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61. 发明申请

US20080262138A1 CURING COMPOSITIONS FOR FLUOROPOLYMERS 有权
标题翻译：氟聚合物固化组合物
公开(公告)号：US20080262138A1
公开(公告)日：2008-10-23
申请号：US12139181
申请日：2008-06-13
申请人： Werner M.A. Grootaert , Eric W. Adair , Miguel A. Guerra
发明人： Werner M.A. Grootaert , Eric W. Adair , Miguel A. Guerra
IPC分类号： C08K5/04 , C08G73/24
CPC分类号： C08K5/19 , C08K5/50 , Y10T428/215 , C08L27/12
摘要： A curative composition comprising a cation and an anion of the formula Anq−Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq− is an anion, provided that at least one Aq− is selected from the formula: wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R′ groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R′ can be the same as R, with the proviso that R′ cannot be halo. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.
摘要翻译：包含阳离子和式A的阴离子的固化剂组合物，其中m ，n，p和q是正整数，其中m * p = n * q，其中Q m +是有机鎓，A q - 是阴离子，条件是从下式中选择至少一个A q - ：其中每个R独立地是H，卤素，烷基，芳基，芳烷基或环烷基，并且也可以是卤化的，氟化的或全氟化的其中R和R'基团中的两个或多个可以一起形成环，其中每个R基团可独立地含有一个或多个杂原子，其中R'可以与R相同，条件是R'不能为光环。还提供了包含该固化剂的含氟聚合物组合物，制备含氟聚合物的方法和含有可固化或固化的含氟聚合物组合物的含氟聚合物制品。

62. 发明授权

US06900287B1 Fluctional fluorocopolymer 有权
标题翻译：荧光含氟共聚物
公开(公告)号：US06900287B1
公开(公告)日：2005-05-31
申请号：US09674249
申请日：1999-04-23
申请人： Nobuhiko Tsuda , Takahiro Kitahara , Miyuki Iwakiri , Masaru Nagato , Ryoichi Fukagawa
发明人： Ryuji Iwakiri
IPC分类号： C08F210/02 , C08F214/26 , C08F214/28 , C08F216/14 , C08G73/24 , C08F214/18
CPC分类号： C08F214/267 , C08F214/265 , C08F214/28 , C08F210/02 , C08F218/00
摘要： To provide a fluorine-containing copolymer having functional group which contains a hydrocarbon vinyl ether unit having functional group and a tetrafluoroethylene unit, has a fluorine content of not less than 10% by weight, is insoluble in tetrahydrofuran substantially, is excellent in adhesion to a substrate and makes it possible to carry out crosslinking easily.
摘要翻译：为了提供具有含有具有官能团的烃类乙烯醚单元和四氟乙烯单元的具有官能团的含氟共聚物，氟含量不小于10重量％，基本上不溶于四氢呋喃，对于底物，并且可以容易地进行交联。

63. 发明授权

US5859182A Fluorine-containing polyquinazolone polymer and separation membrane using the same 失效
标题翻译：含氟聚喹唑酮聚合物和使用其的分离膜
公开(公告)号：US5859182A
公开(公告)日：1999-01-12
申请号：US803981
申请日：1997-02-21
申请人： Hisao Hachisuka , Kenichi Ikeda
发明人： Hisao Hachisuka , Kenichi Ikeda
IPC分类号： B01D71/62 , C08G73/06 , C08G73/24
CPC分类号： C08G73/0694 , B01D71/62
摘要： A fluorine-containing polyquinazolone polymer having a bisquinazolone unit represented by Formula 1 as the repeating unit is used for a gas separation membrane so that great chemical and heat resistance is provided. The membrane also has great permeability and effective separability, as well as excellent mechanical strength. ##STR1## where R.sub.1 indicates a tetravalent organic group, R.sub.2 respectively indicate an alkyl group or an aromatic group, R.sub.3 indicates a divalent organic group, and R.sub.1 and/or R.sub.3 indicates an organic group having at least one fluorine atom.
摘要翻译：将由式1表示的双喹唑酮单元作为重复单元的含氟聚喹唑酮聚合物用于气体分离膜，从而提供极好的耐化学性和耐热性。该膜还具有很好的渗透性和有效的可分离性，以及优异的机械强度。式1其中R1表示四价有机基团，R2分别表示烷基或芳基，R3表示二价有机基团，R 1和/或R 3表示具有至少一个氟原子的有机基团。

64. 发明授权

US5807967A Fluoroaliphatic cyanate resins for low dielectric applications 失效
公开(公告)号：US5807967A
公开(公告)日：1998-09-15
申请号：US621149
申请日：1996-03-21
申请人： Arthur W. Snow , Leonard J. Buckley
发明人： Arthur W. Snow , Leonard J. Buckley
IPC分类号： C08G73/06 , H05K1/03 , C08G63/44 , C08G69/00 , C08G73/24
CPC分类号： C08G73/065 , C08G73/0644 , C08G73/0655 , H05K1/0366 , H05K1/0346 , H05K1/0373 , H05K2201/015 , H05K2201/0209 , H05K2201/0212 , H05K2201/0278 , Y10S428/924 , Y10T428/24926 , Y10T428/31504 , Y10T428/31525
摘要： The present invention is a cyanate resin monomer having the formula: NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCN where n is an even integer from 6 to 10, inclusive. Another aspect of the invention is an essentially pure cyanate resin mono having the formula: NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCN where n=3, 4, 6, 8, or 10. Another aspect of the invention is a prepolymer made by the process of heating a monomer of the invention to a conversion below the gel point. Another aspect of the invention is a method for depositing an interlevel dielectric resin on an integrated circuit, having the steps: (a) coating the integrated circuit with a thin film of a prepolymer made by the process of heating a monomer of the invention to below the gel point, and (b) curing the prepolymer to at least the gel point. Another aspect of the invention is a low dielectric thermoset polymer resin made from these monomers. Another aspect of the invention is a composite of a resin of the invention combined with another material or materials, for structural and/or electronic applications. Such materials include powders and fibers made from, e.g., fused silica or quartz. Another aspect of the invention is making and purifying the monomers of the invention.

65. 发明授权

US5493005A Hydroxy-pendent benzoxazole copolymers 失效
标题翻译：羟基 - 苯并恶唑共聚物
公开(公告)号：US5493005A
公开(公告)日：1996-02-20
申请号：US393587
申请日：1995-02-21
申请人： Fred E. Arnold , Jom P. Chen
发明人： Fred E. Arnold , Jom P. Chen
IPC分类号： C08G73/22 , C08G77/452 , C08L83/02 , C08G73/24
CPC分类号： C08G77/452 , C08G73/22 , C08L83/02
摘要： Alcohol-soluble, aromatic heterocyclic copolymers having repeating units of the formula: ##STR1## wherein x has a value of 0.10 to 0.90 and y has a value of 1.0-x. These copolymers are useful in the preparation of organic/inorganic hybrid materials having transparency which comprise the sol-gel derived, hydrolytically condensed reaction product of a metal alkoxide of the formula M(OR).sub.w wherein R is a lower alkyl group, M is Si, Ti, Al or a mixture thereof, and w is the valence value of M, and the above copolymer.
摘要翻译：具有下式重复单元的醇溶性芳族杂环共聚物：其中x具有0.10至0.90的值，y的值为1.0-x。这些共聚物可用于制备具有透明性的有机/无机杂化材料，其包含式M（OR）w的金属醇盐的溶胶 - 凝胶衍生的水解缩合反应产物，其中R是低级烷基，M是Si ，Ti，Al或它们的混合物，w是M的化合价值，和上述共聚物。

66. 发明授权

US3965184A Novel materials containing nitrogen 失效
标题翻译：含氮的新材料
公开(公告)号：US3965184A
公开(公告)日：1976-06-22
申请号：US327839
申请日：1973-01-30
申请人： Ronald Eric Banks , Robert Neville Haszeldine
发明人： Ronald Eric Banks , Robert Neville Haszeldine
IPC分类号： C08K5/00 , C07C291/00 , C07D241/04 , C07D271/08 , C08G73/00 , C08G73/24 , C08K5/32 , C08K5/35 , C07C135/02
CPC分类号： C08G73/24
摘要： Compositions of matter including the structural unit ##EQU1## wherein R.sub. F ' is a divalent polyfluoroalkylene group having a chain length of from 1 to 4 carbon atoms which may be substituted at one or more positions with chloro-or polyfluoroalkyl, chlorofluoroalkyl or polyfluorocycloalkyl groups containing up to six carbon atoms; and R.sub.F is a monovalent straight or branched chain, or cyclic, polyfluoroalkyl group or a chlorofluoroalkyl group containing up to ten carbon atoms and the R.sub.F groups are the same or different or is a divalent polyfluoroalkylene group having a chain length of from 1 to 4 carbon atoms which may be substituted at one or more positions with chloro or polyfluoroalkyl, chlorofluoroalkyl or polyfluorocycloalkyl groups containing up to six carbon atoms and the R.sub.F groups are interconnected to form a cyclic structure.
摘要翻译：包括结构单元的组合物-N-R'F -NO - | RFRF其中RF'是具有1至4个碳原子的链长的二价多氟亚烷基，其可以在一个或多个位置被取代，含有至多6个碳原子的氯代或多氟烷基，氯氟烷基或多氟环烷基; RF是具有至多10个碳原子的一价直链或支链或环状多氟烷基或氯氟烷基，RF基团相同或不同，或为链长为1至4碳数的二价多氟亚烷基可以在一个或多个位置被氯原子或多氟烷基取代的原子，氯氟烷基或含有至多六个碳原子的多氟环烷基，并且RF基团互连形成环状结构。

67. 发明授权

US3812206A Polyfluoropolymers 失效
标题翻译：聚氟乙烯
公开(公告)号：US3812206A
公开(公告)日：1974-05-21
申请号：US32784073
申请日：1973-01-30
申请人： SECR DEFENCE BRIT
发明人： BANKS R , HASZELDING R
IPC分类号： C08L27/12 , C08F8/30 , C08G73/24 , C08K5/17 , C08F29/16
CPC分类号： C08G73/24 , C08F8/30 , C08F14/18
摘要： A PROCESS FOR CROSS-LINKING A POLYFLUOROPOLYMER CONTAINING PENDANT PERFLUOROVINYL GROUPS INCLUDING THE STEP OF TREATING THE POLYFLUOROPOLYMER WITH AN EFFECTIVE AMOUNT OF A CROSS-LINKING AGENT INCLUDING THE STRUCTURAL UNIT:

-N(-RF)-R''F-N(-RF)-O-O-

WHEREIN R''F IS A DIVALENT POLYFLUOROALKYLENE GROUP HAVING A CHAIN LENGTH OF FROM 1 TO 4 CARBON ATOMS WHICH MAY BE SUBSTITUTED AT ONE OR MORE POSITIONS WITH CHLORO- OR POLYFLUOROALKYL, CHLOROFLUOROALKYL OR POLYFLUOROCYCLOALKYL GROUPS CONTAINING UP TO SIX CARBON ATOMS, AND RF IS A MONOVALENT STRAIGHT OR BRANCHED CHAIN, OR CYCLIC, POLYFLUOROALKYL GROUP OR A CHLOROFLUOROALKYL GROUP CONTAINING UP TO TEN CARBON ATOMS AND THE RF GROUPS ARE THE SAME OR DIFFERENT OR IS A DIVALENT POLYFLUOROALKYLENE GROUP HAVING A CHAIN LENGTH OF FROM 1 TO 4 CARBON ATOMS WHICH MAY BE SUBSTITUTED AT ONE OR MORE POSITIONS WITH CHLORO- OR POLYFLUOROALKYL, CHLOROFLUOROALKYL OR POLYFLUOROCYCLOALKYL GROUPS CONTAINING UP TO SIX CARBON ATOMS AND THE RF GROUPS ARE INTERCONNECTED TO FORM A CYCLIC STRUCTURE.

68. 发明授权

US3733295A Fluorocarbon filled carboxynitroso polybutadiene vulcanizate 失效
标题翻译：氟化硼填充碳氧化钛聚丁二烯
公开(公告)号：US3733295A
公开(公告)日：1973-05-15
申请号：US3733295D
申请日：1970-12-28
申请人： TRW INC
发明人： MARTIN J , BURNS E , MEYERS R
IPC分类号： C08C19/30 , C08G18/69 , C08G73/24 , C08F45/04 , C08F45/14
CPC分类号： C08C19/30 , C08G18/69 , C08G73/24
摘要： A DECREASE IN PERMEABILITY AND AN INCREASE IN CHEMICAL RESISTANCE OF CARBOXYNITROSO RUBBERS CAN BE EFFECTED BY THE ADDITION OF SMALL AMOUNTS OF POLYBUTADIENE RESINS AND POWDERED TETRAFLUOROETHYLENE POLYMER FILLER. LIQUID FUNCTIONALLY TERMINATED POLYBUTADIENE AND POWDERED POLYTETRAFLUOROETHYLENE ARE MIXED INTO A TERPOLYMER CONTAINING TRIFLUORONITROSOMETHANE, TETRAFLUOROETHYLENE, AND A SMALL AMOUNT OF NITROSOPERFLUOROBUTYRIC ACID. THE MIXTURE IS CURED IN THE PRESENCE OF A PEROXIDE FREE RADICAL INITIATOR.

69. 发明授权

US3725374A Cured nitrosofluorocarbon rubber 失效
标题翻译：固化硝基氟橡胶
公开(公告)号：US3725374A
公开(公告)日：1973-04-03
申请号：US3725374D
申请日：1970-10-30
申请人： THIOKOL CHEMICAL CORP
发明人： MAYES N , GREEN J , MICHAELS R
IPC分类号： C08G73/24 , C08F3/24
CPC分类号： C08G73/24
摘要： WHEREIN R is a -O-(lower alkyl) group of one to seven carbon atoms; p is from 1 to 6; T is a halogen, a perhaloalkyl, -NO, and -NO2; and the ratio m : n is from 0 : 1 to 50 : 1, preferrably n can be from 0.1 percent to 10 percent of the units in the polymer. The polymers are cured with such curing agents as an epoxide, a metal oxide, and chromium perfluoroacetate to produce rubbers having good physical properties and chemical resistance. Thus, liquid and solid polymers are provided as well as elastomers derived therefrom.

OR

A cured, nitroso polymer has been provided by curing polymers obtained by polymerizing monomers which have pendant groups convertible to pendant moieties which are crosslinkable. Some of these monomers with the crosslinkable, pendant groups cannot be introduced into the polymer directly. The polymers with the pendant groups are derived from monomers forming recurring units as represented by the general formulas:
摘要翻译：已经通过固化聚合获得的聚合物来提供固化的亚硝基聚合物，该单体具有可转变成可交联的侧基的侧基的单体。这些具有可交联侧基的单体中的一些不能直接引入聚合物。具有侧基的聚合物衍生自形成由通式表示的重复单元的单体：

70. 发明授权

US3554885A Process for preparing nitroso-substituted esters of fluorocarbon acids 失效
标题翻译：制备硝基取代的氟代酯的方法
公开(公告)号：US3554885A
公开(公告)日：1971-01-12
申请号：US3554885D
申请日：1968-05-02
申请人： PCR
发明人： OLIVER WARD H
IPC分类号： C07C201/00 , C07C201/04 , C07C203/00 , C07C207/00 , C08G69/48 , C08G73/24 , B01J1/10 , C07C81/08
CPC分类号： C07C201/00 , C07C201/04 , C08G69/48 , C08G73/24 , C07C203/00 , C07C207/00
摘要： COMPOUNDS OF THE FORMULAS

ON-(CF2)(2,3)-COO-CH3 AND

CH3-OOC-(CF2)(2,3)-O-N(-(CF2)(2,3)-COO-CH3)2

ARE PRODUCED BY REACTING METHYL NITRIETE AND PERFLUOROGLUTARIC ANHYDRIDE OR PERFLUOROSUCCINIC ANHYDRIDE AND THEN DECARBOXYLANTING THE RESULATNT PRODUCT. THE COMPOUNDS, WHICH CAN BE HYDROLYZED TO PRODUCE THE CORRESPONDING NITROSO-SUBSTITUTED FLUORCARBON ACIDS, ARE USED AS COMONOMERS IN NITRROSO RUBBERS.

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