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61. 发明授权

US5707761A Nickel positive electrode and alkaline storage battery using the same 失效
标题翻译：镍正极和碱性蓄电池使用相同
公开(公告)号：US5707761A
公开(公告)日：1998-01-13
申请号：US732186
申请日：1996-10-17
申请人： Kiyoshi Hayashi , Katsuyuki Tomioka , Nobuyasu Morishita , Munehisa Ikoma
发明人： Kiyoshi Hayashi , Katsuyuki Tomioka , Nobuyasu Morishita , Munehisa Ikoma
IPC分类号： H01M4/32 , H01M4/52 , H01M4/62 , H01M10/28 , H01M10/30 , H01M10/34 , H01M6/04
CPC分类号： H01M10/288 , H01M4/32 , H01M4/52 , H01M4/62 , H01M10/30 , H01M10/345 , Y02E60/124
摘要： An improved non-sintered type nickel positive electrode comprising a nickel hydroxide powder as an active material and a cobalt hydroxide powder for improving the utilization of the active material, and an alkaline storage battery configured with the positive electrode are disclosed. In the non-sintered type nickel positive electrode, at least part of the surfaces of the particles of the cobalt hydroxide powder is covered with a stabilizing agent of at least one member selected from the group consisting of a higher carboxylic acid, an ester of carboxylic acid, an aldehyde, a phenol and a vitamin.
摘要翻译：公开了一种改进的非烧结型镍正极，其包含作为活性物质的氢氧化镍粉末和用于提高活性物质利用率的氢氧化钴粉末，以及配置有正极的碱性蓄电池。在非烧结型镍正极中，氢氧化钴粉末颗粒的至少一部分表面被选自以下的至少一种的稳定剂所覆盖：高级羧酸，羧酸酯酸，醛，苯酚和维生素。

62. 发明授权

US5700596A Nickel hydroxide active material powder and nickel positive electrode and alkali storage battery using them 失效
标题翻译：镍氢活性物质粉末和镍正极和碱性蓄电池使用它们
公开(公告)号：US5700596A
公开(公告)日：1997-12-23
申请号：US795845
申请日：1991-11-21
申请人： Munehisa Ikoma , Norikatsu Akutsu , Masashi Enokido , Fumihiko Yoshii , Hideo Kaiya , Shingo Tsuda
发明人： Munehisa Ikoma , Norikatsu Akutsu , Masashi Enokido , Fumihiko Yoshii , Hideo Kaiya , Shingo Tsuda
IPC分类号： H01M4/32 , H01M4/52 , H01M10/34 , H01M4/88 , H01M6/04
CPC分类号： H01M4/52 , H01M10/345 , H01M4/32 , Y02E60/124
摘要： The tap density of nickel hydroxide powders is improved, the expansion of a positive electrode is inhibited and the energy density of the positive electrode and the cycle life characteristics are improved by specifying the shape of the nickel hydroxide powders and besides, adding to the nickel hydroxide powders at least one of Cd, Ca, Zn, Mg, Fe, Co and Mn. The nickel hydroxide active material powders contain 1-7 wt % of at least one of Cd, Ca, Zn, Mg, Fe, Co and Mn and comprise a mixture of spherical or nearly spherical particles and non-spherical particles.
摘要翻译：氢氧化镍粉末的振实密度提高，通过规定氢氧化镍粉末的形状，正极的膨胀被抑制，正极的能量密度和循环寿命特性得到改善，此外，加入氢氧化镍粉碎Cd，Ca，Zn，Mg，Fe，Co和Mn中的至少一种。氢氧化镍活性物质粉末含有1-7重量％的Cd，Ca，Zn，Mg，Fe，Co和Mn中的至少一种，并且包含球形或近似球形的颗粒和非球形颗粒的混合物。

63. 发明授权

US5605585A Method for producing hydrogen storage alloy particles and sealed-type nickel-metal hydride storage battery using the same 失效
标题翻译：储氢合金粒子的制造方法以及使用其的密封型镍氢蓄电池
公开(公告)号：US5605585A
公开(公告)日：1997-02-25
申请号：US271826
申请日：1994-07-07
申请人： Osamu Yamamoto , Katsunori Komori , Kohei Suzuki , Seiji Yamaguchi , Tadao Kimura , Munehisa Ikoma , Yoshinori Toyoguchi
发明人： Osamu Yamamoto , Katsunori Komori , Kohei Suzuki , Seiji Yamaguchi , Tadao Kimura , Munehisa Ikoma , Yoshinori Toyoguchi
IPC分类号： B22F1/00 , B22F9/08 , H01M4/38 , H01M10/34 , H01M4/04
CPC分类号： B22F9/082 , B22F1/0088 , H01M4/383 , B22F2009/0824 , H01M10/345 , Y02E60/124 , Y10S420/90
摘要： A method for manufacturing hydrogen storage alloy particles comprises steps of obtaining a melt of the hydrogen storage alloy and pulverizing the hydrogen storage alloy by water atomizing process, whereby the melt is pulverized by contacting or colliding with high-speed jetting thereto to be dispersed in the form of solidified fine particles. By employing an aqueous solution of hypophosphorous acid or an alkali aqueous solution in place of water during the water atomizing process, or by etching the oxide films once formed on the surface of the hydrogen storage alloy particles with an aqueous solution of a strong acid, the thickness of the oxide film can be made thinner, and thus a high discharge capacity of a battery configured with a negative electrode comprising the alloy particles can be realized.
摘要翻译：一种制造储氢合金粒子的方法包括以下步骤：获得储氢合金的熔体并通过水雾化工艺粉碎储氢合金，由此通过与高速喷射接触或碰撞来熔化熔融物而被分散在凝固细颗粒的形式。通过在水雾化过程中使用次磷酸或碱性水溶液代替水的水溶液，或者通过用强酸水溶液蚀刻一次形成在储氢合金颗粒的表面上的氧化膜，可以使氧化膜的厚度更薄，从而可以实现由包含合金颗粒的负极构成的电池的高放电容量。

64. 发明授权

US5451475A Nickel positive electrode for alkaline storage battery and sealed nickel-hydrogen storage battery using nickel positive electrode 失效
标题翻译：镍正极用于碱性蓄电池和密封镍氢蓄电池使用镍正极
公开(公告)号：US5451475A
公开(公告)日：1995-09-19
申请号：US225278
申请日：1994-04-08
申请人： Kazuhiro Ohta , Hiromu Matsuda , Munehisa Ikoma , Nobuyasu Morishita , Yoshinori Toyoguchi
发明人： Kazuhiro Ohta , Hiromu Matsuda , Munehisa Ikoma , Nobuyasu Morishita , Yoshinori Toyoguchi
IPC分类号： H01M4/52 , H01M4/62 , H01M10/34 , H01M4/60 , H01M4/32 , H01M4/58
CPC分类号： H01M4/52 , H01M10/345 , H01M4/624 , H01M4/625 , Y02E60/124
摘要： A nickel positive electrode for an alkaline storage battery comprises an active material mixture mainly composed of nickel hydroxide and a conductive support. The active material mixture contains at least one member selected from the group consisting of cobalt, cobalt hydroxide and cobalt oxide, and carbon powder having a lattice constant "d" of a (002) plane such that 3.35 .ANG.
摘要翻译：用于碱性蓄电池的镍正电极包括主要由氢氧化镍和导电载体组成的活性材料混合物。活性物质混合物含有选自钴，氢氧化钴和氧化钴中的至少一种，和（002）面的晶格常数“d”的碳粉，使得3.35 ANGSTROM

65. 发明授权

US5034289A Alkaline storage battery and method of producing negative electrode thereof 失效
标题翻译：碱性蓄电池及其负极的制造方法
公开(公告)号：US5034289A
公开(公告)日：1991-07-23
申请号：US356246
申请日：1989-05-24
申请人： Kohji Yuasa , Munehisa Ikoma , Hiroshi Kawano , Osamu Takahashi , Isao Matsumoto
发明人： Kohji Yuasa , Munehisa Ikoma , Hiroshi Kawano , Osamu Takahashi , Isao Matsumoto
IPC分类号： H01M4/24 , H01M4/38 , H01M4/80
CPC分类号： H01M4/383 , H01M4/242 , H01M4/808
摘要： Disclosed is an improvement in a negative electrode of an alkaline storage battery, in which the negative electrode is constituted by a hydrogen absorbing alloy capable of absorbing/desorbing hydrogen electrochemically, and a hydrophobic material and a hydrophilic material are provided in a portion of the surface layer of the negative electrode and in the side of the negative electrode respectively so as to properly secure both the wetting property and hydrophobic property of the negative electrode against the alkaline electrolytic solution. Accordingly, a hydrogen can be absorbed electrochemically in the portion of the negative electrode which is wetted by the electrolytic solution and a hydrogen gas generated in charging the battery can be absorbed by a vapor phase reaction in the hydrophobic portion of the negative electrode which is exposed to the vapor phase so that the internal gas pressure can be reduced to thereby make it possible to perform rapid charging.

66. 发明授权

US07833656B2 Electrochemical device and method for producing the same 失效
标题翻译：电化学装置及其制造方法
公开(公告)号：US07833656B2
公开(公告)日：2010-11-16
申请号：US10540867
申请日：2003-12-09
申请人： Ken Nishimura , Naoto Arai , Toru Oshima , Fumio Daio , Munehisa Ikoma , Norio Saito , Hideo Kaiya
发明人： Ken Nishimura , Naoto Arai , Toru Oshima , Fumio Daio , Munehisa Ikoma , Norio Saito , Hideo Kaiya
IPC分类号： H02M6/46 , H01M2/18 , H01M6/42
CPC分类号： H01M4/13 , H01M2/0207 , H01M2/022 , H01M2/34 , H01M4/66 , H01M4/667 , H01M4/70 , H01M10/0431 , H01M10/0436 , H01M10/0525 , H01M10/0587
摘要： An electrochemical device having an electrode plate assembly. The electrode plate assembly includes (a) at least one first electrode, (b) at least one second electrode, and (c) a separator interposed between the first electrode and the second electrode. The first electrode includes a first current collector sheet and at least one first electrode mixture layer carried thereon. The second electrode includes a second current collector sheet and at least one second electrode mixture layer carried thereon. At least one of the first current collector sheet and the second current collector sheet has a conductive area and an insulating area.
摘要翻译：具有电极板组件的电化学装置。电极板组件包括（a）至少一个第一电极，（b）至少一个第二电极，和（c）介于第一电极和第二电极之间的隔膜。第一电极包括第一集电体片和在其上承载的至少一个第一电极混合物层。第二电极包括第二集电体片和在其上承载的至少一个第二电极混合物层。第一集电体片和第二集电体片中的至少一个具有导电区域和绝缘区域。

67. 发明申请

US20070077492A1 Nickel oxyhydroxide, manufacturing method therefor, and alkaline primary battery 审中-公开
标题翻译：氢氧化镍，其制造方法和碱性一次电池
公开(公告)号：US20070077492A1
公开(公告)日：2007-04-05
申请号：US11540533
申请日：2006-10-02
申请人： Fumio Kato , Munehisa Ikoma
发明人： Fumio Kato , Munehisa Ikoma
IPC分类号： H01M4/52 , C01G53/04
CPC分类号： C01G53/04 , C01P2002/72 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/02 , H01M4/28 , H01M4/32 , H01M4/38 , H01M4/46 , H01M6/08 , H01M2004/021 , H01M2004/028
摘要： A nickel oxyhydroxide having a β-type structure is used to greatly improve low-temperature discharge performance and pulse discharge performance under high-load of an alkaline primary battery including a positive electrode containing nickel oxyhydroxide. In the nickel oxyhydroxide having β-type structure, a half-width of a peak of the (001) plane is 0.2 to 0.49° in a powder X-ray diffraction, an average particle size (D50) based on the secondary particle volume is 5 to 10 μm, and an average valence of nickel is 2.9 to 3.0.
摘要翻译：具有β型结构的羟基氧化镍被用于大大提高含有含有氢氧化正镍的正极的碱性一次电池的高负载下的低温放电性能和脉冲放电性能。在具有β型结构的氢氧化正镍中，在粉末X射线衍射中，（001）面的峰的半值宽度为0.2〜0.49°，平均粒径（D < ）基于二次粒子体积为5〜10μm，镍的平均化合价为2.9〜3.0。

68. 发明授权

US06669742B2 Method for producing a nickel metal-hydride storage battery 有权
标题翻译：镍氢蓄电池的制造方法
公开(公告)号：US06669742B2
公开(公告)日：2003-12-30
申请号：US10090901
申请日：2002-03-04
申请人： Masato Onishi , Katsuyuki Tomioka , Noriyuki Fujioka , Munehisa Ikoma
发明人： Masato Onishi , Katsuyuki Tomioka , Noriyuki Fujioka , Munehisa Ikoma
IPC分类号： H01M600
CPC分类号： H01M2/0277 , H01M2/12 , H01M2/30 , H01M10/0413 , H01M10/345 , H01M10/44 , H01M10/446 , H01M10/613 , H01M10/647 , H01M10/6556 , H01M10/6557 , Y02E60/124 , Y02P70/54 , Y10T29/49108 , Y10T29/5168
摘要： A method for producing a nickel metal-hydride storage battery includes: (i) assembling a battery by enclosing the positive electrodes, the negative electrodes, separators, and an electrolyte in a case; (ii) charging the battery with electric current in a range of 0.05 C (ampere) to 0.2 C (ampere) until a state of charge rises to a range of 10% to 30%; (iii) overcharging the battery that has been subjected to the charging, with electric current in a range of 0.2 C (ampere) to 1 C (ampere), and thereafter discharging the same until the state of charge lowers to 10% or below; and (iv) subjecting the battery after overcharging to a plurality of charging-discharging cycles, each charging-discharging cycle being composed of charging the battery that has been subjected to the overcharging, with electric current in a range of 0.2 C (ampere) to 5 C (ampere) until the state of charge rises to a range of 60% to 95%, and discharging the same until a battery voltage lowers to a range of 0.70 V to 1.05 V. In this method, in the charging-discharging cycles, the battery is cooled with a coolant at a temperature in a range of 30° C. to 60° C. This method makes it possible to produce a nickel metal-hydride storage battery at high productivity and low cost.
摘要翻译：一种镍氢蓄电池的制造方法，其特征在于，包括：（i）将壳体内的正极，负极，隔板和电解质包围而组装电池; （ii）以0.05C（安培）至0.2C（安培）的范围内的电流对电池充电，直到电荷上升到10％至30％的范围; （iii）以0.2C（安培）至1C（安培）的范围内的电流对已进行充电的电池进行过充电，之后将其放电至充电状态下降至10％以下; 和（iv）在过充电之后对多个充电 - 放电循环进行电池充电，每个充电 - 放电循环包括对经过过充电的电池进行充电，其电流范围为0.2℃（安培）至 5安培，直到充电状态上升到60％至95％的范围，并将其放电至电池电压降至0.70V至1.05V的范围内。在该方法中，在充电 - 放电循环，电池在30℃至60℃的温度范围内用冷却剂冷却。这种方法使得可以以高生产率和低成本生产镍氢蓄电池。

69. 发明授权

US06605387B1 Alkaline storage battery 有权
标题翻译：碱性蓄电池
公开(公告)号：US06605387B1
公开(公告)日：2003-08-12
申请号：US09704047
申请日：2000-11-02
申请人： Toshifumi Ueda , Nobuyasu Morishita , Noriyuki Fujioka , Munehisa Ikoma
发明人： Toshifumi Ueda , Nobuyasu Morishita , Noriyuki Fujioka , Munehisa Ikoma
IPC分类号： H01M438
CPC分类号： H01M4/383
摘要： An alkaline storage battery of the present invention has a negative electrode comprising an AB5 type hydrogen storage alloy containing at least nickel as B element. The hydrogen storage alloy contains 1.5 to 5.0% by weight of a magnetic substance comprising metallic nickel. The above-mentioned alkaline storage battery can effect high output from the initial stage of charging and discharging cycles.
摘要翻译：本发明的碱性蓄电池具有包含至少含有镍作为B元素的AB5型储氢合金的负极。储氢合金含有1.5-5.0重量％的包含金属镍的磁性物质。上述碱性蓄电池可以从充电和放电循环的初始阶段产生高的输出。

70. 发明授权

US5955216A Sealed alkaline storage battery 失效
标题翻译：密封碱性蓄电池
公开(公告)号：US5955216A
公开(公告)日：1999-09-21
申请号：US935725
申请日：1997-09-23
申请人： Yasuko Hoshina , Yohei Hattori , Noboru Ito , Nobuyasu Morishita , Munehisa Ikoma
发明人： Yasuko Hoshina , Yohei Hattori , Noboru Ito , Nobuyasu Morishita , Munehisa Ikoma
IPC分类号： H01M2/16 , H01M10/24 , H01M10/34
CPC分类号： H01M2/1686 , H01M2/162 , H01M10/345 , H01M2300/0014 , Y02E60/124
摘要： A sealed alkaline storage battery of the present invention employs a non-woven fabric having a double-layer structure of a dense and sparse layers as a separator to separate a positive electrode from a negative electrode, the sparse layer facing the negative electrode and being lower than the dense layer in fiber density.
摘要翻译：本发明的密封碱性蓄电池使用具有致密和稀疏层的双层结构的无纺织物作为隔板，以将正极与负极分离，稀疏层面向负极并且较低比纤维密度的致密层。

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