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61. 发明授权

US06335401B1 Copolymer grafted via radical polymerization in the presence of stable radicals, its preparation and its uses 失效
标题翻译：共聚物通过自由基聚合在稳定的自由基存在下接枝，其制备及其用途
公开(公告)号：US06335401B1
公开(公告)日：2002-01-01
申请号：US09164717
申请日：1998-10-01
申请人： Denis Bertin , Bernard Boutevin , Jean-Jacques Robin
发明人： Denis Bertin , Bernard Boutevin , Jean-Jacques Robin
IPC分类号： C08L5100
CPC分类号： C08F4/36 , C08F291/00 , C08F291/18 , C08L51/00
摘要： The present invention relates to a grafted copolymer bearing grafts of formula (I): —O—PM1—(PM2)—T (I) in which: PM1 represents a polymer block obtained by (co)polymerization of at least one monomer M1 via a radical route; and PM2, which is optionally present, represents a polymer block obtained by (co)polymerization of at least one monomer M2 via a radical route; and T represents the residue of a stable radical T•.
摘要翻译：本发明涉及具有式（I）的接枝接枝物的接枝共聚物：其中：PM1表示通过自由基途径（共）聚合至少一种单体M1而获得的聚合物嵌段; 和任选存在的PM2表示通过自由基途径（共）聚合至少一种单体M2获得的聚合物嵌段; 和T表示稳定基团T的残基

62. 发明授权

US5708104A Allyl peroxide chain transfer agents 失效
标题翻译：烯丙基过氧化物链转移剂
公开(公告)号：US5708104A
公开(公告)日：1998-01-13
申请号：US857916
申请日：1992-05-15
申请人： Luc Louis Theophile Vertommen , John Meijer , Bernard Jean Maillard
发明人： Luc Louis Theophile Vertommen , John Meijer , Bernard Jean Maillard
IPC分类号： C07C409/04 , C07C409/08 , C07C409/14 , C07C409/16 , C07C409/18 , C07C409/20 , C07C409/38 , C07C409/40 , C07C409/42 , C08F2/38 , C08F4/28 , C08F4/32 , C08F4/34 , C08F4/36 , C08F10/00 , C08F12/00 , C08F12/08 , C08F18/04 , C08F20/10 , C08F20/18 , C08F36/04 , C08F218/02 , C08F220/10 , C08F112/06 , C08F118/04 , C08F120/18 , C08F120/44 , C08F136/02
CPC分类号： C08F2/38 , C08F4/32 , C08F4/34 , C08F4/36
摘要： Novel unsaturated peroxides useful as molecular weight regulators in polymerization reactions are disclosed. Also disclosed are a polymerization process employing these novel unsaturated peroxides as molecular weight regulators, polymers and oligomers made by this process and articles of manufacture comprising one or more polymers or oligomers made by this process. These molecular weight regulating peroxides provide the ability to introduce an epoxy functionality to the oligomer or polymer as well as an additional functionality. Further, omega (di) substituted or alpha, omega disubstituted polymers may be synthesized using the unsaturated peroxides of the present invention.
摘要翻译： PCT No.PCT / EP90 / 01780 Sec。 371日期：1992年5月15日 102（e）日期1992年5月15日PCT提交1990年10月16日PCT公布。公开号WO91 / 07387 日期1991年5月30日公开了用作聚合反应中分子量调节剂的新型不饱和过氧化物。还公开了使用这些新型不饱和过氧化物作为分子量调节剂，通过该方法制备的聚合物和低聚物的聚合方法和包含通过该方法制备的一种或多种聚合物或低聚物的制品。这些分子量调节过氧化物提供了向低聚物或聚合物引入环氧官能团以及附加功能的能力。此外，ω（二）取代或α，ω二取代的聚合物可以使用本发明的不饱和过氧化物合成。

63. 发明授权

US5494988A Unsaturated peroxide compositions, polymeric-peroxides derived therefrom and their uses 失效
公开(公告)号：US5494988A
公开(公告)日：1996-02-27
申请号：US454753
申请日：1995-05-31
申请人： Jose Sanchez , Leonard H. Palys , Daryl L. Stein , John S. Yormick
发明人： Jose Sanchez , Leonard H. Palys , Daryl L. Stein , John S. Yormick
IPC分类号： C07D317/30 , C07C409/16 , C07C409/20 , C07C409/22 , C07C409/38 , C07C409/40 , C07D317/72 , C07D319/06 , C07D323/00 , C08F4/28 , C08F4/34 , C08F4/36 , C08F124/00 , C08F116/36 , C08F120/10 , C08F126/02
CPC分类号： C07C409/40 , C07C409/16 , C07C409/20 , C07C409/22 , C07C409/38 , C08F4/36
摘要： Novel unsaturated peroxide compositions of Structure A,R--Q--X--R.sub.1 A[Where the R--Q-- grouping contains a polymerizable carbon-carbon double bond, --X-- is a direct bond or a connecting diradical and --R.sub.1 is a peroxide containing radical all as defined in the Summary of the Invention Section.], polymeric-peroxide compositions derived from them and their uses are disclosed.

64. 发明授权

US5134213A Polymer-type polymerization initiator 失效
标题翻译：聚合物型聚合引发剂
公开(公告)号：US5134213A
公开(公告)日：1992-07-28
申请号：US753934
申请日：1991-09-03
申请人： Toru Kawaguchi
发明人： Toru Kawaguchi
IPC分类号： C08F4/28 , C08F4/34 , C08F4/36 , C08F20/10 , C08F22/10 , C08F26/00 , C08F26/10 , C08F220/20 , C08F222/18 , C08F222/20 , C08F226/06 , C08F226/10
CPC分类号： C08F4/36 , C08F222/20 , C08F226/06
摘要： A polymer-type polymerization initiator produced by copolymerizing (A) 40 to 60 mole % of an N-vinyllactam and (B) 60 to 40 mole % of at least one fumarate containing a peroxy group, the peroxy-fumarate (B) being represented by the following formula: ##STR1## wherein R1 is a linear alkyl, branched alkyl or cycloalkyl group containing not more than 18 carbon atoms, or an aromatic hydrocarbon group containing 6 to 18 carbon atoms; and R2 is a linear alkyl, branched alkyl or cycloalkyl group containing not more than 13 carbon atoms, or a phenyl group.The peroxy-fumarate (b1) may be used in combination with (b2) at least one diester of fumaric acid selected from the group consisting of alkyl fluoroalkyl fumarate, alkyl silicon-containing-alkyl fumarate, fluoroalkyl silicon-containing-alkyl fumarate, bis(fluoroalkyl) fumarate, and bis(silicon-containing-alkyl) fumarate, a mole ratio of the peroxy-fumarate to the diester of fumaric acid falling within a range of 9 to 1 to 1 to 9.
摘要翻译：通过共聚合（A）40〜60摩尔％的N-乙烯基内酰胺和（B）60〜40摩尔％的至少一种含有过氧基的富马酸酯而制备的聚合物型聚合引发剂，所述过氧富马酸酯（B）其中R 1是含有不超过18个碳原子的直链烷基，支链烷基或环烷基，或含有6-18个碳原子的芳族烃基; 并且R 2是含有不超过13个碳原子的直链烷基，支链烷基或环烷基或苯基。过氧富马酸酯（b1）可以与（b2）至少一种富马酸二酯组合使用，所述富马酸二酯选自富马酸烷基氟烷基酯，富马酸烷基烷基酯，富马酸烷基烷基酯，富马酸氟烷基酯，富马酸烷基酯，富马酸烷基酯（氟烷基）富马酸酯和双（含硅 - 烷基）富马酸酯，过氧富马酸与富马酸的二酯的摩尔比在9至1至1至9的范围内。

65. 发明授权

US5039754A Polymeric peroxides derived from hydroxy-hydroperoxides and dihydroxydialkyl peroxides and their uses 失效
标题翻译：衍生自羟基氢过氧化物和二羟基二烷基过氧化物的聚合过氧化物及其用途
公开(公告)号：US5039754A
公开(公告)日：1991-08-13
申请号：US575031
申请日：1990-08-30
申请人： Jose Sanchez
发明人： Jose Sanchez
IPC分类号： C07C409/16 , C07C409/38 , C08F4/28 , C08F4/32 , C08F4/36 , C08G18/30 , C08G18/86 , C08G63/00 , C08G64/00 , C08G71/00 , C08K5/14 , C08L23/10
CPC分类号： C08L53/00 , C08F293/00 , C08F293/005 , C08F4/36 , C08G18/30 , C08G18/86 , C08G63/00 , C08G64/00 , C08G71/00 , C08K5/14 , C08L2312/00
摘要： A polymeric peroxide comprising a dilvalent recurring unit having the formula: ##STR1## wherein the recurring unit of Formula I has a 10 hour half-life temperature of at least 80.degree. C. and optionally a divalent recurring unit having the formula: ##STR2## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.5, X, X.sup.1, Y, Z, y and z are as defined in the Detailed Description of the Preferred Embodiments and the polymeric peroxide has a molecular weight of 1,000 to 200,000. The polymeric peroxides are derived from hydroxy-hydroperoxides of dihydroxy dialkyl peroxides. These polymeric peroxides can be used for preparing block copolymers and compatibilizing polymer blends and alloys.

66. 发明授权

US4788019A Method of molding a polymer composition containing a tetraalkenyl orthosilicate 失效
标题翻译：模塑含有原硅酸四链烯酯的聚合物组合物的方法
公开(公告)号：US4788019A
公开(公告)日：1988-11-29
申请号：US10877
申请日：1987-02-04
申请人： Lyle R. Kallenbach
发明人： Lyle R. Kallenbach
IPC分类号： C08F4/36 , C08F255/00 , C08K5/5425 , B29C41/04
CPC分类号： C08F255/00 , C08F4/36 , C08K5/5425
摘要： A method for producing molded articles by supplying to a mold a powdered thermoplastic material; heating the mold to fuse the material and cooling the mold to cause the fused thermoplastic material to solidify. The article is molded from a high density monoolefin thermoplastic polymer which contains a catalyst residue, a crosslinking amount of an acetylinic diperoxy compound and a tetraalkenyl orthosilicate compound. The molded article has at least one of increased crosslinking, lowered bubble formation and increased storage modulus.
摘要翻译：一种通过向模具供给粉末状热塑性材料来制造模制品的方法; 加热模具以熔化材料并冷却模具以使熔融的热塑性材料固化。该制品由含有催化剂残余物，交联量的乙炔二过氧化合物和四链烯基原硅酸盐化合物的高密度单烯烃热塑性聚合物模制而成。模制品具有增加的交联，降低的气泡形成和增加的储能模量中的至少一种。

67. 发明授权

US4238381A Process for producing a non-aqueous system dispersed solution of polymers from polymeric peroxides 失效
标题翻译：从聚合物过氧化物制备聚合物的非水系分散溶液的方法
公开(公告)号：US4238381A
公开(公告)日：1980-12-09
申请号：US54239
申请日：1979-07-02
申请人： Takeshi Komai , Masaru Matsushima
发明人： Takeshi Komai , Masaru Matsushima
IPC分类号： C08F2/00 , C08F2/08 , C08F4/00 , C08F4/36 , C08F4/80 , C08F293/00 , C08F297/00 , C08L33/08
CPC分类号： C08F2/08 , C08F293/00 , C08F4/36 , Y10S524/923
摘要： A non-aqueous liquid dispersion of polymers is obtained by a first step of copolymerizing one or more vinyl-type monomers with one or more polymerized peroxides, capable of further polymerization followed by a second step of copolymerizing the resulting copolymer having peroxy bonds therein with one or more vinyl-type monomers different than the one or ones used in the first copolymerization step, in an organic liquid which dissolves the polymers of the vinyl-type monomers of the first copolymerization but does not dissolve the polymers of the vinyl-type monomers used in the second copolymerization. The dispersion is splendid in dispersion stability and it is very useful as a thermosetting, film-type, coating composition.
摘要翻译：聚合物的非水性液体分散体是通过使一种或多种乙烯基型单体与一种或多种聚合过氧化物共聚的第一步骤得到的，该聚合过氧化物能够进一步聚合，随后是将所得到的具有过氧键的共聚物与其中一个或更多个与第一共聚步骤中使用的那些不同的乙烯基型单体，在溶解第一次共聚合的乙烯基型单体的聚合物但不溶解所使用的乙烯基型单体的聚合物的有机液体中在第二次共聚。该分散体在分散稳定性方面是极好的，并且作为热固性，薄膜型涂料组合物是非常有用的。

68. 发明授权

US4079074A Unsymmetrical diperoxides and processes of use in polymerizing unsaturated monomers 失效
标题翻译：不对称的二过氧化物和用于聚合不饱和单体的方法
公开(公告)号：US4079074A
公开(公告)日：1978-03-14
申请号：US757185
申请日：1977-01-06
申请人： Jose Sanchez , Vasanth Rathnakar Kamath , James Charles Halas
发明人： Jose Sanchez , Vasanth Rathnakar Kamath , James Charles Halas
IPC分类号： C08F4/00 , C07C67/00 , C07C407/00 , C07C409/38 , C08F4/28 , C08F4/36 , C08F299/04 , C07C179/18
CPC分类号： C07C409/38 , C08F299/045 , C08F4/36 , C07C2101/14 , C07C2101/16
摘要： Unsymmetrical diperoxides of the general structure: ##STR1## for example, 4-(t-butylperoxycarbonyl)-3-hexyl-6-[7-(tbutylperoxycarbonyl)heptyl] cyclohexene, are useful for polymerizing ethylenically unsaturated monomers (such as styrene). The polymerizations can be carried out at higher temperatures and in shorter times than with conventional initiator systems, without detrimental decrease in polymer molecular weight or significant change in molecular weight distribution. The unsymmetrical diperoxides are also useful as catalysts for curing unsaturated polyester resins.
摘要翻译：一般结构的不对称二过氧化物：例如4-（叔丁基过氧羰基）-3-己基-6- [7-（叔丁基过氧羰基）庚基]环己烯，可用于聚合烯属不饱和单体（如苯乙烯）。聚合可以在比常规的引发剂体系更高的温度和更短的时间内进行，而不会有害地降低聚合物分子量或分子量分布的显着变化。不对称二过氧化物也可用作固化不饱和聚酯树脂的催化剂。

69. 发明授权

US3980629A Organic peroxides derived from unsaturated compounds 失效
标题翻译：衍生自不饱和化合物的有机过氧化物
公开(公告)号：US3980629A
公开(公告)日：1976-09-14
申请号：US554472
申请日：1975-03-03
申请人： Egeo Sacrini , Claudio Cavallotti
发明人： Egeo Sacrini , Claudio Cavallotti
IPC分类号： C07C409/22 , C08F4/36 , C08K5/14 , C08C19/28 , C08F8/06 , C08F255/04 , C08F291/02
CPC分类号： C08K5/14 , C08F4/36
摘要： New organic peroxides having the formula ##EQU1## may be prepared by reacting a monohydroperoxide selected from R.sub.5 OOH and R.sub.6 OOH with an unsaturated carbonyl compound having the formula ##EQU2## the reaction being carried out in the presence of an acid catalyst at a temperature between about -30.degree.C and +80.degree.C, the molar ratio of the carbonyl compound to the hydroperoxide being between about 1:2 and 1:10. The new organic peroxides are particularly useful for crosslinking plastomers, vulcanizing elastomers, and as initiators for radical polymerizations.
摘要翻译：具有式OOR 5的新的有机过氧化物R1-C = CC ANGLE || R2R3R4OOR6可以通过使选自R5OOH和R6OOH的单氢过氧化物与具有式R1-C = CC = O，||RR2R3R4的不饱和羰基化合物反应来制备，反应在酸催化剂存在下在约-30℃至+ 80℃的温度下进行，羰基化合物与氢过氧化物的摩尔比为约1:2至1:10。新的有机过氧化物特别可用于交联塑性体，硫化弹性体和作为自由基聚合的引发剂。

70. 发明授权

US3928466A Organic peroxides derived from unsaturated compounds 失效
公开(公告)号：US3928466A
公开(公告)日：1975-12-23
申请号：US55447475
申请日：1975-03-03
申请人： GOODRICH CO B F
发明人： SACRINI EGEO , CAVALLOTTI CLAUDIO
IPC分类号： C07C409/22 , C08F4/36 , C08K5/14 , C07C179/00 , C07C179/06
CPC分类号： C08F4/36 , C07C409/22 , C07C2601/14 , C07C2602/10 , C08K5/14 , C08L23/16
摘要： New organic peroxides having the formula

may be prepared by reacting a monohydroperoxide selected from R5OOH and R6OOH with an unsaturated carbonyl compound having the formula

the reaction being carried out in the presence of an acid catalyst at a temperature between about -30*C and +80*C, the molar ratio of the carbonyl compound to the hydroperoxide being between about 1:2 and 1:10. The new organic peroxides are particularly useful for crosslinking plastomers, vulcanizing elastomers, and as initiators for radical polymerizations.

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