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    • 53. 发明授权
    • Polycarbonate composition resistant to gamma radiation
    • 耐γ辐射的聚碳酸酯组合物
    • US06197854B1
    • 2001-03-06
    • US09541570
    • 2000-04-03
    • Sivaram KrishnanWolfgang Ebert
    • Sivaram KrishnanWolfgang Ebert
    • C08K545
    • C08K5/15C08K5/46C08L69/00
    • A thermoplastic polycarbonate molding composition having improved resistance to gamma radiation-induced yellowing is disclosed. Particularly suitable for the manufacture of devices targeted for medical applications, the composition contains additive amounts of a first stabilizing compound conforming structurally to wherein in the embodiment where n is 1, R1 is an unsubstituted or substituted carbocyclic or heterocyclic aromatic ring system, and where in the embodiment where n is 2, R1 is unsubstituted or C1-4-alkyl or hydroxy substituted phenylene or naphthylene, and R2, R3, R4 and R5 independently of one another are hydrogen, C1-25-alkyl groups or phenyl. and a saccharine compound.
    • 公开了具有改进的抗γ辐射诱导黄变性的热塑性聚碳酸酯模塑组合物。 该组合物特别适用于制造医疗用途的装置,该组合物含有添加量的结构上符合结构的第一稳定化合物,其中n为1的实施方案中,R 1为未取代或取代的碳环或杂环芳环体系, 其中n为2,R 1为未取代的或C 1-4 - 烷基或羟基取代的亚苯基或亚萘基,R 2,R 3,R 4和R 5彼此独立地为氢,C 1-5 - 烷基或苯基,以及糖精化合物。
    • 59. 发明授权
    • Foamable molding compositions
    • 可发泡成型组合物
    • US4851453A
    • 1989-07-25
    • US305826
    • 1989-02-02
    • Roger J. WhiteSivaram Krishnan
    • Roger J. WhiteSivaram Krishnan
    • C08J9/10
    • C08J9/104
    • A Chemical Blowing Agent (CBA) concentrate was developed comprising a modifying agent and a chemical blowing agent. The CBA is characterized in that its decomposition products contain a primary amine. The modifying agent is a blend of a maleic anhydride copolymer and a butadiene based rubber. It was surprisingly found that resin degradation which often accompanies foam moldings using a CBA of the present type and is expressed in terms of a reduction in the molecular weight of the resin, is much reduced upon the incorporation of the modifying agent and chemical blowing agent of the invention. The concentrate may optionally further comprise a polymeric resin component.
    • 开发了包含改性剂和化学发泡剂的化学发泡剂(CBA)浓缩物。 CBA的特征在于其分解产物含有伯胺。 改性剂是马来酸酐共聚物和丁二烯基橡胶的共混物。 令人惊奇地发现,通常伴随着使用本发明的CBA的泡沫塑料成型并且根据树脂的分子量的降低表示的树脂降解,在引入改性剂和化学发泡剂 本发明。 浓缩物可以任选地进一步包含聚合树脂组分。