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61. 发明授权

US06489403B1 Process for improved coupling of rubbery polymers 失效
标题翻译：改进橡胶状聚合物偶联的方法
公开(公告)号：US06489403B1
公开(公告)日：2002-12-03
申请号：US09461653
申请日：1999-12-14
申请人： Adel Farhan Halasa , Wen-Liang Hsu
发明人： Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： C08F842
CPC分类号： C08F297/04 , C08F297/044
摘要： Rubbery polymers made by anionic polymerization can be coupled with tin halides or silicon halides to improve the characteristics of the rubber for use in some applications, such as tire treads. In cases where the rubbery polymer was synthesized utilizing a polar modifier it is difficult to attain a high level of coupling. This invention is based upon the unexpected finding that coupling efficiency can be significantly improved by conducting the coupling reaction in the presence of a lithium salt of a saturated aliphatic alcohol, such as lithium t-amylate. This invention discloses a process for coupling a living rubbery polymer that comprises reacting the living rubbery polymer with coupling agent selected from the group consisting of tin halides and silicon halides in the presence of a lithium salt of a saturated aliphatic alcohol. The lithium salt of the saturated aliphatic alcohol can be added immediately prior to the coupling reaction or it can be present throughout the polymerization and coupling process. Lithium t-amylate reacts with water to form t-amyl alcohol during steam stripping. Since t-amyl alcohol forms an azeotrope with hexane, it co-distills with hexane and can contaminate recycle feed streams. This problem of recycle stream contamination can be solved by using metal salts of cyclic alcohols that do not co-distill with hexane or form compounds during steam stripping which co-distill with hexane. Thus, the use of metal salts of cyclic alcohols is preferred for this reason and because they are considered to be environmentally safe.
摘要翻译：通过阴离子聚合制备的橡胶聚合物可与锡卤化物或卤化硅偶联，以改善用于某些应用中的橡胶的特性，例如轮胎胎面。在使用极性改性剂合成橡胶状聚合物的情况下，难以获得高水平的偶联。本发明基于意想不到的发现，通过在饱和脂肪醇的锂盐如叔戊醇锂的存在下进行偶联反应可以显着改善偶联效率。本发明公开了一种使活性橡胶状聚合物偶合的方法，其包括在饱和脂肪醇的锂盐存在下使活性橡胶状聚合物与选自锡卤化物和卤化硅的偶联剂反应。饱和脂肪醇的锂盐可以在偶联反应之前立即加入，或者可以在整个聚合和偶联过程中存在。在蒸汽汽提期间，叔戊醇钠与水反应形成叔戊醇。由于叔戊醇与己烷形成共沸物，因此与己烷共蒸馏，可能污染再循环进料流。循环流污染的这个问题可以通过使用在与汽油共蒸馏的汽提过程中不与己烷共蒸馏或形成化合物的环醇的金属盐来解决。因此，由于这个原因，优选使用环状醇的金属盐，并且因为它们被认为是环境安全的。

62. 发明授权

US06326424B1 Tire tread compound 有权
标题翻译：轮胎胎面复合
公开(公告)号：US06326424B1
公开(公告)日：2001-12-04
申请号：US09416844
申请日：1999-10-12
申请人： Olivier Louis , Adel Farhan Halasa , Wen-Liang Hsu
发明人： Olivier Louis , Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： C08K537
CPC分类号： C08K3/36 , B60C1/0016 , C08L7/00 , C08L9/00 , C08L9/06 , Y02T10/862 , Y10T152/10495 , C08L2666/08
摘要： It has been unexpectedly determined that isoprene-butadiene rubber having a high glass transition temperature within the range of about −40° C. to about −25° C. (high Tg IBR) can be loaded with silica as a filler and utilized in manufacturing tire treads that have outstanding performance characteristics. For instance, such tire treads offer lower hysteresis at high temperatures (improved rolling resistance) and higher hysteresis at low temperatures (improved wet traction characteristics). By utilizing high Tg IBR in tire tread compounds, the maximum benefits of silica compounding can be realized without the need for solution or emulsion styrene-butadiene rubber (SBR) in the tread rubber formulations. The tire tread rubber formulations of this invention will normally contain about 20 phr (parts per 100 parts of rubber) to about 100 phr of the high Tg IBR. In other words, the tread rubber will normally contain at least 20 phr of the high Tg IBR and can contain up to 100 phr of the high Tg IBR. The tread compound will also contain 40 phr to 150 phr of a filler with the proviso that at least about 20 phr of silica is included in the filler. The tire tread compound will also contain a silica coupling agent. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) at least about 20 phr of an isoprene-butadiene rubber having a glass transition temperature which is within the range of about −40° C. to −25° C., (2) 40 phr to 150 phr of a filler, with the proviso that the filler contains at least about 20 phr of silica, and (3) a silica coupling agent.
摘要翻译：已经出乎意料地确定了玻璃化转变温度高于约-40℃至约-25℃（高Tg IBR）的异戊二烯 - 丁二烯橡胶可以加载二氧化硅作为填料并用于制造轮胎胎面具有突出的性能特点。例如，这种轮胎胎面在高温下提供较低的滞后（改善的滚动阻力）和较低的滞后（改进的湿牵引特性）。通过在轮胎胎面胶料中利用高Tg IBR，可以实现二氧化硅配混的最大好处，而无需在胎面胶配方中使用溶液或乳液丁苯橡胶（SBR）。本发明的轮胎胎面橡胶制剂通常含有约20phr（每100份橡胶的份数）至约100phr的高Tg IBR。换句话说，胎面胶通常含有至少20phr的高Tg IBR，并且可以含有高达100phr的高Tg IBR。胎面胶料还将含有40phr至150phr的填料，条件是在填料中包含至少约20phr的二氧化硅。轮胎胎面胶料也将含有二氧化硅偶联剂。本发明更具体地公开了一种轮胎胎面橡胶组合物，其包含（1）至少约20phr的玻璃化转变温度在约-40℃至-25℃范围内的异戊二烯 - 丁二烯橡胶，（2）40phr至150phr的填料，条件是填料含有至少约20phr的二氧化硅，和（3）二氧化硅偶联剂。

63. 发明授权

US06289959B1 Technique for reducing the cold flow of rubbers 失效
标题翻译：降低橡胶冷流的技术
公开(公告)号：US06289959B1
公开(公告)日：2001-09-18
申请号：US09640216
申请日：2000-08-16
申请人： Wen-Liang Hsu , Adel Farhan Halasa
发明人： Wen-Liang Hsu , Adel Farhan Halasa
IPC分类号： B60C500
CPC分类号： C08F236/10 , B60C1/0016 , C08F297/04 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L53/02 , Y10T152/10495 , C08F4/48 , C08L2666/02 , C08L2666/24
摘要： Cold flow is a problem that is commonly encountered in the handling and storage of low molecular weight linear rubbers, such as low vinyl polybutadiene rubber and isoprene-butadiene rubber. This invention is based upon the unexpected discovery that the cold flow of such rubbery polymers can be greatly reduced by incorporating a small block of polystyrene therein. The rubbery polymers of this invention which exhibit a low level of cold flow can be synthesized by simply terpolymerizing 1,3-butadiene, isoprene and from about 0.5 phm to about 3 phm of styrene under anionic polymerization conditions in the absence of a polar modifier. It is preferred to utilize batch polymerization techniques. However, continuous polymerization techniques can also be utilized. This invention more specifically disclosed a rubbery polymer which is comprised of polymer chains containing repeat units which are derived from 1,3-butadiene, isoprene and from about 0.5 weight percent to about 3 weight percent styrene, wherein the repeat units which are derived from styrene are in blocks at the ends of the polymer chains, wherein the rubbery polymer has a glass transition temperature which is within the range of about −105° C. to about −65° C. and wherein the rubbery polymer has a number average molecular weight which is within the range of about 50,000 to about 600,000.
摘要翻译：冷流是在低分子量线性橡胶（例如低乙烯基聚丁二烯橡胶和异戊二烯 - 丁二烯橡胶）的处理和储存中通常遇到的问题。本发明基于意想不到的发现，通过在其中加入一小块聚苯乙烯可以大大降低这种橡胶状聚合物的冷流。表现出低水平冷流的本发明的橡胶状聚合物可以在不存在极性改性剂的阴离子聚合条件下简单地将1,3-丁二烯，异戊二烯和约0.5phm至约3phm的苯乙烯进行三聚合而合成。优选使用间歇聚合技术。然而，也可以使用连续聚合技术。本发明更具体地公开了由聚合物链组成的橡胶状聚合物，该聚合物链含有衍生自1,3-丁二烯，异戊二烯和约0.5重量％至约3重量％苯乙烯的重复单元，其中衍生自苯乙烯的重复单元在聚合物链的末端处是嵌段，其中橡胶状聚合物的玻璃化转变温度在约-105℃至约-65℃的范围内，并且其中橡胶状聚合物具有数均分子量其在约50,000至约60万的范围内。

64. 发明授权

US06147164A Technique for reducing the cold flow of rubbers 失效
标题翻译：降低橡胶冷流的技术
公开(公告)号：US06147164A
公开(公告)日：2000-11-14
申请号：US874850
申请日：1997-06-13
申请人： Wen-Liang Hsu , Adel Farhan Halasa
发明人： Wen-Liang Hsu , Adel Farhan Halasa
IPC分类号： B60C1/00 , C08F4/48 , C08F236/10 , C08F297/04 , C08L21/00 , C08F293/00
CPC分类号： C08F236/10 , B60C1/0016 , C08F297/04 , C08L21/00 , C08L9/00 , C08L53/02 , C08L7/00 , C08L9/06 , Y10T152/10495
摘要： Cold flow is a problem that is commonly encountered in the handling and storage of low molecular weight linear rubbers, such as low vinyl polybutadiene rubber and isoprene-butadiene rubber. This invention is based upon the unexpected discovery that the cold flow of such rubbery polymers can be greatly reduced by incorporating a small block of polystyrene therein. The rubbery polymers of this invention which exhibit a low level of cold flow can be synthesized by simply terpolymerizing 1,3-butadiene, isoprene and from about 0.5 phm to about 3 phm of styrene under anionic polymerization conditions in the absence of a polar modifier. It is preferred to utilize batch polymerization techniques. However, continuous polymerization techniques can also be utilized. This invention more specifically disclosed a rubbery polymer which is comprised of polymer chains containing repeat units which are derived from 1,3-butadiene, isoprene and from about 0.5 weight percent to about 3 weight percent styrene, wherein the repeat units which are derived from styrene are in blocks at the ends of the polymer chains, wherein the rubbery polymer has a glass transition temperature which is within the range of about -105.degree. C. to about -65.degree. C. and wherein the rubbery polymer has a number average molecular weight which is within the range of about 50,000 to about 600,000.
摘要翻译：冷流是在低分子量线性橡胶（例如低乙烯基聚丁二烯橡胶和异戊二烯 - 丁二烯橡胶）的处理和储存中通常遇到的问题。本发明基于意想不到的发现，通过在其中加入一小块聚苯乙烯可以大大降低这种橡胶状聚合物的冷流。表现出低水平冷流的本发明的橡胶状聚合物可以在不存在极性改性剂的阴离子聚合条件下简单地将1,3-丁二烯，异戊二烯和约0.5phm至约3phm的苯乙烯进行三聚合而合成。优选使用间歇聚合技术。然而，也可以使用连续聚合技术。本发明更具体地公开了由聚合物链组成的橡胶状聚合物，该聚合物链含有衍生自1,3-丁二烯，异戊二烯和约0.5重量％至约3重量％苯乙烯的重复单元，其中衍生自苯乙烯的重复单元在聚合物链的末端处是嵌段，其中橡胶状聚合物的玻璃化转变温度在约-105℃至约-65℃的范围内，并且其中橡胶状聚合物具有数均分子量其在约50,000至约600,000的范围内。

65. 发明授权

US6017988A Tire tread compositions containing asymmetrically tin-coupled polybutadiene rubber and silica coupling agent 失效
标题翻译：含有不对称锡偶联聚丁二烯橡胶和二氧化硅偶联剂的轮胎胎面组合物
公开(公告)号：US6017988A
公开(公告)日：2000-01-25
申请号：US366236
申请日：1999-08-03
申请人： Edward John Blok , Paul Harry Sandstrom , Cheryl Ann Losey , Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , John Joseph Andre Verthe
发明人： Edward John Blok , Paul Harry Sandstrom , Cheryl Ann Losey , Adel Farhan Halasa , Wen-Liang Hsu , David John Zanzig , John Joseph Andre Verthe
IPC分类号： B60C1/00 , C08C19/44 , C08J3/26 , C08K5/548 , C08L7/00 , C08L9/00 , C08L15/00 , C08L21/00 , C08K3/04 , C08K3/36
CPC分类号： C08L15/00 , B60C1/0016 , C08C19/44 , C08K5/548 , C08L15/005 , C08L21/00 , C08L7/00 , C08L9/00
摘要： This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend. Asymmetrical tin coupling in general also leads to better processability and other beneficial properties. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) from about 20 phr to about 60 phr of tin-coupled polybutadiene rubber, (2) from about 20 phr to about 60 phr of a rubber selected from the group consisting of natural rubber and synthetic polyisoprene and (3) from about 5 phr to about 40 phr of high vinyl polybutadiene rubber.
摘要翻译：本发明涉及一种易于加工的轮胎胎面胶，其可用于改善轮胎的胎面磨损，滚动阻力和牵引特性。本发明的轮胎胎面胶料是锡偶合的聚丁二烯，高乙烯基聚丁二烯和天然橡胶的混合物。这种低玻璃化转变温度橡胶和高玻璃化转变温度橡胶的混合物令人惊奇地易于加工，这使得本发明的概念在商业上可行。因此，本发明的轮胎胎面胶料可用于制造具有极大改善的牵引特性和胎面磨损的轮胎，而不会牺牲滚动阻力。这些改进的性质可能部分是由于与炭黑和/或二氧化硅填料的更好的相互作用和相容性。共混物中的聚丁二烯可以是不对称的锡偶联，以进一步改善橡胶共混物的冷流特性。不对称锡偶联一般也会导致更好的加工性能和其他有益的性能。本发明更具体地公开了一种轮胎胎面橡胶组合物，其包含（1）约20phr至约60phr的锡偶联的聚丁二烯橡胶，（2）约20phr至约60phr的选自下组的橡胶：由天然橡胶和合成聚异戊二烯组成，（3）约5phr至约40phr的高乙烯基聚丁二烯橡胶。

66. 发明申请

US20100288407A1 DENDRIMERS OF RUBBERY POLYMERS 失效
标题翻译：橡胶聚合物胶粘剂
公开(公告)号：US20100288407A1
公开(公告)日：2010-11-18
申请号：US12845171
申请日：2010-07-28
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Chad Aaron Jasiunas
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Chad Aaron Jasiunas
IPC分类号： B60C11/00 , C08F8/18
CPC分类号： C08C19/44 , B60C1/0016 , C08G83/003 , C08L15/00 , C08L101/005 , Y10T152/10 , Y10T152/10495
摘要： This invention discloses a process for synthesizing a dendrimer of a rubbery polymer comprising: (a) reacting a lithium terminated rubbery polymer with a halogenated tin containing compound to produce a polymer which is terminated with halogenated tin moieties, wherein the halogenated tin containing compound is of the structural formula: wherein X represents a halogen atom, wherein Z1 groups can be the same or different and are selected from alkyl groups containing from 1 to 8 carbon atoms, wherein x represents an integer from 1 to 20, wherein the molar ratio of the lithium terminated rubbery polymer to halogen atoms in the halogenated tin containing compound is within the range of 2:n to (n−1):n, wherein n represents the number of halogen atoms that are bonded directly to tin atoms in the halogenated tin containing compound; (b) reacting the polymer which is terminated with halogenated tin moieties with a molar excess of a tertiary alcohol to produce a polymer which is terminated with hydroxy tin moieties; and (c) allowing the polymer which is terminated with the hydroxy tin moieties to couple under conditions sufficient to produce a dendrimer of the rubbery polymer.
摘要翻译：本发明公开了一种用于合成橡胶状聚合物树枝状聚合物的方法，包括：（a）使锂封端的橡胶状聚合物与含卤化锡的化合物反应以制备用卤化锡部分封端的聚合物，其中含卤化锡的化合物为结构式：其中X表示卤素原子，其中Z1基团可以相同或不同，并且选自含有1至8个碳原子的烷基，其中x表示1至20的整数，其中，含卤化锡化合物中的锂封端橡胶状聚合物与卤素原子在2：n至（n-1）：n的范围内，其中n表示与含锡卤化锡中的锡原子直接键合的卤素原子数复合; （b）使用卤化锡部分封端的聚合物与摩尔过量的叔醇反应，以产生用羟基锡部分封端的聚合物; 和（c）允许用羟基锡部分封端的聚合物在足以产生橡胶状聚合物的树枝状聚合物的条件下偶联。

67. 发明授权

US07825203B2 Catalyst system for synthesizing amine functionalized rubbery polymers 有权
标题翻译：用于合成胺官能化橡胶聚合物的催化剂体系
公开(公告)号：US07825203B2
公开(公告)日：2010-11-02
申请号：US11616986
申请日：2006-12-28
申请人： Adel Farhan Halasa , Wen-Liang Hsu
发明人： Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： C08F4/50 , C08F2/06
CPC分类号： C08F36/04 , C08F4/48 , C08F4/54
摘要： The present invention is directed to a catalyst system for synthesizing rubbery polymers, such as polybutadiene rubber, styrene-butadiene rubber, isoprene-butadiene rubber, or styrene-isoprene-butadiene rubber, that are amine functionalized and have a high trans or high vinyl microstructure. The catalyst system, in one embodiment, includes an organolithium amine compound, and one or more of (a) a group IIa metal salt of an amino glycol or a glycol ether, (b) an organoaluminum compound, or (c) an amine compound. The amine functionalized rubbery polymers can be utilized in tire tread rubbers where the rubbery polymers may provide desirable wear properties without substantially sacrificing other performance characteristic(s), e.g., traction properties.
摘要翻译：本发明涉及用于合成胺官能化并具有高反式或高乙烯基显微组织的橡胶状聚合物如聚丁二烯橡胶，苯乙烯 - 丁二烯橡胶，异戊二烯 - 丁二烯橡胶或苯乙烯 - 异戊二烯 - 丁二烯橡胶的催化剂体系。在一个实施方案中，催化剂体系包括有机锂化合物和（a）氨基二醇或二醇醚的IIa族金属盐，（b）有机铝化合物或（c）胺化合物。胺官能化橡胶状聚合物可用于轮胎胎面橡胶中，其中橡胶状聚合物可提供期望的耐磨性，而基本上不会牺牲其它性能特征，例如牵引性能。

68. 发明申请

US20100206443A1 Heterogeneous Rubbery Polymers Having Random, Tapered, and Block Portions Therein and Methods of Making Same 有权
标题翻译：具有随机，锥形和块状部分的异质橡胶聚合物及其制造方法
公开(公告)号：US20100206443A1
公开(公告)日：2010-08-19
申请号：US12371122
申请日：2009-02-13
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu , Warren James Busch , David Michael Smith, SR. , Jennifer Elizabeth Labbe , Scott Edwards Johnson
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu , Warren James Busch , David Michael Smith, SR. , Jennifer Elizabeth Labbe , Scott Edwards Johnson
IPC分类号： B60C11/00 , C08F112/08 , C08F2/00
CPC分类号： B60C1/0016 , C08F212/08 , C08F236/10 , Y10S152/905 , C08F2/001
摘要： A heterogeneous rubbery polymer is provided that includes a polymer chain derived from a vinyl aromatic monomer and a conjugated diolefin monomer, wherein from greater than 20 weight percent to about 40 weight percent of units in the rubbery polymer are derived from the vinyl aromatic monomer and from about 60 weight percent to about 80 weight percent of units in the rubbery polymer are derived from the conjugated diolefin monomer. The polymer chain is further characterized by having greater than zero and less than about 30 weight percent of the vinyl aromatic units in sequences containing 1 vinyl aromatic unit, from about 5 weight percent to about 20 weight percent of the vinyl aromatic units in sequences containing 5 to 8 vinyl aromatic units, and greater than zero and less than about 5 weight percent of the vinyl aromatic units in sequences containing 9 or more vinyl aromatic units.
摘要翻译：提供了一种异相橡胶状聚合物，其包括衍生自乙烯基芳族单体和共轭二烯烃单体的聚合物链，其中橡胶状聚合物中大于20重量％至约40重量％的单元衍生自乙烯基芳族单体和橡胶状聚合物中约60重量％至约80重量％的单元衍生自共轭二烯单体。聚合物链的特征还在于具有大于零且小于约30重量％的含有乙烯基芳族单元的乙烯基芳族单元，约5重量％至约20重量％的乙烯基芳族单元，其序列包含5 至8个乙烯基芳族单元，并且大于零且小于约5重量％的含有9个或更多个乙烯基芳族单元的乙烯基芳族单元。

69. 发明申请

US20100108230A1 SYNTHESIS OF SOLUBLE FUNCTIONALIZED LITHIUM INITIATORS 有权
标题翻译：可溶性功能锂离子发射体的合成
公开(公告)号：US20100108230A1
公开(公告)日：2010-05-06
申请号：US12686768
申请日：2010-01-13
申请人： Adel Farhan Halasa , Wen-Liang Hsu
发明人： Adel Farhan Halasa , Wen-Liang Hsu
IPC分类号： B60C1/00
CPC分类号： B60C1/0016 , C07F1/005 , C07F1/02 , C08C19/44 , C08F36/04 , C08F4/488
摘要： This invention discloses a process for making dilithium initiators in high purity. This process can be conducted in the absence of amines which is desirable since amines can act as modifiers for anionic polymerizations. The dilithium compounds made are highly desirable because they are soluble in aromatic solvents. The present invention also discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is a cured the rubber formulation which is comprised of (a) at least one rubbery polymer containing functional groups of the structural formula: wherein R, R′ and R″ can be the same or different, wherein R is selected from the group consisting of hydrogen atoms, alkyl groups, aryl groups, alkaryl groups, and amino aryl groups, and wherein R′ and R″ represent alkyl groups alkyl groups that contain from 1 to 8 carbon atoms, and (b) at least one member selected from the group consisting of carbon black and silica.
摘要翻译：本发明公开了一种制备高纯度二锂引发剂的方法。该方法可以在不存在胺的情况下进行，因为胺可以用作阴离子聚合的改性剂。所制备的二锂化合物是非常需要的，因为它们可溶于芳族溶剂。本发明还公开了一种轮胎，其包括具有外圆周胎面的大致环形胎体，两个间隔开的胎圈，从胎圈到胎圈延伸的至少一个帘布层和从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁，其中所述胎面适于与地面接触，并且其中所述胎面是固化的橡胶配方，其由（a）至少一种含有以下结构式的官能团的橡胶状聚合物组成：其中R，R'和R“可以是相同或不同，其中R选自氢原子，烷基，芳基，烷芳基和氨基芳基，其中R'和R“表示含有1至8个碳的烷基基团原子，和（b）选自碳黑和二氧化硅中的至少一种。

70. 发明授权

US07662883B2 Rubbery block polymers containing polylactone and rubber compounds including the same 失效
标题翻译：含有聚内酯和包含它们的橡胶化合物的橡胶嵌段聚合物
公开(公告)号：US07662883B2
公开(公告)日：2010-02-16
申请号：US11617342
申请日：2006-12-28
申请人： Adel Farhan Halasa , Abderrahim Khadir , Wen-Liang Hsu , John Robert Zuppo, III , Marc Weydert
发明人： Adel Farhan Halasa , Abderrahim Khadir , Wen-Liang Hsu , John Robert Zuppo, III , Marc Weydert
IPC分类号： C08K3/36 , C08K3/00 , C08L53/02 , C08L53/00
CPC分类号： C08F297/04 , C08F297/044 , C08K3/36 , C08K5/548 , C08L53/02 , Y10S152/905 , C08L2666/02 , C08L2666/14
摘要： The present invention is directed to rubbery block polymers containing a polylactone, such as polycaprolactone, methods of making the same, and to rubber compounds containing those block polymers. The rubbery block polymer is an anionically polymerized block polymer defined by A-B, wherein A includes at least one type of polymerized conjugated diene monomer, a polymerized vinyl aromatic monomer, or a mixture thereof and wherein B is a polylactone, such as polycaprolactone, which is hydroxy terminated. The rubbery block polymer may be compounded so to provide, for example, a tire tread with desirable properties for use in an automobile tire. Such rubber compound, for example, can include the rubbery block polymer, an organosilane coupling agent, such as a bis(trialkoxysilyl) alkane, bis(trialkoxysilylalkyl) polysulfide, or mixtures thereof, and silica filler in specified amounts.
摘要翻译：本发明涉及含有聚内酯如聚己酸内酯的橡胶嵌段聚合物，其制备方法以及含有这些嵌段聚合物的橡胶化合物。橡胶嵌段聚合物是由AB定义的阴离子聚合的嵌段聚合物，其中A包括至少一种聚合的共轭二烯单体，聚合的乙烯基芳族单体或其混合物，其中B是聚内酯，例如聚己内酯，羟基封端。可以将橡胶状嵌段聚合物复合以提供例如具有用于汽车轮胎的期望性能的轮胎胎面。例如，这种橡胶化合物可以包括橡胶嵌段聚合物，有机硅烷偶联剂，例如双（三烷氧基甲硅烷基）烷烃，双（三烷氧基甲硅烷基烷基）多硫化物或其混合物，以及指定量的二氧化硅填料。

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