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51. 发明授权

US4256862A Polyaryl-sulphones containing an ammonium or metal salt of an organic sulphonic acid 失效
标题翻译：含有有机磺酸的铵或金属盐的聚芳香砜
公开(公告)号：US4256862A
公开(公告)日：1981-03-17
申请号：US18113
申请日：1979-03-07
申请人： Rudolf Binsack , Joachim Wank , Eckart Reese
发明人： Rudolf Binsack , Joachim Wank , Eckart Reese
IPC分类号： C08G75/00 , C08K5/42 , C08L81/00 , C08L81/06 , C08F283/00 , C08G75/23
CPC分类号： C08K5/42
摘要： Modified polyaryl-sulphones comprise one or more polyaryl-sulphones and one or more ammonium salts or metal salts of organic sulphonic acids, preferably 0.01 to 5% by weight, relative to the total weight of polyaryl-sulphone plus salt of sulphonic acid, of the one or more organic sulphonic acid salts. These simply produced modified polyaryl-sulphones do not suffer from embrittlement under load, and susceptability to stress-cracking under the influence of solvents and of solutions of unsaturated polyester resins experienced by unmodified polyaryl-sulphones. The modified polyaryl-sulphones are particularly suitable for the production of containers, tubes, sheets and films.
摘要翻译：改性聚芳基砜包括一种或多种聚芳基砜和一种或多种有机磺酸的铵盐或金属盐，相对于聚芳基砜加磺酸盐的总重量，优选为0.01至5重量％一种或多种有机磺酸盐。这些简单生产的改性多芳基砜在负载下不会发生脆化，并且在溶剂和未改性聚芳基砜所经受的不饱和聚酯树脂的溶液的影响下易受应力裂纹的影响。改性聚芳砜特别适用于容器，管，片和薄膜的生产。

52. 发明授权

US4232132A Elastomeric thermoplastic mixtures of polypropylene and ethylene/vinyl acetate copolymers 失效
标题翻译：聚丙烯和乙烯/乙酸乙烯酯共聚物的弹性热塑性混合物
公开(公告)号：US4232132A
公开(公告)日：1980-11-04
申请号：US19788
申请日：1979-03-12
申请人： Ulrich Grigo , Josef Merten , Rudolf Binsack
发明人： Ulrich Grigo , Josef Merten , Rudolf Binsack
IPC分类号： C08L23/00 , C08L23/08 , C08L23/12 , C08L31/04 , C08L101/00
CPC分类号： C08L23/12 , C08L23/0853 , C08L2312/00 , C08L31/04
摘要： An elastomeric thermoplastic mixture comprising (A) from 40 to 95% by weight of polypropylene, and (B) from 5 to 60% by weight of a partially cross-linked ethylene/vinyl acetate copolymer which has a gel content of from 3 to 50% by weight and a vinyl acetate content of from 20 to 80% by weight, the percentages being based on the sum of A+B.
摘要翻译：一种弹性体热塑性混合物，其包含（A）40至95重量％的聚丙烯，和（B）5至60重量％的部分交联的乙烯/乙酸乙烯酯共聚物，其凝胶含量为3至50 重量百分比，乙酸乙烯酯含量为20〜80％（重量），百分比基于A + B的总和。

53. 发明授权

US4207230A Block copolyesters which crystallize rapidly 失效
标题翻译：封闭共聚酯快速结晶
公开(公告)号：US4207230A
公开(公告)日：1980-06-10
申请号：US875047
申请日：1978-02-03
申请人： Peter Bier , Rudolf Binsack
发明人： Peter Bier , Rudolf Binsack
IPC分类号： C08G63/00 , C08G63/18 , C08G63/181 , C08G63/183 , C08G63/66 , C08G63/672 , C08G63/78 , C08G63/91 , C08L67/02 , C08L71/02
CPC分类号： C08G63/672 , C08G63/183 , Y10S260/35
摘要： The current invention is concerned with block copolyesters of low glass transition temperature segments and ethylene glycol based polyester segments linked together by carboxylic acid ester groups and special diols, and a process for preparing these copolyesters. These copolyesters display molded resin properties similar to polyethylene terephthalate but crystallization behavior similar to polybutylene terephthalate, i.e. they have high strength and superior solvent resistance, but they also crystallize rapidly. They are made by subjecting low glass transition temperature (less than 0.degree. C.) polymers with carboxyl, hydroxyl or reactive ester end groups to esterification or transesterification conditions with ethylene glycol based polyester segments having a minimum intrinsic viscosity of 0.2 dl/g and special diols having four to ten carbon atoms with 3 or 4 carbon atoms between the hydroxyl groups in the presence of appropriate catalysts. In a preferred embodiment, the three components are subject to melt homogenization in an extruder and the solidified extrudate is subject to a solid state polycondensation reaction.
摘要翻译：本发明涉及低羧酸酯基和特殊二醇连接在一起的低玻璃化转变温度段和基于乙二醇的聚酯链段的嵌段共聚酯，以及这些共聚酯的制备方法。这些共聚酯显示与聚对苯二甲酸乙二醇酯类似的模塑树脂性能，但结晶行为类似于聚对苯二甲酸丁二醇酯，即它们具有高强度和优异的耐溶剂性，但它们也快速结晶。它们是通过将具有羧基，羟基或活性酯端基的低玻璃化转变温度（低于0℃）的聚合物与具有0.2dl / g的最小特性粘度的乙二醇基聚酯链段进行酯化或酯交换反应而制成的，并且特殊在合适的催化剂存在下，羟基之间具有4至10个碳原子数为3或4个碳原子的二元醇。在优选的实施方案中，三种组分在挤出机中进行熔融均匀化，固化的挤出物进行固态缩聚反应。

54. 发明授权

US4186154A Polycarbonate mixtures which can be processed as thermoplastics 失效
标题翻译：可以加工成热塑性塑料的聚碳酸酯混合物
公开(公告)号：US4186154A
公开(公告)日：1980-01-29
申请号：US916636
申请日：1978-06-19
申请人： Rudolf Binsack , Eckart Reese , Erhard Tresper , Joachim Wank
发明人： Rudolf Binsack , Eckart Reese , Erhard Tresper , Joachim Wank
IPC分类号： C08L69/00 , C08L67/00
CPC分类号： C08L69/00
摘要： The present invention relates to mixtures comprising about 60% by weight to 5% by weight of aromatic polycarbonates which have a Mw between about 60,000 and 120,000 (component A) and about 40% by weight to 95% by weight of aromatic polycarbonates which have a Mw between about 28,000 and 40,000 (component B), as well as to processes for their preparation and their use for the production of shaped articles. The melt which can be prepared from the mixtures according to the invention has a high stability and the films obtainable therefrom have a high resistance towards stress cracking.
摘要翻译：本发明涉及包含约60重量％至5重量％的Mw为约60,000至120,000（组分A）和约40重量％至95重量％的芳族聚碳酸酯的芳族聚碳酸酯的混合物，其具有 Mw约28,000至40,000（组分B），以及其制备方法及其用于生产成型制品的用途。可以由根据本发明的混合物制备的熔体具有高稳定性，并且由其获得的膜对应力开裂具有高的抗性。

55. 发明授权

US4086212A Poly(ethylene/alkylene) terephthalates which crystallize rapidly 失效
标题翻译：聚（乙烯/亚烷基）对苯二甲酸酯快速结晶
公开(公告)号：US4086212A
公开(公告)日：1978-04-25
申请号：US658816
申请日：1976-02-17
申请人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
发明人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
IPC分类号： C08L67/00 , C08G63/00 , C08G63/18 , C08G63/181 , C08G63/183 , C08G63/78 , C08K3/40 , C08L67/02 , C08G63/12
CPC分类号： C08G63/183 , C08G63/78
摘要： Terephthalic copolyesters, the diol component of which mainly consists of ethylene glycol units, crystallize more rapidly than pure polyethylene terephthalate and can be moulded in a way comparable to polybutylene terephthalate.
摘要翻译：对苯二甲酸共聚酯，其二醇组分主要由乙二醇单元组成，比纯聚对苯二甲酸乙二醇酯更快地结晶，并且可以以与聚对苯二甲酸丁二醇酯相当的方式成型。

56. 发明授权

US3931108A Process for preparing polycarbonates 失效
标题翻译：制备聚碳酸酯的方法
公开(公告)号：US3931108A
公开(公告)日：1976-01-06
申请号：US409201
申请日：1973-10-24
申请人： Rudolf Binsack , Heinrich Haupt , Hugo Vernaleken , Eckart Reese
发明人： Rudolf Binsack , Heinrich Haupt , Hugo Vernaleken , Eckart Reese
IPC分类号： C08L69/00 , C08G63/00 , C08G64/00 , C08G64/14 , C08G64/20 , C08G64/22 , C08L67/00 , H01B3/42 , C08G63/62
CPC分类号： C08G64/14 , H01B3/426
摘要： Extruded films having reduced proneness to stress-cracking, good resistance to casting resins of unsaturated polyesters and no blocking effect and produced from branched aromatic polycarbonates which are the reaction products of aromatic dihydroxy compounds and branching agents having more than three phenolic hydroxyl groups, with polycarbonate precursors. The films are useful as insulating films in the electrical industry.

57. 发明授权

US4515918A Thermoplastic moulding compositions based on polycarbonate, polyalkylene terephthalate and, optionally, one or more polymers 失效
标题翻译：基于聚碳酸酯，聚对苯二甲酸亚烷基酯和任选的一种或多种聚合物的热塑性模塑组合物
公开(公告)号：US4515918A
公开(公告)日：1985-05-07
申请号：US602596
申请日：1984-04-20
申请人： Werner Nouvertne , Volker Serini , Dieter Neuray , Rudolf Binsack , Hans-Georg Gehrke , Dieter Rempel , Sivara Krishnai
发明人： Werner Nouvertne , Volker Serini , Dieter Neuray , Rudolf Binsack , Hans-Georg Gehrke , Dieter Rempel , Sivara Krishnai
IPC分类号： C08L51/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/02 , C08L51/04 , C08L67/00 , C08L67/02 , C08L69/00 , C08L77/00 , C08L101/00
CPC分类号： C08L67/02 , C08L69/00
摘要： Moulding compositions of polycarbonate, polyalkylene terephthalate and, optionally, polymer having a glass transition temperature below -20.degree. C. may be processed to form particularly low-distortion mouldings when the polycarbonate consists at least partly of o,o,o',o'-tetramethyl-besphenol-polycarbonate.
摘要翻译：当聚碳酸酯至少部分为o，o，o'，o'时，聚碳酸酯，聚对苯二甲酸亚烷基酯和任选的玻璃化转变温度低于-20℃的聚合物的成型组合物可以加工成特别低的变形模制品，四甲基苯酚聚碳酸酯。

58. 发明授权

US4482672A Thermoplastic moulding compositions of polycarbonate, polyalkylene terephthalate, graft copolymer and polyethylene 失效
标题翻译：聚碳酸酯，聚对苯二甲酸亚烷基酯，接枝共聚物和聚乙烯的热塑性模塑组合物
公开(公告)号：US4482672A
公开(公告)日：1984-11-13
申请号：US487501
申请日：1983-04-22
申请人： Dieter Neuray , Werner Nouvertne , Rudolf Binsack , Dieter Rempel , Peter R. Muller
发明人： Dieter Neuray , Werner Nouvertne , Rudolf Binsack , Dieter Rempel , Peter R. Muller
IPC分类号： C08L51/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/02 , C08L51/04 , C08L67/00 , C08L67/02 , C08L69/00 , C08L101/00
CPC分类号： C08L69/00 , C08L67/02
摘要： Moulding compositions of aromatic polycarbonate, polyalkylene terephthalate and a certain graft copolymer which may be processed into mouldings characterized by high multiaxial impact strength, exhibit an increased Vicat B-temperature if they contain a low amount of an ethylene homo- or copolymer.
摘要翻译：芳族聚碳酸酯，聚对苯二甲酸亚烷基酯和某些接枝共聚物的成型组合物，如果它们含有少量的乙烯均聚物或共聚物，则可加工成具有高多轴冲击强度特征的模制品的维卡特B温度升高。

59. 发明授权

US4446276A Ageing-resistant, processing-stable, high strength mixtures based on thermoplastic polyesters 失效
标题翻译：耐老化，加工稳定，基于热塑性聚酯的高强度混合物
公开(公告)号：US4446276A
公开(公告)日：1984-05-01
申请号：US370788
申请日：1982-04-22
申请人： Rudolf Binsack , Christian Lindner , Dieter Rempel , Karl-Heinz Ott
发明人： Rudolf Binsack , Christian Lindner , Dieter Rempel , Karl-Heinz Ott
IPC分类号： G03F7/09 , C08K7/14 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L67/00 , C08L67/02 , G03C1/93 , G03F7/11 , G03F7/30
CPC分类号： C08L67/02
摘要： A graft polymer is obtained from a completely broken latex of an acrylate rubber which is suspended in water and from copolymerisable monomers, in the absence of a suspending agent, which graft polymer may be distributed in thermoplastic polyesters to form particles having a relatively small average diameter.
摘要翻译：接枝聚合物由完全破碎的丙烯酸酯橡胶胶乳获得，该胶乳悬浮于水和可共聚单体中，在不存在悬浮剂的情况下，该接枝聚合物可以分布在热塑性聚酯中以形成具有相对较小平均直径的颗粒。

60. 发明授权

US4396742A Thermoplastic polyester moulding compositions having improved toughness 失效
标题翻译：具有改善韧性的热塑性聚酯模塑组合物
公开(公告)号：US4396742A
公开(公告)日：1983-08-02
申请号：US310148
申请日：1981-10-09
申请人： Rudolf Binsack , Christian Lindner , Dieter Rempel
发明人： Rudolf Binsack , Christian Lindner , Dieter Rempel
IPC分类号： C08L51/00 , C08L33/00 , C08L33/02 , C08L51/02 , C08L51/06 , C08L67/00 , C08L67/02
CPC分类号： C08L67/02
摘要： Grafted polyacrylates having a specific composition improve the impact strength under multi-axial stress of thermoplastic polyesters.
摘要翻译：具有特定组成的接枝聚丙烯酸酯改善热塑性聚酯的多轴向应力下的冲击强度。

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