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61. 发明授权

US5426162A Production of olefin polymers 失效
标题翻译：生产烯烃聚合物
公开(公告)号：US5426162A
公开(公告)日：1995-06-20
申请号：US171856
申请日：1993-12-22
申请人： Takashi Fujita
发明人： Takashi Fujita
IPC分类号： C08F4/60 , C08F4/642 , C08F4/658 , C08F10/00 , C08F4/654
CPC分类号： C08F10/00
摘要： Ziegler polymerization of .alpha.-olefins is disclosed which is characterized by a solid catalyst component and an organoaluminum component used in the Ziegler catalyst, and also by the temperature used which is 150.degree. to 300.degree. C. The solid catalyst component, Component (A), comprises Sub-component (i) which is a solid catalyst component for Ziegler catalysts comprising Ti, Mg and a halogen; Subcomponent (ii) which is a silicon compound represented by a formula:R.sup.1.sub.m X.sub.n Si(OR.sup.2).sub.4-n-mwherein R.sup.1 indicates a hydrocarbyl group, R.sup.2 which may be the same as or different from R.sup.1 indicates a hydrocarbyl group, X is a halogen atom, and m and n are each a number satisfying equations 0.ltoreq.m.ltoreq.3, 0.ltoreq.n.ltoreq.3 and 0.ltoreq.m+n.ltoreq.3; and Sub-component (iii) which is an organometal compound of a metal of Groups I to IV of the Periodic Table. The organoaluminum component (B) is an organoaluminum compound which is a mixture of the following Sub-component (B.sub.1) and Sub-component (B.sub.2):Sub-component (B.sub.1) which is an organoaluminum compound represented by a formulaR.sup.3.sub.3-a H.sub.a Alwherein R.sup.3 indicates a hydrocarbyl group of 6 to 20 carbon atoms and a is a number satisfying an equation 0.ltoreq.a.ltoreq.1;Sub-component (B.sub.2) which is an organoaluminum compound represented by a formulaR.sup.4.sub.3-b AlY.sub.bwherein R.sup.4 indicates a hydrocarbyl group of 1 to 20 carbon atoms, Y indicates a halogen atom, and b is a number satisfying an equation 0
摘要翻译：公开了α-烯烃的齐格勒聚合，其特征在于齐格勒催化剂中使用的固体催化剂组分和有机铝组分，以及所用温度为150-300℃的固体催化剂组分，组分（A）包括作为包含Ti，Mg和卤素的齐格勒催化剂的固体催化剂组分的副组分（i）作为由式：R1mXnSi（OR2）4-nm表示的硅化合物的副成分（ii）其中R1表示烃基，R2可以相同或不同，表示烃基，X表示卤素原子，并且m和n分别是满足等式0≤n≤3,0≤n≤3且0≤m+n≤3的数字; 和作为元素周期表第I〜Ⅳ族金属的有机金属化合物的亚成分（ⅲ）。有机铝成分（B）是作为下述亚成分（B1）和副成分（B2）的混合物的有机铝化合物：作为由式R33-aHaAl表示的有机铝化合物的副成分（B1），其中， R3表示6〜20个碳原子的烃基，a是满足式0的数。作为由式R43-bAlYb表示的有机铝化合物的副成分（B2），其中，R4表示1〜20个碳原子的烃基，Y表示卤素原子，b表示满足式0

62. 发明授权

US5385993A Production of olefin polymers 失效
标题翻译：生产烯烃聚合物
公开(公告)号：US5385993A
公开(公告)日：1995-01-31
申请号：US136732
申请日：1993-10-14
申请人： Takashi Fujita
发明人： Takashi Fujita
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00 , C08F4/654 , C08F10/06
CPC分类号： C08F10/00
摘要： Ziegler polymerization of C.sub.3 or higher .alpha.-olefins is disclosed which is characterized by a solid catalyst component and an organoaluminum component used in the Ziegler catalyst, and also by the temperature used which is 150.degree. to 300.degree. C. The solid catalyst component, Component (A), comprises Sub-component (i) which is a solid catalyst component for Ziegler catalysts comprising Ti, Mg and a halogen; Sub-component (ii) which is a silicon compound represented by a formula: R.sup.1.sub.m X.sub.n Si(OR.sup.2).sub.4-n-m wherein R.sup.1 indicates a hydrocarbyl group, R.sup.2 which may be the same as or different from R.sup.1 indicates a hydrocarbyl group, X is a halogen atom, and m and n are each a number satisfying equations 0.ltoreq.m.ltoreq.3, 0.ltoreq.n.ltoreq.3 and 0.ltoreq.m+n.ltoreq.3; and Sub-component (iii) which is an organometal compound of a metal of Groups I to IV of the Periodic Table. The organoaluminum component (B) is an organoaluminum compound represented by a formulaR.sup.3.sub.3-p H.sub.p Alwherein R.sup.3 indicates a hydrocarbyl group of up to 5 carbon atoms and p is a number satisfying an equation 0.ltoreq.p.ltoreq.1;the mole ratio in Al/Ti of Component (B) to Component (A) being no higher than 1. The poly .alpha.-olefins produced have a broader molecular weight distribution than those produced at a lower polymerization temperature.
摘要翻译：公开了C3或更高级α-烯烃的齐格勒聚合，其特征在于齐格勒催化剂中使用的固体催化剂组分和有机铝组分，以及150至300℃的温度。固体催化剂组分（A）包含作为包含Ti，Mg和卤素的齐格勒催化剂的固体催化剂组分的副组分（i）作为由式：R1mXnSi（OR2）4-nm表示的硅化合物的副成分（ii），其中R1表示烃基，可以与R1相同或不同的R2表示烃基，X表示卤素原子，并且m和n分别是满足式0≤n≤3,0≤n≤3和0≤m+ n <3的数; 和作为元素周期表第I〜Ⅳ族金属的有机金属化合物的亚成分（ⅲ）。有机铝组分（B）是由式R33-pHpAl表示的有机铝化合物，其中R 3表示最多5个碳原子的烃基，p是满足等式0的数。组分（B）与组分（A）的Al / Ti摩尔比不大于1.所生产的聚α-烯烃的分子量分布比聚合温度较低时的分子量分布宽。

63. 发明授权

US5275993A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US5275993A
公开(公告)日：1994-01-04
申请号：US903963
申请日：1992-06-26
申请人： Takashi Fujita , Kazuyo Kitagawa
发明人： Takashi Fujita , Kazuyo Kitagawa
IPC分类号： C08F4/60 , C08F4/649 , C08F4/654 , C08F8/00 , C08F10/00 , C08F297/08
CPC分类号： C08F297/086 , C08F10/00 , C08F297/083 , Y10S526/904
摘要： An olefin polymerization catalyst which is obtained by contacting the following components (A) and (B): component (A): a product of contacting the following components (A.sub.1) and (A.sub.2):component (A.sub.1): polyolefin powder having specific values of pore diameter, pore volume, average pore diameter and average particle diameter,component (A.sub.2): a solid component for a Ziegler catalyst comprising titanium, magnesium and a halogen as the essential components;component (B): an organoaluminum compound.The supporting state of the catalyst is improved, and a contaminant-free polymer having a satisfactorily large particle diameter without the lowering of the activity or the stereoregularity of the catalyst is successfully obtained.
摘要翻译：通过使以下组分（A）和（B）接触获得的烯烃聚合催化剂：组分（A）：与下列组分（A1）和（A2）接触的产物：组分（A1）：具有特定值的聚烯烃粉末的孔径，孔体积，平均孔径和平均粒径，组分（A2）：包含钛，镁和卤素作为必要组分的齐格勒催化剂的固体组分; 组分（B）：有机铝化合物。催化剂的支持状态得到改善，并且成功地获得了不降低催化剂的活性或立构规整性的具有令人满意的大粒径的无污染物的聚合物。

64. 发明授权

US5143930A Thiazolidine derivatives with anti-diabetic activity, their preparation and their use 失效
标题翻译：具有抗糖尿病活性的噻唑烷衍生物，其制备及其用途
公开(公告)号：US5143930A
公开(公告)日：1992-09-01
申请号：US645108
申请日：1991-01-24
申请人： Takao Yoshioka , Takashi Fujita , Tsutomu Kanai , Kanichi Nakamura , Hiroyoshi Horikoshi , Kunihiro Sasahara , Takeshi Kinoshita
发明人： Takao Yoshioka , Takashi Fujita , Tsutomu Kanai , Kanichi Nakamura , Hiroyoshi Horikoshi , Kunihiro Sasahara , Takeshi Kinoshita
IPC分类号： C07D277/34
CPC分类号： C07D277/34 , Y02P20/55
摘要： Compounds of formula (I): ##STR1## in which: A is a group of formula (II) or (III): ##STR2## W is methylene, carbonyl or >C.dbd.N--OV, where V is hydrogen, sulfo, acyl or alkyl; U is methylene, or W is absent and U is a carbon-carbon double bond between A and --CR.sup.1 (OH)--; R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each hydrogen or alkyl; Y.sup.1 and Y.sup.2 are each hydrogen or a hydroxy-protecting group; and n is 1, 2 or 3 and salts thereof have anti-diabetic activity in mammals. Methods of preparing them are also provided.

65. 发明授权

US5023739A Tape cassette with a trapping layer having a corrosiveness which is equal to or higher than that of the magnetic recording layer on the tape 失效
标题翻译：具有与磁带上的磁记录层相同或更高的腐蚀性的捕获层的带盒
公开(公告)号：US5023739A
公开(公告)日：1991-06-11
申请号：US308765
申请日：1989-02-10
申请人： Koichi Shinohara , Takashi Suzuki , Masao Kawagishi , Nobuo Satoh , Takeshi Murakami , Takashi Fujita
发明人： Koichi Shinohara , Takashi Suzuki , Masao Kawagishi , Nobuo Satoh , Takeshi Murakami , Takashi Fujita
IPC分类号： G11B23/087 , G11B23/50 , G11B33/14
CPC分类号： G11B33/1446 , G11B23/08785 , G11B23/502
摘要： A tape cassette for a magnetic recording tape having metallic magnetic recording layer is provided with a gas trapping layer which is disposed on a portion of the cassette near the path of the magnetic recording tape stretched between a pair of reels. The trapping layer has a trapping tendency which is at least equivalent to that of the magnetic recording tape. Any corrosive gas components coming into the cassette is adsorbed by and made to react with the trapping layer so as to reduce the concentration of the corrosive gas reaching the metallic magnetic recording layer, thus preventing degradation of the magnetic recording layer and ensuring that recording is conducted with high recording density.
摘要翻译：具有金属磁记录层的磁记录带的带盒设置有气体捕获层，该气体捕获层设置在磁带记录带的在一对卷轴之间延伸的路径附近的一部分上。捕获层具有至少等同于磁记录带的捕获趋势。进入该盒的任何腐蚀性气体组分都被吸收层吸收并与捕获层反应，以减少到达金属磁记录层的腐蚀性气体的浓度，从而防止磁记录层的劣化并确保进行记录具有高记录密度。

66. 发明授权

US4977138A FR901228 substance and preparation thereof 失效
标题翻译： FR901228物质及其制备
公开(公告)号：US4977138A
公开(公告)日：1990-12-11
申请号：US375998
申请日：1989-07-06
申请人： Masakuni Okuhara , Toshio Goto , Yasuhiro Hori , Takashi Fujita , Hirotsugu Ueda , Nobuharu Shigematsu
发明人： Masakuni Okuhara , Toshio Goto , Yasuhiro Hori , Takashi Fujita , Hirotsugu Ueda , Nobuharu Shigematsu
IPC分类号： C12N1/20 , A61K38/00 , A61P31/04 , A61P35/00 , C07K5/10 , C07K5/103 , C07K14/195 , C07K14/41 , C12P21/02 , C12P21/04 , C12R1/01
CPC分类号： C07K5/101
摘要： The invention relates to a compound having antimicrobial and antitumor activity, the compound being designated FR901228 substance of the following formula: ##STR1##

67. 发明授权

US4972034A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US4972034A
公开(公告)日：1990-11-20
申请号：US387788
申请日：1989-08-01
申请人： Mitsuyuki Matsuura , Takashi Fujita
发明人： Mitsuyuki Matsuura , Takashi Fujita
IPC分类号： C08F4/64 , C08F4/656 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/904
摘要： A catalyst for the polymerization of olefins comprising a combination of a solid catalyst component (A) comprising a solid catalytic complex (i) containing titanium, magnesium and a halogen as the essential ingredients with an organoaluminium compound (B), wherein said solid catalyst component (A) is obtained by bringing the following ingredients (ii) and (iii) in contact with said solid catalytic complex (i):Ingredient (ii): a silicon compound represented by the general formula:R.sub.m.sup.1 X.sub.n Si(OR.sup.2).sub.4-m-nwherein R.sup.1 and R.sup.2 each stand for a hydrocarbyl residue, X denotes a halogen, and m and n are such that 0.ltoreq.m.ltoreq.3 and 0.ltoreq.n.ltoreq.3 are satisfied on condition that 0.ltoreq.m+n.ltoreq.3, andIngredient (iii): an organometallic compound selected from the group consisting of organozinc compounds and organomagnesium compounds. The catalyst makes it possible to eliminate what is called "outside electron donor" as a component for making up a final catalyst system.

68. 发明授权

US4933355A Thiazole derivatives, their preparation and their use in the treatment of diabetes complications 失效
标题翻译：噻唑衍生物，其制备及其在治疗糖尿病并发症中的应用
公开(公告)号：US4933355A
公开(公告)日：1990-06-12
申请号：US337366
申请日：1989-04-13
申请人： Takao Yoshioka , Takashi Fujita , Yuichi Aizawa , Tsutomu Kanai , Hiroyoshi Horikoshi
发明人： Takao Yoshioka , Takashi Fujita , Yuichi Aizawa , Tsutomu Kanai , Hiroyoshi Horikoshi
IPC分类号： C07D277/20 , C07D277/38 , C07D277/42
CPC分类号： C07D277/20
摘要： Compounds of formula (I): ##STR1## in which: R.sup.1 and R.sup.2 are independently hydrogen, alkyl, aliphatic hydrocarbon groups having one or two carbon-carbon double or treble bonds, cycloalkyl, aryl, substituted aryl, aralkyl, substituted aralkyl, alkanoyl, alkenyol, cycloalkylcarbonyol, arylcarbonyl, substituted arylcarbonyl, arylalkanoyl, substituted arylalkanoyl, arylalkenoyl, substituted arylalkenoyl, alkoxycarbonyl, aryloxycarbonyl, substituted aryloxycarbonyl, aralkyloxycarbonyl, substituted aralkyloxycarbonyl, optionally substituted carbamoyl or thiocarbamoyol, alkylsulfonyl, haloalkylsulfonyl, arylsulfonyl, substituted arylsulfonyl, alkylthio, arylthio and substituted arylthio, or R.sup.1 and R.sup.2, together with the nitrogen atom to which they are attached, form a nitrogen-containing heterocyclic group; one of R.sup.a and R.sup.b is hydrogen, alkyl or halogen, and the other of R.sup.a and R.sup.b is a group of formula (II): ##STR2## R.sup.4 is hydrogen, carboxy, protected carboxy or optionally substituted carbamoyl; R.sup.5 is hydrogen, or carboxyalkyl or protected carboxyalkyl in which the alkyl part is C.sub.1 -C.sub.6 ; n=0, 1 or 2; X is oxygen or sulfur; are useful in the treatment of the complications attendant upon diabetes and may be prepared by condensation of a thiazolidine or rhodanine compound with a compound corresponding to the remainder of the molecule of the compound of formula (I).

69. 发明授权

US4904630A Catalyst for olefin polymerization 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4904630A
公开(公告)日：1990-02-27
申请号：US217983
申请日：1988-07-12
申请人： Mitsuyuki Matsuura , Takashi Fujita
发明人： Mitsuyuki Matsuura , Takashi Fujita
IPC分类号： C08F4/64 , C08F4/656 , C08F10/00
CPC分类号： C08F10/00
摘要： A catalyst for olefin polymerization which comprises:Component (A) which is a solid catalyst component obtained by contacting the following components (i) to (iv):(i) a solid component comprising titanium, magnesium and halogen as essential elements,(ii) a silicon compound represented by the formula (I):R.sup.1.sub.m X.sub.n Si(OR.sup.2).sub.4-m-n (I) wherein R.sup.1 and R.sup.2 each represent a hydrocarbon residue, X represents a halogen, and each of m and n is an integer in the range of 0.ltoreq.m.ltoreq.3, 0.ltoreq.n.ltoreq.3, and 0.ltoreq.m+n.ltoreq.3,(iii) a titanium compound or a silicon compound represented by the formula (II) or (III):Ti(OR.sup.3).sub.4-l X.sub.l (II)R.sup.4.sub.4-l SiX.sub.l (III) wherein R.sup.3 represents a hydrocarbon residue, R.sup.4 represents hydrogen or a hydrocarbon residue, X represents a halogen, and l is an integer in the range of 0

70. 发明授权

US4703026A Catalyst component for polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US4703026A
公开(公告)日：1987-10-27
申请号：US872832
申请日：1986-06-11
申请人： Mitsuyuki Matsuura , Takashi Fujita
发明人： Mitsuyuki Matsuura , Takashi Fujita
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/901
摘要： Disclosed is a catalyst component for polymerization of an olefin, which consists essentially of a contact reaction product of (A) a solid composition obtained by mixing and contacting a precipitating agent with a contact reaction product between a magnesium dihalide and a titanium tetraalkoxide and/or a polymer thereof, the addition of the precipitating agent being carried out with stirring at a stirring intensity lower than a level (2nf) two times the floatation limit stirring intensity (nf) of the reaction system, with (B) a liquid titanium compound and/or a halogen compound of silicon.This catalyst component has a high activity and provides a polymer in which the particle size is relatively large and the particle size distribution is sharply controlled.
摘要翻译：公开了一种用于聚合烯烃的催化剂组分，其主要包括（A）通过将沉淀剂与二卤化镁和四烷氧基钛之间的接触反应产物混合并使其接触而获得的固体组合物的接触反应产物和/或其特征在于，在搅拌强度下，在比（B）液体钛化合物和反应体系的漂浮极限搅拌强度（nf）的2倍的水平（2nf）低的搅拌强度下， /或硅的卤素化合物。该催化剂组分具有高活性，并且提供了其中粒度相对较大并且粒度分布被急剧控制的聚合物。

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