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61. 发明授权

US08338517B2 Aqueous compositions of fluorinated surfactants and methods of using the same 失效
标题翻译：氟化表面活性剂的水性组合物及其使用方法
公开(公告)号：US08338517B2
公开(公告)日：2012-12-25
申请号：US12601143
申请日：2008-05-21
申请人： Rudolf J. Dams , Michael S. Terrazas
发明人： Rudolf J. Dams , Michael S. Terrazas
IPC分类号： C08K5/00
CPC分类号： C11D1/004 , C09D5/027 , C09D7/45 , C09D7/47 , C09G1/04 , C11D3/37
摘要： Aqueous compositions comprising surfactant represented by a formula selected from the group consisting of: [Rf—(O)t—CHF—(CF2)n—COO−]iXi+; {[Rf—(O)t—CQH—CF2—O]m—R—COO−}iXi+; {[Rf—(O)t—CQH—CF2—O]m—R—SO3−}iXi+; and [CF3CFH—O—(CF2)p—COO−]iXi+; wherein Rf represents a partially or fully fluorinated aliphatic group optionally interrupted with at least one oxygen atom; Q is selected from the group consisting of F and CF3; R is selected from the group consisting of alkylene and arylene; Xi+ represents a cation having a valence i, wherein i is 1, 2 or 3; t is 0 or 1; m is 1, 2, or 3; n is 0 or 1; and p is an integer from 1 to 6. The aqueous composition comprises a non-fluorinated polymer and is essentially free of fluoropolymers. Methods of coating a surface and an article having a surface in contact with the composition are provided.
摘要翻译：包含由选自以下的式的表面活性剂组成的水性组合物：[Rf-（O）t-CHF-（CF 2）n -CO 2 - ] i X i + {[Rf-（O）t-CQH-CF2-O] m -R-COO-} iXi +; {[Rf-（O）t-CQH-CF2-O] m -R-SO3-} iXi +; 和[CF 3 CFH-O-（CF 2）p-COO-] i X i +; 其中Rf表示任选被至少一个氧原子间断的部分或完全氟化的脂族基团; Q选自F和CF 3; R选自亚烷基和亚芳基; Xi +表示具有i价的阳离子，其中i为1,2或3; t为0或1; m为1,2或3; n为0或1; 并且p是1至6的整数。水性组合物包含非氟化聚合物并且基本上不含含氟聚合物。提供涂覆表面和具有与组合物接触的表面的制品的方法。

62. 发明申请

US20120065108A1 FLUORINATED POLYMERIC MICROPARTICLES AND USES THEREOF AS FLUID REDUCING ADDITIVES 审中-公开
标题翻译：氟化聚合物微球及其作为减少流体的添加剂的用途
公开(公告)号：US20120065108A1
公开(公告)日：2012-03-15
申请号：US13321579
申请日：2010-06-02
申请人： Tom Opstal , Rudolf J. Dams , Rudy W. Van Campenhout , Francois C. D'Haese
发明人： Tom Opstal , Rudolf J. Dams , Rudy W. Van Campenhout , Francois C. D'Haese
IPC分类号： C09K8/12 , C08F236/20 , C08L47/00
CPC分类号： C08F214/18 , C08F220/10 , C08F220/18 , C08F222/1006 , C08F259/08 , C08L27/12 , C08L33/06 , C08L33/16 , C08L51/003 , C09K8/035 , C09K8/516 , Y10T428/2982 , C08F220/38 , C08F220/06 , C08L2666/04 , C08L2666/02
摘要： Fluorinated polymeric microparticles, processes for preparing them and uses thereof as additives for fluid loss control of drilling fluids and methods of fluid loss control of drilling fluid loss with fluorinated microparticles and uses of fluoropolymers as fluid loss control agents. Said fluorinated polymeric microparticles comprise one or more repeating units derived from one or more fluorinated monomers and one or more repeating units derived from one or more acrylate monomers.
摘要翻译：氟化聚合物微粒，其制备方法及其作为钻井液的流体损失控制的添加剂和氟化微粒的钻井液损失的流体损失控制方法以及氟聚合物作为流体损失控制剂的用途。所述氟化聚合物微粒包含衍生自一种或多种氟化单体的一种或多种重复单元和一种或多种衍生自一种或多种丙烯酸酯单体的重复单元。

63. 发明申请

US20120009438A1 TRIAZINE CONTAINING FLUOROELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 审中-公开
标题翻译：含有低玻璃化转变温度的含荧光物质的TRIAZINE
公开(公告)号：US20120009438A1
公开(公告)日：2012-01-12
申请号：US12833522
申请日：2010-07-09
申请人： Rudolf J. Dams , Steven G. Corveleyn , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
发明人： Rudolf J. Dams , Steven G. Corveleyn , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
IPC分类号： B32B9/00 , C08L27/12 , C08F214/18
CPC分类号： C08G65/007 , C08G2650/48 , C08L71/00 , C08L27/12
摘要： There is provided a curable fluoroelastomer composition comprising i. a first compound which comprising repeating units derived from a fluorinated olefin and further comprising at least one functional group, ii. a second compound comprising repeating units selected from (—C4F8O—), (—C2F4O—) or (—CF2O) or a combination thereof and further containing at least one functional group capable of reacting with the at least one functional group of the first compound either directly or in the presence of a curing compound to form a triazine unit, wherein the composition after curing by forming triazine units has a glass transition temperature of less than −60° C. Also provided are shaped articles comprising the cured compositions, methods of making cured compositions and methods for making shaped articles.
摘要翻译：提供了可固化的含氟弹性体组合物，其包含i。包含衍生自氟化烯烃的重复单元并且还包含至少一个官能团的第一化合物，ii。包含选自（-C 4 F 8 O-），（-C 2 F 4 O-）或（-CF 2 O）的重复单元或其组合的第二化合物，并且还含有至少一个能够与第一化合物的至少一个官能团反应的官能团直接或在固化化合物存在下形成三嗪单元，其中通过形成三嗪单元固化后的组合物具有小于-60℃的玻璃化转变温度。还提供了包含固化组合物的成型制品，制成固化组合物和制造成型制品的方法。

64. 发明申请

US20100247932A1 MEDICINAL INHALATION DEVICES AND COMPONENTS THEREOF 有权
标题翻译：药物吸入装置及其组件
公开(公告)号：US20100247932A1
公开(公告)日：2010-09-30
申请号：US12741542
申请日：2008-11-06
申请人： Philip A. Jinks , Moses M. David , Rudolf J. Dams
发明人： Philip A. Jinks , Moses M. David , Rudolf J. Dams
IPC分类号： B32B17/00 , B01J19/08 , B32B9/04
CPC分类号： A61M16/14 , A61M11/04 , A61M15/0065 , A61M15/0086 , A61M15/009 , A61M15/0091 , A61M15/08 , B05D1/62 , B05D5/083 , B05D5/086 , B05D2202/15 , B65D83/54 , C23C16/0245 , C23C16/26 , C23C16/30 , C23C16/401 , C23C16/56 , Y10T428/265 , Y10T428/31663 , Y10T428/31667
摘要： A medicinal inhalation device having a non-metal coating applied by plasma deposition under ion bombardment conditions.
摘要翻译：一种药物吸入装置，其具有通过离子轰击条件下的等离子体沉积施加的非金属涂层。

65. 发明授权

US07776983B2 Fluorochemical polymeric surfactants 有权
标题翻译：含氟聚合物表面活性剂
公开(公告)号：US07776983B2
公开(公告)日：2010-08-17
申请号：US11026706
申请日：2004-12-30
申请人： Michael S. Terrazas , George G. I. Moore , Michael J. Sierakowski , Rudolf J. Dams
发明人： Michael S. Terrazas , George G. I. Moore , Michael J. Sierakowski , Rudolf J. Dams
IPC分类号： C08F12/30
CPC分类号： C08F220/38 , C08F220/28 , C09D7/47 , C11D1/004 , C11D1/008
摘要： Described are polymeric surfactants which include a fluorinated moiety and a non-fluorinated moiety where the fluorinated moiety contains two perfluoro-lower-alkyl sulfonamido segments in proximity to each other ; the surfactants provide more efficient and effective lowering of the surface tension of liquids and increase of wetting of a coating on a substrate surface.
摘要翻译：描述了包括氟化部分和非氟化部分的聚合物表面活性剂，其中氟化部分包含彼此接近的两个全氟低级烷基亚磺酰氨基部分; 表面活性剂提供更有效和有效地降低液体的表面张力和增加基材表面上的涂层的润湿性。

66. 发明授权

US07728098B2 Fluorochemical composition comprising fluorinated oligomeric silane 有权
标题翻译：包含氟化低聚硅烷的含氟化合物组合物
公开(公告)号：US07728098B2
公开(公告)日：2010-06-01
申请号：US11460303
申请日：2006-07-27
申请人： Rudolf J. Dams , Zai-Ming Qiu
发明人： Rudolf J. Dams , Zai-Ming Qiu
IPC分类号： C08G18/28 , C08L27/12 , C07F7/02
CPC分类号： C08G18/2885
摘要： Fluorochemical oligomeric silanes, compositions comprising such silanes and/or the condensation products of such silanes, and coatings produced with such compositions.
摘要翻译：氟化物低聚硅烷，包含这种硅烷的组合物和/或这种硅烷的缩合产物，以及用这种组合物制备的涂料。

67. 发明授权

US07321018B2 Compositions for aqueous delivery of fluorinated oligomeric silanes 失效
标题翻译：含氟低聚硅烷的水分输送组合物
公开(公告)号：US07321018B2
公开(公告)日：2008-01-22
申请号：US10745003
申请日：2003-12-23
申请人： Rudolf J. Dams , Mark J. Pellerite , Steven J. Martin , Michael S. Terrazas
发明人： Rudolf J. Dams , Mark J. Pellerite , Steven J. Martin , Michael S. Terrazas
IPC分类号： C08G77/20
CPC分类号： C04B41/009 , C03C17/30 , C04B41/495 , C04B41/52 , C04B41/84 , C08F30/08 , C08L27/12 , C09D127/12 , Y10T428/31612 , Y10T428/31663 , C04B41/502 , C04B2103/40 , C04B41/5022 , C04B33/00 , C08L33/00
摘要： The invention relates to a dilutable, non-aqueous concentrate and an aqueous dilution used for aqueous delivery of fluorinated oligomeric silanes to a substrate, a method of treating a substrate with the aqueous dilution composition to render it oil and water repellent, and articles having coatings made from the aqueous dilution.
摘要翻译：本发明涉及一种可稀释的非水性浓缩物和用于将氟化低聚硅烷水性输送到底物的水性稀释液，用水稀释组合物处理底物以使其具有防水和防水性的方法，以及具有涂层的制品由水稀释制成。

68. 发明授权

US06977307B2 Water soluble or water dispersible fluorochemical silanes for rendering substrates oil and water repellent 失效
标题翻译：水溶性或水分散性含氟硅烷，用于使基质油和憎水剂
公开(公告)号：US06977307B2
公开(公告)日：2005-12-20
申请号：US10053001
申请日：2002-01-17
申请人： Rudolf J. Dams
发明人： Rudolf J. Dams
IPC分类号： C09K3/18 , B05D3/04 , B05D3/10 , B05D5/08 , C04B33/34 , C07F7/04 , C07F7/12 , C07F7/18 , C08F20/22 , C08F20/24 , C08F20/38 , C08F220/22 , C08F220/24 , C08F220/38 , C08G81/02
CPC分类号： C04B41/4933 , B05D5/083 , C03C17/30 , C04B41/009 , C04B41/84 , C07F7/1804 , C04B41/502 , C04B33/00
摘要： A water soluble or water dispersible fluorochemical silane represented by the general formula (I): X-MfnMhmMar-G wherein X represents the residue of an initiator or hydrogen; Mf represents units derived from one or more fluorinated monomer; Mh represents units derived from one or more non-fluorinated monomer; Ma represents units having a silyl group; G is a monovalent organic group comprising the residue of a chain transfer agent; n represents a value of 1 to 100; m represents a value of 0 to 100; and r represents a value of 0 to 100; and n+m+r is at least 2; with the proviso that at least one of the following conditions is fulfilled: (a) G contains a silyl group of the formula (III): wherein Y1, Y2 and Y3 each independently represents an alkyl group, an aryl group or a hydrolyzable group and at least one of Y1, Y2 and Y3 represents a hydrolyzable water solubilising group; or (b) r is at least 1 and at least one of Y4, Y5 and Y6 represents a hydrolyzable water solubilizing group.
摘要翻译：由通式（I）表示的水溶性或水分散性含氟硅烷：<？in-line-formula description =“In-line Formulas”end =“lead”？> XM _{n m m =“In-line Formulas”end =“tail”？>其中X表示引发剂或氢的残基; M代表来自一种或多种氟化单体的单元; M h H表示衍生自一种或多种非氟化单体的单元; M ^{a表示具有甲硅烷基的单元; G是包含链转移剂残基的一价有机基团; n表示1〜100的数值。 m表示0〜100的值。 r表示0〜100的值。 n + m + r为2以上; 条件是满足以下条件中的至少一个：（a）G包含式（III）的甲硅烷基：其中Y 1，Y 2和 Y 3各自独立地表示烷基，芳基或可水解基团，Y 1，Y 2和Y 2中的至少一个， SUP> 3 表示可水解水增溶基团; 或（b）r为至少1且Y 4，Y 5和Y 6以及Y 6中的至少一个表示可水解的水溶性基团。}}

69. 发明授权

US06861149B2 Compositions for aqueous delivery of self-emulsifying fluorinated alkoxysilanes 失效
标题翻译：用于自乳化氟化烷氧基硅烷的水输送组合物
公开(公告)号：US06861149B2
公开(公告)日：2005-03-01
申请号：US10447802
申请日：2003-05-29
申请人： Mark J. Pellerite , Michael S. Terrazas , Rudolf J. Dams
发明人： Mark J. Pellerite , Michael S. Terrazas , Rudolf J. Dams
IPC分类号： B05D7/24 , C03C17/30 , C03C17/32 , C04B41/49 , C04B41/52 , C04B41/84 , C08G65/00 , C08G65/336 , C08G65/337 , C08J3/09 , C09D183/08 , C09D183/12 , C09D201/02 , C09K3/18 , B32B17/06
CPC分类号： C08G65/337 , C03C17/32 , C03C17/328 , C04B41/009 , C04B41/4933 , C04B41/52 , C08G65/007 , C08G65/336 , C08J3/09 , C08J2383/12 , C09D183/12 , Y10S528/901 , Y10T428/31663 , C04B41/0072 , C04B41/4535 , C04B41/502 , C04B2103/40 , C04B41/5022 , C04B33/00
摘要： The invention relates to compositions used for aqueous delivery of self-emulsifying fluorinated alkoxysilanes to substrates to provide oil and water resistive coatings for the substrates, a method of treating a substrate to render it oil and water repellent, and articles having coatings made from the compositions.
摘要翻译：本发明涉及用于将自乳化氟化烷氧基硅烷水性输送到基材以提供用于基材的油和水电阻涂层的组合物，一种处理基材以使其具有防油和防水性的方法，以及具有由组合物制成的涂层的制品。

70. 发明授权

US06613860B1 Compositions comprising fluorinated polyether silanes for rendering substrates oil and water repellent 有权
标题翻译：包含氟化聚醚硅烷的组合物，用于使底物油和憎水性
公开(公告)号：US06613860B1
公开(公告)日：2003-09-02
申请号：US09689013
申请日：2000-10-12
申请人： Rudolf J. Dams , Franceska M. Fieuws , Steven J. Martin , Michael S. Terrazas , Mark J. Pellerite
发明人： Rudolf J. Dams , Franceska M. Fieuws , Steven J. Martin , Michael S. Terrazas , Mark J. Pellerite
IPC分类号： C08G7760
CPC分类号： C04B41/009 , C03C17/30 , C04B41/4933 , C04B41/84 , C08G65/007 , C08G65/336 , C04B41/46 , C04B41/463 , C04B41/502 , C04B33/00
摘要： The present invention provides composition for treating a substrate comprising a homogeneous mixture of: (a) a fluorinated polyether silane of the formula: Rf1—[—Q—SiY3−xR1x]y (I) wherein Rf1 represents a monovalent or divalent polyfluoropolyether group, Q represents an organic divalent linking group, R1 represents a C1-C4 alkyl group, Y represents a hydrolysable group; x is 0 or 1 and y is 1 or 2; (b) an organic or an inorganic acid; (c) water; and (d) an organic solvent. The invention further provides a method of making such a composition and the use thereof to treat substrates to render them oil and water repellent.
摘要翻译：本发明提供了一种用于处理底物的组合物，其包含以下均匀混合物：（a）下式的氟化聚醚硅烷：其中Rf1表示一价或二价多氟聚醚基团，Q表示有机二价连接基团，R1表示C1-C4 烷基，Y表示可水解基团; x为0或1，y为1或2;（b）有机或无机酸;（c）水; 和（d）有机溶剂。本发明还提供了一种制备这种组合物的方法及其用途来处理基材以使其具有防水和防水性。

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