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61. 发明授权

US4615961A Protected metal components 失效
标题翻译：受保护的金属部件
公开(公告)号：US4615961A
公开(公告)日：1986-10-07
申请号：US667033
申请日：1984-11-01
申请人： George B. Park , John A. Cook , Robert H. McLoughlin
发明人： George B. Park , John A. Cook , Robert H. McLoughlin
IPC分类号： H01M2/16 , H01M4/02 , H01M4/13 , H01M4/38 , H01M4/66 , H01M6/10 , H01M6/14 , H01M2/32
CPC分类号： H01M4/06 , H01M4/13 , H01M4/381 , H01M4/382 , H01M6/10 , H01M6/14 , H01M2/1673 , H01M2004/027 , H01M2300/0017 , H01M2300/0025 , H01M4/661 , Y10T29/49115
摘要： Continuous metal electrodes are protected by non-porous fluid-impermeable material which is convertible to a fluid-permeable (porous) state, enabling the protective material to act as an electrode separator after the conversion. Conversion by contact with the non-aqueous fluid in a lithium cell is preferred, using strips of lithium protected with a blend of polyethylene and polyethylene oxide, the latter being extractable by the cell liquids.
摘要翻译：连续金属电极由可渗透（多孔）状态的非多孔不透液体材料保护，使得保护材料能够在转化后充当电极分离器。优选使用锂电池中的非水溶液接触进行的转化，使用由聚乙烯和聚环氧乙烷共混物保护的锂条，后者可由电池液体萃取。

62. 发明授权

US4612265A Stabilization of sulfur dioxide solutions containing lithium perchlorate and a tetraalkylammonium perchlorate 失效
标题翻译：稳定含有高氯酸锂和高氯酸四烷基铵的二氧化硫溶液
公开(公告)号：US4612265A
公开(公告)日：1986-09-16
申请号：US776599
申请日：1985-09-16
申请人： John F. Connolly , Robert J. Thrash , Richard A. Kretchmer
发明人： John F. Connolly , Robert J. Thrash , Richard A. Kretchmer
IPC分类号： H01M6/14
CPC分类号： H01M6/14
摘要： Solutions containing lithium perchlorate and a tetraalkylammonium perchlorate dissolved in liquid sulfur dioxide can be stabilized by the addition of a material selected from the group consisting of iodine, bromine, chlorine, iodide salts, bromide salts and chloride salts.
摘要翻译：溶解在液态二氧化硫中的含有高氯酸锂和高氯酸四烷基铵的溶液可通过加入选自碘，溴，氯，碘化物盐，溴化物盐和氯化物盐的材料来稳定。

63. 发明授权

US4594299A Electrode article 失效
标题翻译：电极物品
公开(公告)号：US4594299A
公开(公告)日：1986-06-10
申请号：US667035
申请日：1984-11-01
申请人： John A. Cook , George B. Park , Robert H. McLoughlin
发明人： John A. Cook , George B. Park , Robert H. McLoughlin
IPC分类号： H01M4/06 , H01M2/16 , H01M4/12 , H01M4/13 , H01M4/38 , H01M6/10 , H01M6/14 , H01M6/18 , H01M4/08 , H01M2/14
CPC分类号： H01M4/13 , H01M4/06 , H01M4/381 , H01M4/382 , H01M6/10 , H01M6/14 , H01M6/181 , H01M2/1673 , H01M2004/027 , H01M2300/0025 , Y10T29/49112
摘要： Electrode material, preferably lithium metal, is protected by a layer of material ready to function as an electrode separator and capable of sufficient ionic conductivity to provide an electrolyte, preferably a solvent-free polymeric electrolyte. The electrode material may be rolled to reduce its thickness while so protected.
摘要翻译：电极材料，优选锂金属，被一层准备好作为电极分离器的材料保护并能够具有足够的离子导电性以提供电解质，优选不含溶剂的聚合物电解质。电极材料可以被轧制以减小其厚度，同时如此保护。

64. 发明授权

US4581307A High specific energy electrochemical cell with low initial impedance 失效
标题翻译：具有低初始阻抗的高比能量电化学电池
公开(公告)号：US4581307A
公开(公告)日：1986-04-08
申请号：US715348
申请日：1985-03-25
申请人： Yves Jumel
发明人： Yves Jumel
IPC分类号： H01M4/06 , H01M6/14 , H01M6/16
CPC分类号： H01M4/06 , H01M6/14
摘要： A high specific energy electrochemical cell comprises: a negative active material (4) based on an alkali metal or on an alkaline-earth metal; a separator (8); a non-aqueous liquid electrolyte; and a positive electrode comprising a solid active mass (5). The positive mass is provided, on its electrolyte side, with a porous and electron conductive metal covering (12) which does not participate in the electrochemical reaction, whose thickness is of the order of a few microns, and which is in contact with the metal portions serving as a positive current collector. The covering greatly reduces the initial impedance of the cell.
摘要翻译：高比能量电化学电池包括：基于碱金属或碱土金属的负极活性材料（4）; 分离器（8）; 非水电解液; 和包含固体活性物质（5）的正极。在其电解质侧上提供正质量的多孔和电子导电金属覆盖物（12），其不参与电化学反应，其厚度为几微米量级，并且与金属接触部分作为正极集电体。封装大大降低了电池的初始阻抗。

65. 发明授权

US4565752A Electrochemical cell having wound electrode structures 失效
标题翻译：具有缠绕电极结构的电化学电池
公开(公告)号：US4565752A
公开(公告)日：1986-01-21
申请号：US685638
申请日：1984-12-24
申请人： Franz Goebel , Timothy B. Haskins , David C. Batson
发明人： Franz Goebel , Timothy B. Haskins , David C. Batson
IPC分类号： H01M6/10 , H01M6/14 , H01M6/16
CPC分类号： H01M6/10 , H01M6/14
摘要： A type of electrochemical cell has elements wound in a coil and inserted in a sealed can. One element has a metal substrate carrying a plurality of holes. The metal substrate supports layers of an electrode material such as porous carbon. Both edges and one end of the substrate is kept free of the material. The bare end of the substrate is on the outside of the coil. The substrate is wider than other elements of the coil, so that when the coil is inserted in the can, the substrate makes contact with all the internal surfaces of the can.
摘要翻译：一种电化学电池具有缠绕在线圈中并插入密封罐中的元件。一个元件具有承载多个孔的金属基底。金属基板支撑多孔碳等电极材料层。衬底的两个边缘和一个端部保持没有材料。基板的裸露端在线圈的外侧。衬底比线圈的其它元件宽，使得当线圈插入罐中时，衬底与罐的所有内表面接触。

66. 发明授权

US4543305A Method of pretreating carbon black powder to improve cathode performance and lithium sulfuryl chloride cell including the pretreated carbon black powder 失效
公开(公告)号：US4543305A
公开(公告)日：1985-09-24
申请号：US715808
申请日：1985-03-25
申请人： Michael Binder , Charles W. Walker, Jr. , Eric R. Petersen , William L. Wade, Jr. , Sol Gilman
发明人： Michael Binder , Charles W. Walker, Jr. , Eric R. Petersen , William L. Wade, Jr. , Sol Gilman
IPC分类号： C09C1/56 , H01M4/36 , H01M6/14 , H01M4/96
CPC分类号： C09C1/56 , H01M4/36 , H01M6/14 , C01P2006/12 , C01P2006/40
摘要： Carbon black powder is pretreated with acetone or methanol prior to cathodeabrication to improve the cathode operating voltage and increase the cathode life of lithium sulfuryl chloride electrochemical cells.

67. 发明授权

US4514478A Method of making a porous carbon cathode, a porous carbon cathode so made, and electrochemical cell including the porous carbon cathode 失效
标题翻译：制造多孔碳阴极的方法，如此制造的多孔碳阴极和包括多孔碳阴极的电化学电池
公开(公告)号：US4514478A
公开(公告)日：1985-04-30
申请号：US640265
申请日：1984-08-13
申请人： Michael Binder , Eric R. Petersen , Charles W. Walker, Jr. , William L. Wade, Jr. , Sol Gilman
发明人： Michael Binder , Eric R. Petersen , Charles W. Walker, Jr. , William L. Wade, Jr. , Sol Gilman
IPC分类号： H01M4/96 , H01M6/14
CPC分类号： H01M4/96 , H01M6/14 , Y10T29/49108 , Y10T29/49115
摘要： A porous carbon cathode for use in an electrochemical cell is made by wetg the carbon black with a 1:1 to 1:3 mixture of isopropyl alcohol:water, adding a binding agent thereto, smearing the resulting stiff paste on a thin expanded metal screen and pressing and rolling to the desired thickness, drying the cathode sheet in a vacuum oven at about 100.degree. C. for one hour while a weight is placed above and below the cathode sheet which is sandwiched between two pieces of blotting paper, the total weight applied being sufficient for the cathode to retain structural integrity, removing the weight and blotting papers and inserting the cathode sheet in an elevated drying oven at about 280.degree. C. for about one hour, and cooling the cathode sheet between blotting paper, repressing and rolling. Cathodes prepared by this method appear structurally strong, maintain their physical integrity with a minimum of cracking and flaking, and do not crumble when cut. The porous carbon cathode is particularly advantageous when included in a lithium sulfuryl chloride cell, but can be used in any system requiring porous carbon cathodes.
摘要翻译：用于电化学电池的多孔碳阴极是通过用1:1:1:1:1:1:2的异丙醇：水的混合物润湿炭黑制成的，向其中加入粘结剂，将所得的硬糊涂抹在薄的金属扩孔并压制成所需的厚度，在真空烘箱中在约100℃下干燥阴极片1小时，同时将重量置于夹在两片吸印纸之间的阴极片的上下，总重量施加足以使阴极保持结构完整性，去除重量和吸印纸并将阴极片在约280℃的升高的干燥炉中插入约1小时，并在吸印纸，压制和轧制之间冷却阴极片。通过这种方法制备的阴极在结构上很强，在最小的开裂和剥落下保持其物理完整性，切割时不会破碎。当包含在锂磺酰氯单元中时，多孔碳阴极是特别有利的，但可以用于需要多孔碳阴极的任何系统中。

68. 发明授权

US4510220A Cell with PbCl.sub.2 cathode 失效
标题翻译：电池与PbCl2阴极
公开(公告)号：US4510220A
公开(公告)日：1985-04-09
申请号：US509678
申请日：1983-06-30
申请人： Mysore L. Gopikanth , Han C. Kuo , Carl R. Schlaikjer
发明人： Mysore L. Gopikanth , Han C. Kuo , Carl R. Schlaikjer
IPC分类号： H01M4/58 , H01M6/14 , H01M10/052 , H01M10/0563 , H01M10/36 , H01M4/56
CPC分类号： H01M10/0563 , H01M10/052 , H01M4/582 , H01M6/14
摘要： A non-aqueous electrochemical cell having an alkali or alkaline earth metal anode, an inorganic electrolyte comprised of an electrolyte salt and sulfur dioxide and a cathode comprised of PbCl.sub.2.
摘要翻译：具有碱金属或碱土金属阳极的非水电化学电池，由电解质盐和二氧化硫组成的无机电解质和由PbCl 2组成的阴极。

69. 发明授权

US4508800A Cell with FeBr.sub.3 cathode 失效
标题翻译：电池与FeBr3阴极
公开(公告)号：US4508800A
公开(公告)日：1985-04-02
申请号：US509693
申请日：1983-06-30
申请人： Mysore L. Gopikanth , Han C. Kuo , Carl R. Schlaikjer
发明人： Mysore L. Gopikanth , Han C. Kuo , Carl R. Schlaikjer
IPC分类号： H01M4/58 , H01M6/14 , H01M10/052 , H01M10/0563 , H01M10/36
CPC分类号： H01M10/0563 , H01M10/052 , H01M4/582 , H01M6/14
摘要： A non-aqeous electrochemical cell having an alkali or alkaline earth metal anode, an inorganic electrolyte comprised of an electrolyte salt and sulfur dioxide and a cathode comprised of FeBr.sub.3.
摘要翻译：具有碱金属或碱土金属阳极的非水电解电池，由电解质盐和二氧化硫组成的无机电解质和由FeBr 3组成的阴极。

70. 发明授权

US4499160A Cathode and electrochemical cell containing same 失效
标题翻译：阴极和电化学电池含有相同的
公开(公告)号：US4499160A
公开(公告)日：1985-02-12
申请号：US505118
申请日：1983-06-20
申请人： Matzliach Babai , Uzi Maishar
发明人： Matzliach Babai , Uzi Maishar
IPC分类号： H01M4/06 , H01M4/48 , H01M6/14 , H01M6/38 , H01M4/36 , H01M4/58 , H01M6/36
CPC分类号： H01M4/06 , H01M4/483 , H01M6/14 , H01M6/38
摘要： A novel composite cathode for use in electrochemical lithium reserve cells comprising a self-supporting structure or a grid-supported structure of porous carbon, a binder and a transition metal oxide. Such cathodes are prepared by slurrying porous carbon, possibly with graphite, with a binder, applying to a support, drying, applying a transition metal nitrate or hydrate of such nitrate, and decomposing said nitrate. Reserve cells comprising such cathodes are also disclosed.
摘要翻译：一种用于电化学锂储备电池的新型复合阴极，包括多孔碳，粘合剂和过渡金属氧化物的自支撑结构或网格支撑结构。这样的阴极可以通过用粘合剂将多孔碳（可能与石墨）浆化，施加到载体上，干燥，施加这种硝酸盐的过渡金属硝酸盐或水合物并分解所述硝酸盐来制备。还公开了包括这种阴极的储备电池。

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