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    • 61. 发明申请
    • Device for Catalytic Recombination of Gases for Alkaline Batteries with Shortened Zinc Anode
    • 碱性电池气体与缩短锌阳极催化重组的装置
    • US20080003489A1
    • 2008-01-03
    • US11830975
    • 2007-07-31
    • Bernard BUGNETDenis DONIATRobert ROUGET
    • Bernard BUGNETDenis DONIATRobert ROUGET
    • H01M10/34B01J21/18B01J23/74
    • H01M4/0471B01J21/18B01J23/42B01J35/04H01M4/244H01M4/808H01M10/24H01M10/28H01M10/52H01M10/523H01M10/613H01M10/654H01M10/6551
    • The invention concerns a device for catalytic recombination of gases for alkaline batteries with shortened zinc anode. The invention concerns a device for catalytic recombination of gases formed when charging a zinc anode alkaline battery, characterized in that it consists of a catalytic mass in contact with a crosslinked cellular metal foam serving as catalyst support and heat dissipating structure, said catalytic mass consisting of a mixture of carbon black including metal of platinum metals, and of a hydrophobic binder, the whole assembly being heat-treated to cause the hydrophobic binder of said catalytic mass to be sintered. Said device is advantageously connected to one of the terminals of the battery or to any other metal part constituting part of the cover of the battery case, so as to promote discharge of the calories produced. Such a device enables, in a long lasting manner during the charge-discharge cycles, limited internal pressure levels to be maintained, in particular in installations designed to operate without maintenance.
    • 本发明涉及用于具有缩短的锌阳极的碱性电池的气体的催化重组装置。 本发明涉及一种用于在对锌阳极碱性电池充电时形成的气体的催化重组装置,其特征在于,其由与作为催化剂载体和散热结构的交联的多孔金属泡沫接触的催化物质组成,所述催化剂组合物由 包含铂金属金属的炭黑和疏水性粘合剂的混合物,将整个组合物进行热处理以使所述催化剂物质的疏水性粘结剂被烧结。 所述装置有利地连接到电池的一个端子或构成电池壳体的盖的一部分的任何其它金属部件,以便促进产生的卡路里的放电。 这样的装置能够在充放电循环期间以持久的方式实现有限的内部压力水平的保持,特别是在设计为在没有维护的情况下运行的设备中。
    • 64. 发明授权
    • Methods for production of zinc oxide electrodes for alkaline batteries
    • 生产碱性电池用氧化锌电极的方法
    • US07255720B2
    • 2007-08-14
    • US10471485
    • 2002-03-15
    • Jeffrey Phillips
    • Jeffrey Phillips
    • H01M4/48
    • H01M4/244H01M4/04H01M4/26H01M4/364H01M4/62H01M4/622H01M10/24Y10T29/49115
    • A zinc electrode for use in alkaline batteries comprises a mixture of 0.425 to 1.55 volume parts of zinc oxide with a volume part of a metallic oxide chosen from the group consisting of: calcium oxide, barium oxide, and mixtures thereof, together with hydroxy-ethyl cellulose, an oxide dispersant chosen from the group consisting of: soap derivatives, anionic polyelectrolytes, anionic surfactants, and mixtures thereof, and a binder. The electrode is prepared by mixing zinc oxide with the chosen metallic oxide in an aqueous medium such as water or potassium hydroxide, stirring overnight, filtering and drying the mixture, optionally adding a further small amount of zinc oxide, optionally adding other metallic oxides, and adding hydroxy-ethyl cellulose, an oxide dispersant, and a binder. The aqueous paste os slurry thus formed is placed on a conductive substrate, drawn through a sizing gap, cut and dried, to form low cost pasted zinc oxide electrodes.
    • 用于碱性电池的锌电极包括0.425至1.55体积份量的氧化锌与体积部分金属氧化物的混合物,其选自氧化钙,氧化钡及其混合物,以及羟基乙基 纤维素,选自以下的氧化物分散剂:皂衍生物,阴离子聚电解质,阴离子表面活性剂及其混合物,以及粘合剂。 电极通过在水性介质如水或氢氧化钾中混合氧化锌和选择的金属氧化物,搅拌过夜,过滤并干燥混合物,任选地加入少量氧化锌,任选地加入其它金属氧化物,以及 加入羟乙基纤维素,氧化物分散剂和粘合剂。 将如此形成的水性浆料浆料放置在导电基材上,通过筛分间隙拉伸,切割并干燥,形成低成本的糊化氧化锌电极。
    • 65. 发明申请
    • Alkaline cell with improved anode
    • 改善阳极的碱性电池
    • US20070166620A1
    • 2007-07-19
    • US11334857
    • 2006-01-19
    • Nikolai IssaevMichael Pozin
    • Nikolai IssaevMichael Pozin
    • H01M4/62H01M4/42H01M10/26
    • H01M6/04H01M4/244H01M4/62
    • An alkaline cell having an anode mixture comprising zinc particles, aqueous alkaline electrolyte, and molecular sieve additive. The cathode preferably comprises manganese dioxide. The cell may be cylindrical or any other shape or size. The molecular sieve additive preferably comprises a crystalline aluminosilicate material which is in at least a partially dehydrated state before admixture with the aqueous electrolyte, preferably potassium hydroxide. The aluminosilicate crystalline structure has average pore size between about 3 and 25 Angstrom. The addition of the molecular sieves to the zinc anode improves the cell's discharge capacity and service life. The molecular sieves preferably comprises between about 0.07 and 0.7 percent by weight of the anode mixture.
    • 具有阳极混合物的碱性电池,其包含锌颗粒,碱性电解质水溶液和分子筛添加剂。 阴极优选包含二氧化锰。 电池可以是圆柱形或任何其它形状或尺寸。 分子筛添加剂优选包含在与含水电解质混合之前至少部分脱水状态的结晶硅铝酸盐材料,优选氢氧化钾。 铝硅酸盐晶体结构具有约3至25埃的平均孔径。 向锌阳极添加分子筛可提高电池的放电容量和使用寿命。 分子筛优选占阳极混合物重量的约0.07%至0.7%。