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61. 发明公开

US20230238649A1 SEPARATORS WITH FIBROUS MAT, LEAD ACID BATTERIES USING THE SAME, AND METHODS AND SYSTEMS ASSOCIATED THEREWITH 审中-公开
公开(公告)号：US20230238649A1
公开(公告)日：2023-07-27
申请号：US18127686
申请日：2023-03-29
申请人： DARAMIC, LLC
发明人： Eric H. Miller , Ahila Krishnamoorthy , James P. Perry , J. Kevin Whear
IPC分类号： H01M50/44 , H01M10/12 , B01D69/10 , H01M50/414 , H01M50/42 , H01M50/454 , H01M50/451 , H01M50/417 , H01M50/437
CPC分类号： H01M50/44 , H01M10/12 , B01D69/10 , H01M50/414 , H01M50/42 , H01M50/454 , H01M50/451 , H01M50/417 , H01M50/437 , B01D2325/02 , B01D2325/028 , B01D2325/20 , B01D2325/26 , H01M50/491
摘要： In at least one embodiment, a separator is provided with a fibrous mat for retaining the active material on an electrode of a lead-acid battery. New or improved mats, separators, batteries, methods, and/or systems are also disclosed, shown, claimed, and/or provided. For example, in at least one possibly preferred embodiment, a composite separator is provided with a fibrous mat for retaining the active material on an electrode of a lead-acid battery. In at least one possibly particularly preferred embodiment, a PE membrane separator is provided with at least one fibrous mat for retaining the active material on an electrode of a lead-acid battery. In accordance with at least certain embodiments, aspects and/or objects, the present invention, application, or disclosure may provide solutions, new products, improved products, new methods, and/or improved methods, and/or may address issues, needs, and/or problems of PAM shedding, NAM shedding, electrode distortion, active material shedding, active material loss, and/or physical separation, electrode effectiveness, battery performance, battery life, and/or cycle life, and/or may provide new battery separators, new battery technology, and/or new battery methods and/or systems that address the challenges arising from current lead acid batteries or battery systems, especially new battery separators, new battery technology, and/or new battery methods and/or systems adapted to prevent or impede the shedding of active material from the electrodes, preferably or particularly in enhanced flooded lead acid batteries, PSoC batteries, ISS batteries, ESS batteries, and/or the like.

62. 发明授权

US11652260B2 Composite layers or separators for lead acid batteries 有权
公开(公告)号：US11652260B2
公开(公告)日：2023-05-16
申请号：US17498778
申请日：2021-10-12
申请人： Daramic, LLC
发明人： Ahila Krishnamoorthy , Kumar Manickam , Robert Saffel
IPC分类号： H01M50/44 , H01M4/14 , H01M50/429 , H01M50/403 , H01M50/449 , H01M50/446 , H01M50/437 , H01M50/454 , H01M50/489 , H01M10/12 , H01M4/02
CPC分类号： H01M50/44 , H01M4/14 , H01M50/403 , H01M50/4295 , H01M50/437 , H01M50/446 , H01M50/449 , H01M50/454 , H01M50/489 , H01M10/12 , H01M2004/027 , H01M2004/028
摘要： Disclosed herein are novel or improved fibrous layers, composites, composite separators, separators, composite mat separators, composite mat separators containing fibers and silica particles, battery separators, lead acid battery separators, and/or flooded lead acid battery separators, and/or batteries, cells, and/or methods of manufacture and/or use of such fibrous layers, composites, composite separators, separators, battery separators, lead acid battery separators, cells, and/or batteries. In addition, disclosed herein are methods, systems, and battery separators for enhancing battery life, reducing internal resistance, reducing metalloid poisoning, reducing acid stratification, and/or improving uniformity in at least enhanced flooded batteries.

63. 发明授权

US11502374B2 Separators for enhanced flooded batteries, batteries, and related methods 有权
公开(公告)号：US11502374B2
公开(公告)日：2022-11-15
申请号：US17093389
申请日：2020-11-09
申请人： DARAMIC, LLC
发明人： Mohammed Naiha , Jörg Deiters , Ahila Krishnamoorthy , Eric H. Miller , J. Kevin Whear , Robert W. Saffel , Naoto Miyake , Kanak Kuwelkar
IPC分类号： H01M10/06 , H01M50/446 , H01M4/68 , H01M10/08 , H01M10/10 , H01M10/12 , H01M50/417 , H01M50/497 , H01M50/409 , H01M50/489 , H01M50/491 , H01M50/406 , H01M50/403
摘要： A battery separator has performance enhancing additives or coatings, fillers with increased friability, increased ionic diffusion, decreased tortuosity, increased wettability, reduced oil content, reduced thickness, decreased electrical resistance, and/or increased porosity. The separator in a battery reduces the water loss, lowers acid stratification, lowers the voltage drop, and/or increases the CCA. The separators include or exhibit performance enhancing additives or coatings, increased porosity, increased void volume, amorphous silica, higher oil absorption silica, higher silanol group silica, reduced electrical resistance, a shish-kebab structure or morphology, a polyolefin microporous membrane containing particle-like filler in an amount of 40% or more by weight of the membrane and ultrahigh molecular weight polyethylene having shish-kebab formations and the average repetition periodicity of the kebab formation from 1 nm to 150 nm, decreased sheet thickness, decreased tortuosity, separators especially well-suited for enhanced flooded batteries.

64. 发明申请

US20220158303A1 FUNCTIONALIZED LEAD ACID BATTERY SEPARATORS, IMPROVED LEAD ACID BATTERIES, AND RELATED METHODS 有权
公开(公告)号：US20220158303A1
公开(公告)日：2022-05-19
申请号：US17588321
申请日：2022-01-30
申请人： Daramic, LLC
发明人： J. Kevin Whear , Ahila Krishnamoorthy , Susmitha Appikatla
IPC分类号： H01M50/449 , H01M50/44 , H01M50/403 , H01M50/431 , H01M50/446 , H01M10/12
摘要： In accordance with at least selected embodiments, the present application or invention is directed to novel or improved porous membranes or substrates, separator membranes, separators, composites, electrochemical devices, batteries, methods of making such membranes or substrates, separators, and/or batteries, and/or methods of using such membranes or substrates, separators and/or batteries. In accordance with at least certain embodiments, the present application is directed to novel or improved porous membranes having a coating layer, battery separator membranes having a coating layer, separators, energy storage devices, batteries, including lead acid batteries including such separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries. The disclosed separators and/or batteries have improved charge acceptance, improved surface conductivity, improved oxidation resistance, reduced acid stratification, improved resistance to metal contamination induced oxidation, reduced black residue, improved wettability, and/or improved stiffness.

65. 发明授权

US11335974B2 Separators, lead acid batteries, and methods and systems associated therewith 有权
公开(公告)号：US11335974B2
公开(公告)日：2022-05-17
申请号：US16495132
申请日：2018-03-22
申请人： DARAMIC, LLC
发明人： J. Kevin Whear , Mohammed Naiha
IPC分类号： H01M50/446 , H01M50/44 , H01M50/463 , H01M50/20 , H01M10/06
摘要： A separator is provided with a novel construction and/or a combination of improved properties. Batteries, methods, and systems associated therewith are also provided. In certain embodiments, novel or improved separators, battery separators, enhanced flooded battery separators, batteries, cells, and/or methods of manufacture and/or use of such separators, battery separators, enhanced flooded battery separators, cells, and/or batteries are provided. In addition, there is disclosed herein methods, systems, and battery separators having a reduced ER, improved puncture strength, improved separator CMD stiffness, improved oxidation resistance, reduced separator thickness, reduced basis weight, and any combination thereof. In accordance with at least certain embodiments, separators are provided in battery applications for flat-plate batteries, tubular batteries, vehicle SLI, and HEV ISS applications, deep cycle applications, golf car or golf cart, and e-rickshaw batteries, batteries operating in a partial state of charge (“PSOC”), inverter batteries; and storage batteries for renewable energy sources, and any combination thereof.

66. 发明授权

US11271270B2 Functionalized lead acid battery separators, improved lead acid batteries, and related methods 有权
公开(公告)号：US11271270B2
公开(公告)日：2022-03-08
申请号：US16543727
申请日：2019-08-19
申请人： Daramic, LLC
发明人： J. Kevin Whear , Ahíla Krishnamoorthy , Susmitha Appikatla
IPC分类号： H01M50/449 , H01M50/44 , H01M50/403 , H01M50/431 , H01M50/446 , H01M10/12
摘要： In accordance with at least selected embodiments, the present application or invention is directed to novel or improved porous membranes or substrates, separator membranes, separators, composites, electrochemical devices, batteries, methods of making such membranes or substrates, separators, and/or batteries, and/or methods of using such membranes or substrates, separators and/or batteries. In accordance with at least certain embodiments, the present application is directed to novel or improved porous membranes having a coating layer, battery separator membranes having a coating layer, separators, energy storage devices, batteries, including lead acid batteries including such separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries. The disclosed separators and/or batteries have improved charge acceptance, improved surface conductivity, improved oxidation resistance, reduced acid stratification, improved resistance to metal contamination induced oxidation, reduced black residue, improved wettability, and/or improved stiffness.

67. 发明授权

US11145934B2 Composite layers or separators for lead acid batteries 有权
公开(公告)号：US11145934B2
公开(公告)日：2021-10-12
申请号：US15922052
申请日：2018-03-15
申请人： Daramic, LLC
发明人： Ahila Krishnamoorthy , Kumar Manickam , Robert Saffel
IPC分类号： H01M50/44 , H01M4/14 , H01M50/429 , H01M50/403 , H01M50/431 , H01M50/449 , H01M50/446 , H01M10/12 , H01M4/02
摘要： Disclosed herein are novel or improved fibrous layers, composites, composite separators, separators, composite mat separators, composite mat separators containing fibers and silica particles, battery separators, lead acid battery separators, and/or flooded lead acid battery separators, and/or batteries, cells, and/or methods of manufacture and/or use of such fibrous layers, composites, composite separators, separators, battery separators, lead acid battery separators, cells, and/or batteries. In addition, disclosed herein are methods, systems, and battery separators for enhancing battery life, reducing internal resistance, reducing metalloid poisoning, reducing acid stratification, and/or improving uniformity in at least enhanced flooded batteries.

68. 发明申请

US20210296737A1 IMPROVED LEAD ACID BATTERY SEPARATORS, WATER LOSS REDUCING SEPARATORS, ANTIMONY POISONING MITIGATING SEPARATORS, BATTERIES, SYSTEMS, AND RELATED METHODS 有权
公开(公告)号：US20210296737A1
公开(公告)日：2021-09-23
申请号：US17262102
申请日：2019-07-22
申请人： Daramic, LLC
发明人： James P. Perry , Neal M. Golovin , Daniel R. Alexander , Eric Killmeier , J. Kevin Whear
IPC分类号： H01M50/491 , H01M50/429 , H01M50/44 , H01M50/446 , H01M50/437 , B60L50/64 , H01M50/403 , H01M50/417 , H01M50/42
摘要： Disclosed herein are exemplary embodiments of improved separators for batteries, particularly lead acid batteries, and more particularly enhanced flooded lead acid batteries, improved lead acid batteries incorporating the improved separators, systems incorporating the improved separators and/or batteries, and methods related thereto. The improved separators may contain a cross-linkable component and a surfactant, agent, or additive. Furthermore, the cross-linkable component may be at least partially cross-linked. In addition, the separator may further be composed of a polymer and a filler, and may be additionally paired with a fibrous mat.

69. 发明授权

US11128014B2 Separators with fibrous mat, lead acid batteries using the same, and methods and systems associated therewith 有权
公开(公告)号：US11128014B2
公开(公告)日：2021-09-21
申请号：US16484511
申请日：2018-02-09
申请人： DARAMIC, LLC
发明人： Eric H. Miller , Ahila Krishnamoorthy , James P. Perry , J. Kevin Whear
IPC分类号： H01M2/16 , H01M50/449 , H01M10/12 , H01M50/44 , H01M50/411 , H01M50/463 , B01D69/10
摘要： In at least one embodiment, a separator is provided with a fibrous mat for retaining the active material on an electrode of a lead-acid battery. New or improved mats, separators, batteries, methods, and/or systems are also disclosed, shown, claimed, and/or provided. For example, in at least one possibly preferred embodiment, a composite separator is provided with a fibrous mat for retaining the active material on an electrode of a lead-acid battery. In at least one possibly particularly preferred embodiment, a PE membrane separator is provided with at least one fibrous mat for retaining the active material on an electrode of a lead-acid battery. In accordance with at least certain embodiments, aspects and/or objects, the present invention, application, or disclosure may provide solutions, new products, improved products, new methods, and/or improved methods, and/or may address issues, needs, and/or problems of PAM shedding. NAM shedding, electrode distortion, active material shedding, active material loss, and/or physical separation, electrode effectiveness, battery performance, battery life, and/or cycle life, and/or may provide new battery separators, new battery technology, and/or new battery methods and/or systems that address the challenges arising from current lead acid batteries or battery systems, especially new battery separators, new battery technology, and/or new battery methods and/or systems adapted to prevent or impede the shedding of active material from the electrodes, preferably or particularly in enhanced flooded lead acid batteries, PSoC batteries, ISS batteries, ESS batteries, and/or the like.

70. 发明申请

US20210020886A1 SEPARATORS FOR ENHANCED FLOODED BATTERIES, BATTERIES, AND RELATED METHODS 有权
公开(公告)号：US20210020886A1
公开(公告)日：2021-01-21
申请号：US17063733
申请日：2020-10-06
申请人： DARAMIC, LLC
发明人： Mohammed Naiha , Jörg Deiters , Ahila Krishnamoorthy , Eric H. Miller , J. Kevin Whear , Robert W. Saffel , Naoto Miyake , Kanak Kuwelkar
IPC分类号： H01M2/16 , H01M10/06
摘要： A battery separator has performance enhancing additives or coatings, fillers with increased friability, increased ionic diffusion, decreased tortuosity, increased wettability, reduced oil content, reduced thickness, decreased electrical resistance, and/or increased porosity. The separator in a battery reduces the water loss, lowers acid stratification, lowers the voltage drop, and/or increases the CCA. The separators include or exhibit performance enhancing additives or coatings, increased porosity, increased void volume, amorphous silica, higher oil absorption silica, higher silanol group silica, reduced electrical resistance, a shish-kebab structure or morphology, a polyolefin microporous membrane containing particle-like filler in an amount of 40% or more by weight of the membrane and ultrahigh molecular weight polyethylene having shish-kebab formations and the average repetition periodicity of the kebab formation from 1 nm to 150 nm, decreased sheet thickness, decreased tortuosity, separators especially well-suited for enhanced flooded batteries.

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