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51. 发明授权

US07371909B2 Method for producing 1-olefins using palladium carbene compounds 失效
标题翻译：使用钯卡宾化合物制备1-烯烃的方法
公开(公告)号：US07371909B2
公开(公告)日：2008-05-13
申请号：US10490038
申请日：2002-10-01
申请人： Matthias Beller , Ralf Jackstell , Holger Klein , Dirk Roettger , Klaus-Diether Wiese , Dietrich Maschmeyer , Axel Tuchlenski , Alfred Kaizik , Silvia Santiago Fernandez
发明人： Matthias Beller , Ralf Jackstell , Holger Klein , Dirk Roettger , Klaus-Diether Wiese , Dietrich Maschmeyer , Axel Tuchlenski , Alfred Kaizik , Silvia Santiago Fernandez
IPC分类号： C07C4/02
CPC分类号： C07C11/02
摘要： The invention relates to a process 1-olefins by telomerization of compounds having conjugated double bonds with a telogen in the presence of a noble metal telomerization catalyst, hydrogenation of the telomer and cleavage of the hydrogenated intermediate. Use of the 1-olefin as comonomer.
摘要翻译：本发明涉及一种通过在贵金属调聚催化剂存在下将具有共轭双键的化合物与停用前体进行调聚，调聚物氢化和氢化中间体切割的方法。使用1-烯烃作为共聚单体。

52. 发明授权

US07368621B2 Method for producing 1-octene from crack-C4 失效
标题翻译：裂解C4生产1-辛烯的方法
公开(公告)号：US07368621B2
公开(公告)日：2008-05-06
申请号：US10562454
申请日：2004-05-06
申请人： Joerg Krissmann , Dirk Roettger , Cornelia Borgmann , Kerstin Kaemper , Franz Nierlich , Alfred Kaizik , Udo Knippenberg , Rainer Malzkorn
发明人： Joerg Krissmann , Dirk Roettger , Cornelia Borgmann , Kerstin Kaemper , Franz Nierlich , Alfred Kaizik , Udo Knippenberg , Rainer Malzkorn
IPC分类号： C07C1/207
CPC分类号： C07C1/20 , C07C7/04 , C07C11/02
摘要： The invention relates to a process for preparing 1-octene from a C4 fraction from a cracker by telomerization of the 1,3-butadiene present in the C4 fraction from a cracker by means of methanol in the presence of a catalyst, hydrogenation of the telomer obtained in this way, dissociation of the hydrogenated telomer and work-up of the resulting dissociation product to give pure 1-octene.
摘要翻译：本发明涉及一种从裂解装置从C 4 S 4馏分中制备1-辛烯的方法，该方法是将C 4 H 4 N分馏中存在的1,3-丁二烯从在催化剂存在下通过甲醇裂解，以此方式获得的调聚物的氢化，氢化调聚物的解离和所得到的解离产物的后处理，得到纯的1-辛烯。

53. 发明申请

US20070027346A1 Process for the hydrogenation of oxo aldehydes having high ester contents 失效
标题翻译：氢化具有高酯含量的氧代醛的方法
公开(公告)号：US20070027346A1
公开(公告)日：2007-02-01
申请号：US11494741
申请日：2006-07-28
申请人： Alfred Kaizik , Hans-Gerd Luken , Michael Grass , Dietrich Maschmeyer , Wilfried Buschken
发明人： Alfred Kaizik , Hans-Gerd Luken , Michael Grass , Dietrich Maschmeyer , Wilfried Buschken
IPC分类号： C07C29/14 , B01J23/44
CPC分类号： C07C29/141 , B01J21/04 , B01J23/75 , B01J23/755 , B01J33/00 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J37/0201 , B01J37/0205 , B01J37/18 , C07C29/149 , Y02P20/582 , C07C31/125
摘要： A hydrogenation catalyst is used for the catalytic hydrogenation of an ester-containing aldehyde mixture and the catalyst contains a γ-alumina having a BET surface area of from 70 to 350 m2/g as support material, and at least one component having hydrogenation activity and being selected from the group consisting of nickel, cobalt and mixtures thereof.
摘要翻译：氢化催化剂用于含酯的醛混合物的催化氢化，催化剂含有作为载体材料的BET表面积为70-350m 2 / g的γ-氧化铝，以及至少一种具有氢化活性的组分，并且选自镍，钴及其混合物。

54. 发明申请

US20060281959A1 Method for producing 1-octene from crack-c4 失效
标题翻译：裂纹c4生产1-辛烯的方法
公开(公告)号：US20060281959A1
公开(公告)日：2006-12-14
申请号：US10562454
申请日：2004-05-06
申请人： Jorg Krissmann , Dirk Rottger , Cornella Borgmann , Kerstin Kamper , Franz Nierlich , Alfred Kaizik , Udo Knippenberg , Rainer Malzkorn
发明人： Jorg Krissmann , Dirk Rottger , Cornella Borgmann , Kerstin Kamper , Franz Nierlich , Alfred Kaizik , Udo Knippenberg , Rainer Malzkorn
IPC分类号： C07C2/04
CPC分类号： C07C1/20 , C07C7/04 , C07C11/02
摘要： The invention relates to a process for preparing 1-octene from a C4 fraction from a cracker by telomerization of the 1,3-butadiene present in the C4 fraction from a cracker by means of methanol in the presence of a catalyst, hydrogenation of the telomer obtained in this way, dissociation of the hydrogenated telomer and work-up of the resulting dissociation product to give pure 1-octene.
摘要翻译：本发明涉及一种从裂解装置从C 4 S 4馏分中制备1-辛烯的方法，该方法是将C 4 H 4 N分馏中存在的1,3-丁二烯从在催化剂存在下通过甲醇裂解，以此方式获得的调聚物的氢化，氢化调聚物的解离和所得到的解离产物的后处理，得到纯的1-辛烯。

55. 发明授权

US09353040B2 Method and device for the hydroformylation of isobutene and for the separation of the product mixture 有权
标题翻译：用于异丁烯加氢甲酰化和分离产物混合物的方法和装置
公开(公告)号：US09353040B2
公开(公告)日：2016-05-31
申请号：US14380647
申请日：2013-02-11
申请人： Goetz Baumgarten , Michael Graβ , Alfred Kaizik , Markus Winterberg , Hans-Gerd Lueken , Bart Hamers , Markus Priske , Dirk Fridag , Robert Franke , Dieter Hess
发明人： Goetz Baumgarten , Michael Graβ , Alfred Kaizik , Markus Winterberg , Hans-Gerd Lueken , Bart Hamers , Markus Priske , Dirk Fridag , Robert Franke , Dieter Hess
IPC分类号： C07C51/43 , C07C45/78 , C07C45/50 , C07C51/235 , B01D61/02 , C07C45/82
CPC分类号： C07C51/43 , B01D61/027 , C07C45/50 , C07C45/505 , C07C45/786 , C07C45/82 , C07C51/235 , C07C47/02
摘要： The invention relates to a method for producing a product mixture (2) by means of the technical hydroformylation of a hydrocarbon stream (1) that contains isobutene, and for separating the product mixture (2) that is obtained, as well as to a device for the claimed method and to the use of a claimed device. The problem addressed thereby is that of providing a method and an associated device that allow the amount of high-boiling substances in the product mixture (2) to be kept as low as possible and thus the yield of the reaction to be increased. The problem is solved by the use of a nano-filtration device (M) for separating the catalyst from the product mixture (2), said device having especially high permeability to 3-methylbutanoic acid.
摘要翻译：本发明涉及一种通过含有异丁烯的烃流（1）的技术加氢甲酰化以及用于分离获得的产物混合物（2）以及制备产物混合物（2）的方法，用于所要求保护的方法和所要求保护的装置的使用。由此提出的问题是提供一种方法和相关联的装置，其允许将产物混合物（2）中的高沸点物质的量保持尽可能低，从而提高反应的产率。通过使用纳米过滤装置（M）从产物混合物（2）中分离催化剂来解决该问题，所述装置对3-甲基丁酸具有特别高的渗透性。

56. 发明申请

US20120253083A1 METHOD FOR PRODUCING DECANOLS BY MEANS OF HYDROGENATING DECENALS 有权
标题翻译：通过氢化方法生产癸醇的方法
公开(公告)号：US20120253083A1
公开(公告)日：2012-10-04
申请号：US13502226
申请日：2010-08-13
申请人： Alfred Kaizik , Hans-Gerd Lueken
发明人： Alfred Kaizik , Hans-Gerd Lueken
IPC分类号： C07C29/141
CPC分类号： C07C29/175 , Y02P20/582 , C07C31/125
摘要： The present invention relates to a method for producing at least one decanol by means of hydrogenating at least one decenal, wherein a first hydrogenation is carried out in the liquid phase on a solid first catalyst, wherein the first catalyst contains copper and nickel. The aim of the invention is to provide a method of the type mentioned above, according to which decenals can be hydrogenated into decanols in high yields even after long operating periods. The content of non-reacted decenals in the hydrogenation discharge in particular should be less than 1500 ppm. Said aim is achieved by carrying out the hydrogenation in two steps, which is to say in a first step in a known manner using a catalyst comprising copper, nickel and optionally chromium and/or barium oxide, and subsequently in a second step using a different catalyst that must be free of copper, chromium and nickel.
摘要翻译：本发明涉及通过氢化至少一种癸醛来制备至少一种癸醇的方法，其中第一次氢化在液相中在固体第一催化剂上进行，其中第一催化剂含有铜和镍。本发明的目的是提供一种上述类型的方法，根据该方法，即使在长的操作期后，癸烯也可以高收率氢化成癸醇。氢化放电中未反应的癸醛的含量特别应小于1500ppm。所述目的通过在两步中进行氢化来实现，即在第一步中以已知方式使用包含铜，镍和任选的铬和/或氧化钡的催化剂，然后在第二步中使用不同的必须不含铜，铬和镍的催化剂。

57. 发明申请

US20060183936A1 Catalyst and method for hydrogenating aromatic compounds 有权
标题翻译：用于氢化芳族化合物的催化剂和方法
公开(公告)号：US20060183936A1
公开(公告)日：2006-08-17
申请号：US10511595
申请日：2003-04-26
申请人： Michael Grass , Alfred Kaizik , Wilfried Buschken , Axel Tuchlenski , Dietrich Maschmeyer , Kurt-Alfred Gaudschun , Frank Brocksien
发明人： Michael Grass , Alfred Kaizik , Wilfried Buschken , Axel Tuchlenski , Dietrich Maschmeyer , Kurt-Alfred Gaudschun , Frank Brocksien
IPC分类号： C07C69/74 , C08F4/02 , C07C209/72
CPC分类号： B01J35/10 , B01J23/40 , B01J23/462 , B01J23/74 , B01J35/1014 , B01J35/1061 , B01J35/108 , C07C67/303 , C07C69/75
摘要： The invention relates to the hydrogenation of aromatic compounds, in particular the preparation of alicyclic polycarboxylic acids or esters of these, via ring hydrogenation of the corresponding aromatic polycarboxylic acids or esters of these, and also to catalysts suitable for this purpose.
摘要翻译：本发明涉及芳族化合物的氢化，特别是通过相应的芳族多元羧酸或它们的酯的环加氢制备脂环族多元羧酸或它们的酯，以及适用于该目的的催化剂。

58. 发明申请

US20060041167A1 Microporous catalyst and method for hydrogenating aromatic compounds 审中-公开
标题翻译：微孔催化剂和芳烃化合物的加氢方法
公开(公告)号：US20060041167A1
公开(公告)日：2006-02-23
申请号：US10519413
申请日：2003-06-07
申请人： Michael Grass , Alfred Kaizik , Wilfried Buschken , Axel Tuchlenski , Dietrich Maschmeyer , Kurt-Alfred Gaudschun , Frank Brocksien
发明人： Michael Grass , Alfred Kaizik , Wilfried Buschken , Axel Tuchlenski , Dietrich Maschmeyer , Kurt-Alfred Gaudschun , Frank Brocksien
IPC分类号： C07C61/24
CPC分类号： B01J21/063 , B01J23/40 , B01J23/462 , B01J35/10 , B01J35/1061 , B01J35/108 , B01J37/0018 , C07C51/36 , C07C67/303 , C07C2601/14 , Y02P20/582 , C07C61/135 , C07C69/75
摘要： The invention relates to the hydrogenation of aromatic compounds, in particular the preparation of alicyclic polycarboxylic acids or their esters by core hydrogenation of the corresponding aromatic polycarboxylic acids or their esters, and also to catalysts suitable therefor.
摘要翻译：本发明涉及芳族化合物的氢化，特别是通过相应的芳族多羧酸或其酯的核心氢化制备脂环族多元羧酸或其酯，以及适用于其的催化剂。

59. 发明申请

US20050182277A1 Method for the rhodium-catalyzed hydroformylation of olefins with reduction of rhodium losses 有权
标题翻译：用铑催化的烯烃加氢甲酰化还原铑损失的方法
公开(公告)号：US20050182277A1
公开(公告)日：2005-08-18
申请号：US10511280
申请日：2002-12-05
申请人： Walter Totsch , Alfred Kaizik , Hermann-Josef Schulte-Althoff
发明人： Walter Totsch , Alfred Kaizik , Hermann-Josef Schulte-Althoff
IPC分类号： C07B61/00 , C07C29/16 , C07C45/50 , C07C47/02 , C07C45/49
CPC分类号： C07C29/16 , C07C45/50 , C07C31/125 , C07C47/02
摘要： Process for preparing aldehydes and alcohols by rhodium-catalyzed hydroformylation of olefins having 6-20 carbon atoms with subsequent separation by distillation of the output from the hydroformylation reaction into the hydroformylation products and a rhodium-containing solution and recirculation of this solution to the hydroformylation reaction, wherein the rhodium concentration of the recirculated rhodium-containing solution is 20-150 ppm by mass.
摘要翻译：通过铑催化的具有6-20个碳原子的烯烃的加氢甲酰化制备醛和醇的方法，随后通过蒸馏将加氢甲酰化反应的产物蒸馏成加氢甲酰化产物和含铑溶液并将该溶液再循环到加氢甲酰化反应其中，再循环的含铑溶液的铑浓度为20〜150质量ppm。

60. 发明申请

US20050101800A1 Method for the production of alicyclic polycarboxylic acid esters from partial esters aromatic polycarboxylic acids 失效
标题翻译：从偏酯芳族多元羧酸生产脂环族多元羧酸酯的方法
公开(公告)号：US20050101800A1
公开(公告)日：2005-05-12
申请号：US10474044
申请日：2002-09-14
申请人： Wilfried Büschken , Michael Grass , Alfred Kaizik , Dietrich Maschmeyer , Franz Nierlich , Axel Tuchlenski
发明人： Wilfried Büschken , Michael Grass , Alfred Kaizik , Dietrich Maschmeyer , Franz Nierlich , Axel Tuchlenski
IPC分类号： C07B61/00 , C07C67/08 , C07C67/303 , C07C69/75 , C07C69/74
CPC分类号： C07C67/08 , C07C67/303 , C07C69/75
摘要： The invention relates to a process for preparing full esters of alicyclic polycarboxylic acids from partial esters of aromatic polycarboxylic acids by hydrogenation of the partial ester followed by esterification of this compound.
摘要翻译：本发明涉及通过部分酯的氢化，然后酯化该化合物，由芳族多元羧酸的偏酯制备脂环族多元羧酸的全酯的方法。

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