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61. 发明申请

US20060111253A1 Lubricating compositions 审中-公开
标题翻译：润滑组合物
公开(公告)号：US20060111253A1
公开(公告)日：2006-05-25
申请号：US11262441
申请日：2005-10-28
申请人： Steve Harris , Jan Bock
发明人： Steve Harris , Jan Bock
IPC分类号： C10L1/14
CPC分类号： C10M141/08 , C10M141/10 , C10M163/00 , C10M2207/283 , C10M2207/289 , C10M2219/062 , C10M2219/064 , C10M2219/068 , C10M2223/045 , C10N2210/06 , C10N2220/025 , C10N2220/026 , C10N2230/06 , C10N2240/10 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2270/02
摘要： A lubricating oil composition, comprising as an ester additive component, one or more esters of glycerol and a carboxylic acid such as oleic acid having a defined proportion of monoester, diester and/or triester and an oil-soluble molybdenum compound, which may a trinuclear molybdenum compound.
摘要翻译：一种润滑油组合物，其包含作为酯添加剂组分的一种或多种甘油和羧酸的酯，例如具有确定比例的单酯，二酯和/或三酯的油酸和油溶性钼化合物，其可以是三核的钼化合物。

62. 发明授权

US06306186B1 Oil additives compositions and polymers for use therein 失效
标题翻译：用于其中的油添加剂组合物和聚合物
公开(公告)号：US06306186B1
公开(公告)日：2001-10-23
申请号：US08793525
申请日：1997-07-14
申请人： Brian William Davies , Ramah Jessica Brod , Jan Bock , Tuncel Ibrahim
发明人： Brian William Davies , Ramah Jessica Brod , Jan Bock , Tuncel Ibrahim
IPC分类号： C10L118
CPC分类号： C10L1/195 , C08F210/02 , C08F218/10 , C10L1/143 , C10L1/146 , C10L1/16 , C10L1/1641 , C10L1/165 , C10L1/1658 , C10L1/1666 , C10L1/1881 , C10L1/1883 , C10L1/189 , C10L1/1895 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1985 , C10L1/221 , C10L1/2222 , C10L1/2225 , C10L1/224 , C10L1/2368 , C10L1/238 , C10L1/2383 , C10M143/02 , C10M145/08 , C10M157/00 , C10M2205/022 , C10M2209/04 , C10M2209/06 , C10M2209/062
摘要： Compositions comprising an ethylene/vinyl acetate or propionate/vinyl branched carboxylate terpolymer improve the low temperature properties of fuel oils.
摘要翻译：包含乙烯/乙酸乙烯酯或丙酸酯/乙烯基支链羧酸酯三元共聚物的组合物改善燃料油的低温性能。

63. 发明授权

US5561056A Class of bifunctional additives for bioremediation of hydrocarbon contaminated soils and water 失效
标题翻译：用于碳氢化合物污染土壤和水的生物修复的双功能添加剂类
公开(公告)号：US5561056A
公开(公告)日：1996-10-01
申请号：US544342
申请日：1995-10-17
申请人： Cornelius H. Brons , Jan Bock , Ramesh Varadaraj , Stanley J. Brois
发明人： Cornelius H. Brons , Jan Bock , Ramesh Varadaraj , Stanley J. Brois
IPC分类号： B01F17/00 , B01F17/16 , B09C1/10 , C02F3/34 , C12P1/00 , B09B3/00 , C02F3/00
CPC分类号： C02F3/344 , B01F17/0085 , B09C1/10 , C12P1/00 , Y10S516/07 , Y10S516/915
摘要： The present invention provides for enhanced bioremediation of hydrocarbon contaminated soils and waters by treating soil or water with a surfactant or mixture of surfactants having the general formulae: ##STR1## where A=CH.sub.2, B=CH.sub.2 CH.sub.2 O, x=1-10 and y=2-20.
摘要翻译：本发明通过用具有以下通式的表面活性剂或表面活性剂的混合物处理土壤或水来提供碳氢化合物污染的土壤和水的增强的生物修复：其中A = CH2，B = CH2CH2O，x = 1-10 y = 2-20。

64. 发明授权

US5362827A Solution process for preparation hydrophobically functionalized cationic polymers (C-2691) 失效
标题翻译：制备疏水官能化阳离子聚合物的溶液方法（C-2691）
公开(公告)号：US5362827A
公开(公告)日：1994-11-08
申请号：US919805
申请日：1992-07-27
申请人： Jan Bock , Paul L. Valint , Thomas J. Pacansky , Henry W. H. Yang
发明人： Jan Bock , Paul L. Valint , Thomas J. Pacansky , Henry W. H. Yang
IPC分类号： B01D17/04 , C08F2/10 , C08F4/04 , C08F220/18 , C08F220/34 , C08F220/56 , C08F220/60 , C08F226/04 , C10G33/04
CPC分类号： B01D17/047 , C08F220/18 , C08F220/34 , C08F220/56 , C08F220/60 , C08F226/04 , C10G33/04
摘要： This invention provides a process for preparing novel hydrophobically associating polymers containing cationic functionality which are useful for clean-up of waste waters containing organic contaminants. These water soluble polymers contain both water soluble and water insoluble monomers. The water soluble monomers are acrylamide (AM) and a salt of an unsaturated amine base (C), and the water insoluble monomer is a higher alkyl(meth)acrylamide or alkyl(meth)acrylate (R). These polymers are referred to as CRAM. The process relies on the dissolution of the water insoluble monomer(s) into an aqueous solution of water soluble monomers by means of a water miscible mutual cosolvent. The type and concentration of miscible solvents are chosen to produce a clear, uniform, homogeneous aqueous solution of the hydrophobic monomers in the presence of both nonionic and cationic water soluble monomers and, in addition, the reaction medium remains a clear, uniform, homogeneous mixture with no phase separation as the reaction proceeds to completion. Redox or free radical initiators are used to copolymerize both the water soluble and water insoluble monomers, forming terpolymers of ethylenically unsaturated amine base salts, alkyl(meth)acrylamides of alkyl(meth)acrylates and acrylamide. These polymers provide exceptional clean-up of waste waters containing organic contaminants. Also they are very effective for resolving oil-in-water emulsion, as such as those found in oil production.
摘要翻译：本发明提供了一种制备新颖的含有阳离子官能团的疏水缔合聚合物的方法，该方法可用于清除含有机污染物的废水。这些水溶性聚合物含有水溶性和水不溶性单体。水溶性单体是丙烯酰胺（AM）和不饱和胺碱（C）的盐，水不溶性单体是高级烷基（甲基）丙烯酰胺或（甲基）丙烯酸烷基酯（R）。这些聚合物被称为CRAM。该方法依赖于通过水混溶相互共溶剂将水不溶性单体溶解到水溶性单体的水溶液中。选择混溶溶剂的类型和浓度以在非离子和阳离子水溶性单体存在下产生疏水单体的透明，均匀的均匀水溶液，此外，反应介质保持澄清均匀的均匀混合物随着反应进行到完成，没有相分离。氧化还原或自由基引发剂用于共聚水溶性和水不溶性单体，形成烯属不饱和胺碱盐的三元共聚物，（甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯（甲基）丙烯酰胺和丙烯酰胺。这些聚合物可以清除含有机污染物的废水。此外，它们非常有效地解决水包油乳液，如在石油生产中发现的那些。

65. 发明授权

US5100953A Solutions of hydrophobically associating terpolymers containing sulfonate functionality 失效
标题翻译：疏水缔合含有磺酸酯官能团的三元共聚物的溶液
公开(公告)号：US5100953A
公开(公告)日：1992-03-31
申请号：US545029
申请日：1990-06-28
申请人： Paul L. Valint , Jan Bock
发明人： Paul L. Valint , Jan Bock
IPC分类号： C08F220/56
CPC分类号： C08F220/56
摘要： This invention describes novel hydrophobically associating terpolymers containing sulfonate functionality which are useful as aqueous fluid rheology or flow modifiers. These high molecular weight water soluble polymers contain both water soluble and water insoluble monomers. The water soluble monomers are acrylamide (AM) and a salt of an ethylenically unsaturated sulfonic acid (S) and the water insoluble monomer is a higher alkyl acrylamide (R). These polymers are referred referred to as SRAM. The process for their preparation relies on solubilizing the water insoluble monomer into an aqueous micellar solution containing one or more surfactants and the water soluble monomers. The surfactants are specifically selected to enable homogeneous dispersion of the hydrophobic monomer(s) in the presence of anionic sulfonate containing monomers. Redox or free radical initiators are used to copolymerize both the water soluble and water insoluble monomers, forming terpolymers of ethylenically unsaturated sulfonic acids, alkylacrylamides and acrylamide. Aqueous solutions of these hydrophobically associating polymers exhibit enhanced viscosification, reduced salt sensitivity and other desirable rheological properties found useful in a variety of applications.
摘要翻译：本发明描述了新颖的含有磺酸酯官能团的疏水缔合三元共聚物，其可用作水溶液流变学或流动改性剂。这些高分子量水溶性聚合物含有水溶性和水不溶性单体。水溶性单体是丙烯酰胺（AM）和烯属不饱和磺酸（S）的盐，水不溶性单体是高级烷基丙烯酰胺（R）。这些聚合物被称为SRAM。其制备方法依赖于将水不溶性单体溶解到含有一种或多种表面活性剂和水溶性单体的水性胶束溶液中。特别选择表面活性剂以使得在阴离子磺酸盐单体的存在下均匀分散疏水性单体。氧化还原或自由基引发剂用于共聚水溶性和水不溶性单体，形成烯属不饱和磺酸的三元共聚物，烷基丙烯酰胺和丙烯酰胺。这些疏水缔合聚合物的水溶液表现出增强的粘度，降低的盐敏感性和其它在各种应用中有用的所需的流变性质。

66. 发明授权

US4981935A Hydrophobically associating polymers containing dimethyl acrylamide functionality 失效
公开(公告)号：US4981935A
公开(公告)日：1991-01-01
申请号：US484755
申请日：1990-02-26
申请人： Jan Bock , Paul L. Valint
发明人： Jan Bock , Paul L. Valint
IPC分类号： C08F220/56
CPC分类号： C08F220/56
摘要： This invention describes novel hydrophobically associating ter or tetra polymers which can contain sulfonate functionality which are useful as aqueous fluid rheology or flow modifiers. These high molecular weight water soluble polymers contain both water soluble and water insoluble monomers. The water soluble monomers are N, N dimethylacrylamide acrylamide (DMA) and optionally a salt of an ethylenically unsaturated sulfonic acid (s) or N-vinylpyrrolidinone or a metal acrylate and the water insoluble monomer is a higher alkyl acrylamide (R). The process for their preparation relies on solubilizing the water insoluble monomer into an aqueous micellar solution containing one or more surfactants and the water soluble monomers. The surfactants are specifically selected to enable homogeneous dispersion of the hydrophobic monomer(s) in the presence of anionic sulfonate containing monomers. Redox or free radical initiators are used to copolymerize both the water soluble and water insoluble monomers, forming terpolymers of dimethylacrylamide, alkylacrylamides and acrylamide, and optionally an anionic sulfonate or carboxylate monomer. Aqueous solutions of these hydrophobically associating polymers exhibit enhanced viscosification, reduced salt sensitivity and other desirable rheological properties found useful in a variety of applications.

67. 发明授权

US4835234A Hydrophobically functionalized cationic polymers 失效
标题翻译：疏水官能化阳离子聚合物
公开(公告)号：US4835234A
公开(公告)日：1989-05-30
申请号：US54382
申请日：1987-05-26
申请人： Paul L. Valint , Jan Bock , Donald F. Jacques
发明人： Paul L. Valint , Jan Bock , Donald F. Jacques
IPC分类号： B01D17/04 , B01D17/05 , C08F220/56 , C08F220/60 , C10G33/04
CPC分类号： C10G33/04 , B01D17/047 , C08F220/56 , C08F220/60
摘要： Novel hydrophobically associating terpolymer compositions containing cationic functionality are described. These water soluble or water dispersible polymers contain both water soluble and water insoluble monomers. The water soluble monomers are ethylenically unsaturated nonionic monomers, such as acrylamide (AM), and cationic monomers, such as a salt of an amine base (C), such as 3-methacrylamidopropyltrimethylammonium chloride (MAPTAC), 2-methacrylatoethyltrimethylammonium chloride (METAC) and diallyldimethylammonium chloride (DMDAAC). The hydrophobic or water insoluble monomer is a higher alkyl(meth)acrylamide or alkyl (meth)acrylate (R). These polymers are referred to as CRAM. While the novel compositions of this invention impart unusual properties to water based fluids, they are extremely efficient for clean-up of waste waters containing organic contaminants and for breaking oil-in-water emulsions.
摘要翻译：描述了含有阳离子官能团的新型疏水缔合三元共聚物组合物。这些水溶性或水分散性聚合物含有水溶性和水不溶性单体。水溶性单体是烯键式不饱和非离子单体，如丙烯酰胺（AM）和阳离子单体，如胺碱（C）的盐，如3-甲基丙烯酰胺基丙基三甲基氯化铵（MAPTAC），2-甲基丙烯酰基乙基三甲基氯化铵（METAC）和二烯丙基二甲基氯化铵（DMDAAC）。疏水或不溶于水的单体是高级烷基（甲基）丙烯酰胺或（甲基）丙烯酸烷基酯（R）。这些聚合物被称为CRAM。虽然本发明的新型组合物赋予水基流体不寻常的性质，但是它们对于清除含有机污染物的废水和用于破坏水包油乳液是非常有效的。

68. 发明授权

US4741835A Oil-in-water emulsion breaking with hydrophobically functionalized cationic polymers 失效
标题翻译：用疏水官能化阳离子聚合物打破水包油乳液
公开(公告)号：US4741835A
公开(公告)日：1988-05-03
申请号：US904418
申请日：1986-09-08
申请人： Donald F. Jacques , Jan Bock , Paul L. Valint
发明人： Donald F. Jacques , Jan Bock , Paul L. Valint
IPC分类号： C08F220/34 , B01D17/04 , C08F20/34 , C08F20/52 , C08F26/02 , C08F220/00 , C08F220/10 , C08F220/56 , C08F220/60 , C08F226/04 , C10G33/04 , C02F1/56
CPC分类号： C08F220/56 , B01D17/047 , C08F220/60 , C10G33/04
摘要： A method of breaking an oil-in-water emulsion which comprises the steps of treating said oil-in-water emulsion with at least a de-emulsifying amount of a water dispersible terpolymer formed by polymerization from an acrylamide monomer, a water soluble cationic monomer and a water insoluble, hydrophobic monomer, and separating the formed water phase from the formed phase of terpolymer and the oil.
摘要翻译：一种破坏水包油乳液的方法，其包括以下步骤：用至少一种脱乳剂量的由丙烯酰胺单体聚合形成的水分散性三元共聚物，水溶性阳离子单体和水不溶性疏水性单体，并将形成的水相与三元共聚物和油的形成相分离。

69. 发明授权

US4734205A Hydrophobically associating polymers for oily water clean-up 失效
标题翻译：疏水缔合聚合物，用于油性水清洗
公开(公告)号：US4734205A
公开(公告)日：1988-03-29
申请号：US905073
申请日：1986-09-08
申请人： Donald F. Jacques , Jan Bock
发明人： Donald F. Jacques , Jan Bock
IPC分类号： B01D17/04 , C02F1/54 , C02F1/56
CPC分类号： B01D17/047 , C02F1/54
摘要： The present invention teaches an improved process for clean-up of waste waters containing organic contaminants. In addition, the process is useful for breaking or resolving oil-in-water emulsions, such as those produced during oil recovery operations. Both the extent of clean-up based on residual oil left in the waste water and the efficiency of clean-up based on the treat rate of additive have been found to be significantly improved using the novel process of this invention. The novel process involves the use of a low level of a water dispersible terpolymer consisting of acrylamide, acrylic acid or its salts, and alkylacrylamide or alkylacrylate or alkylmethacrylate; or copolymers consisting of acrylamide and alkylacrylamide or alkylacrylate or alkylmethacrylate alone or in combination with a cationic species used to control the charge, usually negative charge reduction to near neutral, of the oil or organic contamination droplets in the emulsion being treated. The process of this invention is effective for the clean-up of waste waters containing organic contaminants and for the breaking of oil-in-water produced emulsions.
摘要翻译：本发明教导了一种用于清理含有有机污染物的废水的改进方法。此外，该方法可用于破坏或分解水包油乳液，例如在油回收操作期间产生的那些。已经发现使用本发明的新方法，基于废水中残留的油的净化程度和基于添加剂的处理速率的净化效率都得到了显着改善。该新方法涉及使用低水平的由丙烯酰胺，丙烯酸或其盐和烷基丙烯酰胺或丙烯酸烷基酯或甲基丙烯酸烷基酯组成的水分散性三元共聚物; 或由丙烯酰胺和烷基丙烯酰胺或丙烯酸烷基酯或甲基丙烯酸烷基酯单独或与用于控制待处理的乳液中的油或有机污染液滴的电荷（通常为负电荷减少到接近中性）组合的共聚物。本发明的方法对于清除含有机污染物的废水和用于水包油的乳液的破坏是有效的。

70. 发明授权

US4694058A High molecular weight terpolymers of acrylamide, acrylic acid salts and alkylacrylamide 失效
公开(公告)号：US4694058A
公开(公告)日：1987-09-15
申请号：US866724
申请日：1986-05-27
申请人： Donald B. Siano , Jan Bock
发明人： Donald B. Siano , Jan Bock
IPC分类号： C08F8/12 , C08F220/70
CPC分类号： C08F8/12
摘要： Novel water soluble copolymers of acrylamide, oil soluble higher alkylacrylamide and alkali metal acrylate have been found to provide efficient viscosification of water or brine. The process for synthesizing them relies on the complete solubilization of the water insoluble monomer into an aqueous solution of the water soluble monomer(s) by means of a suitable water soluble surfactant. A redox initiator system is used in conjunction with high monomer concentration and a low reaction temperature. The surfactant chosen and its concentration is one that produces a clear, uniform, homogeneous mixture in the presence of the monomers and gives a product which remains a clear uniform, homogeneous mixture with no phase separation as the reaction proceeds toward completion. The molecular weight of the resulting polymer after isolation from the surfactant is sufficiently high that it gives an intrinsic viscosity greater than about 12 dl/g.

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