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    • 53. 发明授权
    • Integrator providing automatic tangential base-line correction
    • 集成商提供自动的基线校正
    • US3818357A
    • 1974-06-18
    • US29954872
    • 1972-10-16
    • HEWLETT PACKARD CO
    • CROCKETT IDAVIDSON I
    • G01N30/86H03M1/00H03K17/00
    • G01N30/8603H03M1/60
    • A system receives output signals from a gas chromatograph and integrates on a real time basis the area under peak curves superimposed on an exponentially decreasing solvent tail. Integration of a peak curve is performed in two parts. First, a constant level baseline correction signal is established at the starting point of the peak, the the curve is integrated with respect to the baseline correction signal during the time interval between the starting point and the crossover point of the peak curve and the baseline correction signal. Secondly, the peak curve is integrated with respect to both the baseline correction signal and a derived peak correction signal during the time interval between the crossover point and an end point of the curve. The sum of the two integrals indicates the area between the peak curve and a sloping baseline which extends from the starting point of the peak curve and is tangent to the exponentially decreasing solvent tail at an end point of the peak curve.
    • 系统接收来自气相色谱仪的输出信号,并在实时基础上积分峰值曲线下叠加在指数减少的溶剂尾部的面积。 峰值曲线的积分分为两部分。 首先,在峰值的起点处建立恒定电平的基准线校正信号,在峰值曲线的起始点和交叉点之间的时间间隔和基线校正期间,相对于基线校正信号将该曲线积分 信号。 其次,在曲线的交叉点和终点之间的时间间隔内,峰值曲线相对于基线校正信号和导出的峰值校正信号被积分。 两个积分的和表示峰值曲线与从峰值曲线的起始点延伸的倾斜基线之间的面积,并且与峰值曲线的终点处的指数下降的溶剂尾部相切。
    • 55. 发明授权
    • Fraction computer for multi-component trace
    • 用于多分量跟踪的分段计算机
    • US3784789A
    • 1974-01-08
    • US3784789D
    • 1972-06-22
    • TRANSIDYNE GEN CORP
    • BROEK J
    • G01N30/86G06F17/00G06J1/00H03M1/00G06K11/02G06F7/48G06F15/20G06G7/12
    • G06J1/00G01N30/8603H03M1/56
    • An electronic system for computing the integrals of various fractions of the time varying electrical output of a scanning densitometer provides that output to a graphic recorder, an analog-to-digital converter and to a slope detector which generates signals representing the boundaries of various fractions of the signal. This detector output is also provided to the recorder to produce a curve representing the amplitude variations of a densitometer signal with marks at the boundaries. The outputs of the analog to digital converter and the slope detector are provided to a shift register. An operator generates correction signals based on an observation of the recorder trace representing desired changes in the boundaries as determined by the slope detector. The densitometer output of the shift register is integrated over time periods controlled by the boundary output of the shift register as manually corrected.
    • 用于计算扫描浓度计的时变电输出的各种分数的积分的电子系统将输出提供给图形记录器,模拟 - 数字转换器和斜率检测器,该斜率检测器产生表示各种分数的边界的信号 信号。 该检测器输出也被提供给记录器以产生表示在边界处具有标记的密度计信号的幅度变化的曲线。 模拟数字转换器和斜率检测器的输出被提供给移位寄存器。 操作者基于由斜率检测器确定的表示边界中期望的变化的记录器轨迹的观察来产生校正信号。 移位寄存器的密度计输出在由手动校正的移位寄存器的边界输出控制的时间段内被积分。
    • 56. 发明授权
    • Signal integrating, storing and analyzing circuit
    • 信号集成,存储和分析电路
    • US3732411A
    • 1973-05-08
    • US3732411D
    • 1971-06-17
    • WILSON CERTIFIED FOODS INC
    • GALEENER C
    • G01N30/86G06G7/186G06G7/18G01N31/08
    • G01N30/8603G06G7/1865
    • A circuit for integrating, storing and analyzing a signal having a plurality of peaks, such as the output of a gas chromatographic detector, in which each of a plurality of storage capacitors is successively connected to an integrator for storing each signal peak integrated. The signals being integrated may be compensated in order that the stored integrals are all on the same basis, e.g., weight percent. After storage of all of the integrals, the total integral and each of the individual integrals may be read out through a buffer which operates to inhibit discharge of the storage capacitors during readout. A voltage control circuit applies a signal to the input of the buffer approximately equal to the value of the total integral to inhibit transients during readout. The values of the stored integrals may be read out in absolute or relative units, for example, each individual integral may be read out as a percentage of the value of the total integral.
    • 用于积分,存储和分析具有多个峰值的信号的电路,例如气相色谱检测器的输出,其中多个存储电容器中的每一个依次连接到积分器,用于存储每个信号峰值的积分。 整合的信号可以被补偿,以便存储的积分全部在相同的基础上,例如重量百分比。 在存储所有积分之后,可以通过缓冲器读出总积分和每个单个积分,该缓冲器用于在读出期间抑制存储电容器的放电。 电压控制电路将信号施加到缓冲器的输入端,大约等于总积分值,以在读出期间抑制瞬变。 存储的积分的值可以以绝对或相对单位读出,例如,每个单独积分可以作为总积分值的百分比读出。
    • 57. 发明授权
    • Method and apparatus for analysis of fluid mixtures
    • 流体混合物分析方法与装置
    • US3607073A
    • 1971-09-21
    • US3607073D
    • 1968-07-22
    • TEXACO INC
    • STAMM RALPH E
    • G01N30/86G01N31/00G01N33/28G01N31/08G01N31/10
    • G01N33/2835G01N30/8603G01N31/00G01N2030/8886Y10T436/212
    • A method and apparatus for continually monitoring a component of a fluid mixture, such as the naphthene content of a hydrocarbon mixture. The apparatus includes a microreactor for subjecting the fluid mixture to a chemical reaction converting, at least in part, a fluid component of the mixture so as to render the fluid component of interest separable from the mixture, and detection means for detecting the fluid component of interest. In a further embodiment a unique computer is provided coupled with the detector for computing the concentration of the fluid component of interest in the fluid mixture. The method of the invention includes reacting the fluid mixture in the aforementioned chemical reaction, and detecting the fluid component of interest. In another version of the method in which the reaction affects more than one component of the mixture converting the affected components to still another component of the mixture, the method includes the further steps of detecting said other component in an unreacted sample of the fluid mixture and generating a signal representative of the concentration in the mixture of the fluid component of interest in accordance with a predetermined relationship between the detected components of the unreacted sample, the reacted sample, and the concentration of the fluid component of interest in the fluid mixture.