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61. 发明授权

US08187456B2 Hydrocracking of heavy feedstocks with improved hydrogen management 有权
标题翻译：加氢裂化重质原料，改善氢气管理
公开(公告)号：US08187456B2
公开(公告)日：2012-05-29
申请号：US11795552
申请日：2006-01-23
申请人： John W. Viets , Narasimhan Sundaram , Bal K. Kaul , David L. Stern
发明人： John W. Viets , Narasimhan Sundaram , Bal K. Kaul , David L. Stern
IPC分类号： C10G49/22
CPC分类号： C10G47/02 , B01D53/0423 , B01D53/0473 , B01D2253/10 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2256/16 , B01D2256/24 , B01D2257/702 , B01D2259/403 , C01B3/56 , C01B2203/042 , C01B2203/048 , C10G47/00 , C10G47/18 , C10G47/20 , C10G2300/1044 , C10G2300/4081
摘要： An improved process for hydrocracking heavy petroleum feedstocks wherein hydrogen-containing streams associated with a hydrocracker are subjected to rapid cycle pressure swing adsorption having a cycle time of less than 30 S.
摘要翻译：加氢裂化重质石油原料的改进方法，其中与加氢裂化器相关的含氢物流经历循环时间小于30S的快速循环变压吸附。

62. 发明申请

US20080237129A1 Regeneration of Sulfuric Acid 有权
标题翻译：硫酸再生
公开(公告)号：US20080237129A1
公开(公告)日：2008-10-02
申请号：US10579175
申请日：2004-12-01
申请人： Bhupender S. Minhas , Dennis G. Peiffer , Jeffrey S. Beck , David L. Stern , Tomas R. Melli
发明人： Bhupender S. Minhas , Dennis G. Peiffer , Jeffrey S. Beck , David L. Stern , Tomas R. Melli
IPC分类号： B01D61/16
CPC分类号： C10G21/28 , C10G17/10 , C10G2300/202 , C10G2300/4081
摘要： This invention relates to a process for recycling acid used to remove nitrogen contaminants from hydrocarbons using polymeric membranes to separate spent acid from the acid extraction of hydrocarbons into acid for recycle and acid for regeneration.
摘要翻译：本发明涉及一种使用聚合物膜从碳氢化合物中除去氮污染物的方法，以将废酸从碳酸的酸萃取中分离出来，再循环酸和用于再生。

63. 发明授权

US07390933B2 Reduction of the Bromine Index of linear alkylbenzenes 有权
标题翻译：线性烷基苯的溴指数的降低
公开(公告)号：US07390933B2
公开(公告)日：2008-06-24
申请号：US11729489
申请日：2007-03-29
申请人： Frederick Y. Lo , David L. Stern , Ronald J. Cimini , James L. Propp
发明人： Frederick Y. Lo , David L. Stern , Ronald J. Cimini , James L. Propp
IPC分类号： C07C5/05 , C07C5/03
CPC分类号： C07C2/66 , C07C7/13 , C07C2529/70 , C07C15/107
摘要： In a process for reducing the Bromine Index of a feed containing a linear alkylbenzene and bromine-reactive olefinic hydrocarbon contaminants, the feed is contacted under conditions effective to remove bromine-reactive olefinic hydrocarbon contaminants with a catalyst comprising zeolite Y catalyst having an alpha value of about 2 to about 30. The feed will normally also contain benzene and linear paraffin remaining from the alkylation process used to produce the linear alkylbenzene.
摘要翻译：在减少含有直链烷基苯和溴反应性烯烃污染物的进料的溴指数的方法中，使用含有沸石Y催化剂的催化剂有效除去溴反应性烯烃污染物的条件进料进料接触，该催化剂的α值为约2至约30.进料通常还含有从用于生产直链烷基苯的烷基化方法残留的苯和线性链烷烃。

64. 发明授权

US07288181B2 Producing low sulfur naphtha products through improved olefin isomerization 失效
标题翻译：通过改进烯烃异构化生产低硫石脑油产品
公开(公告)号：US07288181B2
公开(公告)日：2007-10-30
申请号：US10887681
申请日：2004-07-09
申请人： Stuart S. Shih , David L. Stern , Madhav Acharya
发明人： Stuart S. Shih , David L. Stern , Madhav Acharya
IPC分类号： C10G69/02
CPC分类号： C10G17/06 , C10G61/06 , C10G65/043 , C10G67/06 , C10G2400/02
摘要： The instant invention relates to a process to produce high octane, low sulfur naphtha products through the removal of basic nitrogen-containing compounds with subsequent skeletal isomerization of feed olefins and hydrotreating.
摘要翻译：本发明涉及通过除去碱性含氮化合物和随后的进料烯烃的骨架异构化和加氢处理来生产高辛烷值的低硫石脑油产品的方法。

65. 发明授权

US07238636B2 High temperature calcination of selectivated molecular sieve catalysts for activity and diffusional modification 失效
标题翻译：用于活性和扩散修饰的选择性分子筛催化剂的高温煅烧
公开(公告)号：US07238636B2
公开(公告)日：2007-07-03
申请号：US10625322
申请日：2003-07-23
申请人： Jeffrey S. Beck , William G. Borghard , Arthur W. Chester , Carrie L. Kennedy , David L. Stern
发明人： Jeffrey S. Beck , William G. Borghard , Arthur W. Chester , Carrie L. Kennedy , David L. Stern
IPC分类号： B01J20/04
CPC分类号： C10G11/05 , B01J29/04 , B01J29/06 , B01J29/40 , B01J29/44 , B01J37/08 , B01J2229/12 , B01J2229/32 , B01J2229/40 , C07C5/2708 , C07C6/123 , C07C2529/40 , C07C2529/44 , C10G2300/1044 , C10G2300/1096 , C10G2400/30 , Y02P20/52 , C07C15/08
摘要： A method is disclosed for modifying a catalytic molecular sieve for shape-selective hydrocarbon conversions comprises: a) selectivating said catalytic molecular sieve by contacting with a silicon-containing selectivating agent; and b) calcining the selectivated catalytic molecular sieve at high temperature calcination conditions comprising temperatures greater than 700° C., which conditions are sufficient to reduce acid activity as measured by alpha value and increase diffusion barrier of said catalytic molecular sieve as measured by the rate of 2,3-dimethylbutane uptake, as compared to the selectivated catalyst. Catalytic molecular sieves thus prepared, such as silica-bound ZSM-5, and their use in hydrocarbon conversion processes such as aromatics isomerization, e.g., xylene isomerization, ethylbenzene conversion and aromatics disproportionation, e.g., toluene disproportionation are also disclosed.
摘要翻译：公开了一种修饰用于形状选择性烃转化的催化分子筛的方法，包括：a）通过与含硅选择性剂接触来选择所述催化分子筛; 和b）在包括温度大于700℃的高温煅烧条件下煅烧所选择的催化分子筛，该条件足以降低由α值测量的酸活性，并增加所述催化分子筛的扩散阻挡，通过速率与选择的催化剂相比，2,3-二甲基丁烷的吸收。由此制备的催化分子筛，例如二氧化硅结合的ZSM-5，以及它们在烃转化方法中的用途，例如芳族化合物异构化，例如二甲苯异构化，乙苯转化和芳烃歧化，例如甲苯歧化。

66. 发明授权

US06576582B1 Binderless ex situ selectivated zeolite catalyst 失效
标题翻译：无粘性离子选择性沸石催化剂
公开(公告)号：US06576582B1
公开(公告)日：2003-06-10
申请号：US08558309
申请日：1995-11-15
申请人： Jeffrey S. Beck , Jane C. Cheng , Sharon B. McCullen , David H. Olson , David L. Stern
发明人： Jeffrey S. Beck , Jane C. Cheng , Sharon B. McCullen , David H. Olson , David L. Stern
IPC分类号： B01J2906
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/00
摘要： There is provided a substantially binder-free catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The catalyst may be used in a hydrocarbon conversion process, such as toluene disproportionation.
摘要翻译：提供了基本上不含粘合剂的催化分子筛，其通过用硅化合物进行异地选择而被改性。异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。催化剂可用于烃转化过程中，例如甲苯歧化。

67. 发明授权

US06504075B2 Small crystal ZSM-5, its synthesis and use 有权
标题翻译：小晶体ZSM-5，其合成和使用
公开(公告)号：US06504075B2
公开(公告)日：2003-01-07
申请号：US09767183
申请日：2001-01-22
申请人： Jeffrey S. Beck , Carrie L. Kennedy , Wieslaw J. Roth , David L. Stern
发明人： Jeffrey S. Beck , Carrie L. Kennedy , Wieslaw J. Roth , David L. Stern
IPC分类号： C07C552
CPC分类号： C01B39/38 , B01J29/04 , B01J29/40 , C01B39/40 , C07C5/2702 , C07C6/123 , C07C2529/40 , C07C15/067
摘要： A synthetic porous crystalline material has the structure of ZSM-5 and a composition involving the molar relationship: X2O3:(n)YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is less than 25, and wherein the slope of the nitrogen sorption isotherm of the material at a partial pressure of nitrogen of 0.4 to 0.7 and a temperature 77° K is greater than 30. The material has a mesoporous surface area (MSA) greater than 45 m2/g and is useful as a catalyst in the liquid phase isomerization of xylene.
摘要翻译：合成多孔结晶材料具有ZSM-5的结构和涉及摩尔关系的组成：其中X是三价元素; Y是四价元素; 并且n小于25，并且其中在氮分压为0.4至0.7且温度为77°K的材料的氮吸附等温线的斜率大于30.该材料具有介孔表面积（MSA）大于45m 2 / g，可用作二甲苯液相异构化中的催化剂。

68. 发明授权

US06180550B2 Small crystal ZSM-5, its synthesis and use 有权
标题翻译：小晶体ZSM-5，其合成和使用
公开(公告)号：US06180550B2
公开(公告)日：2001-01-30
申请号：US09218191
申请日：1998-12-22
申请人： Jeffrey S. Beck , Carrie L. Kennedy , Wieslaw J. Roth , David L. Stern
发明人： Jeffrey S. Beck , Carrie L. Kennedy , Wieslaw J. Roth , David L. Stern
IPC分类号： B01J2900
CPC分类号： C01B39/38 , B01J29/04 , B01J29/40 , C01B39/40 , C07C5/2702 , C07C6/123 , C07C2529/40 , C07C15/067
摘要： A synthetic porous crystalline material has the structure of ZSM-5 and a composition involving the molar relationship: X2O3:(n)YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is less than 25, and wherein the slope of the nitrogen sorption isotherm of the material at a partial pressure of nitrogen of 0.4 to 0.7 and a temperature 77° K is greater than 30. The material has a mesoporous surface area (MSA) greater than 45 m2/g and is useful as a catalyst in the liquid phase isomerization of xylene.
摘要翻译：合成多孔结晶材料具有ZSM-5的结构和涉及摩尔关系的组成：其中X是三价元素; Y是四价元素; 并且n小于25，并且其中在氮分压为0.4至0.7且温度为77°K的材料的氮吸附等温线的斜率大于30.该材料具有介孔表面积（MSA）大于45m 2 / g，可用作二甲苯液相异构化中的催化剂。

69. 发明授权

US6049018A Synthetic porous crystalline MCM-68, its synthesis and use 有权
标题翻译：合成多孔结晶MCM-68，其合成与应用
公开(公告)号：US6049018A
公开(公告)日：2000-04-11
申请号：US234544
申请日：1999-01-21
申请人： David C. Calabro , Jane C. Cheng , Robert A. Crane, Jr. , Charles T. Kresge , Sandeep S. Dhingra , Michael A. Steckel , David L. Stern , Simon C. Weston
发明人： David C. Calabro , Jane C. Cheng , Robert A. Crane, Jr. , Charles T. Kresge , Sandeep S. Dhingra , Michael A. Steckel , David L. Stern , Simon C. Weston
IPC分类号： C07D487/04 , B01J29/04 , B01J29/70 , C01B39/08 , C01B39/46 , C01B39/48 , C07B61/00 , C07C2/54 , C07C2/66 , C07C4/18 , C07C5/22 , C07C5/27 , C07C6/12 , C07C15/073 , C07C15/085 , C07D209/56 , C07D487/00 , C01B39/50
CPC分类号： C07C6/126 , B01J29/04 , B01J29/70 , C01B39/085 , C01B39/48 , C07C2/66 , C07C4/18 , C07C5/2708 , C07C6/123 , C07C2529/70
摘要： This invention relates to a new synthetic porous crystalline material, designated MCM-68, a method and novel polycyclic organic cation for its preparation and its use in catalytic conversion of organic compounds. The new crystalline material exhibits a distinctive X-ray diffraction pattern and has a unique crystal structure which contains at least one channel system, in which each channel is defined by a 12-membered ring of tetrahedrally coordinated atoms, and at least two further, independent channel systems, in each of which each channel is defined by a 10-membered ring of tetrahedrally coordinated atoms, wherein the number of unique 10-membered ring channels is twice the number of 12-membered ring channels.
摘要翻译：本发明涉及一种新的合成多孔结晶材料，称为MCM-68，其制备方法和新型多环有机阳离子及其在有机化合物催化转化中的应用。新的结晶材料表现出独特的X射线衍射图案，并且具有独特的晶体结构，其包含至少一个通道系统，其中每个通道由四面体配位的原子的12元环定义，并且至少两个独立的通道系统，其中每个通道由四面体配位原子的10元环定义，其中唯一的10-元环通道的数目是12元环通道数目的两倍。

70. 发明授权

US5741469A Process scheme for SO.sub.x removal from flue gases 失效
标题翻译：从烟道气中去除SOx的工艺方案
公开(公告)号：US5741469A
公开(公告)日：1998-04-21
申请号：US727843
申请日：1996-10-04
申请人： Nazeer A. Bhore , David L. Johnson , Khushrav E. Nariman , David L. Stern
发明人： Nazeer A. Bhore , David L. Johnson , Khushrav E. Nariman , David L. Stern
IPC分类号： B01D53/50 , B01D53/73 , C01B17/04 , B01J8/00 , C01B7/00
CPC分类号： C01B17/0473 , B01D53/508 , B01D53/73 , C01B17/04
摘要： A dry, regenerable solid oxide process directed to convert SO.sub.x from the flue gas stream from a power plant, a coal or oil-fired plant or process heat furnace, or an FCC regenerator to elemental sulfur without using a Claus unit, a hydrogen plant, a regeneration gas separation system, or a hydrogenation section. This dry, regenerable solid oxide process is also effective on Claus plant tail-gas. This process uses solid oxides, such as, for example, magnesium aluminates or spinels to remove sulfur oxides from flue gas streams. The solid oxide is then regenerated by a reducing gas to release the sulfur compounds contained on the solid oxide to produce a gas stream comprising hydrogen sulfide, sulfur oxides and elemental sulfur. The elemental sulfur is then condensed and recovered as a product and the resulting gas stream may be recycled to be reprocessed over the solid oxide.
摘要翻译：一种干式可再生固体氧化物工艺，其特征是将SO x从来自发电厂，煤或燃油电厂或工艺加热炉或FCC再生器的烟道气转化为元素硫，而不使用克劳斯单元，氢厂，再生气体分离系统或氢化部。这种干式可再生固体氧化物工艺对克劳斯植物尾气也是有效的。该方法使用固体氧化物，例如铝酸镁或尖晶石从烟道气流中除去硫氧化物。然后通过还原气体再生固体氧化物以释放固体氧化物上所含的硫化合物，以产生包含硫化氢，硫氧化物和元素硫的气流。然后将元素硫冷凝并回收，作为产物，所得气流可以再循环以在固体氧化物上再处理。

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