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    • 62. 发明授权
    • Substituted triazolinone herbicides and plant growth regulators
    • 取代的三唑啉酮除草剂和植物生长调节剂
    • US5262389A
    • 1993-11-16
    • US868065
    • 1992-04-13
    • Kurt FindeisenMarkus LindigHans-Joachim SantelRobert R. SchmidtKlaus LurssenHarry Strang
    • Kurt FindeisenMarkus LindigHans-Joachim SantelRobert R. SchmidtKlaus LurssenHarry Strang
    • A01N47/38C07D249/12C07D249/14C07D401/12C07D403/12C07D405/12C07D409/12A01N43/653
    • C07D401/12A01N47/38C07D249/12C07D249/14C07D403/12C07D405/12C07D409/12
    • Novel herbicides and plant growth regulants of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkyl, halogenoalkinyl, alkoxyalkyl, alkoxy, cycloalkylalkyl or cycloalkyl, or represents in each case optionally substituted aralkyl or aryl,R.sup.2 represents a radical ##STR2## or represents a radical --S(O).sub.n --R.sup.7, R.sup.3 and R.sup.4 independently of one another each represent hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, cyanoalkyl, hydroxyalkyl, alkoxyalkyl, alkylaminoalkyl, alkoxycarbonylalkyl or alkoxycarbonylalkenyl, or represent in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl or cycloalkenylalkyl, or represent optionally substituted heterocyclylalkyl, or represent in each case optionally substituted aralkyl, aroyl or aryl, or represent alkoxy, alkenyloxy, alkinyloxy, aralkyloxy or aryloxy, or, together with the nitrogen atom to which they are bonded, represent an optionally substituted heterocyclic radical,X represents oxygen or sulphur andY represents oxygen or sulphur,whereinR.sup.5 and R.sup.6 independently of one another each represent alkyl, alkenyl, alkinyl, hatogenoalkyl, halogenoalkenyl, halogenoalkinyl, alkoxyalkyl, alkoxy, cycloalkyl or cycloalkylalkyl, or represent in each case optionally substituted aryl, aralkyl or heteroaryl, or, together with the nitrogen atom to which they are bonded, represent an optionally substituted heterocyclic radical,R.sup.7 represents alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkylalkyl, or represents in each case optionally substituted aralkyl or aryl and n represents the number 0, 1 or 2, but wherein R.sup.2 only represents a radical --S(O).sub.n --R.sup.7 if R.sup.3 and R.sup.4 do not simultaneously represent methyl.Intermediates therefor where NR.sup.3 R.sup.4 is replaced by Cl are also new.
    • 式(I)的新型除草剂和植物生长调节剂,其中R 1表示氢,烷基,烯基,炔基,卤代烷基,卤代烷基,卤代烷基,烷氧基烷基,烷氧基,环烷基烷基或环烷基,或在每种情况下表示任选取代的芳烷基或 芳基,R 2表示基团,或表示基团-S(O)n -R 7,R 3和R 4彼此独立地表示氢,烷基,烯基,炔基,卤代烷基,卤代烯基,卤代烷基,氰基烷基,羟基烷基,烷氧基烷基 或烷基氨基烷基,烷氧基羰基烷基或烷氧基羰基烯基,或在每种情况下表示任选取代的环烷基,环烷基烷基,环烯基或环烯基烷基,或代表任选取代的杂环基烷基,或在每种情况下表示任选取代的芳烷基,芳酰基或芳基,或代表烷氧基,烯氧基,烷氧基,芳烷氧基 或芳氧基,或者与它们所键合的氮原子一起表示任选的亚烷基 取代的杂环基,X表示氧或硫,Y表示氧或硫,其中R5和R6彼此独立地表示烷基,烯基,炔基,半阴离子烷基,卤代烯基,卤代烷基,烷氧基烷基,烷氧基,环烷基或环烷基烷基,或各自表示 任选取代的芳基,芳烷基或杂芳基,或与它们所键合的氮原子一起表示任选取代的杂环基,R 7表示烷基,烯基,炔基,环烷基或环烷基烷基,或在每种情况下表示任选取代的芳烷基或 芳基,n表示数字0,1或2,但如果R3和R4不同时表示甲基,则其中R2仅表示基团-S(O)n-R7。 NR3R4被Cl取代的中间体也是新的。
    • 64. 发明授权
    • Herbicidal 3-amino-5-aminocarbonyl-1,2,4-triazoles
    • 除草剂3-氨基-5-氨基羰基-1,2,4-三唑
    • US5234897A
    • 1993-08-10
    • US762044
    • 1991-09-18
    • Kurt FindeisenHans-Joachim SantelKlaus LurssenRobert R. Schmidt
    • Kurt FindeisenHans-Joachim SantelKlaus LurssenRobert R. Schmidt
    • A01N43/653C07D249/14
    • A01N43/653C07D249/14
    • Herbicidal 3-amino-5-aminocarbonyl-1,2,4-triazoles of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is an alkyl or other organic radical, andR.sup.3 and R.sup.4 each independently is hydrogen or an organic radical,with the exception of the compounds in whicha) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.CH.sub.3, R.sup.3 .dbd.H, R.sup.4 .dbd.cyclohexyl;b) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.C.sub.2 H.sub.5, R.sup.3 .dbd.H, R.sup.4 .dbd.CH.sub.2 -C(CH.sub.3).sub.3 ;c) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.C.sub.2 H.sub.5, R.sup.3 .dbd.H, R.sup.4 .dbd.1-phenyl-ethyl;d) R.sup.1 .dbd.C.sub.2 H.sub.5, R.sup.2 .dbd.CH.sub.3, R.sup.3 .dbd.H, R.sup.4 .dbd.C(CH.sub.3).sub.3 ;e) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.CH.sub.3, R.sup.3 .dbd.CH.sub.3, R.sup.4 .dbd.C(CH.sub.3).sub.3 ;f) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.CH.sub.3, R.sup.3 .dbd.H, R.sup.4 .dbd.--CH(CH.sub.3)--CH.dbd.N--OCH.sub.3 andg) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.CH.sub.3, R.sup.3 =H, ##STR2##
    • 式“IMAGE”的除草3-氨基-5-氨基羰基-1,2,4-三唑其中R 1和R 2各自独立地为烷基或其它有机基团,且R 3和R 4各自独立地为氢或有机基团, 除了其中a)R 1 = CH 3,R 2 = CH 3,R 3 = H,R 4 =环己基的化合物之外。 b)R1 = CH3,R2 = C2H5,R3 = H,R4 = CH2-C(CH3)3; c)R1 = CH3,R2 = C2H5,R3 = H,R4 = 1-苯基 - 乙基; d)R1 = C2H5,R2 = CH3,R3 = H,R4 = C(CH3)3; e)R1 = CH3,R2 = CH3,R3 = CH3,R4 = C(CH3)3; f)R1 = CH3,R2 = CH3,R3 = H,R4 = -CH(CH3)-CH = N-OCH3,g)R1 = CH3,R2 = CH3,R3 = H,
    • 66. 发明授权
    • Herbicidal aminoguanidinoazines
    • 除草氨基胍基嗪
    • US5211740A
    • 1993-05-18
    • US840358
    • 1992-02-24
    • Christa FestRolf KirstenJoachim KluthKlaus-Helmut MullerHans-Jochem RiebelHans-Joachim SantelRobert R. SchmidtHarry Strang
    • Christa FestRolf KirstenJoachim KluthKlaus-Helmut MullerHans-Jochem RiebelHans-Joachim SantelRobert R. SchmidtHarry Strang
    • C07D521/00
    • C07D521/00
    • Herbicidal aminoguanidinoazines of the formula ##STR1## in which R.sup.1 stands for an optionally substituted radical from the series comprising alkyl, aralkyl, aryl and hetaryl,R.sup.2 stands for hydrogen, halogen, hydroxyl, alkyl, halogenoalkyl, alkoxyalkyl, alkoxy, halogenoalkoxy, alkylthio, halogenoalkylthio, amino, alkylamino or dialkylamino,X stands for nitrogen or a --CH group,Y stands for nitrogen or a --CR.sup.3 group whereR.sup.3 stands for hydrogen, halogen, cyano, alkyl, formyl, alkyl-carbonyl or alkoxy-carbonyl, andZ stands for nitrogen or a --CR.sup.4 group whereR.sup.4 stands for hydrogen, halogen, hydroxyl, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, alkylthio, alkylamino or dialkylaminoand their salts,with the exception of the compounds N'-(4,6-dimethyl-pyrimidin-2-yl)-N"-amino-N'"-(2-diethylaminosulphonyl-phenylsulphonyl)-guanidine, N'-(4,6-dimethyl-pyrimidin-2-yl)-N"-amino-N'"-(2-methoxycarbonyl-phenylsulphonyl)-guanidine and N'-(4,6-dimethyl-pyrimidin-2-yl)-N"-amino-N'"-(2-methoxycarbonyl-thiophen-3-yl-sulphonyl)-guanidine and their salts.
    • 式(I)的除草氨基胍基嗪其中R1代表包含烷基,芳烷基,芳基和杂芳基的系列中任意取代的基团,R 2代表氢,卤素,羟基,烷基,卤代烷基,烷氧基烷基,烷氧基,卤代烷氧基 ,烷硫基,卤代烷硫基,氨基,烷基氨基或二烷基氨基,X表示氮或-CH基,Y表示氮或-CR 3基,其中R3表示氢,卤素,氰基,烷基,甲酰基, 羰基,Z代表氮或-CR 4基团,其中R4代表氢,卤素,羟基,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基氨基或二烷基氨基及其盐,除了化合物N' - (4 ,6-二甲基 - 嘧啶-2-基)-N“ - 氨基-N” - (2-二乙基氨基磺酰基 - 苯基磺酰基) - 胍,N' - (4,6-二甲基 - 嘧啶-2-基) -N' - 氨基-N“ - (2-甲氧基羰基 - 庚基磺酰基) - 胍和N' - (4,6-二甲基 - 嘧啶-2-基)-N” - 氨基-N“ - (2-甲基 - 氧羰基 - 噻吩-3-基 - 磺酰基) - 胍及其盐。