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    • 62. 发明授权
    • Oxygen sensor element
    • 氧传感元件
    • US5707503A
    • 1998-01-13
    • US549209
    • 1995-10-27
    • Yasumichi HottaHiromi SanoToshitaka SaitoMasatoshi SuzukiNaoto Miwa
    • Yasumichi HottaHiromi SanoToshitaka SaitoMasatoshi SuzukiNaoto Miwa
    • G01N27/409G01N27/407G01N27/26
    • G01N27/4075
    • According to the present invention, an oxygen sensor element includes a solid electrolyte having a side surface at one side thereof, the side surface being contactable with a gas to be measured, a skeletal electrode provided on the side surface and having a plurality of pore portions, each of the pore portions passing through the skeletal electrode up to the solid electrolyte, and a reactive electrode made of a porous film and provided in each of the pore portions, a thickness of the porous film being smaller than that of said skeletal electrode. An area percentage (SH/SZ) which is a ratio of a total area (SH) of the reactive electrode to a total area (SZ) of the skeletal electrode and the reactive electrode is in a range from 10 to 50%, an average area (SA) of the pore portions is 100 .mu.m.sup.2 or less, a film thickness of the skeletal electrode is in a range from 1.5 to 4 .mu.m, and the film thickness of the reactive electrode is in a range from 0.6 to 1.5 .mu.m. The oxygen sensor element is superior in the heat resistance characteristics and the response characteristics.
    • 根据本发明,氧传感器元件包括固体电解质,其一侧具有侧表面,侧表面可与待测气体接触,骨架电极设置在侧表面上并具有多个孔部分 每个孔部分通过骨架电极直到固体电解质,以及由多孔膜制成的反应性电极,并设置在每个孔部分中,多孔膜的厚度小于所述骨架电极的厚度。 作为骨架电极和反应性电极的反应电极的总面积(SH)与总面积(SZ)的比的面积百分比(SH / SZ)在10〜50%的范围内,平均 孔部的面积(SA)为100μm以下,骨架电极的膜厚在1.5〜4μm的范围内,反应电极的膜厚在0.6〜1.5μm的范围内 m。 氧传感器元件的耐热特性和响应特性优异。
    • 67. 发明授权
    • Oxygen concentration detector having heat-treated support layer
providing high responsivity endurance
    • 具有热处理支撑层的氧浓度检测器提供高响应能力
    • US5472591A
    • 1995-12-05
    • US305712
    • 1994-09-14
    • Toshitaka SaitoNamitsugu FujiiYasumichi HottaSatoru NomuraHiromi SanoMasatoshi Suzuki
    • Toshitaka SaitoNamitsugu FujiiYasumichi HottaSatoru NomuraHiromi SanoMasatoshi Suzuki
    • G01N27/409G01N27/407
    • G01N27/4075
    • An oxygen concentration detector provides high durability by increasing the thermal stability of coating layers applied to an electrode face thereof. A catalyst layer is formed on an outer surface of an electrode at the analysis gas side of a partition wall made of an ion oxygen conductive ceramic for generating electromotive force according to the difference between the concentration of oxygen in the analysis gas and the concentration of oxygen in the reference gas. The catalyst layer is composed of heat resistant ceramic particles and a particulate metallic catalyst made of platinum, rhodium or the like, supported by the surface of the heat resistant ceramic particles. The catalyst layer is formed so that the catalyst is supported by the heat resistant support particles. The support particles are heat treated to grow to a particle size so that particle growth can be restrained when the support particles are exposed to the exhaust gas from an internal combustion engine. The outside of the electrode of the partition wall is covered with support particles having such heat treated large cohered catalyst particles, and good responsivity of the sensor is thereby maintained.
    • 氧浓度检测器通过增加施加到其电极面上的涂层的热稳定性而提供高耐久性。 催化剂层形成在由离子氧传导陶瓷制成的分隔壁的分析气体侧的电极的外表面上,用于根据分析气体中的氧浓度与氧浓度之间的差产生电动势 在参考气体中。 催化剂层由耐热陶瓷颗粒和由耐热陶瓷颗粒的表面支撑的由铂,铑等制成的颗粒状金属催化剂组成。 催化剂层形成为使得催化剂被耐热支撑颗粒支撑。 支撑颗粒被热处理以生长成粒径,使得当载体颗粒暴露于来自内燃机的废气时,可以抑制颗粒生长。 分隔壁的电极的外侧覆盖有具有这种经热处理的大型粘结催化剂颗粒的支撑颗粒,从而保持传感器的良好的响应性。
    • 70. 发明授权
    • Compound type microscope
    • 复合型显微镜
    • US5360977A
    • 1994-11-01
    • US921129
    • 1992-07-29
    • Tetsuji OnukiMasatoshi SuzukiHiroyuki Matsushiro
    • Tetsuji OnukiMasatoshi SuzukiHiroyuki Matsushiro
    • G01B21/30G01B7/34G01N37/00G01Q20/02G01Q30/02G01Q60/24G02B21/00H01J37/28H01J37/26
    • G01Q60/16B82Y35/00G01Q30/025G01Q60/04G01Q60/38G02B21/00B82Y20/00Y10S977/869
    • A compound type microscope is provided which can observe the measurement sample of an atomic force microscope (AFM) by means of an optical microscope. This compound type microscope is comprised of an optical microscope having an objective and an observation optical system, a cantilever having a reflecting surface and detecting an atomic force, an irradiating optical system for applying a spotlight to the cantilver, a detector for detecting the displacement of reflected light caused by the displacement of the cantilever, and a sample stage for placing a sample thereon. The arrangement can be designed to accommodate the use of a scanning tunnel type microscope (STM) interchangeably with the AFM so that the sample can be measured by the STM instead of by the AFM. To this end, the probe of the STM can be detachably mountable coaxially with respect to the objective of the optical microscope, whereby the probe of the STM and the cantilever of the AFM can be selectively disposed below the objective.
    • 提供一种复合型显微镜,可以通过光学显微镜观察原子力显微镜(AFM)的测量样品。 该复合型显微镜由具有物镜和观察光学系统的光学显微镜,具有反射面的悬臂和检测原子力组成,用于将光束施加到悬臂的照射光学系统,用于检测位移的检测器 由悬臂的位移引起的反射光和用于在其上放置样品的样品台。 可以将该装置设计成可以与AFM互换地使用扫描隧道型显微镜(STM),以便可以通过STM而不是AFM来测量样品。 为此,STM的探针可以相对于光学显微镜的目的可同轴地可拆卸地安装,由此STM的探针和AFM的悬臂可以选择性地设置在物镜下方。