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61. 发明申请

US20170088957A1 ELECTROCHEMICAL GAS GENERATOR FOR AMMONIA WITH THE USE OF IONIC LIQUIDS AND USE OF THE GAS GENERATOR 审中-公开
公开(公告)号：US20170088957A1
公开(公告)日：2017-03-30
申请号：US15277330
申请日：2016-09-27
申请人： Dräger Safety AG & Co. KGaA
发明人： Peter TSCHUNCKY , Kerstin LICHTENFELDT
IPC分类号： C25B1/00 , C25B11/04 , C25B11/12 , C25B9/08
CPC分类号： C25B1/00 , C25B9/08 , C25B11/04 , C25B11/041 , C25B11/0447 , C25B11/12
摘要： An electrochemical gas generator for ammonia with the use of ionic liquids containing nitrate ions as the electrolyte and to the use of the gas generator for generating gaseous ammonia, especially for testing the function of and/or calibrating gas sensors.

62. 发明授权

US09566576B2 Metal complex catalysts and uses thereof 有权
标题翻译：金属络合物催化剂及其用途
公开(公告)号：US09566576B2
公开(公告)日：2017-02-14
申请号：US14449100
申请日：2014-07-31
申请人： University of Memphis Research Foundation
发明人： Xuan Zhao , Charles E. Webster
IPC分类号： C25B1/04 , B01J31/18 , B01J31/22 , C25B11/04 , C01B3/02 , C25B1/00
CPC分类号： B01J31/1815 , B01J31/2295 , B01J2531/845 , C01B3/02 , C25B1/003 , C25B1/04 , C25B11/0447 , Y02E60/366
摘要： The invention relates to novel metal complexes useful as catalysts in redox reactions (such as, hydrogen (H2) production). In particular, the invention provides novel transition metal (e.g., cobalt (Co) or nickel (Ni)) complexes, in which the transition metal is coupled with N,N-Bis(2-pyridinylmethyl)-2,2′-Bipyridine-6-methanamine (DPA-Bpy), 6′-((bis(pyridin-2-ylmethyl)amino)methyl)-N,N-dimethyl-2,2′-bipyridin-6-amine (DPA-ABpy), N,N-bis((isoquinolin-1-yl)methyl)(6-(pyridin-2-yl)pyridin-2-yl)methanamine (DIQ-Bpy), or a derivative thereof. The invention also relates to a method of producing H2 from an aqueous solution by using the metal complex as a catalyst. In certain embodiments, the invention provides a metal complex of the formulae as described herein.
摘要翻译：本发明涉及可用作氧化还原反应（例如氢（H 2）生产）中的催化剂的新型金属络合物。特别地，本发明提供了新的过渡金属（例如钴（Co）或镍（Ni））络合物，其中过渡金属与N，N-双（2-吡啶基甲基）-2,2'-联吡啶 - 6-甲胺（DPA-Bpy），6' - （（双（吡啶-2-基甲基）氨基）甲基）-N，N-二甲基-2,2'-联吡啶-6-胺（DPA-ABpy），N ，（N，N-二（（异喹啉-1-基）甲基）（6-（吡啶-2-基）吡啶-2-基）甲胺（DIQ-Bpy）或其衍生物。本发明还涉及通过使用金属络合物作为催化剂从水溶液中生产H 2的方法。在某些实施方案中，本发明提供了如本文所述的式的金属络合物。

63. 发明申请

US20170022618A1 Electrochemical Devices Comprising Novel Catalyst Mixtures 有权
标题翻译：包含新型催化剂混合物的电化学装置
公开(公告)号：US20170022618A1
公开(公告)日：2017-01-26
申请号：US15226894
申请日：2016-08-02
申请人： Dioxide Materials, Inc.
发明人： Richard I. Masel , Zengcai Liu , Brian Rosen
IPC分类号： C25B11/04 , G01N27/48 , C25B1/00 , C25B3/04 , C25B9/08
CPC分类号： C25B11/0405 , B01J31/02 , C01B32/40 , C07C45/00 , C25B1/00 , C25B3/00 , C25B3/04 , C25B9/08 , C25B11/04 , C25B11/0415 , C25B11/0447 , G01N27/416 , G01N27/48 , H01M4/90 , H01M8/00 , H01M8/0612 , Y02P20/135
摘要： Electrochemical devices comprising electrocatalyst mixtures include at least one Catalytically Active Element and, as a separate constituent, one Helper Catalyst. The electrocatalysts can be used to increase the rate, modify the selectivity or lower the overpotential of chemical reactions. These electrocatalysts are useful for a variety of chemical reactions including, in particular, the electrochemical conversion of CO2. Chemical processes employing these catalysts produce CO, HCO−, H2CO, (HCO2)−, H2CO2, CH3OH, CH4, C2H4, CH3CH2OH, CH3COO−, CH3COOH, C2H6, (COOH)2, or (COO−)2. Devices using the electrocatalysts include, for example, a CO2 sensor and a CO2 electrolyzer.
摘要翻译：包含电催化剂混合物的电化学装置包括至少一种催化活性元素和作为单独成分的一种助催化剂。电催化剂可用于提高速率，改变选择性或降低化学反应的超电势。这些电催化剂可用于各种化学反应，包括特别是二氧化碳的电化学转化。使用这些催化剂的化学方法产生CO，HCO-，H 2 CO，（HCO 2） - ，H 2 CO 2，CH 3 OH，CH 4，C 2 H 4，CH 3 CH 2 OH，CH 3 COO-，CH 3 COOH，C 2 H 6，（COOH）2或（COO-）2。使用电催化剂的装置包括例如CO 2传感器和CO 2电解槽。

64. 发明申请

US20160289849A1 BIFUNCTIONAL WATER SPLITTING CATALYSTS AND ASSOCIATED METHODS 审中-公开
标题翻译：双功能水分离催化剂及相关方法
公开(公告)号：US20160289849A1
公开(公告)日：2016-10-06
申请号：US15087999
申请日：2016-03-31
申请人： Yujie Sun , Nan Jiang , Bo You
发明人： Yujie Sun , Nan Jiang , Bo You
IPC分类号： C25B1/04 , C25D13/02
CPC分类号： C25B1/04 , C25B11/0415 , C25B11/0447 , C25D3/56 , C25D3/562 , C25D3/58 , C25D7/00 , C25D13/02 , Y02E60/366
摘要： A catalyst, including a conductive substrate coated with a metal-phosphorus-derived film, where the metal is Manganese, Iron, Cobalt, Nickel, or Copper. In some embodiments, the conductive substrate includes copper, titanium, glassy carbon, fluorine-doped tin oxide, indium-doped tin oxide, tin, nickel, or stainless steel. Methods for producing the catalysts and for hydrogen evolution reactions and oxygen evolution reactions employing the catalysts are also described herein.
摘要翻译：一种催化剂，包括涂覆有金属磷衍生膜的导电基材，其中金属是锰，铁，钴，镍或铜。在一些实施例中，导电衬底包括铜，钛，玻璃碳，氟掺杂氧化锡，铟掺杂氧化锡，锡，镍或不锈钢。本文还描述了使用催化剂制备催化剂和析氢反应和析氧反应的方法。

65. 发明申请

US20160237578A1 ANODE FOR ALKALINE WATER ELECTROLYSIS 审中-公开
标题翻译：碱性水电解阳极
公开(公告)号：US20160237578A1
公开(公告)日：2016-08-18
申请号：US15029952
申请日：2014-10-29
申请人： PERMELEC ELECTRODE LTD. , CHLORINE ENGINEERS CORP., LTD , THYSSENKRUPP UHDE CHLORINE ENGINEERS (JAPAN), LTD
发明人： Hiroki ICHIKAWA , Shigenori MITSUSHIMA , Ikuo NAGASHIMA , Yoshio SUNADA , Akihiro KATO , Liang YIN , Akiyoshi MANABE , Yoshinoñ NISHIKI
IPC分类号： C25B11/04 , C25B1/04
CPC分类号： C25B11/0405 , B01J23/78 , C25B1/04 , C25B11/0415 , C25B11/0431 , C25B11/0447 , C25B11/0478 , Y02E60/366 , Y02E70/10 , Y02P20/133 , Y02P20/134
摘要： An anode for alkaline water electrolysis includes a conductive substrate having at least a surface made of nickel or a nickel-base alloy and a lithium-containing nickel oxide catalytic layer formed on a surface of the substrate. The molar ratio (Li/Ni) of lithium and nickel in the catalytic layer is in the range of 0.005 to 0.15.
摘要翻译：用于碱水电解的阳极包括至少具有由镍或镍基合金制成的表面的导电基底和在基底表面上形成的含锂镍氧化物催化层。催化剂层中锂和镍的摩尔比（Li / Ni）在0.005〜0.15的范围内。

66. 发明授权

US09415363B2 Method and apparatus for efficient on-demand production of H2 and O2 from water using waste heat and environmentally safe metals 有权
标题翻译：使用废热和环境安全金属从水中高效按需生产H2和O2的方法和设备
公开(公告)号：US09415363B2
公开(公告)日：2016-08-16
申请号：US12706639
申请日：2010-02-16
申请人： Jeff Carey
发明人： Jeff Carey
IPC分类号： C25B1/04 , C25B15/08 , C25B15/00 , B01J7/02 , C01B3/04 , C01B13/02
CPC分类号： C01B3/042 , B01J7/02 , B01J21/02 , B01J23/50 , B01J23/72 , B01J38/48 , B01J2219/00006 , B01J2219/00144 , C01B3/04 , C01B13/0203 , C25B1/04 , C25B11/0447 , C25B15/02 , C25B15/08 , Y02E60/364 , Y02E60/366 , Y02P20/129
摘要： A method of and apparatus for efficient on-demand production of H2 and O2 from water and heat using environmentally safe metals are disclosed. In one aspect, the apparatus for the hydrogen generation through water decomposition reaction includes a main reactor, an oxidizer reactor, and a computer controlling system. The main reactor contains a hydrogen generating substance, such as aluminum hydroxide. In some embodiments, the main reactor includes hydroxide shuttles, such as Cu ion and Ag ion. In another aspect, the system for hydrogen generation through water decomposition includes the steps of (1) REDOX reaction, (2) pre-generation reaction, (3) generation reaction, (4) regeneration reaction, (5) second hydrogen reaction, and (6) oxygen reaction.
摘要翻译：公开了一种使用环境安全金属从水和热中高效按需生产H2和O2的方法和设备。一方面，通过水分解反应生成氢的装置包括主反应器，氧化反应器和计算机控制系统。主反应器含有氢生成物质，例如氢氧化铝。在一些实施方案中，主反应器包括氢氧化物梭，例如Cu离子和Ag离子。另一方面，通过水分解产生氢的体系包括以下步骤：（1）REDOX反应，（2）预发生反应，（3）生成反应，（4）再生反应，（5）第二氢反应和（6）氧反应。

67. 发明申请

US20160160365A1 METAL NITRIDE CATALYSTS FOR PROMOTING A HYDROGEN EVOLUTION REACTION 审中-公开
标题翻译：用于促进氢演化反应的金属氮化物催化剂
公开(公告)号：US20160160365A1
公开(公告)日：2016-06-09
申请号：US14906656
申请日：2014-08-05
申请人： BROOKHAVEN SCIENCE ASSOCIATES, LLC , THE RESEARCH FOUNDATION FOR THE STATE UNIVERSITY OF NEW YORK
发明人： Bingfei Cao , Peter Gabriel Khalifah
IPC分类号： C25B11/04 , C25B1/02
CPC分类号： C25B11/0447 , B01J27/24 , B01J35/0033 , C25B1/02 , C25B9/00 , C25B11/04
摘要： The present invention provides metal nitrides and methods of making and using same, including using such metal nitrides as catalysts for hydrogen evolution reactions.
摘要翻译：本发明提供金属氮化物及其制造和使用方法，包括使用这种金属氮化物作为析氢反应的催化剂。

68. 发明申请

US20160090657A1 A HYDROGEN GAS GENERATOR SYSTEM 审中-公开
标题翻译：氢气发电机系统
公开(公告)号：US20160090657A1
公开(公告)日：2016-03-31
申请号：US14785313
申请日：2014-04-15
申请人： CLEAN POWER HYDROGEN LIMITED
发明人： Williamson NIGEL
IPC分类号： C25B15/02 , C25B15/08 , C25B11/04 , C25B9/20 , C25B9/06 , C25B1/08 , C25B11/02
CPC分类号： C25B1/08 , C25B1/06 , C25B9/06 , C25B9/063 , C25B9/20 , C25B9/203 , C25B11/02 , C25B11/0447 , C25B11/0452 , C25B15/02 , C25B15/08 , Y02E60/366
摘要： A hydrogen gas generator system comprises a reactor stack adapted to perform electrolysis on water in an electrolyte solution, the reactor stack comprising a plurality of spaced apart electrode plates and electrolyte solution disposed between the plates, each plate having an upper outlet aperture and a lower inlet aperture to allow movement of electrolyte solution across the plates. A separator is configured to receive a mixture of gas and electrolyte solution from a top of the reactor stack and separate the gas from the electrolyte solution. A gas outlet configured to remove gas from the separator, and an electrolyte solution inlet configured to return electrolyte solution from the separator to a bottom of the reactor stack. The system comprises a pump configured to pump electrolyte solution in a circuit from the electrolyte solution outlet of the separator/reservoir, through the reactor stack at velocity, and back to the separator/reservoir, and in which in the upper and lower apertures are sufficiently large to allow pumped flow through the reactor stack.
摘要翻译：氢气发生器系统包括适于在电解质溶液中对水进行电解的反应器堆，反应堆堆叠包括多个间隔开的电极板和设置在板之间的电解质溶液，每个板具有上出口孔和下入口孔以允许电解质溶液跨过板移动。分离器构造成从反应器堆叠的顶部接收气体和电解质溶液的混合物，并将气体与电解质溶液分离。气体出口，被配置为从分离器除去气体，以及电解质溶液入口，其构造成将电解质溶液从分离器返回到反应堆堆叠的底部。该系统包括一泵，该泵配置成将来自分离器/储存器的电解液出口的回路中的电解质溶液以速度通过反应器堆叠并且返回到分离器/储存器，并且其中上孔和下孔足够大的允许泵送流过反应堆堆。

69. 发明申请

US20160032462A1 SEMICONDUCTOR PHOTOCATALYST AND ARTIFICIAL PHOTONIC SYNTHESIS DEVICE HAVING THE SAME 有权
标题翻译：半导体光子学和人造光子合成装置
公开(公告)号：US20160032462A1
公开(公告)日：2016-02-04
申请号：US14748399
申请日：2015-06-24
申请人： DENSO CORPORATION
发明人： Hitoshi YAMAGUCHI
IPC分类号： C25B1/00 , C25B11/04 , C25B13/04 , C25B9/08 , H01G9/20 , C25B1/04
CPC分类号： C25B1/003 , C25B1/04 , C25B9/08 , C25B11/0405 , C25B11/0421 , C25B11/0447 , C25B13/04 , H01G9/2045 , Y02E60/364 , Y02E60/368
摘要： A semiconductor photocatalyst includes first and second layers made of first and second materials, respectively. Band gaps of the first and second materials are equal to or smaller than 1.5 eV and 2.5 eV, respectively. A lower electric potential of a conduction band of the second material is disposed on a positive side from the first material. An upper electric potential of a valence band of the second material is disposed on a positive side from the first material and from an oxidation electric potential of water when the first and second layers are bonded to each other in the hetero junction manner. The lower electric potential of the conduction band of the first layer is disposed on a negative side from a reduction electric potential of hydrogen when the first and second layers are bonded to each other in the hetero junction manner.
摘要翻译：半导体光催化剂包括分别由第一和第二材料制成的第一和第二层。第一和第二材料的带隙分别等于或小于1.5eV和2.5eV。第二材料的导带的较低电位设置在从第一材料的正侧。当第一和第二层以异质连接方式彼此接合时，第二材料的价带的上电势被设置在从第一材料的正侧和水的氧化电位上。当第一和第二层以异质连接方式彼此接合时，第一层的导带的较低的电位被设置在从氢的还原电位的负侧。

70. 发明申请

US20150361567A1 POSITIVE ELECTRODE CATALYST AND DEVICE 有权
标题翻译：正极电极催化剂和装置
公开(公告)号：US20150361567A1
公开(公告)日：2015-12-17
申请号：US14763932
申请日：2014-01-28
申请人： FUJI ELECTRIC CO., LTD. , SANTOKU CORPORATION , NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY
发明人： Nobuaki OHGURI , Hiroshi TAKANO , Tadatoshi MUROTA , Motofumi MATSUDA , Tatsuya TAKEGUCHI
IPC分类号： C25B11/04 , H01M12/08 , H01M4/92 , H01M4/90
CPC分类号： C25B11/0463 , B01J23/78 , C25B1/04 , C25B11/0447 , C25B11/0473 , H01M4/9016 , H01M4/9033 , H01M4/9041 , H01M4/92 , H01M12/08 , H01M2220/10 , H01M2220/20 , Y02E60/366
摘要： A positive electrode catalyst, for use in a positive electrode in a device provided with the positive electrode and a negative electrode, in which a reaction represented by 4 OH−→O2+2 H2O+4 e− is performed on a side of the positive electrode. The positive electrode catalyst includes a layered metal oxide, wherein the layered metal oxide is a Ruddlesden-Popper type layered perovskite represented by (La1−xAx) (Fe1−yBy)3(Sr1−zCz)3O10−a wherein, A is a rare earth element other than La, B is a transition metal other than Fe, and C is an alkaline earth metal other than Sr; and x satisfies an expression: 0≦x
摘要翻译：在设置有正极和负极的装置中的正极中使用的正极催化剂，其中由4OH-→O 2 + 2 H 2 O + 4e-表示的反应在阳性的一侧进行电极。正极催化剂包括层状金属氧化物，其中层状金属氧化物是由（La1-xAx）（Fe1-yBy）3（Sr1-zCz）3O10-a表示的Ruddlesden-Popper型层状钙钛矿，其中A是罕见的 B以外的过渡金属，C是除Sr以外的碱土金属，并且x满足表达式：0＆nlE; x <1，y满足表达式：0＆nlE; y <1，z满足表达式：0＆nlE; z <1，a满足表达式：0＆nlE; a＆nlE; 3。

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