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    • 61. 发明授权
    • Layered membrane and processes utilizing same
    • 分层膜和利用它们的方法
    • US4242193A
    • 1980-12-30
    • US957876
    • 1978-11-06
    • Karl Moeglich
    • Karl Moeglich
    • B01D61/46B01D61/50C02F1/46C02F1/469C25B13/02C25C7/04
    • B01D61/52B01D61/50B01D69/04C25B13/02C25C7/04C02F1/4606C02F1/469C02F2201/46115
    • The invention relates to a membrane assembly and processes for the utilization of the membrane assembly, or membrane assemblies having like properties. The membrane assembly comprises intermixed layers of capillary material and high dielectric constant impermeable material, forming capillary channels parallel to the direction of ion transport through the membrane. The membrane is anion permeable, does not have membrane potential and will not foul even over extended operation, allows cross-flow of anions and cations, and is highly efficient. It is possible to remove complex metals from any contaminated acid by electrodialysis, such as removing vanadium and uranium in recoverable form from contaminated phosphoric acid, while producing food grade phosphoric acid in the process. Additionally, simple metals may be removed from mine waste liquids (from leaching), chlorine can be produced from a chloride containing salt, and chromium can be removed from chromium contaminated water by electrolysis. Milling sludge can be treated to form water, caustic, and acid, and mineralized water can be treated to form de-mineralized water, by subjecting the feed liquids to electrodialysis.
    • 本发明涉及膜组件和利用膜组件的方法,或具有相似性质的膜组件。 膜组件包括毛细管材料和高介电常数不渗透材料的混合层,形成平行于通过膜的离子传输方向的毛细管通道。 膜是阴离子可渗透的,不具有膜电位,即使在延长的操作中也不会弄脏,允许阴离子和阳离子的交叉流动,并且是高效的。 可以通过电渗析从任何污染的酸中除去复杂的金属,例如从污染的磷酸中除去可回收的钒和铀,同时在该过程中生产食品级磷酸。 另外,简单的金属可以从矿石废液中除去(浸出),可以由含氯化物的盐生成氯,并且可以通过电解从铬污染的水中除去铬。 研磨泥浆可以处理形成水,苛性碱和酸,并且可以通过对进料液进行电渗析来处理矿化水以形成去矿化水。