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51. 发明申请

US20130261337A1 HYDROCARBOXYLATION OF METHYLENE DIPROPIONATE IN THE PRESENCE OF PROPIONIC ACID AND A HETEROGENEOUS CATALYST 有权
标题翻译：在丙酸和异构催化剂存在下亚甲基二苯甲酸酯的甲基化
公开(公告)号：US20130261337A1
公开(公告)日：2013-10-03
申请号：US13431386
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/347
CPC分类号： C07C51/09 , C07C67/00 , C07C67/36 , C07C59/06 , C07C53/122 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a solid acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the propionic acid stream is readily removed from the glycolic acid and the propionic acid is recycled.
摘要翻译：公开了一种在固体酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。本发明公开了加氢羧化和相应的乙醇酸分离，其中丙酸流容易从乙醇酸中除去，丙酸被再循环。

52. 发明申请

US20130261328A1 HYDROCARBOXYLATION OF FORMALDEHYDE IN THE PRESENCE OF A HIGHER ORDER CARBOXYLIC ACID AND A HOMOGENEOUS CATALYST 有权
标题翻译：甲醛在较高级羧酸和均相催化剂存在下的氢化反应
公开(公告)号：US20130261328A1
公开(公告)日：2013-10-03
申请号：US13431369
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Andrew James Vetter
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Andrew James Vetter
IPC分类号： C07C67/36 , C07C29/149 , C07C51/12
CPC分类号： C07C67/58 , C07C51/09 , C07C51/493 , C07C67/00 , C07C67/36 , C07C59/06 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a homogeneous acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the carboxylic acid is readily removed from the glycolic acid and the carboxylic acid is recycled.
摘要翻译：公开了一种在均相酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。均匀的酸催化剂容易从加氢羧化反应流出物中分离并再循环，羧酸容易从乙醇酸中除去，羧酸被再循环。

53. 发明授权

US08536367B2 Vinyl ester production from acetylene and carboxylic acid utilizing homogeneous catalyst 有权
标题翻译：使用均相催化剂由乙炔和羧酸生产乙烯基酯
公开(公告)号：US08536367B2
公开(公告)日：2013-09-17
申请号：US13454376
申请日：2012-04-24
申请人： Barbara F. M. Kimmich , Hannah E. Toomey , Qiang Yao , G. Paull Torrence , Jan Cornelis van der Waal , Michael J. Doyle
发明人： Barbara F. M. Kimmich , Hannah E. Toomey , Qiang Yao , G. Paull Torrence , Jan Cornelis van der Waal , Michael J. Doyle
IPC分类号： C07C69/00
CPC分类号： C07C67/04 , C07C69/78 , C07C69/24
摘要： A process for the selective production of vinyl ester by the reaction of a carboxylic acid with acetylene with a homogeneous catalyst is disclosed and claimed. In one aspect, esters of neoacids are provided.
摘要翻译：公开并要求保护通过羧酸与乙炔与均相催化剂反应选择性生产乙烯基酯的方法。在一个方面，提供新酸的酯。

54. 发明授权

US08530684B2 Method for preparing fatty acid alkyl ester using fatty acid 有权
标题翻译：使用脂肪酸制备脂肪酸烷基酯的方法
公开(公告)号：US08530684B2
公开(公告)日：2013-09-10
申请号：US12934923
申请日：2008-04-01
申请人： Hyun-Jun Cho , Byung-Hui Kim , Soo-Hyun Kim , Yong-Jun Shin , Shin-ho Chun
发明人： Hyun-Jun Cho , Byung-Hui Kim , Soo-Hyun Kim , Yong-Jun Shin , Shin-ho Chun
IPC分类号： C11B3/00
CPC分类号： C11C3/003 , C07C67/08 , C10G2300/1011 , Y02E50/13 , Y02P30/20 , C07C69/24 , C07C69/52
摘要： A method for preparing fatty acid alkyl ester for bio-diesels is disclosed, wherein fatty acid, specifically fatty acid distillate reacts with alcohol in the presence of metal catalyst instead of conventional acid or solid acid catalyst. The method does not require the glycerin purification process, and has the superior conversion ratio of fatty acid. The method for preparing fatty acid alkyl ester comprises the step of carrying out an esterification reaction of fatty acid raw material with alcohol in the presence of metal catalyst. Preferably, the esterification reaction is carried out at the temperature of 200 to 350° C. and the pressure of atmospheric pressure to 10 bar, and the metal catalyst is a compound containing metal selected from the group consisting of cobalt, iron, manganese, zinc, titanium and mixture thereof.
摘要翻译：公开了一种制备用于生物柴油的脂肪酸烷基酯的方法，其中脂肪酸特别是脂肪酸馏出物在金属催化剂的存在下代替常规的酸或固体酸催化剂与醇反应。该方法不需要甘油纯化方法，具有优异的脂肪酸转化率。制备脂肪酸烷基酯的方法包括在金属催化剂存在下，进行脂肪酸原料与醇的酯化反应的步骤。优选地，酯化反应在200-350℃的温度和大气压至10巴的温度下进行，金属催化剂是选自钴，铁，锰，锌的金属的化合物，钛及其混合物。

55. 发明申请

US20130231504A1 METHOD FOR PRODUCING BIORESOURCED PROPIONIC ACID FROM GLYCEROL 有权
标题翻译：从甘油生产生物活性酸的方法
公开(公告)号：US20130231504A1
公开(公告)日：2013-09-05
申请号：US13861683
申请日：2013-04-12
申请人： ARKEMA FRANCE
发明人： Jean-Luc DUBOIS
IPC分类号： C07C53/122
CPC分类号： C07C53/122 , C07C45/52 , C07C51/235 , C07C51/377 , C07C67/055 , Y02E50/17 , C07C47/22 , C07C57/04 , C07C69/01 , C07C69/24
摘要： A method for producing bioresourced propionic acid from glycerol. Also, a composition comprising more than 85 mass % of bioresourced propionic acid, and to the use of the propionic acid obtained from the method as a solvent, as a food preservative, for producing herbicide or for preparing vinyl propionate.
摘要翻译：从甘油生产生物来源的丙酸的方法。另外，含有85质量％以上生物活性丙酸的组合物，以及使用由该方法得到的丙酸作为溶剂作为食品防腐剂，用于制备除草剂或用于制备丙酸乙烯酯。

56. 发明授权

US08497400B2 Homogeneous asymmetric hydrogenation process 有权
公开(公告)号：US08497400B2
公开(公告)日：2013-07-30
申请号：US12703079
申请日：2010-02-09
申请人： Hideo Shimizu , Daisuke Igarashi , Wataru Kuriyama , Yukinori Yusa
发明人： Hideo Shimizu , Daisuke Igarashi , Wataru Kuriyama , Yukinori Yusa
IPC分类号： C07C29/14 , C07C27/04 , B01J31/00
CPC分类号： C07C29/145 , B01J31/2409 , B01J31/2452 , B01J31/2457 , B01J2231/643 , B01J2531/0266 , B01J2531/16 , C07B35/02 , C07B53/00 , C07B2200/07 , C07C29/175 , C07C41/26 , C07C45/62 , C07C67/303 , C07C231/12 , C07C2601/14 , C07C2601/16 , C07D209/08 , C07D307/46 , C07F9/5045 , C07F9/65517 , C07C49/403 , C07C69/612 , C07C69/24 , C07C233/47 , C07C43/196 , C07C31/125 , C07C33/18 , C07C33/22 , C07C35/08 , C07C35/18
摘要： Provide that a useful catalyst for homogeneous hydrogenation, particularly a catalyst for homogeneous asymmetric hydrogenation for hydrogenation, particularly asymmetric hydrogenation, which is obtainable with comparative ease and is excellent in economically and workability, and a process for producing a hydrogenated compound of an unsaturated compound, particularly an optically active compound using said catalyst with a high yield and optical purity.

57. 发明申请

US20130150611A1 PROCESS FOR PRODUCING CARBOXYLIC ACID ESTER 审中-公开
标题翻译：生产羧酸酯的方法
公开(公告)号：US20130150611A1
公开(公告)日：2013-06-13
申请号：US13817352
申请日：2011-08-25
申请人： Koji Hagiya
发明人： Koji Hagiya
IPC分类号： C07C67/44
CPC分类号： C07C67/44 , C07C67/39 , C07C319/20 , C07C323/52 , C07C69/716 , C07C69/738 , C07C69/24 , C07C69/78
摘要： The present invention relates to a process for producing a carboxylic acid ester, comprising a step of oxidizing an aldehyde by mixing an alcohol, carbon dioxide, the aldehyde and at least one compound selected from the group consisting of compounds represented by the formulae (2-1) and (2-2): wherein R2 represents an alkyl group optionally having a substituent or the like; R3 and R4 each independently represents an alkyl group optionally having a substituent or the like or R3 and R4 are linked together to form a divalent hydrocarbon group optionally having a substituent or the like; Y represents a group of —S— or a group of —N(R5)—, wherein R5 represents an alkyl group optionally having a substituent or the like, or R5 is linked to R4 to form a divalent hydrocarbon group optionally having a substituent; and R8 represents an alkyl group.
摘要翻译：本发明涉及一种制备羧酸酯的方法，其包括通过将醇，二氧化碳，醛和至少一种选自由式（2- 1）和（2-2）：其中R 2表示任选具有取代基的烷基等; R3和R4各自独立地表示任选具有取代基等的烷基或R3和R4连接在一起形成任选具有取代基等的二价烃基; Y表示-S-或-N（R5） - 基的基团，其中R5表示任选具有取代基的烷基等，或R5与R4连接形成任选具有取代基的二价烃基; 并且R 8表示烷基。

58. 发明授权

US08415495B2 Process for continuous production of organic carbonates or organic carbamates and solid catalysts therefore 有权
标题翻译：因此，连续生产有机碳酸酯或有机氨基甲酸酯和固体催化剂的方法
公开(公告)号：US08415495B2
公开(公告)日：2013-04-09
申请号：US12914290
申请日：2010-10-28
申请人： J. Yong Ryu
发明人： J. Yong Ryu
IPC分类号： C07C69/96
CPC分类号： C07C68/06 , B01J21/08 , B01J31/04 , B01J31/38 , B01J37/0203 , B01J37/0209 , B01J37/06 , B01J38/485 , B01J38/56 , B01J2531/46 , C07C67/03 , C07C68/00 , C07C68/065 , Y02E50/13 , Y02P20/584 , C07C69/52 , C07C69/24 , C07C69/96
摘要： Processes for the alcoholysis, inclusive of transesterification and/or disproportionation, of reactants are disclosed. The alcoholysis process may include feeding reactants and a trace amount of soluble organometallic compound to a reactor comprising a solid alcoholysis catalyst, wherein the soluble organometallic compound and the solid alcoholysis catalyst each independently comprise a Group II to Group VI element, which may be the same element in various embodiments. As an example, diphenyl carbonate may be continuously produced by performing transesterification over a solid catalyst followed by disproportionation, where a trace amount of soluble organometallic compound is fed to the transesterification reactor. Also disclosed is a process for reactivating a spent solid alcoholysis catalyst, such as a catalyst useful for transesterifications and/or disproportionations, the process including removing polymeric materials deposited on the catalyst and re-depositing catalytically active metals on the solid catalyst.
摘要翻译：公开了醇解的方法，包括酯交换和/或歧化反应。醇解方法可以包括将反应物和微量的可溶性有机金属化合物加入到包含固体醇解催化剂的反应器中，其中可溶性有机金属化合物和固体醇解催化剂各自独立地包含第II至第VI族元素，其可以相同元件。作为实例，可以通过在固体催化剂上进行酯交换，然后进行歧化，连续生产碳酸二苯酯，其中将微量的可溶性有机金属化合物加入到酯交换反应器中。还公开了一种用于再利用废固体醇解催化剂的方法，例如可用于酯交换和/或歧化的催化剂，该方法包括除去沉积在催化剂上的聚合物材料，并将催化活性金属重新沉积在固体催化剂上。

59. 发明申请

US20130035317A1 Di-Aspirin Derivatives 有权
标题翻译：二阿司匹林衍生物
公开(公告)号：US20130035317A1
公开(公告)日：2013-02-07
申请号：US13578934
申请日：2011-02-15
申请人： Christopher John Perry , Iain Douglas Nicholl
发明人： Christopher John Perry , Iain Douglas Nicholl
IPC分类号： C07C69/035 , C07C69/24 , C07C69/40 , C07C69/44 , C07C69/50 , C07C69/773 , C07C69/60 , C07C69/78 , C07C235/60 , C07C235/88 , A61K31/609 , C07C69/63 , C07C203/04 , C07C69/96 , C07C205/57 , C07C69/90 , A61P35/00 , A61K31/616
CPC分类号： A61K31/60 , A61K31/609 , A61K31/616 , A61K31/621 , C07C69/24 , C07C69/40 , C07C69/44 , C07C69/60 , C07C69/63 , C07C69/76 , C07C69/78 , C07C69/82 , C07C69/96 , C07C205/43 , C07C235/60 , C07C235/88
摘要： The invention relates to the use of di-aspirin (bis(2-carboxyphenyl)succinate) and its derivatives in the treatment of colon and colorectal cancer. It also relates to novel derivatives of di-aspirin and to a method of synthesis of the di-aspirin and its derivatives.
摘要翻译：本发明涉及二阿司匹林（琥珀酸双（2-羧基苯基）酯）及其衍生物在结肠癌和结肠直肠癌的治疗中的应用。它还涉及二阿司匹林的新衍生物和二阿司匹林及其衍生物的合成方法。

60. 发明申请

US20120309613A1 CARBONYLATION PROCESS 审中-公开
标题翻译：碳化过程
公开(公告)号：US20120309613A1
公开(公告)日：2012-12-06
申请号：US13516176
申请日：2009-12-15
申请人： Graham Ronald Eastham , Philip Ian Richards
发明人： Graham Ronald Eastham , Philip Ian Richards
IPC分类号： B01J31/24
CPC分类号： B01J31/24 , B01J2231/321 , B01J2531/80 , B01J2531/82 , B01J2531/824 , C07C45/50 , C07C67/38 , C07C47/02 , C07C69/24
摘要： A method of increasing the TON of a catalyst system for the monocarbonylation of ethylenically unsaturated compounds using carbon monoxide in the presence of a co-reactant, other than water or a source thereof, having a mobile hydrogen atom is described. The catalyst system is obtainable by combining: (a) a metal of Group (8, 9) or (10) or a suitable compound thereof; (b) a ligand of general formula (I) wherein the groups X3 and X4 independently represent univalent radicals of up to 30 atoms or X3 and X4 together form a bivalent radical of up to 40 atoms and X5 has up to 400 atoms; Q1 represents phosphorus, arsenic or antimony; and c) optionally, a source of anions. The method includes the step of adding water or a source thereof to the catalyst system. The method is preferably carried out in the presence of an electropositive metal.
摘要翻译：描述了在具有可移动氢原子的非水或其来源的共反应物存在下，使用一氧化碳增加烯属不饱和化合物的单羰基化催化剂体系的TON的方法。催化剂体系可以通过以下方法获得：（a）组（8,9）或（10）的金属或其合适的化合物; （b）通式（I）的配体，其中基团X3和X4独立地表示至多30个原子的一价基团，或者X 3和X 4一起形成至多40个原子的二价基团，X 5具有多达400个原子; Q1代表磷，砷或锑; 和c）任选的阴离子源。该方法包括将水或其源添加到催化剂体系中的步骤。该方法优选在正电性金属存在下进行。

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