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61. 发明申请

US20090117439A1 ELECTROLYTE MEMBRANE FOR FUEL CELL 有权
标题翻译：燃料电池用电解质膜
公开(公告)号：US20090117439A1
公开(公告)日：2009-05-07
申请号：US12265828
申请日：2008-11-06
申请人： Tatsuo Fujinami , Takuya Mase , Masayoshi Takami
发明人： Tatsuo Fujinami , Takuya Mase , Masayoshi Takami
IPC分类号： H01M8/10
CPC分类号： H01M8/1037 , H01M8/1023 , H01M8/1027 , H01M8/1039 , H01M8/1051 , H01M8/1067 , H01M2008/1095 , H01M2300/0082 , H01M2300/0091
摘要： An electrolyte membrane for a fuel cell includes: a proton conductive material in which hollow inorganic fine particles having through-holes on the surface of the hollow inorganic fine particles, are filled with an electrolyte resin; and a non-proton conductive polymer.
摘要翻译：用于燃料电池的电解质膜包括：质子传导材料，其中在中空无机细颗粒的表面上具有通孔的中空无机细颗粒填充有电解质树脂; 和非质子导电聚合物。

62. 发明申请

US20090068544A1 FUEL CELL USING POLYHYDRIC MIXTURES DIRECTLY AS A FUEL 审中-公开
标题翻译：燃料电池直接作为燃料使用聚合物混合物
公开(公告)号：US20090068544A1
公开(公告)日：2009-03-12
申请号：US12205873
申请日：2008-09-06
申请人： Steven Ragsdale , Chris Ashfield
发明人： Steven Ragsdale , Chris Ashfield
IPC分类号： H01M8/00 , C10L1/18
CPC分类号： H01M8/1013 , C10L1/1216 , C10L1/1233 , C10L1/1802 , C10L1/1822 , C10L1/1826 , C10L1/19 , C10L1/191 , H01M4/8605 , H01M4/9016 , H01M4/923 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1037 , Y02E60/522
摘要： There is disclosed a fuel cell having an anode and cathode and using either glycerol or biodiesel process waste (containing about 90% glycerol) as a fuel source to generate power and oxidize glycerol to oxidized fragments and carbon dioxide. More particularly, there is disclosed a liquid fuel cell incorporating a membrane-electrode assembly (MEA) wherein the electrocatalysts are embedded in or adjacent a polymeric conducting membrane with which they form the fuel cell body and glycerol or biodiesel process waste is oxidized to form the power source.
摘要翻译：公开了一种具有阳极和阴极的燃料电池，并且使用甘油或生物柴油工艺废料（含有约90％的甘油）作为燃料源以产生动力并将甘油氧化成氧化的碎片和二氧化碳。更具体地，公开了一种结合了膜 - 电极组件（MEA）的液体燃料电池，其中电催化剂嵌入或邻近形成燃料电池体的聚合物导电膜，并且甘油或生物柴油工艺废物被氧化形成能量源。

63. 发明授权

US07368198B2 Polymer nanocomposite membrane and fuel cell using the same 有权
标题翻译：聚合物纳米复合膜和使用其的燃料电池
公开(公告)号：US07368198B2
公开(公告)日：2008-05-06
申请号：US10927194
申请日：2004-08-27
申请人： Hae-kyoung Kim , Jae-sung Lee , Chang-houn Rhee , Hyuk Chang
发明人： Hae-kyoung Kim , Jae-sung Lee , Chang-houn Rhee , Hyuk Chang
IPC分类号： H01M8/10 , C08J5/20
CPC分类号： B82Y30/00 , H01B1/122 , H01M8/1009 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1037 , H01M8/1039 , H01M8/1044 , H01M8/1048 , H01M8/1053 , H01M2300/0082
摘要： A hydrogen ionic conductive inorganic material having a layered structure, wherein a moiety containing a functional group with hydrogen ionic conductivity is introduced between layers of an inorganic material having a nano-sized interlayer distance. A polymer nanocomposite membrane including a reaction product of the hydrogen ionic conductive inorganic material and a conductive polymer, and a fuel cell using the same, are also provided. In the polymer nanocomposite membrane, a conductive polymer may be intercalated to a hydrogen ionic conductive inorganic material having a layered structure or products exfoliated from an inorganic material having a layered structure are dispersed in a conductive polymer.
摘要翻译：具有层状结构的氢离子导电无机材料，其中含有具有氢离子导电性的官能团的部分被引入具有纳米尺寸层间距离的无机材料的层之间。还提供了包括氢离子导电无机材料和导电聚合物的反应产物的聚合物纳米复合膜以及使用其的燃料电池。在聚合物纳米复合膜中，可以将导电性聚合物嵌入到具有层状结构的氢离子导电性无机材料或从具有层状结构的无机材料剥离的产物分散在导电性聚合物中。

64. 发明申请

US20080070094A1 Organic/inorganic composite electrolyte membranes using zeolite and fuel cell comprising the same 有权
标题翻译：使用沸石的有机/无机复合电解质膜和包含该有机/无机复合电解质膜的燃料电池
公开(公告)号：US20080070094A1
公开(公告)日：2008-03-20
申请号：US11812536
申请日：2007-06-19
申请人： Yong Park , Chong Shin , Kwon Sohn , Bong Lee , Jae Chang , Eun Ju Kim
发明人： Yong Park , Chong Shin , Kwon Sohn , Bong Lee , Jae Chang , Eun Ju Kim
IPC分类号： H01M4/86 , H01M8/02
CPC分类号： H01M8/1051 , H01M4/92 , H01M4/926 , H01M4/96 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1037 , H01M8/1039 , H01M2300/0082 , H01M2300/0091
摘要： Disclosed is an organic/inorganic composite electrolyte membrane comprising: (a) a sulfonated fluorine-free hydrocarbon-based polymer; and (b) inorganic particles capable of collecting moisture, wherein the inorganic particles include zeolite. Also, disclosed are an electrode comprising the zeolite as a component for forming a catalyst layer, a membrane electrode assembly comprising the electrolyte membrane and/or the electrode, and a fuel cell having the membrane electrode assembly. The organic/inorganic composite electrolyte membrane using the hydrophilic zeolite in combination with the sulfonated fluorine-free hydrocarbon-based polymer shows high proton conductivity, and thus can impart excellent quality to a fuel cell even under high-temperature and low-humidity conditions.
摘要翻译：公开了一种有机/无机复合电解质膜，其包含：（a）磺化无氟烃基聚合物; 和（b）能够收集水分的无机颗粒，其中无机颗粒包括沸石。此外，公开了包含沸石作为形成催化剂层的组分的电极，包含电解质膜和/或电极的膜电极组件和具有膜电极组件的燃料电池。使用亲水性沸石与磺化无氟烃基聚合物组合的有机/无机复合电解质膜显示高质子传导性，因此即使在高温低湿条件下也能赋予燃料电池优异的品质。

65. 发明申请

US20070213495A1 Proton conducting membrane, method for producing the same, and fuel cell using the same 审中-公开
标题翻译：质子导电膜及其制造方法以及使用其的燃料电池
公开(公告)号：US20070213495A1
公开(公告)日：2007-09-13
申请号：US11727036
申请日：2007-03-23
申请人： Shigeki Nomura , Toshiya Sugimoto , Masanori Nakamura , Kenji Yamauchi
发明人： Shigeki Nomura , Toshiya Sugimoto , Masanori Nakamura , Kenji Yamauchi
IPC分类号： C08G77/04
CPC分类号： C08G77/28 , C08G77/50 , C08J5/2275 , C08J2383/06 , H01B1/122 , H01M4/8605 , H01M8/1037 , H01M8/1051 , H01M8/1074 , H01M2300/0082 , H01M2300/0091 , Y02P70/56 , Y10T442/2467
摘要： The present invention provides relates to a crosslinkable, proton-conducting membrane having a crosslinked structure, excellent in heat resistance, durability, dimensional stability and fuel barrier characteristics, and showing excellent proton conductivity at high temperature, characterized by comprising (a) an organic/inorganic hybrid structure (A) covalently bonded to 2 or more silicon-oxygen crosslinks and, at the same time, having a carbon atom, and (b) an acid containing structure (B) having an acid group, covalently bonded to a silicon-oxygen crosslink and having an acidic group; and provides a fuel cell using the same membrane. The present invention also provides a method for producing the proton-conducting membrane, comprising steps of preparing a mixture containing an organic/inorganic hybrid, crosslinkable compound (C) and compound (D), the former having 2 or more crosslinkable silyl groups and carbon atoms each being bonded to the silyl group via the covalent bond and the latter having a crosslinkable silyl group and acid group, as the first step; forming the above mixture into a film as the second step; and hydrolyzing/condensing or only condensing the hydrolyzable silyl group contained in the mixture formed into the film to form a crosslinked structure as the third step.
摘要翻译：本发明涉及具有交联结构，耐热性，耐久性，尺寸稳定性和燃料阻隔特性优异的交联性质子传导膜，并且在高温下显示出优异的质子传导性，其特征在于包括（a）有机/ 共价结合到2个以上的硅 - 氧交联基团，同时具有碳原子的无机杂化结构（A），和（b）具有酸基的含酸结构体（B），共价键合到硅 - 氧交联并具有酸性基团; 并提供使用相同膜的燃料电池。本发明还提供一种生产质子传导膜的方法，包括以下步骤：制备含有有机/无机杂化物，可交联化合物（C）和化合物（D）的混合物，前者具有2个或更多个可交联甲硅烷基和碳作为第一步，各自通过共价键与甲硅烷基键合的原子，后者具有交联性甲硅烷基和酸基; 将上述混合物形成为第二步骤的膜; 并将形成的混合物中所含的可水解甲硅烷基水解/缩合或缩合形成第三步的交联结构。

66. 发明申请

US20070122675A1 Neutral Protic-Salt Electrolytes and Protic-Salt Imbibed Polymer Membranes for High Temperature Fuel Cell Applications 有权
标题翻译：用于高温燃料电池应用的中性衍生盐电解质和衍生盐吸收聚合物膜
公开(公告)号：US20070122675A1
公开(公告)日：2007-05-31
申请号：US11535467
申请日：2006-09-26
申请人： Charles Angell , Xiao-Guang Sun , Jean-Philippe Belieres , Dominic Gervasio
发明人： Charles Angell , Xiao-Guang Sun , Jean-Philippe Belieres , Dominic Gervasio
IPC分类号： H01M8/10 , C08J5/22
CPC分类号： H01M8/1004 , H01B1/122 , H01M8/0293 , H01M8/08 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1037 , H01M8/1051 , H01M8/1072 , H01M2008/1095 , H01M2300/0082 , Y02P70/56
摘要： A neutral protic salt electrolyte and a protic-salt imbibed polymer electrolyte membrane exhibiting high ionic conductivity and thermal stability at temperatures greater than 100° C. without requiring additional humidification systems or hydrating water is disclosed. The protic salt is the neutral product of acids and bases for which the proton transfer energy lies in the range from 0.5 to 1.5 eV. A polymer electrolyte membrane having the general formula: wherein A is a repeating unit in the main chain, B is a crosslinker chain, C is an end group, YZ is a neutralized couple at chain end, Il is an ionic liquid, and NP is a nanoparticle which absorbs the protic liquid yielding membranes that combine high mechanical strength with high conductivity. The present polymer electrolyte membrane is useful in high temperature fuel cell for automotive, industrial, and mobile communication applications.
摘要翻译：公开了一种中性质子盐电解质和质子盐吸收的聚合物电解质膜，其在高于100℃的温度下表现出高离子导电性和热稳定性，而不需要额外的加湿系统或水合水。质子盐是酸和碱的中性产物，其质子转移能量在0.5至1.5eV的范围内。一种具有以下通式的聚合物电解质膜：其中A是主链中的重复单元，B是交联剂链，C是端基，YZ是链端的中和的二价，Il是离子液体，NP是吸收质子液体的纳米颗粒，产生具有高机械强度和高导电性的膜。本发明的高分子电解质膜可用于汽车，工业和移动通信应用的高温燃料电池。

67. 发明申请

US20070059577A1 Proton exchange membrane fuel cell using solid electrolyte membrane of sheet silicate minerals and an intercalation compound 审中-公开
标题翻译：质子交换膜燃料电池使用硅酸铝矿物的固体电解质膜和插层化合物
公开(公告)号：US20070059577A1
公开(公告)日：2007-03-15
申请号：US10529877
申请日：2003-10-20
申请人： Yasuaki Takeuchi , Satoru Suzuki , Katsuyuki Kawamura , Mitsuru Sano
发明人： Yasuaki Takeuchi , Satoru Suzuki , Katsuyuki Kawamura , Mitsuru Sano
IPC分类号： H01M8/10 , H01M4/94
CPC分类号： H01M8/1016 , H01B1/122 , H01M8/1004 , H01M8/1009 , H01M8/1018 , H01M8/1027 , H01M8/1037 , H01M8/1048 , Y02E60/522 , Y02E60/523
摘要： A solid proton exchange membrane and a membrane-electrode assembly (MEA) for use in fabricating an inexpensive and efficient proton exchange fuel cell (PEFC) which enables direct use of an organic fuel without a reformer and use of hydrogen gas. In particular, an electrochemical cell including a solid electrolyte membrane made of one or plural kinds of layered silicate minerals or intercalation compounds. The layered silicate minerals can be easily fabricated into a solid electrolyte membrane which shows a “molecular sieve effect” on the target fuel if the density and impregnated liquid contents are properly controlled. The catalyst can be selected from a wide range of candidate materials. The use of the layered silicate mineral allows to fabricate an inexpensive direct methanol fuel cell (DMFC) and a realistic direct ethanol fuel cell (DEFC). Furthermore, an energy-efficient PEFC using hydrogen gas can also be produced therefrom.
摘要翻译：用于制造廉价且有效的质子交换燃料电池（PEFC）的固体质子交换膜和膜 - 电极组件（MEA），其能直接使用无重整器的有机燃料并使用氢气。特别是，包括由一种或多种层状硅酸盐矿物或嵌入化合物制成的固体电解质膜的电化学电池。层状硅酸盐矿物可以容易地制成固体电解质膜，如果密度和浸渍的液体内容物被适当地控制，其对目标燃料显示“分子筛效应”。催化剂可以从广泛的候选材料中选择。使用层状硅酸盐矿物允许制造廉价的直接甲醇燃料电池（DMFC）和现实的直接乙醇燃料电池（DEFC）。此外，也可以由其制造使用氢气的节能型PEFC。

68. 发明授权

US07183370B2 Phosphonic-acid grafted hybrid inorganic-organic proton electrolyte membranes (PEMs) 有权
标题翻译：膦酸接枝杂化无机 - 有机质子电解质膜（PEMs）
公开(公告)号：US07183370B2
公开(公告)日：2007-02-27
申请号：US10938268
申请日：2004-09-10
申请人： Siwen Li , Meilin Liu , Kohei Hase , Masatsugu Nakanishi , Wen Li , Junzo Ukai
发明人： Siwen Li , Meilin Liu , Kohei Hase , Masatsugu Nakanishi , Wen Li , Junzo Ukai
IPC分类号： C08G77/30
CPC分类号： C08L83/08 , C08G77/30 , H01M8/1037 , H01M8/1039 , H01M8/1072 , H01M2300/0082 , Y02P70/56
摘要： A proton conducting polymer is formed by the copolymerization of a plurality of compounds, including a silicon compound comprising an organic chain, and a compound including at least one acid group. The polymer comprises a hybrid organic-inorganic matrix having acid groups linked through a linking group. The linking group may include one or more electron withdrawing groups. The electron withdrawing group may be a halogen.
摘要翻译：通过多种化合物（包括含有有机链的硅化合物）与包含至少一个酸基的化合物的共聚形成质子传导性聚合物。聚合物包含具有通过连接基团连接的酸基团的杂化有机 - 无机基质。连接基团可以包括一个或多个吸电子基团。吸电子基团可以是卤素。

69. 发明申请

US20060199059A1 Ion conductive polymer electrolyte and its membrane electrode assembly 审中-公开
标题翻译：离子导电聚合物电解质及其膜电极组件
公开(公告)号：US20060199059A1
公开(公告)日：2006-09-07
申请号：US11364405
申请日：2006-02-28
申请人： Helen Xu
发明人： Helen Xu
IPC分类号： H01M8/10 , C08J5/20 , B05D5/12
CPC分类号： H01M8/1011 , B01D69/141 , H01M4/8828 , H01M4/8878 , H01M8/1004 , H01M8/1023 , H01M8/103 , H01M8/1034 , H01M8/1037 , H01M8/1039 , H01M8/1072 , H01M8/1081 , H01M2300/0082 , H01M2300/0094 , Y02E60/523 , Y02P70/56
摘要： A membrane electrode assembly comprising a solid proton conducting polymer membrane, an anode, a cathode, the anode and the cathode being on opposing surfaces of the membrane, and a catalyst layer in contact with each surface of the membrane, the assembly comprising a polymer electrolyte comprising a base polymer containing ionic conducting groups, said polymer having flexible and strong molecular chains, and rigid, conductive nanoparticles disbursed among the base polymer.
摘要翻译：一种膜电极组件，包括固体质子导电聚合物膜，阳极，阴极，阳极和阴极在膜的相对表面上，以及与膜的每个表面接触的催化剂层，该组件包括聚合物电解质包括含有离子导电基团的基础聚合物，所述聚合物具有柔性和强分子链，以及在基础聚合物中分配的刚性导电纳米颗粒。

70. 发明申请

US20060194089A1 Method for producing a membrane for a fuel cell 失效
标题翻译：燃料电池用膜的制造方法
公开(公告)号：US20060194089A1
公开(公告)日：2006-08-31
申请号：US11351697
申请日：2006-02-10
申请人： Hubertus Biegert , Peter Britz , Gabor Toth , Peter Urban
发明人： Hubertus Biegert , Peter Britz , Gabor Toth , Peter Urban
IPC分类号： H01M8/10 , C08J5/22
CPC分类号： C08J5/2218 , H01M8/1023 , H01M8/1037 , H01M8/1039 , H01M8/1044 , H01M8/1074 , Y02P70/56 , Y10T29/49115
摘要： The invention relates to an ion-conductive polymer membrane for a fuel cell, whereby the polymer membrane is configured from a polymer-forming hydrocarbon material and to a method for producing the same. The membrane also has a metal-containing gel which has been hydrolysed and/or condensed from a metal alkoxide starting material and which is deposited in the polymer and/or is chemically bonded to the polymer. The proportion of metal alkoxide by weight, in relation to the membrane, lies between 25% and 1%.
摘要翻译：本发明涉及一种用于燃料电池的离子导电聚合物膜，其中聚合物膜由形成聚合物的烃材料构成，并且涉及其制造方法。膜还具有已经从金属醇盐起始材料水解和/或冷凝并且沉积在聚合物中和/或化学键合到聚合物上的含金属凝胶。相对于膜，金属醇盐的重量比例在25％至1％之间。

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