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    • 61. 发明申请
    • THERMOPLASTIC ELASTOMER COMPOSITION AND PNEUMATIC TIRE USING THE SAME
    • 热塑性弹性体组合物和使用其的气动轮胎
    • US20100036028A1
    • 2010-02-11
    • US12500340
    • 2009-07-09
    • Naoyuki Morooka
    • Naoyuki Morooka
    • C08K5/435C08L51/00
    • C08L77/00B60C1/0008C08K3/346C08K5/0016C08K5/435C08K2201/008C08L51/06C08L79/02C08L2666/20C08L2666/24
    • To improve the balance of the low temperature durability, gas barrier property, and melt processability of a thermoplastic elastomer composition comprising an aliphatic polyamide resin in which an ethylene-based modifying polymer is dispersed, a thermoplastic elastomer composition comprising a thermoplastic resin composition (A) and a modified ethylene-based modifying polymer (B) graft modified with acid anhydride groups, wherein the thermoplastic resin composition (A) comprises 60 to 90 percent by weight of a layered silicate modified aliphatic polyamide resin (A1) prepared by an interlayer polymerization method and 10 to 40 percent by weight of a hydrophobic plasticizer (A2) having a solubility parameter (SP value) of 10 to 12 (cal/cm2)1/2, the modified ethylene-based modifying polymer (B) is 70 of 120 parts by weight based on 100 parts by weight of the thermoplastic elastomer composition, and the modified ethylene-based modifying polymer (B) forms a dispersed particle phase.
    • 为了提高包含分散有乙烯系改性聚合物的脂肪族聚酰胺树脂的热塑性弹性体组合物的低温耐久性,阻气性和熔融加工性的平衡,包含热塑性树脂组合物(A)的热塑性弹性体组合物, 和用酸酐基接枝改性的改性乙烯类改性聚合物(B),其中,热塑性树脂组合物(A)含有60〜90重量%的通过层间聚合法制备的层状硅酸酯改性脂族聚酰胺树脂(A1) 和10〜40重量%的溶解度参数(SP值)为10〜12(cal / cm 2)1/2的疏水性增塑剂(A2),改性乙烯类改性聚合物(B)为120份 ,基于100重量份的热塑性弹性体组合物,和改性的乙烯改性聚合物(B)形成分散的颗粒相。
    • 65. 发明授权
    • Polyamide-based composition for flexible pipes containing oil or gas
    • 用于含油或气体的柔性管的基于聚酰胺的组合物
    • US06913043B2
    • 2005-07-05
    • US10378077
    • 2003-03-04
    • Bernard JacquesBernard PeesMichael Werth
    • Bernard JacquesBernard PeesMichael Werth
    • F16L11/04B32B1/08B32B27/34C08K5/435C08L9/02C08L15/00C08L77/00C08L77/02C08L77/06F16L9/14
    • C08L77/00B32B1/08B32B27/34C08K5/435C08L9/02C08L15/005C08L77/02C08L77/06Y10T428/1352Y10T428/1355C08L2666/08
    • A composition comprising by weight: 70 to 96% of at least one polyamide chosen from PA-11, PA-12, aliphatic polyamides resulting from the condensation of an aliphatic diamine having from 6 to 12 carbon atoms and an aliphatic diacid having from 9 to 12 carbon atoms, and 11/12 copolyamides having either more than 90% of nylon-11 units or more than 90% of nylon-12 units; 4 to 10% of a plasticizer; 0 to 25% of an NBR or H-NBR elastomer; and the sum of the amount of plasticizer and the amount of elastomer is between 4 and 30%; can be manufactured by melt-blending the various constituents using standard techniques for thermoplastics. The composition is particularly useful for pipes used in the operation of offshore oil and gas fields. They exhibit very good ageing resistance. They are also useful for simpler pipes in motor vehicles, these compositions withstanding the ageing caused by the temperature under the bonnet of motor vehicles and the nature of the fluids transported. Pipes which comprise at least one layer of this composition are useful for offshore uses and for simpler pipes used in motor vehicles.
    • 一种组合物,其包含70至96%的至少一种选自PA-11,PA-12的聚酰胺,由具有6至12个碳原子的脂族二胺缩合得到的脂肪族聚酰胺和9至9的脂肪族二酸 12个碳原子和11/12共聚酰胺,其具有超过90%的尼龙-11单元或大于90%的尼龙-12单元; 4〜10%的增塑剂; 0至25%的NBR或H-NBR弹性体; 并且增塑剂的量与弹性体的量之和为4〜30%。 可以通过使用热塑性塑料的标准技术将各种成分熔融共混来制造。 该组合物特别适用于海上油气田操作中使用的管道。 它们具有非常好的抗老化性能。 它们对于机动车辆中更简单的管道也是有用的,这些组合物承受由汽车发动机罩下的温度引起的老化和运输的流体的性质。 包含该组合物的至少一层的管道可用于海上使用和用于机动车辆中的更简单的管道。
    • 68. 发明申请
    • Additive for polyester base synthetic resin containing plasticizer and plasticizer for biodegradable resin
    • 含有增塑剂的聚酯基合成树脂和可生物降解树脂增塑剂的添加剂
    • US20040152810A1
    • 2004-08-05
    • US10703625
    • 2003-11-10
    • Akira TakenakaMasaaki Tsuchihashi
    • C08K005/10
    • C08K5/20C08K5/10C08K5/435C08L67/00
    • An additive to a polyester base synthetic resin containing a plasticizer that comprises at least one compound selected from hydroxy aliphatic monocarboxylic acid ester and carboxylic acid amide is provided. Also, a polyester base synthetic resin composition comprising a polyester-base synthetic resin, a plasticizer, and at least one compound selected from hydroxy aliphatic monocarboxylic acid ester and carboxylic acid amide are also provided. Further, the invention provides a plasticizer for biodegradable resins that can impart flexibility without disturbing the transparency of the biodegradable resins. The plasticizer for biodegradable resins comprises a compound selected from (i) to (III) below. A biodegradable composition comprises the plasticizer. (i) An ester selected from a hydroxy aromatic carboxylic acid ester and a hydroxy alicyclic carboxylic acid ester, (ii) a compound having a sulfonamide group, and (iii) an ester of a polycarbonate diol containing a structural unit (I) and having a hydroxy group at each of both ends with an aromatic monocarboxylic acid (II), condensed polycyclic aromatic monocarboxylic acid or the like. 1 (wherein n denotes an integer of 2 to 6, X1 denotes H, OH, an alkyl group of C1-22 or the like, and m denotes an integer of 1 to 5.)
    • 提供了含有包含至少一种选自羟基脂族一元羧酸酯和羧酸酰胺的化合物的增塑剂的聚酯基合成树脂的添加剂。 此外,还提供了包含聚酯基合成树脂,增塑剂和至少一种选自羟基脂族一元羧酸酯和羧酸酰胺的化合物的聚酯基合成树脂组合物。 此外,本发明提供了一种可生物降解的树脂的增塑剂,其可以赋予柔软性而不干扰生物可降解树脂的透明度。 用于可生物降解树脂的增塑剂包含选自下述(i)至(III)的化合物。 可生物降解的组合物包含增塑剂。 (i)选自羟基芳族羧酸酯和羟基脂环族羧酸酯的酯,(ii)具有磺酰胺基的化合物,和(iii)含有结构单元(I)的聚碳酸酯二醇的酯,并具有 两端各自具有芳香族单羧酸(II),缩合多环芳香族单羧酸等的羟基。 (其中n表示2至6的整数,X 1表示H,OH,C 1-2-22的烷基等,m表示1至5的整数。)