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    • 61. 发明授权
    • Epoxy formulation adapted to be used in conjunction with no-lead solder in electronic components
    • 适用于电子部件中无铅焊料的环氧树脂配方
    • US06548576B1
    • 2003-04-15
    • US10045461
    • 2001-11-07
    • Raymond L. Winter
    • Raymond L. Winter
    • C08K336
    • H05K3/285C08G59/226C08G59/5026C08L61/06C08L63/00H01L23/293H01L2924/0002C08L2666/14C08L61/04H01L2924/00
    • A one part, several-months-useful-shelf-life epoxy material suitable for potting and sealing electronic components, and which is compatible with the high, approximately 255° C. to 275° C. temperatures required for soldering modem lead-free solders comprises an intimate mixture of the following components: approximately 2 to 13 per cent by weight of diglycidyl ether bisphenol A resin; approximately 40 to 70% phenol formaldehyde resin and the following further components [(2-methylphenoxy)methyl]-oxirane or o-cresol glycidyl ether) 0.5-8% by weight; polypropyleneglycol-glycidyl ether resin (plasticizer) 2-10% by weight; cycloaliphatic polyamine (catalyst) 4-15% by weight; kaolin clay (filler) 2-20% by weight; magnesium alumino silicate (filler) 2-15% by weight; Sb2O3 (filler) 4-5% by weight, and hydrated Al2O3 (filler) 0-15% by weight.
    • 适用于封装和密封电子元件的一个零件,几个月的有用的保质期环氧树脂,并且与用于焊接调制解调器无铅焊料所需的大约255°C至275°C的高温兼容 包括以下组分的紧密混合物:约2至13重量%的二缩水甘油醚双酚A树脂; 约40至70%的苯酚甲醛树脂和以下其它组分[(2-甲基苯氧基)甲基] - 环氧乙烷或邻甲酚缩水甘油醚)0.5-8重量%;聚丙二醇 - 缩水甘油醚树脂(增塑剂)2-10% 重量比为4-15重量%的脂环族聚胺(催化剂); 2-20重量%的高岭土(填料); 2-15重量%的硅铝酸镁(填料); Sb2O3(填料)4-5重量% 水合Al2O3(填料)0-15重量%。
    • 68. 发明授权
    • Process for producing modified phenolic resin
    • 改性酚醛树脂生产工艺
    • US06320013B1
    • 2001-11-20
    • US09601336
    • 2000-08-10
    • Mitsunori TakedaMasamichi Sato
    • Mitsunori TakedaMasamichi Sato
    • C08G1404
    • C08G59/621C08G8/28C08G10/04C08G14/04C08L63/00C08L61/04
    • A process for producing a modified phenolic resin, comprising heating a heavy oil or pitch of given average molecular weight and, per mol, calculated from the average molecular weight, of the heavy oil or pitch; 0.3 to 25 mol, in terms of formaldehyde, a formaldehyde compound and 0.5 to 50 mol of a phenol of the formula (I) (wherein R1 represents a linear or branched unsaturated hydrocarbon group having 1 to 2 unsaturated bonds and having 2 to 10 carbon atoms, p is 1 or 2, X represents an alkyl group having 1 to 5 carbon atoms, and q is 0 or 1) under stirring in the presence of an acid catalyst to thereby effect a polycondensation. The modified phenolic resin obtained by this process, as compared with the conventional modified phenolic resin produced from a heavy oil or pitch as a feedstock, has an extremely low softening point so as to be flowable at about room temperature and has also a low melt viscosity, thereby ensuring very excellent moldability. Further, in combination with an epoxy resin, the modified phenolic resin can be formed into a molded article which is excellent in not only heat resistance, moisture resistance, corrosion resistance and adhesive force but also mechanical properties such as dimensional stability and strength.
    • 一种制备改性酚醛树脂的方法,包括加热重油或沥青的给定平均分子量,每摩尔由重油或沥青的平均分子量计算; 0.3〜25摩尔,以甲醛计,甲醛化合物和0.5〜50摩尔式(I)的苯酚(其中,R1表示具有1〜2个不饱和键且具有2〜10个碳原子的直链或支链的不饱和烃基 原子,p为1或2,X表示碳原子数1〜5的烷基,q为0或1)在酸催化剂的存在下搅拌,进行缩聚。 通过该方法获得的改性酚醛树脂与由重油或沥青作为原料生产的常规改性酚醛树脂相比具有极低的软化点,以便可在约室温下流动并且还具有低熔体粘度 ,从而确保非常优异的成型性。 此外,与环氧树脂组合,可以将改性酚醛树脂形成为不仅具有耐热性,耐湿性,耐腐蚀性和粘合力优异的机械性能如尺寸稳定性和强度的成型品。
    • 69. 发明授权
    • Semiconductor sealing resin composition, semiconductor device sealed with the same, and process for preparing semiconductor device
    • 半导体密封树脂组合物,用其密封的半导体器件,以及半导体器件的制备方法
    • US06319619B1
    • 2001-11-20
    • US09403311
    • 1999-10-20
    • Yuko YamamotoMiho YamaguchiHitomi Shigyo
    • Yuko YamamotoMiho YamaguchiHitomi Shigyo
    • H01L2912
    • H01L23/293C08K3/22C08L63/00H01L2924/0002Y10T428/12528Y10T428/31511Y10T428/31529C08L61/04H01L2924/00
    • The present invention relates to a semiconductor encapsulating resin composition which is safe and superior in moisture resistance, flame retardance and moldability, and to a highly reliable semiconductor device which is fabricated by encapsulating a semiconductor element with such a semiconductor encapsulating resin composition. The resin composition according to the present invention comprises a thermosetting resin, a hardening agent and a compound metal hydroxide of polyhedral crystal form represented by the following general formula (1): m(MaOb).n(QdOe).cH2O  (1) [wherein M and Q are different metal elements; Q is a metal element which belongs to a group selected from IVa, Va, VIa, VIIa, VIII, Ib and IIb groups in the periodic table; m, n, a, b, c, d and e, which may be the same or different, each represents a positive number]. In accordance with the present invention, reduction in the fluidity of the resin composition can be suppressed, so that transfer molding can be performed with an improved moldability without any trouble. Further, the resin composition ensures improvement in soldering resistance and mechanical strength.
    • 本发明涉及一种安全且优异的耐湿性,阻燃性和成型性的半导体封装树脂组合物以及通过用这种半导体封装树脂组合物包封半导体元件而制造的高可靠性半导体器件。 根据本发明的树脂组合物包含热固性树脂,硬化剂和由以下通式(1)表示的多面体晶体的复合金属氢氧化物:[其中M和Q是不同的金属元素; Q是属于周期表中选自IVa,Va,VIa,VIIa,VIII,Ib和IIb族的基团的金属元素; m,n,a,b,c,d和e可以相同或不同,各自表示正数]。 根据本发明,可以抑制树脂组合物的流动性的降低,从而可以在没有任何麻烦的情况下以改进的成型性进行传递模塑。 此外,树脂组合物确保了耐焊接性和机械强度的提高。