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    • 68. 发明申请
    • PROCESS FOR PRODUCING A PURIFIED SYNTHESIS GAS STREAM
    • 生产纯化合成气流的方法
    • US20120046370A1
    • 2012-02-23
    • US13262109
    • 2010-03-30
    • Gerald Sprachmann
    • Gerald Sprachmann
    • C07C27/06C01C3/00C01B3/38
    • C01B3/16B01D53/75B01D2257/304B01D2257/308B01D2257/406B01D2257/408B01D2257/504C01B3/501C01B3/506C01B3/52C01B3/56C01B3/58C01B17/05C01B17/164C01B2203/0415C01B2203/0435C01B2203/0465C01B2203/0475C01B2203/0485Y02P20/152
    • A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising besides the main constituents carbon monoxide and hydrogen also hydrogen sulphide, HCN and/or COS, the process comprising the steps of: (a) contacting one part of the feed synthesis gas stream with a water gas shift catalyst in a shift reactor in the presence of water and/or steam to react at least part of the carbon monoxide to hydrogen and carbon dioxide, to obtain a shifted synthesis gas stream enriched in hydrogen and in carbon dioxide; (b) contacting another part of the feed gas stream with a hydrolysis catalyst in the presence of water to remove HCN and/or COS to obtain a hydrolysed synthesis gas stream depleted in HCN and/or COS; (c) removing H2S from the shifted synthesis gas stream and from the hydrolysed synthesis gas stream by contacting these gas streams in a H2S-removal zone with an aqueous alkaline washing liquid to obtain a H2S-depleted synthesis gas stream and a sulphide-comprising aqueous stream; (d) contacting the sulphide-comprising aqueous stream with sulphide-oxidizing bacteria in the presence of oxygen in a bioreactor to obtain a sulphur slurry and aregenerated aqueous alkaline washing liquid; (e) removing carbon dioxide from the H2S-depleted synthesis gas stream, to obtain the purified synthesis gas stream.
    • 一种从原料合成气流生产纯化的合成气流的方法,除了主要成分一氧化碳和氢气外,还包括硫化氢,HCN和/或COS,该方法包括以下步骤:(a)使一部分进料 合成气流与水煤气变换催化剂在变换反应器中在水和/或蒸汽存在下反应至少一部分一氧化碳与氢气和二氧化碳,以获得富含氢气和碳的转移合成气流 二氧化碳 (b)在水存在下使进料气流的另一部分与水解催化剂接触以除去HCN和/或COS,以获得耗尽HCN和/或COS的水解合成气流; (c)通过将H2S去除区中的这些气流与碱性洗涤液水溶液接触,从移动的合成气流和水解的合成气流中除去H 2 S,以获得贫硫酸的合成气流和含硫化物的水 流; (d)在生物反应器中,在氧的存在下使含硫化物的含水物流与硫化物 - 氧化细菌接触以获得硫浆液并且生成水性碱性洗涤液; (e)从除去H2S的合成气流中除去二氧化碳,以获得纯化的合成气流。