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    • 66. 发明授权
    • Light-sensitive material for silver salt diffusion transfer process with
antihalation dye
    • 光敏材料用于银盐扩散转移工艺与防晕染料
    • US4619893A
    • 1986-10-28
    • US700245
    • 1985-02-11
    • Yoshihiro TakagiKeiichi Adachi
    • Yoshihiro TakagiKeiichi Adachi
    • G03C8/48G03C1/825G03C1/83G03C8/06G03C1/84G03C5/54
    • G03C1/831G03C8/06
    • A light-sensitive material for a silver salt diffusion transfer process is described, having an antihalation layer containing at least one oil-soluble dye represented by following general formula (I) ##STR1## wherein X represents a benzene ring, a thiazole ring or a benzothiazole ring each having at least one electron attractive group selected from a nitro group, a cyano group, an alkylsulfonyl group, a halogen atom, and a trifluoromethyl group; R.sub.1, R.sub.2, R.sub.3, R.sub.4 each represents hydrogen, a substituted or unsubstituted alkyl group having 1 to 12 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 12 carbon atoms, a substituted or unsubstituted alkylamido group having 2 to 30 carbon atoms or a substituted or unsubstituted arylamido group having 6 to 30 carbon atoms; any Y and Z each represents hydrogen or a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms.
    • 描述了用于银盐扩散转移方法的感光材料,其具有含有至少一种由以下通式(I)表示的油溶性染料的防晕层:其中X表示苯环,噻唑 环或苯并噻唑环,其各自具有至少一个选自硝基,氰基,烷基磺酰基,卤素原子和三氟甲基的吸电子基团; R 1,R 2,R 3,R 4各自表示氢,取代或未取代的碳原子数1〜12的烷基,取代或未取代的碳原子数1〜12的烷氧基,取代或未取代的碳原子数2〜30的烷基酰胺基或 取代或未取代的碳原子数为6〜30的芳基酰氨基; 任何Y和Z各自表示氢或具有1至10个碳原子的取代或未取代的烷基。
    • 68. 发明授权
    • Polymeric pH-sensitive optical filter agents having hydrazone moieties
attached thereto
    • 具有连接有腙部分的聚合物pH敏感光学滤光剂
    • US4468494A
    • 1984-08-28
    • US250401
    • 1981-04-02
    • Derek H. R. BartonIrena Y. Bronstein-BonteLloyd D. Taylor
    • Derek H. R. BartonIrena Y. Bronstein-BonteLloyd D. Taylor
    • G03C8/48C08F8/34C08F8/30
    • G03C8/48
    • Polymeric optical filter agents and photographic products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive optical filter agents comprising polymeric backbone units having the following hydrazone moiety: ##STR1## where R is a group which can provide a double bond for conjugation with the ##STR2## portion of the moiety to provide light-absorbing capability for the agent at a pH above its pKa, and X represents a substituent of R providing at least one electron-withdrawing group. The polymeric pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The polymeric optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosenstive elements against the occurence of fogging during in-light development.
    • 公开了聚合物光学滤光剂和使用它们的照相产品和方法。 聚合物光学过滤剂是pH敏感的光学过滤剂,其包含具有以下腙部分的聚合物主链单元:其中R是能够提供双键以与该部分的“IMAGE”部分缀合以提供光的基团 - 在高于其pKa的pH下的试剂的吸收能力,X表示提供至少一个吸电子基团的R的取代基。 聚合物pH敏感光学过滤剂在高于pKa的pH下具有高度着色的光吸收形式,并且在低于pKa的pH下基本上不吸收。 聚合物光学滤光剂可用于照相胶片单元和用于保护光敏光敏元件免于在光照显影过程中发生雾化的过程。
    • 69. 发明授权
    • Thiazine-1,1-dioxide and isothiazole-1,1-dioxide derivatives
    • 噻嗪-1,1-二氧化物和异噻唑-1,1-二氧化物衍生物
    • US4359574A
    • 1982-11-16
    • US175291
    • 1980-08-04
    • Stanley M. BloomAlan L. BorrorJames W. Foley
    • Stanley M. BloomAlan L. BorrorJames W. Foley
    • C07C43/225C07D275/06C07D279/02C07D295/073C07D309/12C07D455/04C07F7/18C09B11/04G03C8/48C07D275/04C07D279/08
    • C07D275/06C07C43/225C07D279/02C07D295/073C07D309/12C07D455/04C07F7/1804C09B11/04G03C8/48Y02P20/55
    • In one aspect, this invention relates to a method of synthesizing certain 3-(4'-OH-carbocyclic aryl)-3-(carbocyclic aryl)-2,3-dihydrobenz[d]isothiazole-1,1-dioxides (and -2,3-dihydronaphtho[1,8-de]-1,2-thiazine-1,1-dioxides) by reacting a 3-(4'-OP-carbocyclic aryl)-3-(carbocyclic aryl)-2,3-dihydrobenz[d]isothiazole-1,1-dioxide (or a 3-(4'-OP-carbocyclic aryl)-3-(carbocyclic aryl)-2,3-dihydronaphtho[1,8-de]-1,2-thiazine-1,1-dioxide) wherein P is a protecting group with a carboxylic acid halide in pyridine to yield the corresponding 2-carbonyl derivative followed by removing the protecting group with weak acid to give the product. Optionally, the acylation step may be carried out by sequentially reacting the starting compound with an alkali metal hydride to give the corresponding 2-alkali metal salt and then reacting with the carboxylic acid halide in a suitable inert organic solvent. The products produced comprise phenol and 1-naphthol sulfam(na)phthaleins useful, for example, as photographic optical filter agents and filter agent precursors.In another aspect, the present invention relates to the carbonyl-substituted and alkali metal-substituted 2,3-dihydrobenz[d]isothiazole-1,1-dioxides and 2,3-dihydronaphtho[1,8-de]-1,2-thiazine-1,1-dioxides produced as intermediates in the above synthesis.
    • 一方面,本发明涉及合成某些3-(4'-OH-碳环芳基)-3-(碳环芳基)-2,3-二氢苯并[d]异噻唑-1,1-二氧化物(和 - 2,3-二氢萘并[1,8-de] -1,2-噻嗪-1,1-二氧化物),使3-(4'-OP-碳环芳基)-3-(碳环芳基)-2,3 - 二氢苯并[d]异噻唑-1,1-二氧化物(或3-(4'-OP-碳环芳基)-3-(碳环芳基)-2,3-二氢萘并[1,8-de] -1,2 - 噻嗪-1,1-二氧化物)其中P是在吡啶中的羧酰卤的保护基,得到相应的2-羰基衍生物,随后用弱酸除去保护基,得到产物。 任选地,酰化步骤可以通过使起始化合物与碱金属氢化物顺序反应来进行,得到相应的2-碱金属盐,然后在合适的惰性有机溶剂中与羧酸卤化物反应。 所生产的产品包括苯酚和1-萘酚亚磺酸(na)酞类,其可用作例如照相光学过滤剂和过滤剂前体。 另一方面,本发明涉及羰基取代的和碱金属取代的2,3-二氢苯并[d]异噻唑-1,1-二氧化物和2,3-二氢萘并[1,8-de] -1,2 在上述合成中作为中间体生产的噻嗪-1,1-二氧化物。