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61. 发明授权

US5202472A Asymmetric hydrogenation of aromatic-substituted olefins using organonickel catalyst 失效
标题翻译：使用有机镍催化剂对芳族取代烯烃进行不对称加氢
公开(公告)号：US5202472A
公开(公告)日：1993-04-13
申请号：US716012
申请日：1991-06-17
申请人： Thanikavelu Manimaran , W. Dirk Klobucar , Charles H. Kolich
发明人： Thanikavelu Manimaran , W. Dirk Klobucar , Charles H. Kolich
IPC分类号： C07C51/36 , C07C211/27
CPC分类号： C07C51/36 , C07C211/27
摘要： A process for the asymmetric reduction of carboxylic acids of the formula ##STR1## or the amine salts thereof, where R and R.sub.1 are the same or different and are hydrogen, alkyl, cycloalkyl or haloalkyl and Ar is aryl or substituted aryl is disclosed.
摘要翻译：公开了用于不对称还原式IMA的羧酸或其胺盐的方法，其中R和R 1相同或不同，并且是氢，烷基，环烷基或卤代烷基，Ar是芳基或取代的芳基。

62. 发明授权

US5187135A Asymmetric hydrogenation of aromatic-substituted olefins using organo-cobalt catalyst 失效
标题翻译：使用有机钴催化剂对芳族取代烯烃进行不对称加氢
公开(公告)号：US5187135A
公开(公告)日：1993-02-16
申请号：US716017
申请日：1991-06-17
申请人： Charles H. Kolich , Thanikavelu Manimaran , W. Dirk Klobucar
发明人： Charles H. Kolich , Thanikavelu Manimaran , W. Dirk Klobucar
IPC分类号： B01J31/24 , B01J31/28 , C07C51/36 , C07F15/06
CPC分类号： B01J31/2452 , B01J31/2234 , B01J31/24 , C07C51/36 , C07F15/065 , B01J2231/645 , B01J2531/0266 , B01J2531/845
摘要： A process for the asymmetric reduction of carboxylic acids of the formula ##STR1## or the amine salts thereof, where R and R.sub.1 are the same or different and are hydrogen, alkyl, cycloalkyl or haloalkyl and Ar is aryl or substituted aryl is disclosed.
摘要翻译：公开了用于不对称还原式IMA的羧酸或其胺盐的方法，其中R和R 1相同或不同，并且是氢，烷基，环烷基或卤代烷基，Ar是芳基或取代的芳基。

63. 发明授权

US5102963A Acrylate cured polyphosphazenes 失效
标题翻译：丙烯酸酯固化聚磷腈
公开(公告)号：US5102963A
公开(公告)日：1992-04-07
申请号：US334357
申请日：1989-04-07
申请人： Charles H. Kolich , Suae-Chen Chang
发明人： Charles H. Kolich , Suae-Chen Chang
IPC分类号： C08F299/02 , C08G79/02
CPC分类号： C08F299/024 , C08G79/025
摘要： Polyorganophosphazenes having at least some N-(acryloxyhydrocarbyl)ureidohydrocarbyloxy groups: ##STR1## bonded to an oxygen substituted on at least some of the phosphorus atoms of the phosphazene chain. These compounds can be cross-linked by exposure to ultraviolet radiation.
摘要翻译：具有至少一些N-（丙烯酰氧基烃基）脲基氧氧基的多有机膦腈：与在磷腈链的至少一些磷原子上取代的氧键合。这些化合物可以通过暴露于紫外线辐射而交联。

64. 发明授权

US4945140A Process for preparation of phosphonitrilic fluoroelastomers 失效
标题翻译：制备膦酰基含氟弹性体的方法
公开(公告)号：US4945140A
公开(公告)日：1990-07-31
申请号：US373449
申请日：1989-06-30
申请人： Charles H. Kolich , W. Dirk Klobucar
发明人： Charles H. Kolich , W. Dirk Klobucar
IPC分类号： C08G79/02
CPC分类号： C08G79/025
摘要： An improved process for the preparation of highly fluorinated phosphonitrilic elastomers is disclosed. The fluoroalkoxy substituents on phosphonitrilic fluoroelastomers which contain some or all fluoroalkoxy groups in which the terminal carbon bears one or more hydrogen atoms are exchanged with fully fluorinated alkoxide groups in which the terminal carbon bears three fluorines. The process is accomplished using a ligand replacement mixture of an alkali metal fluoroalkoxide of the formula MOC.sub.n.sup.f and a fluoroalcohol of the formula HOC.sub.n.sup.f' where C.sub.n.sup.f is --(CH.sub.2).sub.y (CF.sub.2).sub.n CF.sub.3 where y is an integer 1 or 2 and n is an integer from 0 to 20 and C.sub.n.sup.f' is the same or different from C.sub.n.sup.f where C.sub.n.sup.f' is --(CH.sub.2).sub.y (CF.sub.2).sub.n CF.sub.3 where y and n are as previously defined.
摘要翻译：公开了制备高度氟化的膦腈基弹性体的改进方法。含有末端碳带有一个或多个氢原子的一部分或全部氟代烷氧基的磷腈基含氟弹性体上的氟代烷氧基取代基与其中末端碳带有三个氟的完全氟化的醇盐基团交换。该方法使用式MOCnf的碱金属氟代烷氧化物和式HOCnf'的氟代醇（其中C nf是 - （CH 2）y（CF 2）n CF 3）的配体置换混合物完成，其中y是整数1或2，并且n是 Cnf'与Cnf相同或不同，其中Cnf'是 - （CH2）y（CF2）nCF3，其中y和n如前所定义。

65. 发明授权

US4945139A Process for surface treating phosphonitrilic fluoroelastomers 失效
标题翻译：表面处理膦酸三氟弹性体的方法
公开(公告)号：US4945139A
公开(公告)日：1990-07-31
申请号：US383642
申请日：1989-07-24
申请人： Charles H. Kolich , W. Dirk Klobucar , Jeffrey T. Books
发明人： Charles H. Kolich , W. Dirk Klobucar , Jeffrey T. Books
IPC分类号： C08G79/02
CPC分类号： C08G79/025
摘要： A process for treating the surface of a cured phosphonitrilic fluoroelastomer of the formula ##STR1## where x is an integer of from about 3 to about 50,000, Q and Q' are the same or different and are fluoroalkoxy of the formula --OCH.sub.2 (CF.sub.2).sub.m CF.sub.2 Z where m is an integer from 0 to 20 and Z is hydrogen or fluorine and Q" is a group having some olefinic unsaturation with a solution of an alkali metal fluoroalkoxide of the formula MOC.sub.n.sup.f where M is an alkali metal and C.sub.n.sup.f is a fluorocarbon moiety of the formula --(CH.sub.2).sub.y (CF.sub.2).sub.n CF.sub.3 where y is 1 or 2 and n is an integer from 1 to 20. The process of this invention causes the replacement of some of the Q and Q' groups with --OC.sub.n.sup.f. The decreased number of Q and Q' where Z is hydrogen results in a cured phosphonitrilic fluoroelastomer surface displaying improved resistance to polar solvents.
摘要翻译：一种用于处理下式的化合物的表面的方法，其中x是约3至约50,000的整数，Q和Q'相同或不同，并且是式-OCH 2（CF 2）的氟代烷氧基， mCF2Z其中m是0至20的整数，Z是氢或氟，Q“是具有式MOCnf的碱金属氟代烷烃的溶液具有一些烯属不饱和基团，其中M是碱金属，Cnf是碳氟化合物式（ - ） - （CH2）y（CF2）nCF3的部分，其中y为1或2，n为1至20的整数。本发明的方法导致用-OCnf替换一些Q和Q'基团。其中Z是氢的Q和Q'的减少的数量导致固化的膦腈基含氟弹性体表面显示改善的极性溶剂的抗性。

66. 发明授权

US4633026A Process for preparing ring-halogenated vinyl aromatic monomers 失效
标题翻译：制备环卤代乙烯基芳族单体的方法
公开(公告)号：US4633026A
公开(公告)日：1986-12-30
申请号：US656432
申请日：1984-10-01
申请人： Charles H. Kolich
发明人： Charles H. Kolich
IPC分类号： C07C17/25 , C07C17/34
CPC分类号： C07C17/25
摘要： A process for preparing ring-halogenated vinyl aromatic monomers comprising reacting ring-halogenated (alpha- or beta-bromoethyl)benzenes or ring-halogenated (alpha- or beta-bromoethyl)toluenes with a strong aqueous alkali base in the presence of a poly(ethylene glycol) catalyst and an amine selected from the group consisting of the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are independently selected from the group consisting of hydrogen and C.sub.1 to C.sub.10 alkyl groups. The organic phase is separated, washed and neutralized and the ring-halogenated vinyl aromatic monomer is recovered.
摘要翻译：一种制备环 - 卤代乙烯基芳族单体的方法，包括使环 - 卤代（α-或β-溴乙基）苯或环 - 卤代（α-或β-溴乙基）甲苯与强碱性碱水溶液在聚乙二醇）催化剂和选自以下结构的胺：其中R 1，R 2，R 3，R 4和R 5独立地选自氢和C 1至C 10烷基。分离有机相，洗涤并中和，回收环 - 卤代乙烯基芳族单体。

67. 发明授权

US4241034A Process for purifying cyclic phosphonitrilic chlorides 失效
标题翻译：环丙基氯化亚铜的纯化方法
公开(公告)号：US4241034A
公开(公告)日：1980-12-23
申请号：US44309
申请日：1979-05-31
申请人： Charles H. Kolich
发明人： Charles H. Kolich
IPC分类号： C01B21/098 , C01B25/10
CPC分类号： C01B21/0986
摘要： A process for improving the purity of phosphonitrilic chloride polymers, namely the trimer and tetramer by (1) contacting a solution of open-chain phosphonitrilic chloride oligomers admixed with cyclic oligomers of phosphonitrilic chloride in a normally liquid hydrocarbon with aqueous lower alkylnitrile, (2) separating the liquid hydrocarbon phase laden with trimer and some tetramer from the aqueous phase thereby produced, and (3) recovering highly purified cyclic trimer and tetramer from the hydrocarbon phase.
摘要翻译：（1）将普通液态烃与环丙基氯化锆的环状低聚物混合的开链膦酰氯化物低聚物溶液与低级烷基腈水溶液接触，提高三氯化磷聚合物的纯度，即三聚物和四聚体的方法，（2）从水相中分离载有三聚物和一些四聚体的液相烃相，由此产生，和（3）从烃相中回收高纯度的环状三聚体和四聚体。

68. 发明授权

US3996312A Halophenoxyphosphazene fire retardants 失效
标题翻译：卤代氧磷腈阻燃剂
公开(公告)号：US3996312A
公开(公告)日：1976-12-07
申请号：US525932
申请日：1974-11-21
申请人： Charles H. Kolich , Henry G. Braxton, Jr. , Urho A. Lehikoinen
发明人： Charles H. Kolich , Henry G. Braxton, Jr. , Urho A. Lehikoinen
IPC分类号： C07F9/6581 , C08G79/02 , C08L101/00 , C07C9/06 , C08K5/53
CPC分类号： C08G79/025 , C07F9/65812 , C08L101/00
摘要： The fire retardancy of polyesters is enhanced with halophenoxyphosphazenes that contain a P--O--P bond. Preferred materials are reaction products of a halogenated phenol and a phosphonitrilic halide. Brominated phenols are preferred although chlorophenols can be used. Of the brominated phenols, preferred starting materials are p-bromophenol, 2,4-dibromophenol and mixtures thereof. Phosphonitrilic chlorides are preferred starting materials. Pure phosphonitrilic halides can be used; however, phosphonitrilic halide mixtures are preferred because of their availability. Cyclic and linear phosphonitrilic halides are useful as well as mixtures thereof. Saturated and unsaturated polyesters can be made fire retardant by this invention, as can thermoplastic and thermosetting materials. Linear and crosslinked polyesters can be treated. Preferred polyesters are fiber-forming polyesters of a diol and dibasic acid, such as poly(ethylene terephthalate) and poly(1,4-cyclohexylenedimethyleneterephthalate).
摘要翻译：使用含有P-O-P键的卤代苯氧基磷腈可以提高聚酯的阻燃性。优选的材料是卤代苯酚和膦酰基卤化物的反应产物。尽管可以使用氯酚，但优选溴化酚。在溴化酚中，优选的原料是对溴苯酚，2,4-二溴苯酚及其混合物。次膦酸氯化物是优选的原料。可以使用纯的三氯化鏻; 然而，由于它们的可用性，优选膦酰氯化物混合物。环状和线性的膦酰氯化物是有用的，以及它们的混合物。饱和和不饱和聚酯可以通过本发明制成阻燃剂，如热塑性和热固性材料。可以处理线性和交联的聚酯。优选的聚酯是二醇和二元酸的成纤聚酯，例如聚（对苯二甲酸乙二醇酯）和聚（1,4-环己烯二甲基对苯二甲酸酯）。

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