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61. 发明授权

US4380619A Oxy- and thioaryl-phenylated aromatic heterocyclic polymers 失效
标题翻译：氧基和硫代芳基 - 苯基芳族杂环聚合物
公开(公告)号：US4380619A
公开(公告)日：1983-04-19
申请号：US366744
申请日：1982-04-08
申请人： Bruce A. Reinhardt , Fred E. Arnold
发明人： Bruce A. Reinhardt , Fred E. Arnold
IPC分类号： C07C45/74 , C07C49/753 , C07D209/48 , C07D277/64 , C07D277/68 , C08G16/00 , C08G61/12 , C08G73/12 , C08G2/26 , C08G12/00
CPC分类号： C07D209/48 , C07C323/00 , C07C45/74 , C07C49/753 , C07D277/64 , C07D277/68 , C08G16/00 , C08G61/12
摘要： Oxy- and thio-aryl-phenylated aromatic heterocyclic polymers having the general formula ##STR1## wherein Ar is a monovalent aromatic radical containing an oxy- or thio-linkage, Ar' is a divalent aromatic radical, R is a monovalent aromatic radical, Z is a divalent heterocyclic radical and n is an integer equal to the number of repeating units, are prepared from biscyclopentadienones with diethynyl heterocyclic compounds.
摘要翻译：具有通式的氧基和硫代芳基 - 苯基芳族杂环聚合物，其中Ar是含有氧基或硫键的单价芳族基团，Ar'是二价芳族基团，R是一价芳族基团，Z 是二价杂环基，n是等于重复单元数的整数，由具有二乙炔杂环化合物的双环戊二烯酮制备。

62. 发明授权

US4268654A Acetylene terminated matrix and adhesive oligomeric compositions 失效
标题翻译：乙炔封端基质和粘合剂低聚组合物
公开(公告)号：US4268654A
公开(公告)日：1981-05-19
申请号：US88504
申请日：1979-10-26
申请人： Fred E. Arnold , Bruce A. Reinhardt
发明人： Fred E. Arnold , Bruce A. Reinhardt
IPC分类号： C08G73/06
CPC分类号： C08G73/0694
摘要： A composition prepared by mixing a high Tg, acetylene-terminated phenylquinoxaline oligomer with an acetylene-substituted reactive diluent. The presence of the reactive diluent in the mixture effectively lowers the Tg of the oligomer so as to provide the composition with adequate flow for melt processing.
摘要翻译：通过将高Tg，乙炔封端的苯基喹喔啉低聚物与乙炔取代的反应性稀释剂混合制备的组合物。混合物中反应性稀释剂的存在有效地降低了低聚物的Tg，从而为组合物提供足够的流动用于熔融加工。

63. 发明授权

US4178428A Thermally stable enyne polysulfone polymers 失效
标题翻译：热稳定的烯烃聚砜聚合物
公开(公告)号：US4178428A
公开(公告)日：1979-12-11
申请号：US946291
申请日：1978-09-27
申请人： Fred E. Arnold , Bruce A. Reinhardt
发明人： Fred E. Arnold , Bruce A. Reinhardt
IPC分类号： C07C37/055 , C08G75/23 , C08L81/06
CPC分类号： C08G75/23 , C07C37/04 , C08L81/06 , C08G2650/60
摘要： High molecular weight enyne polysulfone thermoplastics are prepared by the reaction of alkali metal salts of 1,4-bis(3-hydroxyphenyl)-buta-1-ene-3-yne and various aromatic diols with aromatic dihalosulfones. Because of the presence of the enyne moiety in the polymer backbone, the polymer can be lightly crosslinked to provide solvent resistant thermoplastics. The polymers are useful in fabricating graphite thermoplastic composites for structural applications.
摘要翻译：通过1,4-二（3-羟基苯基）丁-1-烯-3-炔与各种芳族二醇与芳族二卤代砜的碱金属盐的反应制备高分子量烯丙聚砜热塑性塑料。由于在聚合物骨架中存在烯炔部分，聚合物可以轻度交联以提供耐溶剂的热塑性塑料。聚合物可用于制造用于结构应用的石墨热塑性复合材料。

64. 发明授权

US4022746A Bis-ethynyl heterocyclic compositions and method of snythesis 失效
标题翻译：双乙炔杂环组合物和方法
公开(公告)号：US4022746A
公开(公告)日：1977-05-10
申请号：US612078
申请日：1975-09-10
申请人： Robert F. Kovar , Fred E. Arnold
发明人： Robert F. Kovar , Fred E. Arnold
IPC分类号： C08G73/06 , C08L79/04 , C08K5/34
CPC分类号： C08G73/0694 , C08L79/04
摘要： Bis-ethynyl quinoxaline compositions are prepared by the condensation reaction of an aromatic diglyoxyl or dibenzil with an ethynyl-substituted aromatic ortho-diamine. The compositions are useful as polymerizable plasticizers for heterocyclic thermoplastic resins in the fabrication of composites. Polymerizable plasticizers are materials that remain fluid and act as a plasticizer during early stages of fabrication and then polymerize to a rigid resin.
摘要翻译：双乙炔基喹喔啉组合物通过芳族二氧化二或二苄苯与乙炔基取代的芳族邻二胺的缩合反应来制备。该组合物可用作复合材料制造中的杂环热塑性树脂的可聚合增塑剂。可聚合的增塑剂是在制造的早期阶段保持流体并用作增塑剂的材料，然后聚合成刚性树脂。

65. 发明授权

US4021409A Thermally stable benzimidazonaphthyridine compositions 失效
标题翻译：热稳定性苯并咪唑基萘啶组合物
公开(公告)号：US4021409A
公开(公告)日：1977-05-03
申请号：US588736
申请日：1975-06-19
申请人： Fred E. Arnold
发明人： Fred E. Arnold
IPC分类号： C08G73/20
CPC分类号： C08G73/20
摘要： Thermally stable benzimidazonaphthyridine polymers are synthesized by the polycondensation of an aromatic tetraamine and 4,4',5,5'-tetracarboxy-8,8'-biquinoline dianhydride. The polymers are useful in high temperature applications such as in the fabrication of plastics, composites, fibrous materials, protective coatings and films.
摘要翻译：通过芳族四胺和4,4'，5,5'-四羧基-8,8'-二喹啉二酐的缩聚合成热稳定的苯并咪唑基萘啶聚合物。该聚合物可用于高温应用，例如塑料，复合材料，纤维材料，保护涂层和薄膜的制造。

66. 发明授权

US3987003A Thermally stable dioxo and dithio-benzisoquinoline compositions and process of synthesizing same 失效
标题翻译：热稳定二氧化物和二硫代苯并喹啉组合物及其合成方法
公开(公告)号：US3987003A
公开(公告)日：1976-10-19
申请号：US584568
申请日：1975-06-06
申请人： Gerard A. Loughran , Fred E. Arnold
发明人： Gerard A. Loughran , Fred E. Arnold
IPC分类号： C08G73/10 , C08K5/13
CPC分类号： C08G73/1071 , C08G73/1053 , C08G73/1064
摘要： Thermally stable dioxo and dithio-benzisoquinoline polymers are synthesized by the polycondensation of oxyarylene and thioarylene bis-naphthalic acid dianhydrides and aromatic diamino compounds. The compositions are particularly useful in high temperature applications such as in the fabrication of plastics, composites, fibrous materials, protective coatings and films.

67. 发明授权

US3944614A 2,2'-Bis(phenylethynyl-5,5'-diaminobenzidine 失效
标题翻译： 2,2 {40-双（苯基乙炔基-5,5（40-二氨基联苯胺）
公开(公告)号：US3944614A
公开(公告)日：1976-03-16
申请号：US526192
申请日：1974-11-22
申请人： Frederick L. Hedberg , Fred E. Arnold
发明人： Frederick L. Hedberg , Fred E. Arnold
IPC分类号： C08G73/06 , C07C87/54 , C07D241/42
CPC分类号： C08G73/0694
摘要： Quinoxaline polymers are synthesized by solution polycondensation of 2,2'-bis(phenylethynyl)-5,5'-diaminobenzidine with aromatic bis-benzils. Upon heating the polymers so prepared at a temperature ranging from about 240.degree. to 300.degree.C, they undergo a thermal intramolecular cyclization reaction, thereby providing cured, thermally stable, highly fused quinoxaline composition. Because of their solubility in aprotic solvents and the mechanism whereby they are cured, the quinoxaline polymers are particularly suitable for use in high temperature applications such as in the fabrication of plastic composites and protective coatings.
摘要翻译：喹喔啉聚合物通过2,2'-双（苯基乙炔基）-5,5'-二氨基联苯胺与芳族双 - 苯偶姻的溶液缩聚合成。在加热在约240℃至300℃的温度范围内制备的聚合物时，它们进行热分子内环化反应，从而提供固化的，热稳定的高度稠合的喹喔啉组合物。由于它们在非质子溶剂中的溶解性及其固化机理，所以喹喔啉聚合物特别适用于高温应用，如塑料复合材料和保护涂层的制造。

68. 发明授权

US5175232A Rigid-rod benzobisazole copolymer containing cyclic phosphate ester 失效
标题翻译：含有环磷酸酯的刚性棒状苯并双酚共聚物
公开(公告)号：US5175232A
公开(公告)日：1992-12-29
申请号：US886999
申请日：1992-05-22
申请人： Fred E. Arnold , Jom P. Chen
发明人： Fred E. Arnold , Jom P. Chen
IPC分类号： C08G73/06 , C08G73/18 , C08G73/22 , C08G75/32
CPC分类号： C08G73/18 , C08G73/06 , C08G73/22 , C08G75/32
摘要： Rigid-rod aromatic heterocyclic copolymers having repeating units of the formula: ##STR1## wherein n has a value of about 0.10 to 0.99, m is 1.0-n, Ar is a para-ordered divalent aromatic moiety, as defined hereinafter, and wherein Ba is a benzobisazole moiety of the formula: ##STR2## wherein X is --O--, --S-- or --NH. Ar can be any para-ordered divalent moiety such as, for example, 1,4-phenylene, 4,4'-biphenylene, 4,4"-terphenylene, and the like, as well as substituted divalent moieties, such as, for example: ##STR3## wherein R is Q or an alkyl group having 1 to 4 carbon atoms, wherein Q is ##STR4## wherein Z is --O-- or --S--; ##STR5## wherein R is as defined above, or ##STR6## wherein R.sup.1 and R.sup.3 are --H or -phenyl, R.sup.2 is --H or ##STR7## wherein Q is as defined above, and R.sup.4 is R.sup.2 or ##STR8##
摘要翻译：具有下式重复单元的刚性 - 芳族芳族杂环共聚物：其中n具有约0.10至0.99的值，m为1.0-n，Ar为如下文所定义的有序二价芳族部分，并且其中Ba 是下式的苯并二唑部分：其中X是-O - ， - S-或-NH。 Ar可以是任何对位二价部分，例如1,4-亚苯基，4,4'-亚联苯基，4,4“ - 三亚苯基等，以及取代的二价部分，例如：其中R是Q或具有1至4个碳原子的烷基，其中Q是其中Z是-O-或-S-; 其中R如上所定义，或者其中R 1和R 3是-H或 - 苯基，R 2是-H或者其中Q如上所定义，并且R 4是R 2或R 3，

69. 发明授权

US5086120A Ionically blended molecular composites 失效
标题翻译：离子共混分子复合材料
公开(公告)号：US5086120A
公开(公告)日：1992-02-04
申请号：US652728
申请日：1991-02-08
申请人： Loon-Seng Tan , Fred E. Arnold
发明人： Loon-Seng Tan , Fred E. Arnold
IPC分类号： C08L79/04 , C08L81/00
CPC分类号： C08L79/04 , C08L81/00
摘要： A molecular composite system consisting essentially of a para-oriented benzobisazole polymer and a matrix polymer, poly(2-acrylamido-2-methylpropanesulfonic acid).
摘要翻译：基本上由对位的苯并二唑聚合物和基质聚合物聚（2-丙烯酰胺基-2-甲基丙烷磺酸）组成的分子复合体系。

70. 发明授权

US4977223A Thermoset rigid rod molecular composite system 失效
公开(公告)号：US4977223A
公开(公告)日：1990-12-11
申请号：US307112
申请日：1989-02-02
申请人： Fred E. Arnold , Thaddeus E. Helminiak , Donald R. Wiff , Loon S. Tan , Wen F. Hwang , Hoe Chuah
发明人： Fred E. Arnold , Thaddeus E. Helminiak , Donald R. Wiff , Loon S. Tan , Wen F. Hwang , Hoe Chuah
IPC分类号： C08G73/18 , C08G73/22 , C08J5/18 , C08L77/00 , C08L79/04 , D01F6/94
CPC分类号： C08J5/18 , C08G73/18 , C08G73/22 , C08L77/00 , C08L79/04 , D01F6/94 , C08J2377/00 , C08J2379/04
摘要： Provided is a molecular composite comprising a rigid-rod aromatic heterocyclic polymer, a flexible, coil-like thermoplastic polymer and a thermosetting polymer.Also provided is a method for fabricating a molecular composite film or fiber which comprises the steps of forming a biphasic, stir opalescent solution of a rigid-rod aromatic heterocyclic polymer, a thermoplastic polymer, a thermosetting polymer and a solvent which is common to the three polymers, adding solvent to the solution until the solution becomes isotropic and stir opalescence has ceased to determine the critical concentration of polymers in the solvent, adding additional solvent to the solution so that the polymer concentration is below the critical concentration, extruding the solution into a non-solvent for the polymers to form the desired film or fiber, drying the film or fiber and hot drawing the film or fiber at a temperature above the Tg of the thermoplastic, but below the polymerization temperature (Tpoly) of the thermosetting resin.

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