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61. 发明授权

US4223113A Polyester compositions which crystallize rapidly 失效
标题翻译：快速结晶的聚酯组合物
公开(公告)号：US4223113A
公开(公告)日：1980-09-16
申请号：US40387
申请日：1979-05-18
申请人： Peter Bier , Rudolf Binsack
发明人： Peter Bier , Rudolf Binsack
IPC分类号： C08K5/12 , C08L67/02 , C08G63/76
CPC分类号： C08K5/12 , C08L67/02 , C08L67/025
摘要： Polyalkylene terephthalates containing 0.5-30% by weight of oligomeric carboxylic acid polyesters have a higher crystallization speed and thus allow lower mold temperatures and shorter injection cycles. The polyalkylene terephthalates generally have intrinsic viscosities in excess of about 0.4 dl/g in 1:1 phenol tetrachloroethane at 25.degree. C. and are at least about 90 mol % terephthalic acid based. The oligomer additive is based on carboxylic acids, with sebacic and adipic being preferred, and aliphatic, cycloaliphatic or araliphatic dihydric alcohols. This additive has a minimum polymerization degree of 2 and a maximum number-average molecular weight of about 6000.Faster crystallization rates can be imparted to polyalkylene terephthalates by mixing them with the ester additive and melt homogenizing the mixture.
摘要翻译：含有0.5-30％（重量）低聚羧酸聚酯的聚对苯二甲酸亚烷基酯具有较高的结晶速度，从而允许较低的模具温度和较短的注射循环。聚对苯二甲酸亚烷基酯通常在25℃在1：1苯酚四氯乙烷中具有超过约0.4dl / g的特性粘度，并且是至少约90mol％对苯二甲酸。低聚物添加剂基于羧酸，优选癸二酸和己二酸，脂肪族，脂环族或芳脂族二元醇。该添加剂的最小聚合度为2，最大数均分子量为约6000.通过将它们与酯添加剂混合并将混合物熔融均化，可以将聚对苯二甲酸亚烷基酯提供更快的结晶速率。

62. 发明授权

US4163100A Rapidly crystallizing polyester compositions 失效
标题翻译：快速结晶聚酯组合物
公开(公告)号：US4163100A
公开(公告)日：1979-07-31
申请号：US889710
申请日：1978-03-24
申请人： Peter Bier , Rudolf Binsack
发明人： Peter Bier , Rudolf Binsack
IPC分类号： C08K5/42 , C08G63/70 , C08G63/76
CPC分类号： C08K5/42 , Y10S260/35
摘要： The present invention is concerned with polyalkylene terephthalate molding compositions which have improved crystallization behavior as a result of blending with selected sulphonic acid esters. The addition of an effective amount of these esters, generally between about 0.5 to 30 wt. %, improves the rate of crystallization of polyalkylene terephthalates such as polyethylene terephthalate thus permitting the use of shorter mold residence and lower mold temperatures in injection molding.The invention is also concerned with a process for improving the crystallization behavior of polyalkylene terephthalates by melt blending them with selected sulphonic acid esters.
摘要翻译：本发明涉及由于与选择的磺酸酯共混而具有改进的结晶行为的聚对苯二甲酸亚烷基酯模塑组合物。加入有效量的这些酯，通常为约0.5至30wt。％，提高聚对苯二甲酸亚烷基酯如聚对苯二甲酸乙二醇酯的结晶速率，从而允许在注射成型中使用较短的模具停留和较低的模具温度。

63. 发明授权

US4036748A Asymmetric, semipermeable membranes of polybenz-1,3-oxazine diones-(2,4) 失效
标题翻译：聚苯并-1,3-恶嗪二酮（2,4）的不对称半透膜
公开(公告)号：US4036748A
公开(公告)日：1977-07-19
申请号：US568605
申请日：1975-04-16
申请人： Birger Knickel , Rudolf Binsack , Hans Rudolph , Hans Jurgen Rosenkranz , Ludwig Bottenbruch
发明人： Birger Knickel , Rudolf Binsack , Hans Rudolph , Hans Jurgen Rosenkranz , Ludwig Bottenbruch
IPC分类号： C08J5/18 , B01D71/62 , B01D71/66 , C08G73/06 , C08J9/26 , B01D13/00
CPC分类号： B01D71/62 , C08G73/06
摘要： An asymmetric semipermeable membrane of a homo- or co-polybenz-1,3-oxazine dione-(2,4).
摘要翻译：同型或共 - 聚苯并-1,3-恶嗪二酮 - （2,4）的不对称半透膜。

64. 发明授权

US4025492A Thermoplastic copolyesters and a process for their production 失效
标题翻译：热塑性共聚酯及其生产方法
公开(公告)号：US4025492A
公开(公告)日：1977-05-24
申请号：US589912
申请日：1975-06-24
申请人： Rudolf Binsack , Ludwig Bottenbruch , Hans Hespe
发明人： Rudolf Binsack , Ludwig Bottenbruch , Hans Hespe
IPC分类号： C08G63/00 , C08G63/18 , C08G63/181 , C08G63/78 , C08G63/80 , C08G63/26
CPC分类号： C08G63/18 , C08G63/80
摘要： The heat distortion resistance and the molecular weight of polypropylene terephthalate and polybentylene terephthalate can be increased by cocondensing up to 10 mol-% of aliphatic diols containing 5 to 10 carbon atoms or of cycloaliphatic diols containing 8 to 12 carbon atoms.
摘要翻译：聚对苯二甲酸丙二醇酯和聚对苯二甲酸丁二醇酯的耐热变形性和分子量可以通过使高达10mol％的含有5至10个碳原子的脂族二醇或含有8至12个碳原子的脂环族二醇共聚来增加。

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