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61. 发明授权

US4621072A Process for preparing abrasion-resistant coated catalysts 失效
标题翻译：制备耐磨涂层催化剂的方法
公开(公告)号：US4621072A
公开(公告)日：1986-11-04
申请号：US710078
申请日：1985-02-26
申请人： Dietrich Arntz , Gunter Prescher , Werner Burkhardt , Johannes Heilos , Reinhard Manner
发明人： Dietrich Arntz , Gunter Prescher , Werner Burkhardt , Johannes Heilos , Reinhard Manner
IPC分类号： C07C57/05 , B01J23/22 , B01J23/30 , B01J23/34 , B01J23/68 , B01J23/84 , B01J23/88 , B01J23/885 , B01J23/89 , B01J27/192 , B01J27/198 , B01J27/199 , B01J33/00 , B01J37/02 , C07B31/00 , C07B33/00 , C07B61/00 , C07C27/00 , C07C27/14 , C07C45/00 , C07C45/35 , C07C47/052 , C07C47/22 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C253/00 , C07C253/18 , C07C255/08 , C07D213/84 , B01J27/224 , B01J23/00 , B01J27/19
CPC分类号： C07D213/84 , B01J23/885 , B01J27/192 , B01J37/0223 , C07C45/35 , C07C51/252 , B01J2523/00
摘要： A process is disclosed for preparing coated catalysts, inter alia, for gas phase oxidations in organic chemistry, comprised of an inert support and a coating of catalyst material enclosing this support, wherein a suspension of the starting material for the coating is sprayed onto an agitated bed of the support, while the suspending medium is being partially removed by a gas stream, and the raw material is then dried and heat-treated. For this purpose, the support bed is mechanically agitated and loosened by a gas stream blown in from below. The catalyst precursor containing a binder and, if appropriate, a pore-former is sprayed in an increasing amount from above onto the bed, the ratio between suspending medium sprayed on and drawn off remaining about constant. The thermal expansion coefficient of the precursor as a dry powder must not deviate by more than 15% from that of the support. The applied coating is densified by continuing the mechanical and fluidizing mixing motion, the material is then dried in a continuing gas stream and heat-treated, if appropriate after decomposition of an added pore-former.
摘要翻译：公开了一种用于制备涂覆的催化剂的方法，特别是用于有机化学中的气相氧化，包括惰性载体和包围该载体的催化剂材料的涂层，其中用于涂层的起始材料的悬浮液被喷涂到搅拌的同时通过气流部分地除去悬浮介质，然后将原料干燥和热处理。为此，支撑床被从下方吹入的气流机械搅拌和松动。含有粘合剂的催化剂前体，如果合适的话，将成孔剂从上面以增加的量喷洒到床上，喷雾和吸出的悬浮介质之间的比例保持不变。作为干粉的前体的热膨胀系数不能偏离载体的热膨胀系数的15％以上。施加的涂层通过继续机械和流化混合运动致密化，然后将材料以连续的气流干燥，并在适当的情况下在加入的成孔剂分解后进行热处理。

62. 发明授权

US4609634A High efficiency extraction method for recovering oxidation catalyst material from dimethyl terephthalate esterified oxidate residue and the like 失效
标题翻译：从对苯二甲酸二甲酯酯化氧化残渣等回收氧化催化剂材料的高效提取方法
公开(公告)号：US4609634A
公开(公告)日：1986-09-02
申请号：US227012
申请日：1981-01-21
申请人： William M. King, Jr.
发明人： William M. King, Jr.
IPC分类号： B01J23/68 , B01J38/68 , C07C67/08 , C07C67/48
CPC分类号： B01J23/68
摘要： Disclosed is a highly efficient continuous method for the aqueous extraction of water-soluble oxidation catalyst material from a residue such as that generated in the production of dimethyl terephthalate from p-xylene by the molecular oxygen oxidation and methanol esterification process. In the method the desired end product is an aqueous solution of the catalyst material. The residue to be extracted is established in finely dispersed condition in part of the aqueous solution at a weight ratio of aqueous solution to residue of above about 1:1 and maintained in that condition for a length of time sufficient for maximum transfer of catalyst material from the residue to the aqueous solution to take place. The resulting dispersion then is separated in a phase separation zone into an aqueous phase and an extracted residue phase. The separated aqueous phase is withdrawn from the phase separation zone as the aqueous solution. The separated extracted residue phase is withdrawn from the phase separation zone, and part of it is admixed gently with an aqueous solvent (for example, water) and returned to the phase separation zone.
摘要翻译：公开了一种高效连续的方法，用于通过分子氧氧化和甲醇酯化方法从残留物中提取水溶性氧化催化剂材料，例如通过对二甲苯生产对苯二甲酸二甲酯产生的残留物。在该方法中，所需的最终产物是催化剂材料的水溶液。要提取的残余物以细分散的条件在水溶液中以水溶液与残余物的重量比高于约1：1，并在该条件下保持一段足以使催化剂材料从残留物发生水溶液。然后将所得分散体在相分离区中分离成水相和萃取的残余相。分离的水相作为水溶液从相分离区取出。将分离的萃取的残留相从相分离区取出，并将其一部分与水性溶剂（例如水）轻轻混合并返回到相分离区。

63. 发明授权

US4504599A Method for production or activation of antimony-containing metal oxide catalysts 失效
标题翻译：用于生产或活化含锑金属氧化物催化剂的方法
公开(公告)号：US4504599A
公开(公告)日：1985-03-12
申请号：US551741
申请日：1983-11-14
申请人： Yutaka Sasaki , Yoshimi Nakamura
发明人： Yutaka Sasaki , Yoshimi Nakamura
IPC分类号： B01J27/02 , B01J23/18 , B01J23/20 , B01J23/34 , B01J23/36 , B01J23/64 , B01J23/68 , B01J23/84 , B01J23/843 , B01J23/85 , B01J23/89 , B01J27/057 , B01J27/18 , B01J27/186 , B01J37/04 , B01J37/08 , B01J38/00 , B01J38/02 , C07B61/00 , C07C51/235 , C07C51/25 , C07C67/00 , C07C253/00 , C07C253/26 , C07C255/08 , B01J23/10 , B01J23/72
CPC分类号： C07C51/252 , B01J23/18 , B01J23/8435 , B01J23/85 , B01J27/0576 , B01J27/186 , C07C51/235 , C07C51/25
摘要： Antimony-containing metal oxide catalysts are produced or activated by dry blending (a) a catalyst or catalyst precursor composed of an antimony-containing metal oxides composition containing antimony and at least one element selected from the group consisting of iron, cobalt, nickel, manganese, cerium, uranium, tin, titanium, and copper, and (b) elemental antimony or an antimony compound, and contacting the components (a) and (b) with each other at about 300.degree. C. to about 1000.degree. C. in a non-reducing gas atmosphere for a period sufficient for the elemental antimony or antimony compound (b) to deposit on the catalyst or catalyst precursor (a).
摘要翻译：含锑金属氧化物催化剂通过干混（a）催化剂或催化剂前体来制备或活化，所述催化剂或催化剂前体由含有锑的金属氧化物组合物组成，所述组合物含有锑和至少一种选自铁，钴，镍，锰，铈，铀，锡，钛和铜，和（b）元素锑或锑化合物，并使组分（a）和（b）彼此在约300℃至约1000℃下接触非还原气体气氛使元素锑或锑化合物（b）沉积在催化剂或催化剂前体（a）上足够长的时间。

64. 发明授权

US4415757A Production of saturated carbonyl compounds 失效
标题翻译：饱和羰基化合物的制备
公开(公告)号：US4415757A
公开(公告)日：1983-11-15
申请号：US358103
申请日：1982-03-15
申请人： David R. Pyke , Robert Reid
发明人： David R. Pyke , Robert Reid
IPC分类号： B01J23/50 , B01J23/68 , B01J23/89 , C07C29/50 , C07C45/33 , C07C47/07 , C07C51/215 , C07C45/32
CPC分类号： C07C51/215 , B01J23/50 , B01J23/68 , B01J23/89 , C07C29/50 , C07C45/33
摘要： A process for the production of a saturated carbonyl compound which comprises bringing into reaction at an elevated temperature in the gas phase an alkane with molecular oxygen and a hydrogen halide in the presence of a solid particulate catalyst composition comprising (1) metallic silver and/or a compound thereof and (2) one or more compounds of at least one other metal having a variable valency.Useful for the production of acetaldehyde from ethane.
摘要翻译：一种制备饱和羰基化合物的方法，其包括在固体颗粒催化剂组合物的存在下，在气相中使分子氧和卤化氢的烷烃在高温下进行反应，所述固体颗粒催化剂组合物包含（1）金属银和/或其化合物和（2）一种或多种具有可变价态的至少一种其它金属的化合物。适用于从乙烷生产乙醛。

65. 发明授权

US4415482A Oxidation and ammoxidation catalyst 失效
标题翻译：氧化和氨氧化催化剂
公开(公告)号：US4415482A
公开(公告)日：1983-11-15
申请号：US320403
申请日：1981-11-12
申请人： Jerry R. Ebner
发明人： Jerry R. Ebner
IPC分类号： B01J23/31 , B01J23/34 , B01J23/68 , B01J27/057 , B01J27/198 , B01J27/199 , C07B61/00 , C07C45/34 , C07C45/35 , C07C47/22 , C07C67/00 , C07C253/00 , C07C255/08 , B01J29/16 , B01J21/02 , B01J27/02 , B01J27/14
CPC分类号： C07C45/35 , B01J23/002 , B01J23/31 , B01J23/686 , B01J27/0573 , B01J27/0576 , B01J27/199 , C07C253/26 , C07C45/34 , B01J2523/00 , Y02P20/52
摘要： Disclosed herein are catalysts useful for oxidation and ammoxidation of hydrocarbons. Such catalysts have the empirical formulaBiMo.sub.a V.sub.b Sb.sub.c M.sub.d O.sub.xwherein a is 0.5-2, b is 0.01-0.12, c is 0.01-10, d is 0-0.5 and x is selected to satisfy the valence requirements of the other elements present. In such catalysts, M is one or more elements selected from Groups I-A, II-A, III-A, V-A, VI-A, I-B, IV-B, VI-B and VII-B of the Periodic Table.Catalysts according to the invention are prepared by forming a slurry of a vanadium component, an antimony component, a hydrophilic bismuth molybdate component having the empirical formulaBiMo.sub.a O.sub.x. Y(H.sub.2 O) wherein a is 0.5-2, x is selected to satisfy the valence requirements of the bismuth and molybdenum and Y is a number such that the bound water is 5 to 40 weight percent of the total component, and optionally, the compound M and/or a support material, drying the slurry, and calcining to form the catalyst.Such catalysts are specifically useful for production of acrylonitrile from propylene, ammonia and an oxygen-containing gas.
摘要翻译：本文公开了可用于烃的氧化和氨氧化的催化剂。这样的催化剂具有经验式BiMoaVbSbcMdOx，其中a为0.5-2，b为0.01-0.12，c为0.01-10，d为0-0.5，x选择为满足存在的其它元素的化合价要求。在这样的催化剂中，M是选自元素周期表的I-A，II-A，III-A，V-A，VI-A，I-B，IV-B，VI-B和VII-B族中的一种或多种元素。根据本发明的催化剂通过形成具有经验式BiMoaOx的钒组分，锑组分，亲水性钼酸铋组分的浆料来制备。 Y（H 2 O）其中a为0.5-2，选择x以满足铋和钼的化合价要求，Y为结合水为总组分的5至40重量％，并且任选地，化合物 M和/或载体材料，干燥浆料，并煅烧以形成催化剂。这种催化剂特别适用于从丙烯，氨和含氧气体生产丙烯腈。

66. 发明授权

US4389382A Method of using a simplified low cost catalyst system 失效
标题翻译：使用简化的低成本催化剂体系的方法
公开(公告)号：US4389382A
公开(公告)日：1983-06-21
申请号：US284763
申请日：1981-07-20
申请人： Haren S. Gandhi , Karen M. Adams
发明人： Haren S. Gandhi , Karen M. Adams
IPC分类号： B01D53/94 , B01J23/64 , B01J23/644 , B01J23/652 , B01J35/02 , B01D53/36 , B01J23/68
CPC分类号： B01D53/945 , B01J23/6527 , Y02T10/22
摘要： There is disclosed a method of using an exhaust gas catalyst for treatment of exhaust gases developed by burning a hydrocarbon based fuel in an internal combustion engine. These exhaust gases contain varying amounts of unburned hydrocarbons, carbon monoxide and oxides of nitrogen depending upon the operating conditions of the internal combustion engine. This specification teaches use of an improved catalyst composition in which a support medium is provided for supporting the catalyst system, the support medium having an upstream support portion and a downstream support portion over which the exhaust gases pass in succession. The upstream support portion of the support medium has palladium deposited thereon and the downstream support portion of the support medium has tungsten deposited thereon. The catalyst system has particular utility as a three-way catalyst operating at approximately stoichiometric conditions or as a catalyst for use in conjunction with the fast burn engines or as an oxidation catalyst.
摘要翻译：公开了一种使用废气催化剂来处理通过在内燃机中燃烧烃类燃料而产生的废气的方法。根据内燃机的运行条件，这些废气含有不同量的未燃烧的烃，一氧化碳和氮的氧化物。本说明书教导了使用改进的催化剂组合物，其中提供支撑介质以支撑催化剂体系，所述载体介质具有上游支撑部分和下游支撑部分，排气通过该下游支撑部分连续通过。支撑介质的上游支撑部分具有沉积在其上的钯，并且支撑介质的下游支撑部分上沉积有钨。该催化剂体系作为在大约化学计量条件下操作的三元催化剂或作为与快速燃烧发动机结合使用的催化剂或作为氧化催化剂的特殊用途。

67. 发明授权

US4317747A Promoted U-Sb-oxide catalysts 失效
标题翻译：促进的U-Sb氧化物催化剂
公开(公告)号：US4317747A
公开(公告)日：1982-03-02
申请号：US95886
申请日：1979-11-16
申请人： Dev D. Suresh , Robert K. Grasselli
发明人： Dev D. Suresh , Robert K. Grasselli
IPC分类号： B01J23/18 , B01J23/24 , B01J23/68 , B01J23/88 , B01J23/888 , C07C5/48 , B01J23/12 , B01J23/20
CPC分类号： B01J23/8875 , B01J23/24 , B01J23/68 , B01J23/8876 , B01J23/8877 , B01J23/888 , C07C253/26 , C07C5/48 , Y02P20/52
摘要： Certain multiply promoted U-Sb-oxides are superior catalysts for the ammoxidation of olefins to the corresponding unsaturated nitriles, the selective oxidation of olefins to unsaturated aldehydes and acids, and the oxyde-hydrogenation of olefins to diolefins.
摘要翻译：某些多重促进的U-Sb氧化物是用于将烯烃氨氧化成相应的不饱和腈的优异催化剂，将烯烃选择性氧化成不饱和醛和酸，以及将烯烃氧化成氢化成二烯烃。

68. 发明授权

US4272408A Stable molybdenum catalysts for high conversion of C.sup.3 and C.sup.4 olefins to corresponding unsaturated aldehydes and acids 失效
标题翻译：稳定的钼催化剂用于将C3和C4烯烃转化为相应的不饱和醛和酸
公开(公告)号：US4272408A
公开(公告)日：1981-06-09
申请号：US133045
申请日：1980-03-24
申请人： Chelliah Daniel
发明人： Chelliah Daniel
IPC分类号： C07C57/05 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/32 , B01J23/652 , B01J23/68 , B01J23/88 , B01J27/02 , B01J27/057 , B01J27/186 , B01J27/188 , B01J27/19 , B01J27/192 , B01J27/198 , B01J27/199 , C07C45/34 , C07C45/35 , C07C45/38 , C07C51/00 , C07C51/25 , C07C67/00 , C07C253/00 , C07C255/08 , B01J27/14 , B01J27/06 , B01J27/24
CPC分类号： B01J23/8885 , B01J23/24 , B01J23/88 , B01J23/887 , B01J23/8876 , B01J27/02 , B01J27/0573 , B01J27/0576 , B01J27/186 , C07C45/34 , C07C45/35 , C07C45/38 , C07C51/252 , B01J2523/00
摘要： A stabilized heteropoly molybdate catalyst precursor in calcined form and containing anionic molybdenum in defect state is surface impregnated with certain metal cations. The stabilized precursor is one obtained by incorporating into the reaction product of a molybdate and a soluble phosphate, silicate or arsenate, an aqueous chloride ion and a compound of phosphotungstate, silicotungstate, vanadium arsenate, silico-arsenate, phosphovanadate, or silicovanadate, followed by drying and calcining. During the chloride ion stabilization step other metals may be optionally incorporated in forming the stabilized precursor.The obtained precursor is catalytically active in the conversion of the unsaturated aldehydes to the corresponding unsaturated carboxylic acids with or without incorporation of the metal cation during the chloride ion stabilization step. When the obtained calcined precursor is surface impregnated with a Group VIII metal cation, preferably cobalt and/or iron, and with a compound of selenium or tellurium, the resulting catalysts are highly active and are capable of direct conversion of C.sub.3 -C.sub.4 monoolefins in a single step to the corresponding unsaturated carboxylic acids.
摘要翻译：煅烧形式的稳定的杂多钼酸盐催化剂前体和含有缺陷状态的阴离子钼的表面用某些金属阳离子浸渍。稳定化的前体是通过掺入钼酸盐和可溶性磷酸盐，硅酸盐或砷酸盐的反应产物，氯化物离子和磷钨酸盐，硅钨酸盐，砷酸砷砷，硅酸钙，磷酸钒酸盐或硅酸钒酸盐的反应产物，然后是干燥和煅烧。在氯离子稳定化步骤期间，其它金属可以任选引入到形成稳定的前体中。所得前体在氯离子稳定化步骤中，在不加入金属阳离子的情况下，不饱和醛转化为相应的不饱和羧酸具有催化活性。当所获得的煅烧前体用第VIII族金属阳离子，优选钴和/或铁表面浸渍，并与硒或碲化合物一起表面浸渍时，所得催化剂具有高活性，并且能直接转化C 3 -C 4单烯烃单步进入相应的不饱和羧酸。

69. 发明授权

US4271091A Vapor phase catalytic oxidation and/or ammoxidation of cyclohexanone and/or cyclohexanol to phenol and/or aniline 失效
标题翻译：环己酮和/或环己醇对苯酚和/或苯胺的气相催化氧化和/或氨氧化
公开(公告)号：US4271091A
公开(公告)日：1981-06-02
申请号：US916649
申请日：1978-06-17
申请人： Robert K. Grasselli , Dev D. Suresh
发明人： Robert K. Grasselli , Dev D. Suresh
IPC分类号： B01J23/16 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/68 , B01J23/84 , B01J23/88 , B01J23/888 , B01J27/186 , C07C37/06 , C07C37/07 , C07C85/06 , C07C7/12 , C07C7/144
CPC分类号： B01J23/887 , B01J23/16 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/68 , B01J23/84 , B01J23/888 , B01J27/186 , C07C37/06 , C07C37/07 , Y02P20/52
摘要： Cyclohexanone and/or cyclohexanol can be oxidized in the vapor phase to phenol by contacting the cyclohexanone and/or cyclohexanol with a suitable oxidation catalyst in the presence of molecular oxygen. Suitable catalysts are solids comprising Mo, W, Sb and/or V oxides or complexes thereof. The catalysts may be promoted with additional elements.
摘要翻译：环己酮和/或环己醇可以在气相中被氧化成苯酚，通过在分子氧存在下使环己酮和/或环己醇与合适的氧化催化剂接触。合适的催化剂是包含Mo，W，Sb和/或V氧化物或其络合物的固体。可以用附加元素促进催化剂。

70. 发明授权

US4250054A Catalysts for producing unsaturated aliphatic acids 失效
标题翻译：用于生产不饱和脂肪酸的催化剂
公开(公告)号：US4250054A
公开(公告)日：1981-02-10
申请号：US691691
申请日：1976-06-01
申请人： Wilfrid G. Shaw , Ernest C. Milberger , Serge R. Dolhyj
发明人： Wilfrid G. Shaw , Ernest C. Milberger , Serge R. Dolhyj
IPC分类号： B01J23/28 , B01J23/30 , B01J23/32 , B01J23/34 , B01J23/36 , B01J23/68 , B01J23/88 , B01J23/887 , B01J23/888 , B01J23/89 , B01J27/199 , C07C51/25 , B01J23/10 , B01J23/22 , B01J27/18
CPC分类号： B01J23/8878 , B01J23/002 , B01J23/28 , B01J23/30 , B01J23/32 , B01J23/34 , B01J23/36 , B01J23/68 , B01J23/887 , B01J23/8885 , B01J23/8993 , B01J27/199 , C07C51/25 , C07C51/252 , B01J2523/00
摘要： The present invention relates to a process for the production of unsaturated aliphatic acids and the catalyst therefor, by the vapor phase oxidation of the corresponding unsaturated aliphatic aldehydes with molecular oxygen, optionally in the presence of steam, in the presence of an oxidation catalyst consisting of the oxides of the elements molybdenum, vanadium, tungsten and lanthanum, and optionally one or more of the oxides of the elements manganese, iron, copper, aluminum, cobalt, nickel, phosphorus, zinc, bismuth, silver, cadmium, niobium, arsenic, chromium, the alkali and the alkaline earth elements.
摘要翻译：本发明涉及一种制备不饱和脂族酸及其催化剂的方法，通过相应的不饱和脂族醛与分子氧的气相氧化，任选地在蒸汽存在下，在氧化催化剂的存在下，在由元素钼，钒，钨和镧的氧化物，以及锰，铁，铜，铝，钴，镍，磷，锌，铋，银，镉，铌，砷，铬，碱和碱土元素。

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