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    • 54. 发明授权
    • High molecular polycarbonates containing s-triazine rings
    • 含有三嗪环的高分子聚碳酸酯
    • US3894991A
    • 1975-07-15
    • US39750273
    • 1973-09-14
    • BAYER AG
    • NEURAY DIETERVERNALEKEN HUGORUDOLPH HANS
    • C07D251/12C07D251/34C07D251/38C07D251/46C08G63/00C08G64/00C09K21/10C08G17/13
    • C08G64/00
    • Polycarbonates based on aromatic bis-hydroxy compounds which contain s-triazines of the formula

      WHERE: Z represents a single bond, -O-, -S-, -NH- or -NR6-, where R6 denotes hydrogen, n-alkyl radicals with 1 to 30 carbon atoms or their isomers, n-alkenyl radicals with 2 to 30 carbon atoms or their isomers, cycloalkyl radicals with 5 to 12 carbon atoms, alkyl-substituted or alkenyl-substituted cycloalkyl radicals with 5 - 12 ring carbon atoms and 1 to 5 carbon atoms in the sidechain, mononuclear or polynuclear aryl or heteroaryl radicals, such as pyridine, pyprimidine or imidazole radicals, with up to 14 carbon atoms, or aralkyl radicals with a total of up to 30 carbon atoms or the aryl-carbon atom bonded halogen and/or C1-C6alkyl and/or C1-C6-alkoxy and/or nitrosubstituted derivatives of the aryl, heteroaryl or aralkyl radicals; R has the same meaning as R6, and is identical or not identical with R6, and can be linked to R6 via alkylene radicals with 2 to 5 carbon atoms which can be interrupted by hetero-atoms, such as O, S and NR7, that is R + R6 can be alkylene with 2 to 5 carbon atoms which can be interrupted by O,S and NR7, with the proviso that the rings formed by R, Z and R6 are from three- to sixmembered rings; and WHEREIN R7 is an alkyl radical with 1 to 4 carbon atoms, a phenyl radical or an alkylaryl radical with a total of up to 10 carbon atoms, OR R and R6 can be aryl linked via a single bond or O or S, as linkages between the aromatic bis-hydroxy compounds and bonded to the oxygen atoms of the latter.
    • 基于芳族双羟基化合物的聚碳酸酯,其含有下式的s-三嗪: