions for exterior applications.
摘要翻译：使用含有0.5至100重量％的碳酸酯（甲基）丙烯酸酯的可辐射固化组合物，基于可辐射固化的化合物的总量，作为用于外部应用的涂料组合物。

73. 发明授权

US06288185B1 Initiators for radical polymerization 失效
公开(公告)号：US06288185B1
公开(公告)日：2001-09-11
申请号：US09677889
申请日：2000-10-03
申请人： Rainer Königer , Reinhold Schwalm , Roman Benedikt Raether
发明人： Rainer Königer , Reinhold Schwalm , Roman Benedikt Raether
IPC分类号： C08F404
CPC分类号： C08F4/04 , C07D231/54 , C07D271/12 , C07D487/08 , C07F7/0814
摘要： Initiators for free-radical addition polymerization comprising as structural feature the Diels-Alder adduct of an azo group (—N═N—) with a conjugated double bond (diene).

74. 发明授权

US06242101B1 Radiation-curable formulations 失效
标题翻译：可辐射固化的配方
公开(公告)号：US06242101B1
公开(公告)日：2001-06-05
申请号：US09283864
申请日：1999-04-01
申请人： Reinhold Schwalm , Rainer Königer , Erich Beck , Klaus Menzel , Wolfgang Paulus , Peter Enenkel
发明人： Reinhold Schwalm , Rainer Königer , Erich Beck , Klaus Menzel , Wolfgang Paulus , Peter Enenkel
IPC分类号： C08F246
CPC分类号： C09D175/16 , C08F290/06 , C08F290/14 , C08G18/282 , C08G18/672 , C08G18/792 , C08G18/8175 , C09D4/00 , C09D4/06 , Y10T428/31551 , Y10T428/31605 , C08F222/1006 , C08F290/147
摘要： Radiation-curable formulations based on ethylenically unsaturated prepolymers and difunctional esters of ethylenically unsaturated carboxylic acids with diols having a linear alkylene chain of 7 to 14 carbon atoms, a process for coating substrates using these radiation-curable formulations, and their use as automotive topcoats.
摘要翻译：基于烯键式不饱和预聚物和烯键式不饱和羧酸的双官能酯与具有7-14个碳原子的直链亚烷基链的二醇的可辐射固化制剂，使用这些可辐射固化制剂涂覆基质的方法及其作为汽车面漆的用途。

75. 发明授权

US06177379B1 Initiators for radical polymerization 失效
标题翻译：自由基聚合引发剂
公开(公告)号：US06177379B1
公开(公告)日：2001-01-23
申请号：US09080239
申请日：1998-05-18
申请人： Rainer Königer , Reinhold Schwalm , Roman Benedikt Raether
发明人： Rainer Königer , Reinhold Schwalm , Roman Benedikt Raether
IPC分类号： B01J3100
CPC分类号： C08F4/04 , C07D231/54 , C07D271/12 , C07D487/08 , C07F7/0814
摘要： A method of initiating free-radical addition polymerization, which entails effecting a free-radical addition polymerization in the presence of an initiator, which contains, as a structural feature, a Diels-Alder adduct of an azo group (—N═N—) with a conjugated double bond (diene).
摘要翻译：引发自由基加成聚合的方法，其需要在引发剂的存在下进行自由基加成聚合，其包含作为结构特征的偶氮基团的狄尔斯 - 阿尔德加合物（-N = N-）与共轭双键（二烯）。

76. 发明授权

US6143233A Polymers containing 2,3-dihydrofuran groups 失效
标题翻译：含有2,3-二氢呋喃基团的聚合物
公开(公告)号：US6143233A
公开(公告)日：2000-11-07
申请号：US142171
申请日：1998-09-22
申请人： Wolfgang Reich , Reinhold Schwalm , Erich Beck , Lukas Haussling , Oskar Nuyken , Roman-Benedikt Raether
发明人： Wolfgang Reich , Reinhold Schwalm , Erich Beck , Lukas Haussling , Oskar Nuyken , Roman-Benedikt Raether
IPC分类号： C08J7/04 , C08F2/46 , C08F8/00 , C08F8/14 , C08F220/18 , C09D133/14 , G03F7/038 , C08G65/14 , C08G65/16
CPC分类号： C08F8/14
摘要： A polymer which can be crosslinked by high-energy radiation and contains from 0.1 to 50% by weight, based on the polymer, of 2,3-dihydrofuran groups or derivatives thereof, each calculated as 2,3-dihydrofuran.
摘要翻译： PCT No.PCT / EP97 / 01206 Sec。 371日期：1998年9月22日 102（e）1998年9月22日PCT 1997年3月10日PCT公布。公开号WO97 / 35907 日期1997年10月2日一种可以通过高能辐射交联并且基于聚合物含有0.1至50重量％的2,3-二氢呋喃基或其衍生物的聚合物，其分别计算为2,3-二氢呋喃。

77. 发明授权

US06066746A Radiation curing of dihydrofuran derivatives 失效
标题翻译：二氢呋喃衍生物的辐射固化
公开(公告)号：US06066746A
公开(公告)日：2000-05-23
申请号：US266913
申请日：1999-03-12
申请人： Wolfgang Reich , Reinhold Schwalm , Erich Beck , Lukas Haussling , Oskar Nuyken , Roman-Benedikt Raether
发明人： Wolfgang Reich , Reinhold Schwalm , Erich Beck , Lukas Haussling , Oskar Nuyken , Roman-Benedikt Raether
IPC分类号： C08F34/00 , C08F34/02 , C08G59/24 , C08G61/10 , C08G61/12 , C08G65/14 , C08G65/16 , C09D4/00 , C09D163/00 , C07D307/26 , C07D307/32
CPC分类号： C09D4/00 , C08F34/02 , C08G59/24 , C08G65/14 , C08G65/16 , C09D163/00
摘要： Process for producing coatings or moldings by radiation curing, which involves using high-energy light to irradiate radiation-curable compositions containing 1-100% by weight, based on the total amount of free-radically or cationically polymerizable compounds, of compounds A) containing at least one cationically polymerizable 2,3-dihydrofuran group.
摘要翻译：用于通过辐射固化生产涂层或模制品的方法，其涉及使用高能量光以基于自由基或阳离子聚合化合物的总量计，含有1-100重量％的可辐射固化组合物含有化合物A）至少一种阳离子可聚合的2,3-二氢呋喃基。

78. 发明授权

US5914219A Radiation-sensitive mixture and the production of relief structures having improved contrast 失效
标题翻译：辐射敏感的混合物和具有改善的对比度的浮雕结构的生产
公开(公告)号：US5914219A
公开(公告)日：1999-06-22
申请号：US735114
申请日：1996-10-22
申请人： Dirk Funhoff , Reinhold Schwalm , Horst Binder
发明人： Dirk Funhoff , Reinhold Schwalm , Horst Binder
IPC分类号： C08K5/375 , C08K5/42 , C09D125/02 , C09D125/18 , C09D143/04 , G03F7/004 , G03F7/029 , G03F7/032 , G03F7/039 , H01L21/027 , G03F7/38 , G03F7/40
CPC分类号： G03F7/039 , C08K5/375 , C08K5/42 , C09D125/02 , C09D125/18 , C09D143/04 , G03F7/0045 , Y10S430/111 , Y10S430/122
摘要： Positive-working radiation-sensitive mixtures, essentially consisting of(a1) a water-insoluble organic binder which contains acid-labile groups and is rendered soluble in aqueous alkaline solutions by the action of an acid, or(a2.1) a polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions and(a2.2) an organic compound whose solubility in an aqueous alkaline developer is increased by the action of an acid, and(b) an organic compound which produces an acid under the action of actinic radiation, which additionally contain(c) a strongly basic organic compound having hydroxide, alkoxide or phenoxide anions, are suitable for the production of relief structures having improved contrast.
摘要翻译：正面工作的辐射敏感混合物，主要由（a1）含有酸不稳定基团的水不溶性有机粘合剂组成，并且通过酸的作用使其溶于碱性水溶液，或（a2.1）聚合物粘合剂其不溶于水但可溶于碱性水溶液，（a2.2）其在碱性显影液中的溶解度由于酸的作用而增加的有机化合物，和（b）在作用下产生酸的有机化合物另外含有（c）具有氢氧化物，醇盐或酚盐阴离子的强碱性有机化合物的光化辐射适用于生产具有改善的对比度的浮雕结构。

79. 发明授权

US5318876A Radiation-sensitive mixture containing acid-labile groups and production of relief patterns 失效
标题翻译：含有酸不稳定组的辐射敏感混合物和浮雕图案的生成
公开(公告)号：US5318876A
公开(公告)日：1994-06-07
申请号：US862949
申请日：1992-04-03
申请人： Reinhold Schwalm , Horst Binder , Dirk Funhoff
发明人： Reinhold Schwalm , Horst Binder , Dirk Funhoff
IPC分类号： C08K5/42 , C08K5/51 , G03F7/004 , G03F7/039 , H01L21/027 , G03G1/73 , G03G5/56
CPC分类号： G03F7/0045 , Y10S430/115 , Y10S430/122
摘要： A radiation-sensitive mixture which contains(a) a polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions and(b) an organic compound whose solubility in an aqueous alkaline developer is increased by the action of an acid and which contains one or more groups cleavable by an acid and in addition a group which forms a strong acid under the action of radiation, and additionally(c) an alkyl- or arylsulfonate of a hydroxyaromatic, is suitable for the production of relief patterns.
摘要翻译：一种辐射敏感性混合物，其包含（a）不溶于水但可溶于碱性水溶液的聚合物粘合剂，和（b）通过酸的作用使其在碱性显影剂中的溶解度增加的有机化合物，并含有一种或更多的基团，并且另外在辐射作用下形成强酸的基团，另外（c）羟基芳族化合物的烷基或芳基磺酸盐适用于产生浮雕图案。

80. 发明授权

US5252436A Process for developing a positive-working photoresist containing poly(p-hydroxystyrene) and sulfonium salt with an aqueous developer containing basic organic compounds 失效
标题翻译：用含有碱性有机化合物的含水显影剂开发含有聚（对羟基苯乙烯）和锍盐的正性光致抗蚀剂的方法
公开(公告)号：US5252436A
公开(公告)日：1993-10-12
申请号：US976004
申请日：1992-11-13
申请人： Horst Binder , Reinhold Schwalm
发明人： Horst Binder , Reinhold Schwalm
IPC分类号： G03F7/32 , G03F7/30
CPC分类号： G03F7/322
摘要： An aqueous developer suitable in particular for developing photoresists which contain a phenolic resin and an onium salt contains from 0.5 to 5 % by weight of a tetraalkylammonium hydroxide and from 5 to 25% by weight of at least one amine of the general formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and each is hydrogen, alkyl, hydroxyalkyl or aminoalkyl, or two of R.sup.1 to R.sup.3 combine to form a N-containing ring, with at least one of R.sup.1 to R.sup.3 being hydroxyalkyl or aminoalkyl.
摘要翻译：特别适用于显影含有酚醛树脂和鎓盐的光致抗蚀剂的水性显影剂含有0.5-5重量％的四烷基氢氧化铵和5-25重量％的至少一种通式为“IMAGE”的胺，其中R 1，R 2和R 3相同或不同并且各自为氢，烷基，羟基烷基或氨基烷基，或者R 1至R 3中的两个结合形成含N的环，其中至少一个R 1至R 3为羟烷基或氨基烷基。

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