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71. 发明授权

US4801675A Process for the preparation of prepolymers containing isocyanate groups, the prepolymers obtainable by this process and their use as binders in one-component lacquers 失效
标题翻译：用于制备含异氰酸酯基团的预聚物的方法，可通过该方法获得的预聚物及其作为单组分漆中的粘合剂的用途
公开(公告)号：US4801675A
公开(公告)日：1989-01-31
申请号：US60782
申请日：1987-06-10
申请人： Josef Pedain , Michael Sonntag , Klaus Konig
发明人： Josef Pedain , Michael Sonntag , Klaus Konig
IPC分类号： C08G18/10 , C08G18/42 , C08G18/44 , C08G18/66 , C08G18/79 , C09D175/00 , C09D175/04 , C08G18/28 , C08G18/70 , C08G18/77
CPC分类号： C08G18/792 , C08G18/10 , C08G18/42 , C08G18/423 , C08G18/44 , C08G18/664
摘要： The invention is directed to a process for the preparation of prepolymers containing free isocyanate groups and having an isocyanate content of 1 to 16% by weight by the reaction of(a) a polyisocyanate component with(b) a polyhydroxyl component based on (i) at least one polyester polyol having a hydroxyl functionality (average) of about 1.8 to 5 and a hydroxyl number (average) of from 15 to 300 or (ii) mixtures of polyester polyols of the type mentioned under (i) with up to about 10% by weight, based on the weight of the mixture, of (cyclo)alkane polyols having a hydroxyl number above about 300 and optionally containing ester groupsat an NCO/OH equivalent ratio above 2:1, characterized in that the compounds used as component (a) contain triisocyanato-isocyanurates having aliphatically or cycloaliphatically bound isocyanate groups. The present invention also relates to the prepolymers with free isocyanate groups obtainable by this process and their use as binders for moisture hardening one-component lacquers.
摘要翻译：本发明涉及通过（a）多异氰酸酯组分与（b）多羟基组分的反应制备含有游离异氰酸酯基团和异氰酸酯含量为1至16重量％的预聚物的方法，其基于（i）至少一种具有羟基官能度（平均值）为约1.8至5，羟值（平均）为15至300）的聚酯多元醇或（ii）（i）所述类型的聚酯多元醇与高达约10 重量％，基于混合物的重量，羟基数大于约300的（环）烷烃多元醇和任选地含有高于2:1的NCO / OH当量比的酯基，其特征在于用作组分的化合物（a）含有具有脂族或环脂键结合的异氰酸酯基团的三异氰酸酯 - 异氰脲酸酯。本发明还涉及可通过该方法获得的具有游离异氰酸酯基团的预聚物及其作为湿润硬化单组分漆的粘合剂的用途。

72. 发明授权

US4734532A Process for the preparation of 4,4'-dinitrodibenzyls 失效
标题翻译：制备4,4'-二硝基二苄基的方法
公开(公告)号：US4734532A
公开(公告)日：1988-03-29
申请号：US871018
申请日：1986-06-04
申请人： Richard Kopp , Gerhard Grogler , Klaus Konig , Manfred Schmidt
发明人： Richard Kopp , Gerhard Grogler , Klaus Konig , Manfred Schmidt
IPC分类号： C07C67/00 , C07C201/00 , C07C201/12 , C07C205/06 , C07C205/12 , C07C79/10
CPC分类号： C07C201/12
摘要： 4,4'-dinitrodibenzyls are prepared by reaction of 4-nitrotoluenes, in the presence of an organic solvent and/or diluent, with an alkali metal-alcoholate and/or an alkaline earth metal alcoholate, and subsequent treatment of the reaction mixture with an aqueous solution of hypohalous acids and/or their salts or with chlorine, bromine or an aqueous solution of hydrogen peroxide and/or its salts, or with organic or inorganic peracids and/or their salts.
摘要翻译： 4,4'-二硝基二苄基通过4-硝基甲苯在有机溶剂和/或稀释剂存在下与碱金属醇盐和/或碱土金属醇化物反应制备，随后用反应混合物处理次卤酸和/或其盐的水溶液或氯，溴或过氧化氢和/或其盐的水溶液，或与有机或无机过酸和/或其盐的水溶液。

73. 发明授权

US4692550A Continuous process for thermal splitting of carbamic acid esters 失效
标题翻译：氨基甲酸酯热分解的连续工艺
公开(公告)号：US4692550A
公开(公告)日：1987-09-08
申请号：US485347
申请日：1983-04-15
申请人： Theodor Engbert , Gunter Hammen , Hartmut Knofel , Klaus Konig
发明人： Theodor Engbert , Gunter Hammen , Hartmut Knofel , Klaus Konig
IPC分类号： C07C263/04 , C07C27/00 , C07C31/02 , C07C31/125 , C07C67/00 , C07C241/00 , C07C265/00 , C07C265/04 , C07C265/12 , C07C118/00
CPC分类号： C07C263/04
摘要： N-monosubstituted carbamic acid esters are thermally split on a continuous basis in a tube reactor. The carbamic acid ester which is flowed down or passed over the inner wall of a tube reactor is thermally split at a temperature of from 150.degree. to 450.degree. C. and under a pressure of from 0.001 to 20 bar into at least two fractions. One fraction is predominantly isocyanate and a second fraction is predominantly hydroxyl compound. These fractions may be separated by removing one as a gaseous fraction formed under the splitting conditions from the head of the reactor and collecting the second fraction as a liquid which accumulates at the base of the reactor. If both fractions are gaseous under the splitting conditions, they are both removed from the head of the reactor and subsequently separated by fractionating columns for example. This process is particularly advantageous in that isocyanate and hydroxyl fractions are obtained in high yield without using a solvent.
摘要翻译： N-单取代氨基甲酸酯在管式反应器中以连续的方式热分解。流过或流过管式反应器内壁的氨基甲酸酯在150℃至450℃的温度和0.001至20巴的压力下热分解成至少两个馏分。一个部分主要是异氰酸酯，第二部分主要是羟基化合物。这些级分可以通过除去在分离条件下从反应器的头部形成的气态馏分来分离，并将第二馏分作为积聚在反应器底部的液体进行收集。如果两个馏分在分解条件下都是气态的，则它们都从反应器的头部移出，并随后通过分馏塔例如分离。该方法特别有利的是在不使用溶剂的情况下以高产率获得异氰酸酯和羟基部分。

74. 发明授权

US4525590A Simplified process for the production of polyamines by the alkaline hydrolysis of compounds containing NCO-groups 失效
标题翻译：通过碱性水解含有NCO基团的化合物制备多胺的简化方法
公开(公告)号：US4525590A
公开(公告)日：1985-06-25
申请号：US398493
申请日：1982-07-15
申请人： Werner Rasshofer , Klaus Konig , Holger Meyborg , Walter Meckel , Armin Zenner
发明人： Werner Rasshofer , Klaus Konig , Holger Meyborg , Walter Meckel , Armin Zenner
IPC分类号： C07D251/34 , C07B61/00 , C07C67/00 , C07C213/02 , C07C239/00 , C07C265/02 , C07C265/12 , C07C269/02 , C07C271/20 , C07C271/46 , C07C273/18 , C07C275/00 , C07C275/30 , C07C275/40 , C07C275/62 , C08G18/00 , C08G18/10 , C08G18/50 , C08G18/64 , C08G18/83 , C07C125/06 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to an improved process for the production of polyamines containing urethane and/or urea and/or biuret and/or isocyanurate groups and, preferably, also alkylene ether, carbonate and/or acetal groups by the alkaline hydrolysis of corresponding compounds containing terminal aliphatic and/or aromatic isocyanate groups.To this end, the compounds containing terminal NCO-groups, preferably NCO-preadducts, are converted by means of selected bases into the carbamates and neutralized by introduction into equivalent quantities of acid or by the simultaneous introduction of the components in equivalent quantities into a reaction vessel, after which the polyamines are directly isolated by methods known per se.The invention also relates to the use of the polyamines obtained by the process for the production of polyurethanes.
摘要翻译：本发明涉及一种用于生产含氨基甲酸酯和/或脲和/或缩二脲和/或异氰脲酸酯基团的多胺的改进方法，并且优选还通过碱性水解含有末端的相应化合物的亚烷基醚，碳酸酯和/或缩醛基团脂族和/或芳族异氰酸酯基团。为此，含有末端NCO基团，优选NCO-前加合物的化合物通过选定的碱被转化成氨基甲酸酯并通过引入等量的酸中和或通过同时引入相当量的组分进入反应然后通过本身已知的方法直接分离多胺。本发明还涉及通过该方法生产聚氨酯得到的多胺的用途。

75. 发明授权

US4430505A Process for the preparation of N,O-disubstituted urethanes useful for the preparation of isocyanates 失效
标题翻译：用于制备可用于制备异氰酸酯的N，O-二取代的聚氨酯的方法
公开(公告)号：US4430505A
公开(公告)日：1984-02-07
申请号：US197032
申请日：1980-10-15
申请人： Peter Heitkamper , Klaus Konig , Kurt Findeisen , Rudolf Fauss , Rudolf Sundermann
发明人： Peter Heitkamper , Klaus Konig , Kurt Findeisen , Rudolf Fauss , Rudolf Sundermann
IPC分类号： C07C269/00 , C07C67/00 , C07C241/00 , C07C265/00 , C07C269/04 , C07C271/06 , C07C271/08 , C07C271/28 , C07C271/32 , C07C301/00 , C07C303/30 , C07C303/34 , C07C309/02 , C07C311/00 , C07C313/00 , C07C323/44 , C07C325/00 , C07C331/10 , C07C331/12 , C07C125/065 , C07C125/073
CPC分类号： C07C271/06
摘要： A process for the preparation of N,O-disubstituted urethanes. Urea or polyurets, primary amines and alcohols are reacted at 120.degree.-350.degree. C. in the presence of N-substituted urethanes and/or N-mono- or N,N'-disubstituted ureas or polyureas. In a preferred embodiment, the reactants further include catalysts known to be useful in esterification of carboxylic acids. The urethanes produced in accordance with this process are particularly useful as starting materials for preparation of isocyanates.
摘要翻译：制备N，O-二取代的聚氨酯的方法。在N-取代的氨基甲酸酯和/或N-单或N，N'-二取代的脲或聚脲的存在下，将脲或聚脲，伯胺和醇在120-350℃下反应。在优选的实施方案中，反应物还包括已知可用于羧酸酯化的催化剂。根据该方法制备的聚氨酯特别可用作制备异氰酸酯的原料。

76. 发明授权

US4427798A Solutions of oligo-urethane ethers in polyether polyols and their use in a process for the production of polyurethane foams 失效
标题翻译：聚醚多元醇中的寡聚氨酯醚的溶液及其在生产聚氨酯泡沫体的方法中的应用
公开(公告)号：US4427798A
公开(公告)日：1984-01-24
申请号：US356877
申请日：1982-03-10
申请人： Klaus Konig , Gernot Becker , Peter Seifert
发明人： Klaus Konig , Gernot Becker , Peter Seifert
IPC分类号： C08L71/00 , C08G18/00 , C08G18/10 , C08G18/38 , C08G18/48 , C08G18/50 , C08G18/66 , C08J3/12 , C08L71/02 , C09J5/00 , C09J5/08 , C08G18/14
CPC分类号： C08G18/5045 , C08G18/10 , C08G18/3831 , C08G18/4804 , C08G18/6666
摘要： The invention relates to solutions of(A) from 3 to 60% by weight, based on the combined ether-polyol content, of separately prepared oligo-urethane ethers containing terminal OH.sup.- groups in the form of reaction products of(a) diisocyanates with(b) dialcohols having an average molecular weight of from 200 to 800, the stoichiometric ratio of (a) to (b) amounting to various values based on the average molecular weight of the dialcohols, in(B) polyether polyols containing at least 2 hydroxyl groups and having an average molecular weight of from 1000 to 12,000 and to their use in a proess for the production of polyurethane foams capable of being effectively flame-laminated and (high-frequency) welded without any adverse effect upon their other properties. The process for producing flame-laminatable and high-frequency-weldable flexible polyurethane foams is characterized by the reaction of(i) polyisocyanates with(ii) relatively high molecular weight compounds containing at least 2 hydroxyl groups,(iii) optionally other relatively high molecular weight and/or low molecular weight compounds containing isocyanate-reactive hydrogen atoms and water,(iv) optionally in the presence of other blowing agents, catalysts, foam stabilizers and other additives,such solutions described above being exclusively or partly used as the relatively high molecular weight compounds which contain hydroxyl groups.
摘要翻译：本发明涉及（A）基于所组合的醚 - 多元醇含量的（A）3至60重量％的分别制备的（a）二异氰酸酯与（a）二异氰酸酯的反应产物形式的末端OH-基团的低聚 - （b）平均分子量为200至800的二醇，（a）至（b）的化学计量比为基于二醇的平均分子量而计算的各种值，（B）含至少2个羟基，其平均分子量为1000至12,000，并且用于生产能够有效地进行火焰层压和（高频）焊接的聚氨酯泡沫体，而对其它性能没有任何不利影响。用于生产火焰层压和高频可焊性软质聚氨酯泡沫的方法的特征在于（i）多异氰酸酯与（ii）含有至少2个羟基的相对高分子量化合物的反应，（iii）任选其它相对高分子量含有异氰酸酯反应性氢原子和水的重量和/或低分子量化合物，（iv）任选地在其它发泡剂，催化剂，泡沫稳定剂和其它添加剂的存在下，上述这样的溶液仅仅或部分用作相对高的含有羟基的分子量化合物。

77. 发明授权

US4388238A Process for the preparation of N,O-disubstituted urethanes suitable as a starting material for the preparation of isocyanates 失效
标题翻译：制备适合作为异氰酸酯制备原料的N，O-二取代氨基甲酸酯的方法
公开(公告)号：US4388238A
公开(公告)日：1983-06-14
申请号：US197042
申请日：1980-10-15
申请人： Peter Heitkamper , Klaus Konig , Rudolf Fauss , Kurt Findeisen
发明人： Peter Heitkamper , Klaus Konig , Rudolf Fauss , Kurt Findeisen
IPC分类号： C07B61/00 , B01J23/00 , B01J23/06 , B01J27/00 , B01J31/00 , B01J31/02 , C07C67/00 , C07C239/00 , C07C269/00 , C07C269/04 , C07C271/10 , C07C271/24 , C07C271/26 , C07C271/58 , C07D307/91 , C07C125/065 , C07C125/073 , C07C125/077
CPC分类号： C07D307/91
摘要： A process for the preparation of N,O-disubstituted urethanes. Primary amines and alcohols are reacted with organic compounds having carbonyl groups at 120.degree. to 350.degree. C. Suitable carbonyl-containing compounds include N-unsubstituted urethanes. N-mono-substituted, N,N'-disubstituted ureas, or polyureas may be used in combination with the N-unsubstituted urethane. The product urethanes are particularly suitable for the preparation of isocyanates.
摘要翻译：制备N，O-二取代的聚氨酯的方法。伯胺和醇与120℃至350℃下具有羰基的有机化合物反应。合适的含羰基化合物包括N-未取代的氨基甲酸酯。 N-单取代的N，N'-二取代的脲或聚脲可以与N-未取代的氨基甲酸酯组合使用。产品聚氨酯特别适用于制备异氰酸酯。

78. 发明授权

US4297455A Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups and their use for the preparation of polyester-diol bis-diphenol carbonates and polyester/polycarbonates 失效
标题翻译：通过碳酸酯基延长的聚酯二醇的碳酸芳酯的制备方法及其用于制备聚酯 - 二醇双二酚碳酸酯和聚酯/聚碳酸酯的用途
公开(公告)号：US4297455A
公开(公告)日：1981-10-27
申请号：US910986
申请日：1978-05-30
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
IPC分类号： C08G63/64 , C08G63/00 , C08G63/76
CPC分类号： C08G63/64
摘要： The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups obtained according to the instant invention and their use for the preparation of polyester diol bis-diphenol carbonates, lengthened via carbonate groups, characterized in that polyester-diol bis-aryl carbonates are reacted with a diphenol at a temperature of from about 100.degree. to about 200.degree. C. in vacuo below about 35 mm Hg in the presence of a catalyst, wherein more than 1 mol of diphenol is employed per mol of carbonic acid aryl ester groups of the polyester-diol bis-aryl carbonate, lengthened via carbonate groups, and the resulting hydroxyaryl compound is distilled off.The invention finally relates to the polyester-diol bis-diphenol carbonates, lengthened via carbonate groups obtained according to the instant invention and their use for the preparation of polyester/polycarbonates and the polycarbonate/polyesters so prepared.
摘要翻译：本发明涉及通过-OCOO-基团延长的聚酯二醇的双碳酸芳基酯的制备方法，其特征在于分子量Mn（数均分子）超过250的聚酯二醇优选超过 600，在约100℃至200℃之间，优选约110℃至180℃之间的温度下，用碳酸双芳基酯加热，真空度低于约35mmHg，优选约25mm 和1mm Hg，在催化剂的存在下，每聚酯二醇的OH基和所形成的羟基芳基化合物使用少于1摩尔的碳酸双芳基酯。本发明还涉及通过根据本发明获得的-OCOO-基团延长的聚酯二醇的双碳酸芳基酯及其用于制备通过碳酸酯基团延长的聚酯二醇双 - 二酚酚酸酯的用途，其特征在于在催化剂存在下，聚酯 - 二醇双芳基碳酸酯与二酚在约100至约200℃的温度下在真空下在约35mm Hg下真空反应，其中每次使用多于1mol的二酚将通过碳酸酯基延长的聚酯 - 二醇双芳基碳酸酯的碳酸芳基酯基和所得羟基芳基化合物蒸馏出。本发明最终涉及通过根据本发明获得的碳酸酯基团延长的聚酯 - 二醇双 - 二酚碳酸酯及其制备聚酯/聚碳酸酯和如此制备的聚碳酸酯/聚酯的用途。

79. 发明授权

US4267303A Process for the preparation of polymers with diphenol carbonate end groups 失效
标题翻译：用二酚酚酸酯端基制备聚合物的方法
公开(公告)号：US4267303A
公开(公告)日：1981-05-12
申请号：US070072
申请日：1979-08-27
申请人： Klaus Konig , Manfred Schreckenberg , Christian Lindner , Carlhans Suling , Dieter Freitag
发明人： Klaus Konig , Manfred Schreckenberg , Christian Lindner , Carlhans Suling , Dieter Freitag
IPC分类号： C08G63/00 , C08G63/64 , C08G64/00 , C08G64/20 , C08G63/62
CPC分类号： C08G63/64 , C08G64/00
摘要： This disclosure is concerned with a single step process for the production of diphenol terminated polycarbonates by the transesterification of diphenols, bis-aryl carbonates and polymeric diols with aliphatically bound terminal hydroxyl groups. These diols are selected from polyesters, polyethers, polythioethers and polyacetals. The transesterification is carried out at elevated temperatures under vacuum optionally in the presence of a catalyst with the ratios of the reactants being such as to avoid the retention of any terminal aliphatic hydroxyl groups or aryl carbonate groups.
摘要翻译：本公开涉及通过二酚，双芳基碳酸酯和聚合二醇与脂族结合的末端羟基的酯交换来生产二苯酚封端的聚碳酸酯的单步方法。这些二醇选自聚酯，聚醚，聚硫醚和聚缩醛。酯交换反应在真空下在升高的温度下进行，任选地在催化剂存在下进行，其中反应物的比例为避免保留任何末端脂族羟基或芳基碳酸酯基团。

80. 发明授权

US4231952A Process for the production of monoisocyanate 失效
标题翻译：单异氰酸酯生产工艺
公开(公告)号：US4231952A
公开(公告)日：1980-11-04
申请号：US827913
申请日：1977-08-26
申请人： Hartmut Knofel , Klaus Konig
发明人： Hartmut Knofel , Klaus Konig
IPC分类号： C07C265/02 , C07C20060101 , C07C67/00 , C07C241/00 , C07C263/04 , C07C265/04 , C07C118/00
CPC分类号： C07C263/04
摘要： This invention relates to an improved process for the production of aliphatic relatively low boiling monoisocyanates from the corresponding carbamic acid chlorides, comprising adding an at least equivalent quantity, based on the hydrogen chloride bound in the carbamic acid chloride, of a relatively high boiling organic monoisocyanate or polyisocyanate whose boiling point is higher than the boiling point of the relatively low boiling monoisocyanate to be produced, to the carbamic acid chloride, optionally dissolved in inert organic solvents and then distilling off the relatively low boiling monoisocyanate by heating and/or applying a vacuum, or by means of an inert gas stream.
摘要翻译：本发明涉及用于从相应的氨基甲酸氯化物生产脂族相对低沸点单异氰酸酯的改进方法，其包括以相对高沸点的有机单异氰酸酯为基础，加入基于氨基甲酸氯化物中结合的氯化氢至少等量的或多异氰酸酯，其沸点高于要生产的相对低沸点单异氰酸酯的沸点，氨基甲酸氯化物，任选地溶解在惰性有机溶剂中，然后通过加热和/或施加真空蒸馏掉相对低沸点的单异氰酸酯，或通过惰性气流。

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