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    • 55. 发明授权
    • New unsaturated polyester-based products
    • 新型不饱和聚酯系列产品
    • US4540741A
    • 1985-09-10
    • US613345
    • 1984-05-23
    • Giovanni Corrado
    • Giovanni Corrado
    • C08G63/00C08F283/01C08G63/52C08G63/676
    • C08G63/676
    • New unsaturated polyester resin alkyds are disclosed which have an acid number in the 30 to 60 range, viscous behavior at room temperature, a viscosity not exceeding 300,000 cps at 45.degree. C. and a viscosity not exceeding 500 cps at 25.degree. C. when diluted with styrene up to a content of 31% by weight referred to the total of alkyd plus styrene. The alkyds are obtained by reacting together compounds selected from classes including: (A) acids and unsaturated anhydrides in amounts ranging from 0.4 to 1.0 moles; (B) other dicarboxylic acids; (C) one or more polymeric glycols comprising molecules which contain more than 90% by weight of 1,2-propyleneoxide units at a rate of at least 50%, preferably 60%, moles out of the total of (C)+(D) glycols; and (D) other glycols at a rate of no more than 50% moles out of the total of C+D glycols, there being at all times present at least one component selected from class (A) and at least one component selected from class (C). The invention is also concerned with unsaturated polyester resin compositions incorporating said alkyd and at least one cross-linking monomer selected from vinyl and allyl monomers in amounts no smaller than 10% by weight of the total weight.
    • 公开了新的不饱和聚酯树脂醇酸树脂,其酸值在30至60的范围内,在室温下的粘性行为,在45℃下粘度不超过30万厘泊,当在25℃时粘度不超过500厘泊 苯乙烯含量高达31重量%,涉及醇酸加苯乙烯的总量。 醇酸树脂通过使选自以下的化合物一起反应获得:包括:(A)酸和不饱和酸酐,其量为0.4-1.0摩尔; (B)其他二羧酸; (C)包含分子的一种或多种聚合物二醇,其以(C)+(D)的总量为至少50%,优选60%摩尔的速率含有大于90重量%的1,2-环氧丙烷单元 )二醇; 和(D)其它二醇的总共C + D二醇中不超过50%摩尔的速率,总是存在至少一种选自(A)类和至少一种选自类别 (C)。 本发明还涉及不饱和聚酯树脂组合物,该组合物含有不少于总重量10重量%的所述醇酸树脂和至少一种选自乙烯基和烯丙基单体的交联单体。